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Dissertations / Theses on the topic 'Homogeneous Binary Liquid Mixtures'

Author: Grafiati

Published: 5 June 2025

Last updated: 15 July 2025

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1

Di, Felice Renzo. "Liquid fluidisation of binary-solid mixtures." Thesis, University College London (University of London), 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.362618.

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2

Parghi, Deven D. "Antiferroelectric liquid crystals : hosts and binary mixtures." Thesis, University of Hull, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.397062.

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3

Bribesh, Fathi. "Free surface films of binary liquid mixtures." Thesis, Loughborough University, 2012. https://dspace.lboro.ac.uk/2134/9810.

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Model-H is used to describe structures found in the phase separation in films of binary liquid mixture that have a surface that is free to deform and also may energetically prefer one of the components. The film rests on a solid smooth substrate that has no preference for any component. On the one hand the study focuses on static aspects by investigating steady states that are characterised by their concentration and film height profiles. A large variety of such states are systematically analysed by numerically constructing bifurcation diagrams in dependence of a number of control parameters.

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4

Sarkar, Sudipta Kumar. "Phase transition in Binary Liquid Crystalline Mixtures." Thesis, University of North Bengal, 2017. http://hdl.handle.net/123456789/2674.

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5

Bartle, Elizabeth Anne. "The polymorphism of binary lipid mixtures." Thesis, University of Southampton, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.305427.

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6

Stevar, M. S. P. "Dissolution dynamics of liquid/liquid binary mixtures in porous media." Thesis, University of Southampton, 2013. https://eprints.soton.ac.uk/349974/.

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In this project has been undertaken an experimental study aimed at understanding the dissolution dynamics of binary mixtures within porous media. The porous medium can be roughly represented as a network of capillary tubes. This allowed for the initial research to be focused on understanding the dissolution dynamics of binary mixtures (i.e. glycerol/water, soybean oil/hexane, and isobutyric acid/water) within single capillary tubes. Further, the dissolution process was investigated within a 2D micromodel built as a network of capillary tubes. In the experiments with the capillary tubes, the di

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7

Cooney, Anthony M. "Thermodynamic properties of binary liquid mixtures containing fluoroalcohols." Thesis, University of Leicester, 1988. http://hdl.handle.net/2381/34062.

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A detailed investigation into the thermodynamic properties of pure fluoroalcohols and binary mixtures containing fluoroalcohols is described. A batch calorimeter was used to measure excess enthalpies over the complete composition range and enthalpies of solution were obtained using an L.K.B. 8700 calorimeter. The excess volumes were determined using both batch and dilution dilatometers. Vapour-liquid equilibrium diagrams for binary mixtures have been determined from vapour pressure measurements using a static vapour pressure apparatus. Enthalpies of vaporisation of the fluoroalcohols were dete

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8

Mercer-Chalmers, June Dawn. "The thermodynamics of solutions and binary liquid mixtures." Thesis, Rhodes University, 1993. http://hdl.handle.net/10962/d1005055.

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The thesis is presented in two parts. In part one, the excess thermodynamic properties have been determined for several binary liquid mixtures, with the aim of testing theories of liquid mixtures. The excess molar enthalpies, Hem, have been determined using an LKB flow microcalorimeter, and the excess molar volumes, Vem, have been determined using an Anton Paar densitometer. The HemS and VemS have been measured at 298.15 K for binary systems involving an alkanol (methanol, ethanol, I-propanol, 2-propanol) mixed with a hydrocarbon (l-hexene, I-heptene, l-octene, I-hexyne, I-heptyne, l-octyne, t

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9

Bowles, R. J. "Density profiles and concentration fluctuations in liquid binary mixtures." Thesis, University of East Anglia, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.370382.

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10

Singh, Amrat Paul. "An experimental and theoretical study of binary nematogenic mixtures." Thesis, University of Southampton, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.277801.

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11

Dong, Shaosheng. "Liquid Crystal Polymers And Dendritic Liquid Crystals: Synthesis, Morphology, Rheology And Binary Mixtures." online version, 2005. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=case1094584392.

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12

Sibanda, V. S. "The determination of excess thermodynamic functions of binary liquid mixtures." Thesis, Keele University, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.376300.

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13

Howse, Jonathan R. "Reflectivity studies of non-critical interfaces in binary liquid mixtures." Thesis, University of Sheffield, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.310789.

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14

Roy, Prithwi Dev. "Study of physical properties of binary mixtures of liquid crystals." Thesis, University of North Bengal, 2006. http://hdl.handle.net/123456789/859.

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15

Bemrose, Richard Antony. "A molecular dynamics study of liquid crystal mixtures." Thesis, Sheffield Hallam University, 1999. http://shura.shu.ac.uk/19339/.

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Results are presented from molecular dynamics simulations of binary liquid crystal mixtures using a generalisation of a well established Gay-Berne intermolecular potential. The simulations are undertaken in both the microcanonical (NVE) and the isoenthalpic-isobaric (NPH) ensembles. Firstly a 50:50 mixed system is simulated in the NVE ensemble containing generalised Gay-Berne (GGB) rod-like molecules with length to breadth axial ratios of 3.5:1 (molecules A) and 3:1 (molecules B). The molecules in this system differs only slightly from the well-characterised Gay-Berne (GB) potential with lengt

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16

Zhou, Qing-Hua. "Study on reverse osmosis membrane separation of binary organic liquid mixtures." Thesis, University of Ottawa (Canada), 1990. http://hdl.handle.net/10393/5810.

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There is an increasing interest for the separation of organic liquid mixtures with reverse osmosis primarily due to its great promise in industrial applications. Based on Surface Force-Pore Flow model (SFPF) developed by Matsuura and Sourirajan, the study was conducted with the aid of a computer program, for the separation of organic liquid mixtures by reverse osmosis for the purpose of design and prediction of membrane performance. The results show that for a given separation system the pore size on the membrane surface and the interaction force between the membrane material and solute are tw

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17

Huang, Tsang-Min. "Phase Equilibria of Binary Liquid Crystal Mixtures Involving Induced Ordered Phases." University of Akron / OhioLINK, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=akron1284381816.

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18

Baxter, Rodney Charles. "The thermodynamics of binary liquid mixtures of compounds containing multiple bonds." Thesis, Rhodes University, 1989. http://hdl.handle.net/10962/d1016079.

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Excess thermodynamic properties have been determined for several binary liquid mixtures with the aim of testing various thermodynamic theories and postulates. Excess molar enthalpies, HEm, have been determined using an LKB flow microcalorimeter and excess molar volumes, VEm, have been determined using an Anton Paar vibrating tube densitometer. The activity coefficients at infinite dilution ƴ∞₁₃, have been determined using an atmospheric pressure gas-liquid chromatograph. The excess molar enthalpies and the excess molar volumes have been measured at 298.15 K for systems involving the bicyclic c

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19

Abusleme, Julio A. "Measurements, models and simulations in mixtures : thermodynamics of aminealcohol binary systems." Thesis, McGill University, 1987. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=75760.

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The major aim of this thesis has been to contribute to the understanding of the CH$ sb2$/OH/NH$ sb2$ group interactions by means of studies of alcohol-amine mixtures in the gas and liquid phases.<br>To study these interactions in the gas phase a Burnett type equipment was designed, built and operated at low pressure, obtaining experimental pressure-temperature (P-T) data for various systems including alcohol-amylamine mixtures. The P-T data were reduced by a method developed in this work to give values of second virial coefficients. Measurements on known systems were in excellent agreement wit

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20

Chakraborty, Susanta. "Phase transitions in Binary mixtures of calamitic and Bent-Core-Mesogens." Thesis, University of North Bengal, 2019. http://hdl.handle.net/123456789/2847.

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21

Clements, Patricia J. "Critical point behaviour in binary and ternary liquid mixtures with particular reference to rheological and interfacial properties in model mixtures for microemulsions." Thesis, University of Sheffield, 1997. http://etheses.whiterose.ac.uk/10187/.

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The phase behaviour, rheological effects and interfacial properties of binary and ternary liquid mixtures have been studied near critical points. In particular, measurements have been made of the viscosity-at the bulk macroscopic level by capillary viscometry and at the microscopic level by fluorescence depolarisatiorr-and of critical-point wetting and adsorptiorr-at the solid-liquid interface using evanescent-wave-generated fluorescence spectroscopy and at the liquid-vapour interface using specular neutron reflection. The systems investigated have been mostly alkane + perfluoroalkane mixtures

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22

Grice, Sarah Jane. "Predicting the phase equilibria of associating and reacting systems." Thesis, University of Sheffield, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.310786.

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23

Zhu, Qingyong, Geoffrey D. Moggridge, and Carmine D’Agostino. "A local composition model for the prediction of mutual diffusion coefficients in binary liquid mixtures from tracer diffusion coefficients: A local composition model for the prediction of mutual diffusioncoefficients in binary liquid mixtures from tracer diffusion coefficients." Diffusion fundamentals 24 (2015) 58, S. 1, 2015. https://ul.qucosa.de/id/qucosa%3A14577.

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24

Brown, Matthew D. "Verification of universal surface scaling behavior in critical binary liquid mixtures with neutron and x-ray reflectometry." Diss., Kansas State University, 2007. http://hdl.handle.net/2097/320.

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Doctor of Philosophy<br>Department of Physics<br>Bruce M. Law<br>We have studied two critical binary liquid mixtures in the mixed phase regime with x-ray and neutron reflectometry to verify universal critical scaling at a non-critical interface. We compared our results with previous results obtained with ellipsometry. At a solid-liquid or liquid-vapor interface of an AB binary liquid mixture the component with the lower surface tension will dominate that interface. If the surface tension differential between the components of the mixture is large enough the composition of the surface laye

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25

Prasad, Akhileshwar. "STUDY OF THE INDUCTION OF SMECTIC Ad AND RE-ENTRANT NEMATIC PHASES IN BINARY MIXTURES OF LIQUID CRYSTALS." Thesis, University of North Bengal, 2013. http://hdl.handle.net/123456789/938.

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26

Zhu, Qingyong, Geoffrey D. Moggridge, and Carmine D’Agostino. "A local composition model for the prediction of mutual diffusion coefficients in binary liquid mixtures from tracer diffusion coefficients." Universitätsbibliothek Leipzig, 2016. http://nbn-resolving.de/urn:nbn:de:bsz:15-qucosa-198798.

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27

Thapa, Nabin K. "Characterizing Liquid-Fluid Interfaces Using Surface Light Scattering Spectroscopy." Kent State University / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=kent1564059703319064.

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28

Aouini, Abir. "Cristaux liquides nématiques de type Twist-Bend - mécanismes de commutation et applications." Thesis, Ecole nationale supérieure Mines-Télécom Atlantique Bretagne Pays de la Loire, 2020. http://www.theses.fr/2020IMTA0226.

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Les cristaux liquides se retrouvent aujourd’hui dans nombreuses applications. La phase cristal liquide la plus connue et la plus utilisée est la phase nématique. En 2011 une nouvelle phase, la phase Nématique Twist Bend (NTB), a été découverte. Très prometteuse pour de futures applications, elle pourrait stimuler le développement d’une nouvelle génération de dispositifs électro-optiques. Deux problèmes principaux limitent cependant son utilisation. La phase NTB est difficile à orienter sur de grandes surfaces. Un second défi réside dans l’obtention d’une phase NTB stable à température ambiante

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29

Neyt, Jean-Claude. "Calcul de la tension interfaciale de mélanges gaz / eau, gaz / huile et huile / eau par simulation moléculaire." Phd thesis, Université Blaise Pascal - Clermont-Ferrand II, 2013. http://tel.archives-ouvertes.fr/tel-00962483.

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La prédiction de valeurs de tension interfaciale des fluides est capitale dans de nombreuses applications industrielles. Les techniques de simulation moléculaire et l'évolution rapide des moyens de calcul intensif permettent depuis quelques années de prédire des valeurs de tension interfaciale pour des systèmes complexes. Des travaux concernant des équilibres liquide / vapeur des corps purs SO2, O2, N2 et Ar montrent que les modèles choisi pour chaque molécule peuvent influencer la qualité des prédictions de tension interfaciale. Des simulations d'équilibres gaz acide / alcane de type CO2 / n-

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30

Kindler, Kolja. "On Soret Convection in Binary and Pseudo-Binary Liquid Mixtures." Doctoral thesis, 2007. http://hdl.handle.net/11858/00-1735-0000-000D-F164-3.

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31

Ji, Wong-wing, and 紀婉韻. "Isobaric Vapor-Liquid Equilibrium for Binary Mixtures Containing Propionates." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/y9q67h.

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碩士<br>國立臺灣科技大學<br>化學工程系<br>94<br>Isobaric vapor-liquid phase equilibrium (VLE) data were measured for the binary systems of methyl propionate + methyl acetate, propionic acid + methyl propionate, propionic acid + methyl acetate, acetic acid + methyl propionate, and isopropyl propionate + isopropanol at 760 mmHg. All the binary VLE data passed the thermodynamic consistency test. While the system of isopropyl propionate + isopropanol exhibited negative deviation, the other four binary systems showed positive deviation. The VLE data were correlated with the Wilson, the NRTL, and the UNIQUAC model

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32

Chien, Yu-cheng, and 簡宇程. "Isothermal Vapor-Liquid Equilibrium for Binary Mixtures Containing Butylated Hydroxytoluene." Thesis, 2011. http://ndltd.ncl.edu.tw/handle/tf5zsf.

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碩士<br>國立臺灣科技大學<br>化學工程系<br>99<br>A static-type apparatus with a liquid-phase circulation loop was used to measure isothermal vapor-liquid equilibrium (VLE) data for the binary systems of 2-tert-butyl 4-methyl phenol + butylated hydroxytoluene and 2,6-di-tert-butyl phenol + butylated hydroxytoluene at temperatures from 433.15 K to 473.15 K. The experimental results showed no azeotrope formation and positive deviations from ideality in each binary system. While the vapor pressure data of pure substances were fitted to the Antoine equation , the binary VLE data were correlated with the Wilson, th

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33

Chi-wei, Hwu, and 胡志瑋. "Vapor-Liquid Equilibrium Measurements of Binary Mixtures at 101.32 kPa." Thesis, 2001. http://ndltd.ncl.edu.tw/handle/90644258011009651184.

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碩士<br>國立臺灣大學<br>化學工程學研究所<br>89<br>Binary vapor-liquid equilibrium data of cyclopentane + ethyl acetate, ethyl propionate, propyl acetate, ethanol and n-propanol are measured at 101.32 kPa in this work. These experimental data are not available in previous literature. The attainment of equilibrium under the experimental conditions is supported in the three different kinds of the thermodynamic consistency tests at the same time. Activity coefficients for each component in the binary mixtures are calculated and correlated to determine the optimum binary parameters with three different liquid mode

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34

Huang, Hsien-chen, and 黃顯程. "Study on the Binary Mixtures of Blue Phase Liquid Crystals." Thesis, 2012. http://ndltd.ncl.edu.tw/handle/11120072329340264512.

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碩士<br>大同大學<br>化學工程學系(所)<br>100<br>A few of liquid crystal materials exhibiting blue phases have been reported in a single compound, moreover, the blue phases in the materials possess a very small temperature range (cal.1-2℃), mainly because of the blue phases are frustration phases. Thus, the relationship between molecule structure and the formation of blue phases has never been established. Neither the liquid-crystal mixture technique has been explored and studied yet. The main objective of this experiment work is to explore whether the binary mixture of the blue phase materials could enhan

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35

Kindler, Kolja [Verfasser]. "On Soret convection in binary and pseudo-binary liquid mixtures / vorgelegt von Kolja Kindler." 2008. http://d-nb.info/990413969/34.

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36

Das, Bhabani Sankar, and Biswajeet Patnaik. "Hydrodynamic study of Three Phase semi Fluidized Bed with Irregular and homogeneous binary mixtures." Thesis, 2010. http://ethesis.nitrkl.ac.in/1824/1/final_thesis01.pdf.

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Fluidization refers to a process by which a fluid like state is imparted to granular solid particles by the passing of a fluid upwards through the bed of particles. A semi fluidized bed is characterized by a fluidized bed and a packed bed in a series within a single contacting vessel. Gas-liquid-solid semi fluidization is defined as an operation in which a bed of solid particles is suspended in gas and/or liquid upward flowing media due to the net gravitational force on the particles and the motion of the particles is restricted by a top restraint. Such an operation generates intimate contact

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37

Tai, Wen-ping, and 戴文平. "Isothermal Vapor-Liquid Equilibrium for Binary Mixtures Containing Furfural and Its Derivatives." Thesis, 2013. http://ndltd.ncl.edu.tw/handle/93511184412777568276.

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碩士<br>國立臺灣科技大學<br>化學工程系<br>101<br>A static-type apparatus with a liquid-phase circulation loop was used to measure isothermal vapor-liquid equilibrium (VLE) data for the binary systems of 2-methylfuran + furfuryl alcohol, isopropanol + furfuryl alcohol, and furan + furfural at 353.15 K, 373.15 K, and 408.15 K. The experimental results showed no azeotrope formation and positive deviations from ideality in each binary system. The vapor pressures of pure 2-methylfuran were also measured from 348.15 K to 409.02 K and fitted to the extended Antoine equation. The thermodynamic consistency of the new

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38

Lai, Tzu-Yu, and 賴姿妤. "Solid-Liquid Equilibrium Measurements of Organic Acids Binary Mixtures by using DSC." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/91321637819973722783.

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碩士<br>中國文化大學<br>材料科學與奈米科技研究所<br>98<br>Solid-liquid equilibria of the following four systems have been measured using Differential Scanning Calorimetry ( DSC )：Adipic acid ( 1 ) + Benzoic acid ( 2 )、Benzoic acid ( 1 ) + Glutaric acid ( 2 )、Adipic acid ( 1 ) + Glutaric acid ( 2 )、Benzoic acid ( 1 ) + Pimelic acid ( 2 )、Adipic acid ( 1 ) + Pimelic acid ( 2 )、Pimelic acid ( 1 ) + Glutaric acid ( 2 ). Simple eutectic phase diagrams were observed, and experimental data are not available in previous literature. The study can supply the data of solid-liquid equilibrium for developing in thermodynamics

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39

Wu, Dong-ha, and 吳東樺. "Isothermal Vapor-Liquid Equilibrium for Binary Mixtures Containing Methanol and Methyl Esters." Thesis, 2009. http://ndltd.ncl.edu.tw/handle/42748756038182860920.

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碩士<br>國立臺灣科技大學<br>化學工程系<br>97<br>A static-type apparatus with a liquid-phase circulation loop was used to measure isothermal vapor-liquid equilibrium (VLE) data for the binary systems of methanol + methyl palmitate , methanol + methyl oleate, and methanol + methyl linoleate at temperatures from 353.15 K to 403.15 K. The experimental results showed no azeotrope formation and positive deviation from ideality in each binary system. The Antoine equation fitted the vapor pressure data of pure substances to within an average absolute percentage deviations of 1 %. Binary VLE data were correlated with

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40

Abdurrokhman, Iqbaal, and Iqbaal Abdurrokhman. "Thermophysical Properties of Binary Mixtures Containing Good’s Buffer Ionic Liquid [TBP][TAPS]." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/21115651313966337014.

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碩士<br>國立臺灣科技大學<br>化學工程系<br>104<br>A novel ionic liquid [TBP][TAPS] derived from basic hydroxide solution tetra-n-butylphosponium ([TBP][OH], 40 wt% in H2O) and Good’s biological buffer n-[tris(hydroxymethyl)]-3-amino-propanesulfonic acid has been synthesized by simple acid-base neutralization method. The physical properties, including density, thermal expansion, apparent molar volume, viscosity, conductivity, and molar conductivity have been determined for the binary ionic solutions of [TBP][TAPS] with water, methanol, ethanol, 1-propanol, 2-propanol, or tert-butanol at temperatures from 283.1

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41

Homendra, Naorem. "Physico-chemical and thermodynamic investigations of some binary liquid mixtures of Furfural." Thesis, 1989. http://localhost:8080/iit/handle/2074/3492.

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42

Giraudet, C., T. Klein, M. H. Rausch, T. M. Koller, and A. P. Fröba. "Mass diffusivities of binary mixtures of normal alcanes with dissolved gases." 2017. https://ul.qucosa.de/id/qucosa%3A31663.

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43

Cheng-Feng, Tang, and 唐振峰. "Synthesis of Achiral liquid crystals and the Electro-optical Properties in Binary Mixtures." Thesis, 2004. http://ndltd.ncl.edu.tw/handle/23626629174938832889.

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碩士<br>國立臺灣科技大學<br>高分子工程系<br>92<br>Two different structural achiral liquid crystals [2-methyle- thyl4-(4-decyloxy- biphenyl-4-carbonyloxy)benzoate] ,h ;[2-methylethyl4-(4’-decyloxybiphenyl-4-carbonyloxy)-3-fluorobenzoate], f had been synthesized. Utilized melting point apparatus and 1H-NMR to make sure molecular structure and all the final products were further confirmed with 13C-NMR and element analysis(EA). Polarizing microscope was used to observe texture of the mesophases and DSC was used to find out phase transition temperature. The study of electro-optical behavior f

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44

Chen, Tzu-Ying, and 陳姿穎. "Isothermal Vapor-Liquid Equilibrium for Binary Mixtures of Ethylene Glycol Purification Related Systems." Thesis, 2015. http://ndltd.ncl.edu.tw/handle/p6wqwn.

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碩士<br>國立臺灣科技大學<br>化學工程系<br>103<br>A static-type apparatus with a liquid-phase circulation loop was used to measure isothermal vapor-liquid equilibrium (VLE) data for the binary systems of solvent A + 1,2-butanediol and solvent A + ethylene glycol at 393.15 K, 423.15 K, and 453.15 K. And also measured the binary systems of solvent B + 1,2-butanediol at 353.15 K, 393.15 K, 433.15 K, and 473.15 K, and solvent B + ethylene glycol at 393.15 K, 433.15 K, and 473.15 K. The experimental results exhibit no azeotropic behavior and positive deviations from Raoult’s law for each binary system. The thermod

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45

Agustinus, Afrianto, and 亞飛. "Vapor-Liquid Phase Behavior of Binary Mixtures Containing Carbon Dioxide near Critical Region." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/rqwyqb.

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碩士<br>國立臺灣科技大學<br>化學工程系<br>94<br>Vapor-liquid phase equilibria near critical region of binary systems of CO2 with styrene, propylene carbonate, and dimethyl carbonate were measured over the temperature range from 308.15 K to 363. 15 K and the pressure range from 1.9 MPa to 33 MPa. The measurements of equilibrium data of binary system CO2 + styrene were conducted by using both the semi-flow phase equilibrium apparatus and the visual and volume-variable high-pressure phase equilibrium analyzer (PEA). The measurement of equilibrium data of binary systems CO2 + propylene carbonate and CO2 + dimeth

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46

Lin, Bo-Ting, and 林柏廷. "Isothermal Vapor-Liquid Equilibrium for Binary Mixtures of Containing Water and Ionic Liquids." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/55710848611930312632.

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碩士<br>國立臺灣科技大學<br>化學工程系<br>104<br>In the present study, the total pressure method was used to measure isothermal vapor-liquid equilibrium (VLE) data for the binary systems of water + choline glycolate , water + diethylmethylammoniummethane sulfonate , water + 1-ethyl-3-methylimidazolium acetate , water + 1-ethyl-3-methylimidazolium diethylphosphate , and water + tetrabutylammorimum 2-(bis(2-hydroxyethyl)amino)acetic acid at 278.2 K to 413.2 K. The experimental results show that all binary systems are negative deviations. The UNIQUAC model was applied used to correlate the VLE data for each b

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47

Chen, Chong-Yi, and 陳崇毅. "Prediction of solid-liquid-gas equilibrium for binary mixtures of carbon dioxide + organic compounds." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/01634403517165550867.

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碩士<br>國立中央大學<br>化學工程與材料工程學系<br>105<br>The knowledge of the solid–liquid–gas equilibrium (SLGE) for binary mixtures of organic compounds in CO2 is one of the key information determine the best operation condition for many supercritical fluid processes. In this work, the SLGE of 21 organic compounds in carbon dioxide is calculated from six approaches based on Peng-Robinson equation of state (PR EOS) and the COSMO-SAC models. These methods include two versions of PR+COSMOSAC EOS and combining PR EOS with MHV1 or Wong-Sandler (WS) mixing rules and two versions of COSMO-SAC models. The PR+COSMOSAC(

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48

Feng, Li-chia, and 馮立佳. "Vapor-Liquid Equilibria for Three Binary Mixtures of CO2 with Esters at Elevated Pressures." Thesis, 1999. http://ndltd.ncl.edu.tw/handle/10012948145121588692.

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碩士<br>國立臺灣大學<br>化學工程學研究所<br>87<br>A semi-flow type apparatus was used to measured the vapor-liquid equilibrium (VLE) data of CO2 + ethyl benzoate, CO2 + diethyl succinate and CO2 + isoamyl acetate binary mixtures at temperatures 308.15 K, 318.15 K and 328.15 K over the pressure range from 1 MPa to 12 MPa. Total 82 new data were obtained for these three binary mixtures. The KI equation was used to correlate the solubility of CO2 in esters and the Henry's constants were obtained. The Henry's constants increase with the increasing temperature. Equation of state method was us

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蘇長清. "Vapor-Liquid Equilibria for Binary Mixtures of 2-Methoxyphenol, 1,2-Dimethoxybenzene and Auxiliary Agents." Thesis, 2002. http://ndltd.ncl.edu.tw/handle/13471579965990746107.

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碩士<br>國立臺灣科技大學<br>化學工程系<br>90<br>A static-type apparatus with a liquid-phase circulation loop was used to measure isothermal vapor-liquid equilibrium ( VLE ) data for the systems containing high-melting point compounds. The apparatus was also employed to determine vapor pressures for 2-methoxyphenol, 1,2-dimethoxy -benzene, morpholine, tert-butanol, 2-butoxyethyl acetate, 2-2(ethoxyethoxy)ethyl acetate, diethyl methylmalonate, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, and diethylene glycol hexyl ether at temperatures from 308.15 K to 473.15 K and pressures from 2 kPa

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Chen, Shao-Yu, and 陳劭瑜. "From Pure Component Properties to Calculate Vapor-Liquid Equilibrium of Binary Non-polar Mixtures." Thesis, 2008. http://ndltd.ncl.edu.tw/handle/8pesde.

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碩士<br>國立臺北科技大學<br>化學工程研究所<br>96<br>The phase behavior of vapor-liquid equilibrium and thermodynamics properties of mixtures are important for distillation separation processes, Pseudocritical rules have been developed which enable the calculation of vapor-liquid equilibrium (VLE) values and thermodynamic properties for nonpolar mixtures for wide ranges of temperatures and pressures. Interaction constants of mixtures are obtained by procedures for the calculation of interaction second virial coefficient with relationships for the Kihara spherical core potential with generalized correlation of T

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