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Journal articles on the topic 'Homogeneous Binary Liquid Mixtures'

Author: Grafiati

Published: 5 June 2025

Last updated: 15 July 2025

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1

Bribesh, Fathi A., and Hamza A. Daoub. "Off-critical Composition of Thin Liquid Films of Binary Mixture." University of Zawia Journal of Natural Sciences 1, no. 1 (2024): 41–50. http://dx.doi.org/10.26629/uzjns.2024.06.

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This study concentrates on the non-linear solutions of bounded films of binary mixtures with free-modulated surfaces, situated on an energetically neutral solid substrate and subject to periodic boundary conditions on the lateral walls. The Cahn-Hilliard model in its static limit is employed to investigate the problem, and the free surface is considered sharp with its own surface tension. The internal interfaces between the two polymers are allowed to diffuse. The problem is explored through its bifurcations varying several parameters, specifically the surface tension γ, film lateral domain si

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2

Ryzhkin, D. A., and V. M. Raeva. "Comparison of methods for calculating the enthalpy of vaporization of binary azeotropic mixtures." Fine Chemical Technologies 19, no. 4 (2024): 279–92. http://dx.doi.org/10.32362/2410-6593-2024-19-4-279-292.

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Objectives. To calculate the molar enthalpy of vaporization of binary homogeneous mixtures based on isothermal and isobaric vapor– liquid equilibrium data, and to compare the results of calculation of molar enthalpy of vaporization by different methods with experimental data.Methods. Simulation of the vapor–liquid equilibrium of binary systems according to the Non-Random Two Liquid “local compositions” equation and thermodynamic calculations of molar vaporization enthalpies of binary mixtures at different conditions of vapor–liquid equilibrium were used.Results. Arrays of calculated data were

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3

Sharma, Pradeep K., and Phillip C. Wankat. "Distillation-Adsorption Hybrid Processes to Separate Binary Liquid Mixtures with Homogeneous Azeotrope." Separation Science and Technology 48, no. 1 (2013): 1–14. http://dx.doi.org/10.1080/01496395.2012.723101.

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4

Dąbrowski, Andrzej, and Mieczysław Jaroniec. "A new equation for bilayer adsorption from binary liquid mixtures on homogeneous solid surfaces." Chemical Engineering Science 40, no. 3 (1985): 473–80. http://dx.doi.org/10.1016/0009-2509(85)85108-3.

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5

Glukhov, Alexander F. "Subcritical convection in colloids and liquid binary mixtures with positive thermal diffusion." Вестник Пермского университета. Физика, no. 2 (2024): 19–26. http://dx.doi.org/10.17072/1994-3598-2024-2-19-26.

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The paper analyzes convection of molecular binary mixtures and colloids with positive thermal diffusion that occurs in the case of heating from below and below the equilibrium stability threshold for a homogeneous liquid. The convection is pulsed in nature and is realized in the form of periodic bursts. Positive thermal diffusion displaces the heavy component into the upper cold layers of the liquid. There, the heavy component accumulates in the boundary layer, forming a growing unstable density stratification. When the inhomogeneity exceeds the critical value for a given geometry, a convectiv

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6

Novák, Josef P., Jaroslav Matouš, Květuše Říčná, and Vladimír Kubíček. "Liquid-liquid equilibrium in the water-ethanol-toluene system. Correlation of equilibrium data." Collection of Czechoslovak Chemical Communications 54, no. 3 (1989): 586–601. http://dx.doi.org/10.1135/cccc19890586.

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Liquid-liquid equilibrium data in the water-ethanol-toluene system were correlated by the superposition of the Wilson and Redlich-Kister equations with a ternary term. The correlation of both homogeneous binary systems was taken from the literature. The ternary liquid-liquid equilibrium data were at all temperatures satisfactorily described on using only three ternary parameters determined from the equilibrium data at 50 °C. The parameters obtained by the correlation yield also a good estimate of boiling point and composition of homogeneous azeotropic mixture.

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7

Dietrich, Erik, Maaike Rump, Pengyu Lv, E. Stefan Kooij, Harold J. W. Zandvliet, and Detlef Lohse. "Segregation in dissolving binary-component sessile droplets." Journal of Fluid Mechanics 812 (December 28, 2016): 349–69. http://dx.doi.org/10.1017/jfm.2016.802.

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The dissolution of a single droplet, containing a mixture of oils, in water is experimentally studied. The oils in the droplet varied in terms of their solubility in water and their hydrophobicity. We demonstrate that the polarity of the droplet constituents strongly influences the dissolution dynamics. A binary-component droplet, containing two polar components (one soluble the other insoluble) exhibits a retarded dissolution as compared to a droplet containing only the soluble component. We argue that in this case the mixture in the droplet can be assumed homogeneous, leading to a smaller ef

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8

Narasimha Reddy, S., and P. S. T. Sai. "Continuous segregation of homogeneous binary mixture of solids by a liquid fluidised bed classifier." Indian Chemical Engineer 62, no. 1 (2019): 28–39. http://dx.doi.org/10.1080/00194506.2019.1623090.

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9

Dabrowski, A., K. Nieszporek, Z. Fekner, R. Leboda, and J. K. Garbacz. "Application of the Dubinin–Radushkevich Equation for Describing Adsorption from Solutions on to Various Carbons." Adsorption Science & Technology 10, no. 1-4 (1993): 105–21. http://dx.doi.org/10.1177/0263617499010001-410.

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Dozens of papers have been published recently describing adsorption processes from solutions on to solid surfaces, but a certain lack of understanding of this problem is still observed. This article deals with the description of adsorption from binary solutions of non-electrolytes on to solids. This description covers adsorption both on homogeneous and heterogeneous surfaces from ideal and non-ideal liquid mixtures. Some important factors determining the adsorption process, i.e. the heterogeneity of the solid surface, interactions between the species in the bulk and surface phases, differences

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10

Liu, Xinxin, Ndungutse Jean Maurice, Mugabekazi Joie Claire, et al. "A simulation study on the process design and optimization pressure swing separation of azeotropic mixture methanol and toluene." PLOS ONE 19, no. 12 (2024): e0310541. https://doi.org/10.1371/journal.pone.0310541.

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Pressure Swing Distillation (PSD) is the only advanced technology that does not require the addition of third components to the system to enhance the separation of azeotropic mixtures. It outperforms homogeneous distillation for separating pressure-sensitive azeotropic mixtures. In this study, we aimed to separate methanol and toluene using the Non-Random Two-Liquid (NRTL) and Aspen Plus thermodynamic calculation models to simulate a binary homogeneous azeotropic system. The standard PSD process was employed to separate methanol and toluene. Furthermore, multiple optimization sequences were ut

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11

Yang, Cheng, and Xin Zhou. "The multiple local structures in liquid water." International Journal of Modern Physics B 32, no. 18 (2018): 1840003. http://dx.doi.org/10.1142/s0217979218400039.

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The debate over whether the structure of liquid water is homogeneous or mixed with a variety of structures has been going on for more than one century. With the discovery of different amorphous ices and advances in computer technology, mixture model is gaining more and more attention. In this paper, the latest progress in the experiment and simulation of the local structure of liquid water is introduced firstly. Secondly, the principal component analysis is used to study the water’s Raman spectra and tetrahedral-order distributions. We find that both the spectra and distributions can be obtain

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12

GILBERTSON, M. A., and I. EAMES. "Segregation patterns in gas-fluidized systems." Journal of Fluid Mechanics 433 (April 25, 2001): 347–56. http://dx.doi.org/10.1017/s0022112001003950.

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The formation of segregation patterns in initially homogeneous, fluidized, binary mixtures of particles has been studied. The adjustment of the bed depends on the proportions of fine and coarse particles in the mixture and the gas flow rate relative to the minimum fluidization velocities of the two components. The particles are immobile until the gas flow rate is sufficiently large to fluidize the mixture of particles. When the gas flow rate exceeds this critical value, alternating vertical bands of coarse and fine particles form. At a second critical gas velocity this pattern breaks down and

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13

Samal, Deepak Kumar, Yashobanta Kumar Mohanty, and Gopendra Kishore Roy. "Prediction of bed pressure drop and top packed bed formation in gas-liquid-solid semi-fluidized bed with irregular homogeneous binary mixtures." Korean Journal of Chemical Engineering 30, no. 6 (2013): 1326–34. http://dx.doi.org/10.1007/s11814-013-0030-y.

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14

Kalabiński, Jakub, Aleksandra Drozd-Rzoska, Szymon Starzonek, and Sylwester J. Rzoska. "Pre-critical and Giant Post-Freezing and Pre-Melting Effects for Dielectric Properties in a Binary Mixture of Limited Miscibility." Crystals 14, no. 7 (2024): 612. http://dx.doi.org/10.3390/cryst14070612.

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This report presents the results of dielectric studies in a nitrobenzene–decane critical mixture in the homogeneous liquid, biphasic mesophase, and the solid crystal phase. It focuses on detecting critical effects in the broad surrounding of the critical consolute temperature and pre-melting and post-freezing effects in the solid crystal phase. The strong manifestation of the diameter critical anomaly in the biphasic domain and the Mossotti catastrophe type pre-melting and post-freezing effects in the solid phase are evidenced. Studies include the puzzling low-frequency (LF) domain related to

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15

Rice, Peter A., and Harden M. McConnell. "Critical shape transitions of monolayer lipid domains." Proceedings of the National Academy of Sciences 86, no. 17 (1989): 6445–48. http://dx.doi.org/10.1073/pnas.86.17.6445.

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Fluorescence microscopy can be used to visualize coexisting fluid phases in lipid monolayers composed of cholesterol and dipalmitoyl phosphatidylcholine under specified conditions of temperature, composition, and lateral pressure. At a critical composition of ≈30 mol% cholesterol, decreasing the average molecular area below ac [unk]50 Å2 per molecule forces the binary mixture through a critical point, where the monolayer becomes homogeneous. At molecular areas ≈10% above this critical area, we observe shape transitions from liquid domains with circular shapes to domains with less symmetrical s

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16

Sahimi, Muhammad, H. Ted Davis, and L. E. Scriven. "Thermodynamic Modeling of Phase and Tension Behavior of CO2/Hydrocarbon Systems." Society of Petroleum Engineers Journal 25, no. 02 (1985): 235–54. http://dx.doi.org/10.2118/10268-pa.

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Abstract The gradient theory of in homogeneous fluid is used to predict phase splits and compositions, interfacial composition profiles, and interfacial tension (IFT) of liquid-liquid, liquid-vapor, and liquid-liquid-vapor equilibria in binary and ternary mixtures of CO2 with propane and decane. The theory's input are the equation of state (EOS) of homogeneous fluid and the influence parameters of inhomogeneous fluid. An efficient computational algorithm is presented for simultaneously generating phase behavior, critical points, interfacial composition profiles, and tension between the phases.

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17

Hatton, D. C., and A. W. Woods. "Diffusion-controlled dissolution of a binary solid into a ternary liquid with partially molten zone formation." Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences 464, no. 2094 (2008): 1615–37. http://dx.doi.org/10.1098/rspa.2007.0241.

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We build a theoretical model of equilibrium dissolution of a homogeneous, solid mixture of two salts A and B, KCl and NaCl being used as the type example, into an aqueous solution of the two salts, with diffusive transport. We find that there are two sharp dissolution fronts, separating fluid, a partially molten zone containing a single solid and mixed solid. The phase change happens almost entirely at the two sharp fronts. In equilibrium, the leading front exhibits a small amount of precipitation of NaCl, simultaneous with complete dissolution of KCl. There is a unique surface in the space of

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18

Nawaz, Haq, Paulo A. R. Pires, Thaís A. Bioni, Elizabeth P. G. Arêas, and Omar A. El Seoud. "Mixed solvents for cellulose derivatization under homogeneous conditions: kinetic, spectroscopic, and theoretical studies on the acetylation of the biopolymer in binary mixtures of an ionic liquid and molecular solvents." Cellulose 21, no. 3 (2014): 1193–204. http://dx.doi.org/10.1007/s10570-014-0184-8.

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19

Veena, B. N., and P. G. Siddheshwar. "Energy Stability Analysis of Rayleigh-Bénard-Marangoni Convection in Homogeneous and Heterogeneous Nanoliquids." Journal of Nanofluids 13, no. 6 (2024): 1177–91. https://doi.org/10.1166/jon.2024.2203.

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This study delves into the examination of stability characteristics in both linear and non-linear systems, comparing terrestrial and microgravity environments. The primary focus is on the dynamic behavior exhibited by a range of binary nanoliquids, encompassing homogeneous and heterogeneous compositions such as Water-Copper, Water-Alumina, Ethylene glycol-Copper, Ethylene glycol-Alumina, Water-Copper-Alumina, Ethylene glycol-Copper-Alumina, Water-Ethylene glycol-Copper, and Water-Ethylene glycol-Alumina. The Khanafer-Vafai-Lightstone single-phase model is employed for this investigation. Therm

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20

Serizawa, Nobuyuki, Suguru Kuwahara, Xiaoyi Li, and Yasushi Katayama. "The Local Changes in the Physicochemical Properties during Cu Electrodeposition in an Ionic Liquid Composed of [CuCl₂]^–." ECS Meeting Abstracts MA2024-02, no. 57 (2024): 3861. https://doi.org/10.1149/ma2024-02573861mtgabs.

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The binary equimolar mixtures of cuprous chloride, CuCl, and some organic chlorides have been reported to behave as an ionic liquid containing [CuCl2]– [1]. The high concentration of the Cu(I) species is advantageous for the application to the electrodeposition. In addition, electrical charge transferred during electrodeposition is half that of the conventional aqueous system containing Cu(II) species, because the dissolved Cu species in these ionic liquids are monovalent. On the other hand, the viscosity of the mixture has been reported to depend on the composition [2], suggesting that the lo

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21

Harfash, Akil, and Ghufran A. Al-Musawi. "Global existence of a pair of coupled Cahn-Hilliard equations with nondegenerate mobility and logarithmic potential." Gulf Journal of Mathematics 16, no. 1 (2024): 9–35. http://dx.doi.org/10.56947/gjom.v16i1.1368.

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We conducted a mathematical investigation on a system of interconnected Cahn-Hilliard equations featuring a logarithmic potential, nondegenerate mobility, and homogeneous Neumann boundary conditions. This system emerges from a model depicting the phase separation of a binary liquid mixture in a thin film. Assuming certain conditions on the initial data, we successfully established the existence, uniqueness, and stability estimates for the weak solution. Our approach involved initially replacing the logarithmic potential with a smooth counterpart, resulting in the regularization of the original

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22

El Seoud, Omar A., Marc Kostag, Kerstin Jedvert, and Naved I. Malek. "Cellulose in Ionic Liquids and Alkaline Solutions: Advances in the Mechanisms of Biopolymer Dissolution and Regeneration." Polymers 11, no. 12 (2019): 1917. http://dx.doi.org/10.3390/polym11121917.

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This review is focused on assessment of solvents for cellulose dissolution and the mechanism of regeneration of the dissolved biopolymer. The solvents of interest are imidazole-based ionic liquids, quaternary ammonium electrolytes, salts of super-bases, and their binary mixtures with molecular solvents. We briefly discuss the mechanism of cellulose dissolution and address the strategies for assessing solvent efficiency, as inferred from its physico-chemical properties. In addition to the favorable effect of lower cellulose solution rheology, microscopic solvent/solution properties, including e

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23

Pandey, Vijay Kumar, Sunil Kumar Jatav, Upendra Pandel, and Rajendra Kumar Duchaniya. "Effect of composition on thermal stability and microstructural behaviour of non-prototype material (CaO-Fe2O3)." Journal of Mechanical Engineering and Sciences 15, no. 1 (2021): 7885–93. http://dx.doi.org/10.15282/jmes.15.1.2021.21.0622.

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The role of simulant materials becomes necessary for the predictive study of the nuclear severe accident phenomena due to its similarity with corium (a liquid form of UO2 and steel). Since simulant material is eco-friendly and has similar properties to corium, it has been widely used in the research field of severe accident management. In this study, material CaO-Fe2O3 a non-eutectic binary mixture is considered for characterization purpose to address the thermophysical properties at different compositional ratios. The CaO-Fe2O3 powder mixture was prepared in mortar for 40 minutes manually to

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24

Aminabhavi, T. M., L. S. Manjeshwar, and R. H. Balundgi. "Viscosities of binary liquid mixtures." Journal of Chemical & Engineering Data 32, no. 1 (1987): 50–52. http://dx.doi.org/10.1021/je00047a014.

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25

Balázs, N. L. "Viscosity of binary liquid mixtures." Recueil des Travaux Chimiques des Pays-Bas 70, no. 5 (2010): 412–18. http://dx.doi.org/10.1002/recl.19510700505.

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26

Al-Sharif, A., K. Chamniprasart, K. R. Rajagopal, and A. Z. Szeri. "Lubrication With Binary Mixtures: Liquid-Liquid Emulsion." Journal of Tribology 115, no. 1 (1993): 46–55. http://dx.doi.org/10.1115/1.2920985.

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There are numerous instances of technical importance in which multicomponent lubricants are utilized either by design or by necessity. In many of these cases one of the components is a liquid while the other component is a gas, as in squeeze film dampers during high frequency operation, or both components are liquids, as in the oil-water emulsion used in metal forming processes. In this paper our objective is to develop a self-consistent theory of hydrodynamic lubrication with bicomponent, liquid-liquid lubricants. The basic scientific method utilized is the continuum theory of mixtures. In th

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27

Maršík, František, Tomáš Němec, Jan Hrubý, et al. "Binary Homogeneous Nucleation in Selected Aqueous Vapor Mixtures." Journal of Solution Chemistry 37, no. 12 (2008): 1671–708. http://dx.doi.org/10.1007/s10953-008-9337-4.

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28

de Melo, Maria J. Pratas, Ana M. A. Dias, Marijana Blesic, et al. "Liquid–liquid equilibrium of (perfluoroalkane+alkane) binary mixtures." Fluid Phase Equilibria 242, no. 2 (2006): 210–19. http://dx.doi.org/10.1016/j.fluid.2006.02.003.

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29

Alnaimi, S. M., J. Mitchell, J. H. Strange, and J. B. W. Webber. "Binary liquid mixtures in porous solids." Journal of Chemical Physics 120, no. 5 (2004): 2075–77. http://dx.doi.org/10.1063/1.1643730.

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30

Aliotta, F., J. Gapiński, M. Pochylski, R. C. Ponterio, F. Saija, and G. Salvato. "Excess compressibility in binary liquid mixtures." Journal of Chemical Physics 126, no. 22 (2007): 224508. http://dx.doi.org/10.1063/1.2745292.

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31

Krech, Michael. "Casimir forces in binary liquid mixtures." Physical Review E 56, no. 2 (1997): 1642–59. http://dx.doi.org/10.1103/physreve.56.1642.

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32

Kehiaian, H. V. "Thermodynamics of binary liquid organic mixtures." Pure and Applied Chemistry 57, no. 1 (1985): 15–30. http://dx.doi.org/10.1351/pac198557010015.

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33

Douillard, J. M., R. Bennes, M. Privat, and L. Tenebre. "Surface transitions in binary liquid mixtures." Journal of Colloid and Interface Science 106, no. 1 (1985): 146–53. http://dx.doi.org/10.1016/0021-9797(85)90390-x.

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34

Papaioannou, D., and C. Panayiotou. "Surface tension of binary liquid mixtures." Journal of Colloid and Interface Science 130, no. 2 (1989): 432–38. http://dx.doi.org/10.1016/0021-9797(89)90120-3.

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35

Voorhees, P. W. "Coarsening in binary solid-liquid mixtures." Metallurgical Transactions A 21, no. 1 (1990): 27–37. http://dx.doi.org/10.1007/bf02656421.

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36

Toxvaerd, Søren, Ulf R. Pedersen, Thomas B. Schrøder, and Jeppe C. Dyre. "Stability of supercooled binary liquid mixtures." Journal of Chemical Physics 130, no. 22 (2009): 224501. http://dx.doi.org/10.1063/1.3144049.

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37

Piazza, Roberto, Vittorio Degiorgio, and Tommaso Bellini. "Kerr effect in binary liquid mixtures." Journal of the Optical Society of America B 3, no. 12 (1986): 1642. http://dx.doi.org/10.1364/josab.3.001642.

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38

Philip, John, and T. A. Prasada Rao. "Kerr effect in binary liquid mixtures." Journal of Molecular Liquids 50 (October 1991): 207–14. http://dx.doi.org/10.1016/0167-7322(91)80046-7.

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39

Getta, X., and S. Dietrich. "Interfacial wetting in binary liquid mixtures." Berichte der Bunsengesellschaft für physikalische Chemie 98, no. 3 (1994): 403–4. http://dx.doi.org/10.1002/bbpc.19940980324.

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40

Tzabar, N., and H. J. M. ter Brake. "Modeling of vapor–liquid–liquid equilibria in binary mixtures." International Journal of Refrigeration 70 (October 2016): 219–24. http://dx.doi.org/10.1016/j.ijrefrig.2016.02.023.

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41

Pomraning, G. C. "Cussic transport problems in binary homogeneous markov statistical mixtures." Transport Theory and Statistical Physics 17, no. 5-6 (1988): 595–613. http://dx.doi.org/10.1080/00411458808230878.

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42

Oswal, S. L., P. Oswal, and R. P. Phalak. "Viscosity of nonelectrolyte liquid mixtures. IV. Binary mixtures containingp-Dioxane." International Journal of Thermophysics 17, no. 6 (1996): 1255–67. http://dx.doi.org/10.1007/bf01438668.

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43

Lall-Ramnarine, S., S. Suarez, N. Zmich, et al. "Binary Ionic Liquid Mixtures for Supercapacitor Applications." ECS Transactions 64, no. 4 (2014): 57–69. http://dx.doi.org/10.1149/06404.0057ecst.

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44

Piñeiro, Ángel, Pilar Brocos, Alfredo Amigo, J. Gracia-Fadrique, and M. Guadalupe Lemus. "Extended Langmuir Isotherm for Binary Liquid Mixtures." Langmuir 17, no. 14 (2001): 4261–66. http://dx.doi.org/10.1021/la001210s.

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45

Kapanowski, A., and K. Sokalski. "Elastic Constants of Binary Liquid Crystalline Mixtures." Zeitschrift für Naturforschung A 53, no. 12 (1998): 963–76. http://dx.doi.org/10.1515/zna-1998-1207.

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Abstract Microscopic expressions for the elastic constants of binary liquid crystalline mixtures composed of short rigid uniaxial molecules are derived in the thermodynamic limit at small distorsions and a small density. Uniaxial and biaxial nematic phases are considered. The expressions involve the one-particle distribution functions and the potential energy of two-body short-range interactions. The theory is used to calculate the phase diagram of a mixture of rigid prolate and oblate molecules. The concentration dependence of the order parameters and the elastic constants are obtained. The p

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46

Raszewski, Zbigniew. "Dielectric studies of binary liquid-crystalline mixtures." Liquid Crystals 3, no. 3 (1988): 307–22. http://dx.doi.org/10.1080/02678298808086377.

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47

Qunfang, Lei, and Hou Yu-Chun. "Correlation of viscosity of binary liquid mixtures." Fluid Phase Equilibria 154, no. 1 (1999): 153–63. http://dx.doi.org/10.1016/s0378-3812(98)00415-4.

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48

Hoyt, Andrea E., and Samuel J. Huang. "Binary Mixtures of Liquid Crystalline Ester Bismaleimides." Journal of Macromolecular Science, Part A 32, no. 11 (1995): 1931–45. http://dx.doi.org/10.1080/10601329508009371.

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49

Bubnov, A., Věra Hamplová, M. Kašpar, et al. "Thermal analysis of binary liquid crystalline mixtures." Journal of Thermal Analysis and Calorimetry 90, no. 2 (2007): 431–41. http://dx.doi.org/10.1007/s10973-006-7913-7.

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50

Campanella, Luigi, Valentina Micieli, Mauro Tomassetti, and Stefano Vecchio. "Solid–liquid phase diagrams of binary mixtures." Journal of Thermal Analysis and Calorimetry 99, no. 3 (2010): 887–92. http://dx.doi.org/10.1007/s10973-010-0680-5.

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