Academic literature on the topic 'Homochiral complex'

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Journal articles on the topic "Homochiral complex"

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Liu, Yu-Ling, Jia-Zhen Ge, Zhong-Xia Wang, and Ren-Gen Xiong. "Metal–organic ferroelectric complexes: enantiomer directional induction achieved above-room-temperature homochiral molecular ferroelectrics." Inorganic Chemistry Frontiers 7, no. 1 (2020): 128–33. http://dx.doi.org/10.1039/c9qi01197h.

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Colquhoun, Howard M., C. Timothy Powell, Zhixue Zhu, et al. "Enantiospecific Assembly of a Homochiral, Hexanuclear Palladium Complex." European Journal of Inorganic Chemistry 2009, no. 8 (2009): 999–1002. http://dx.doi.org/10.1002/ejic.200801045.

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Jiao, Luyang, Mengying Du, Yameng Hou, Yuan Ma, and Xianglei Kong. "Homochiral or Heterochiral: A Systematic Study of Threonine Clusters Using a FT ICR Mass Spectrometer." Symmetry 14, no. 1 (2022): 86. http://dx.doi.org/10.3390/sym14010086.

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The strong chiral preferences of some magic clusters of amino acids have attracted continually increasing interests due to their unique structures, properties and possible roles in homochirogenesis. However, how chirality can influence the generation and stability of cluster ions in a wild range of cluster sizes is still unknown for most amino acids. In this study, the preference for threonine clusters to form homochiral and heterochiral complex ions has been investigated by electrospray ionization (ESI) mass spectrometry. Abundant cluster [Thrn+mH]m+ ions (7 ≤ n ≤ 78, 1 ≤ m ≤ 5) have been obs
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Bhattacharyya, Anik, Biswa Nath Ghosh, Santiago Herrero, Kari Rissanen, Reyes Jiménez-Aparicio, and Shouvik Chattopadhyay. "Formation of a novel ferromagnetic end-to-end cyanate bridged homochiral helical copper(ii) Schiff base complex via spontaneous symmetry breaking." Dalton Transactions 44, no. 2 (2015): 493–97. http://dx.doi.org/10.1039/c4dt03166k.

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Rose-Munch, Françoise, Vanessa Gagliardini, Anne Perrotey, et al. "Two-step synthesis of homochiral monoaminals of tricarbonylphthalaldehydechromium complex." Chemical Communications, no. 20 (1999): 2061–62. http://dx.doi.org/10.1039/a906043j.

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Fu, Da-Wei, Yu-Mei Song, Guo-Xi Wang, et al. "Dielectric Anisotropy of a Homochiral Trinuclear Nickel(II) Complex." Journal of the American Chemical Society 129, no. 17 (2007): 5346–47. http://dx.doi.org/10.1021/ja0701816.

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Zhang, Qichun, Xianhui Bu, Zhien Lin, Maurizio Biasini, W. P. Beyermann, and Pingyun Feng. "Metal-Complex-Decorated Homochiral Heterobimetallic Telluride Single-Stranded Helix." Inorganic Chemistry 46, no. 18 (2007): 7262–64. http://dx.doi.org/10.1021/ic701135h.

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Zhang, Jing, Wen Li, Weifeng Bu, Lixin Wu, Ling Ye, and Guangdi Yang. "The homochiral metallosupramolecular column structure of rhenium (I) complex." Inorganica Chimica Acta 358, no. 4 (2005): 964–70. http://dx.doi.org/10.1016/j.ica.2004.11.039.

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Wang, Guo-Xi, Guang-Fan Han, Qiong Ye, et al. "Dielectric anisotropy of a homochiral rare-earth metal complex." Dalton Transactions, no. 19 (2008): 2527. http://dx.doi.org/10.1039/b719580j.

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Roithová, Jana. "Diastereoisomeric proton-bound complexes of 1,5-diaza-cis-decalin in the gas phase." Collection of Czechoslovak Chemical Communications 74, no. 2 (2009): 243–54. http://dx.doi.org/10.1135/cccc2008185.

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Diastereoisomeric proton-bound complexes of 1,5-diaza-cis-decalin (1) with butan-2-amine (2) are studied by means of the DFT calculations and mass spectrometry. The calculations reveal that 2 is bound via proton to only one nitrogen atom of the bicyclic base 1. The homochiral complex is favored by about 4 kJ/mol over the heterochiral complex. For a more loosely bound ion-pair complex [(1H)I(2H)]+ of the protonated bases 1 and 2 with an iodine counterion the energy difference drops to about 2 kJ/mol. Chiral effects in the formation of [(1)H(2)]+ are studied by the collision-induced dissociation
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Dissertations / Theses on the topic "Homochiral complex"

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Dussart, Caitlyn. "Chiral self-recognition study of metallic complexes : towards coordination polymers." Electronic Thesis or Diss., Strasbourg, 2024. http://www.theses.fr/2024STRAE006.

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Les assemblages polymériques métallo-supramoléculaires constituent une nouvelle classe de matériaux apparue au cours des dernières décennies. Ces matériaux présentent un large éventail de propriétés qui dépendent de la nature des métaux et des ligands ditopiques utilisés. La réversibilité des liaisons de coordination offre également un caractère dynamique au système qui peut répondre à un stimulus externe. En introduisant de la chiralité dans ces systèmes moléculaires, nous pouvons étudier la capacité de ces structures moléculaires à s’associer ou à se désolidariser pour former des espèces hom
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Preston, Simon Christopher. "Asymmetric synthesis via iron acyl complexes." Thesis, University of Oxford, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.236153.

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Buffet, Jean-Charles. "Homochiral metal complexes for biodegradable polymer synthesis." Thesis, University of Edinburgh, 2010. http://hdl.handle.net/1842/4618.

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Chapter One introduces the principle of alkoxide and phosphine oxide as ligands for lanthanides and electropositive metals, ligand self-recognition, stereoselective polymerisation of lactide, fixation of CO2 and finally copolymerisation of CO2 and epoxide. Chapter Two shows the synthesis of the proligands rac-HLR (a racemic phosphine oxide-alkoxide, A, where R = tBu, Ph or C6H3-Me-3,5) and explores the resolution into diastereomeric RRR- and SSS-M(LR)3 to afford C3–symmetric M(LR)3 complexes, B (where M = Sc, Lu, Y, In, Bi or La). It also demonstrates that the process is under thermodynamic co
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Book chapters on the topic "Homochiral complex"

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Jin, Mingoo. "Luminescent Mechanochromism of a Chiral Complex: Distinct Crystal Structures and Color Changes of Racemic and Homochiral Gold(I) Isocyanide Complexes with a Binaphthyl Moiety." In Novel Luminescent Crystalline Materials of Gold(I) Complexes with Stimuli-Responsive Properties. Springer Singapore, 2020. http://dx.doi.org/10.1007/978-981-15-4063-9_3.

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Beaulieu, Pierre l., and robert dáziel. "Addition of electrophilic organoselenium reagents to carbon-carbon double bonds." In Organoselenium Chemistry. Oxford University PressOxford, 1999. http://dx.doi.org/10.1093/oso/9780198501411.003.0003.

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Abstract Since the discovery in the late 1950s that species of the type RSeX add stereospecifically to simple alkenes, electrophilic selenium-based reagents have provided the synthetic chemist with an ever-growing arsenal of methods for the construction of complex organic molecules. Comprehensive reviews of the rich chemistry characteristic of electrophilic selenium species have appeared. In this chapter we have concentrated on the practical aspects of this chemistry, limiting ourselves to the generation and use of novel organoselenium electrophiles. Representative examples are provided of app
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