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Dissertations / Theses on the topic 'Host - guest inclusion complexes'

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Published: 18 May 2024

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1

Bezuidenhout, Charl Xavier. "Polar ordering of guest molecules in host-guest inclusion complexes." Thesis, Stellenbosch : Stellenbosch University, 2011. http://hdl.handle.net/10019.1/18107.

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Thesis (MSc)--Stellenbosch University, 2011.<br>ENGLISH ABSTRACT: 2,7-dimethylocta-3,5-diyne-2,7-diol forms inclusion complexes with various guests molecules, where the guest molecules are polar-ordered. A Cambridge Structural Database (CSD) search revealed ten inclusion complexes where the guest molecules were polar-ordered. Using Density Functional Theory (DFT) computational methods (in the absence of the host), we evaluated the intra-channel and lateral guest-guest interactions between the guest molecules. Two polar-ordered inclusion complexes ((1,4,7-cyclohexane-1,2,4,5,7,8-hexaoxonane)·C

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2

Roy, Aditi. "Study to explore molecular inclusion complexes of cyclic hosts with vital guests in various environments." Thesis, University of North Bengal, 2018. http://ir.nbu.ac.in/handle/123456789/2633.

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3

O'Brien, Mark. "Spectroscopic Studies of Inclusion Host-Guest Complexes Between Cyclophane Corrals and Polcyclic Aromatic Hydrocarbons." TopSCHOLAR®, 2005. http://digitalcommons.wku.edu/theses/470.

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Cyclophanes are macromolecules that are known to effectively bind with molecules to form host-guest complexes. Several cyclophane molecules, referred to as corrals (1-6) by their founders, have been synthesized. The characterization of these compounds and their complexes has been investigated using combined spectroscopic and theoretical methods. Hostguest interactions of cyclophane-anthracene (C-A), cyclophane-9-fluorenone (C-F) and cyclophane-pyrene (C-P) complex systems in dichloromethane are presented in this thesis. The stability constants, log Ka, for the C-A, C-F and C-P complexes are de

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4

Kundu, Mitali. "Exploration of inclusion complexes between host and guest molecules and solvation effect of some vital molecules in various environments." Thesis, University of North Bengal, 2017. http://ir.nbu.ac.in/handle/123456789/2689.

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5

Mondal, Jaygopal. "Solvation consequences of different aqueous media on some biologically active compounds: a physico-chemical study." Thesis, University of North Bengal, 2021. http://ir.nbu.ac.in/handle/123456789/4751.

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6

Barman, Siti. "Investigation on solvation behaviour and host guest inclusion complexes of some significant molecules with diverse cyclic compounds." Thesis, University of North Bengal, 2017. http://ir.nbu.ac.in/handle/123456789/2588.

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7

Roy, Niloy. "Synthesis, characterization and innovative applications of inclusion complexes and nanocomposites of some biologically potent molecules." Thesis, University of North Bengal, 2022. http://ir.nbu.ac.in/handle/123456789/4754.

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8

Groom, Jazerie J. "Evaluation of Apparent Formation Constants of Host-Guest Inclusion Complexes of Solutes with Soluble Calixarenes Using High Performance Liquid Chromatography." Youngstown State University / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1389273191.

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9

Saha, Binoy Chandra. "Host guest inclusion complexes and thermodynamic properties of some imperative molecules with the manifestation of diverse interections by physiochemical investigation." Thesis, University of North Bengal, 2020. http://ir.nbu.ac.in/handle/123456789/3966.

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10

Rahaman, Habibur. "Diverse Interactions of Some Significant Compounds Prevailing in Different Solvent Systems with the Manifestation of Solvation Consequence by Physicochemical Investigations." Thesis, University of North Bengal, 2019. http://ir.nbu.ac.in/handle/123456789/2814.

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11

Nikolaou, Panayiotis. "SPECTROSCOPIC STUDIES OF NUCLEAR SPINS POLARIZED VIA SPIN EXCHANGE OPTICAL PUMPING AND DYNAMIC COUPLING IN CRYPTOPHANE HOST-GUEST COMPLEXES." OpenSIUC, 2010. https://opensiuc.lib.siu.edu/dissertations/185.

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NMR is a powerful analytical spectroscopic tool used to perform detailed studies of structure and dynamics of molecules in solution. However, despite NMR's excellent spectral sensitivity, most NMR methods suffer from low detection sensitivity. This low detection sensitivity results largely from extremely small (Boltzmann) nuclear spin polarization at thermal equilibrium--in even the strongest of magnets. This dissertation focuses on selected research areas that maybe used to combat the limitations presented by NMR and measure weak spectral responses with atomic-scale precision. In particular,

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12

Takacs, Zoltan. "Chloromethane Complexation by Cryptophanes : Host-Guest Chemistry Investigated by NMR and Quantum Chemical Calculations." Doctoral thesis, Stockholms universitet, Institutionen för material- och miljökemi (MMK), 2012. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-81472.

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Host–guest complexes are widely investigated because of their importance in many industrial applications. The investigation of their physico–chemical properties helps understanding the inclusion phenomenon. The hosts investigated in this work are cryptophane molecules possessing a hydrophobic cavity. They can encapsulate small organic guests such as halo–methanes (CH2Cl2, CHCl3). The encapsulation process was investigated from both the guest and the host point of view. With the help of Nuclear Magnetic Resonance (NMR), the kinetics of complex formation was determined. The information was furth

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13

Silva, Cassio Pacheco da. "Complexos de inclusão de antocianinas e análogos sintéticos de antocianinas." Universidade de São Paulo, 2015. http://www.teses.usp.br/teses/disponiveis/46/46136/tde-17122015-094757/.

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As antocianinas compreendem o maior conjunto de pigmentos naturais do Reino Vegetal. São caracterizadas pelas colorações vermelha, roxa e azul de uma variedade de flores, frutas e folhas. A sua estabilidade é influenciada por diversos fatores como o pH local do meio, temperatura, luz ou copigmentos. A inclusão das antocianinas e análogos sintéticos, os sais de flavílio, dentro da cavidade da cucurbit[7]uril (CB[7]), sistema hóspede-hospedeiro, foi estudada a partir da espectroscopia de fluorescência. As antocianinas sintéticas utilizadas foram o cloreto de 7-hidroxi-4-metilflavílio (HMF) e o c

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14

Saha, Subhadeep. "Study to explore the formation of host - guest inclusion complexes of cyclodextrins with biologically active moleculars and crown ethers with ionic liquids by spectroscopic and physicochemical techniques." Thesis, University of North Bengal, 2018. http://ir.nbu.ac.in/handle/123456789/2648.

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15

Escobar, González Luis. "Molecular containers based on aryl-extended calix[4]Pyrroles." Doctoral thesis, Universitat Rovira i Virgili, 2019. http://hdl.handle.net/10803/668442.

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Aquesta Tesi s'ocupa del disseny i síntesi de receptors còncaus que posseeixen cavitats hidrofíliques: receptors covalents, caixes metàl·liques i càpsules no covalents. Per a la seva construcció, triem la bastida de calix[4]pirrol aril-estès (C[4]P-AE), que proporciona una cavitat aromàtica profunda tancada en un extrem per un lloc d'unió polar i oberta a l'extrem oposat. També investiguem les propietats de reconeixement dels receptors sintetitzats en dissolvents orgànics així com en aigua. Específicament, descrivim un mètode sintètic per l'allargament de la cavitat de C[4]P-AEs que condueix a

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16

Daver, Henrik. "Quantum Chemical Modeling of Phosphoesterase Mimics and Chemistry in Confined Spaces." Doctoral thesis, Stockholms universitet, Institutionen för organisk kemi, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-148259.

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In this thesis, density functional theory is employed in the study of two kinds of systems that can be considered to be biomimetic in their own ways. First, three binuclear metal complexes, synthesized by the group of Prof. Ebbe Nordlander, have been investigated. The complexes are designed to resemble the active sites of phosphatase enzymes and have been examined in complexes where either two Zn(II) ions or one Fe(III) and one Mn(II) ion are bound. These dinuclear compounds were studied as catalysts for the hydrolysis of bis(2,4-dinitrophenyl) phosphate and the transesterification of 2-hydrox

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17

Smith, Anne Catherine. "Cyclodextrin host-guest and pseudorotaxane complexes." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp04/mq20700.pdf.

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18

Cameron, Diana Louise. "Pressure perturbation calorimetry of host-guest complexes." Thesis, University of Glasgow, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.404451.

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19

Guerra, Roberto, Andrea Benassi, Andrea Vanossi, Ming Ma, and Michael Urbakh. "Friction and adhesion mediated by supramolecular host–guest complexes." Royal Society of Chemistry, 2016. https://tud.qucosa.de/id/qucosa%3A36377.

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The adhesive and frictional response of an AFM tip connected to a substrate through supramolecular host–guest complexes is investigated by dynamic Monte Carlo simulations. Here, the variation of the pull-off force with the unloading rate recently observed in experiments is unraveled by evidencing simultaneous (progressive) breaking of the bonds at fast (slow) rates. The model reveals the origin of the observed plateaus in the retraction force as a function of the tip-surface distance, showing that they result from the tip geometrical features. In lateral sliding, the model exhibits a wide rang

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20

Metherell, A. J. "Self-assembly and host-guest studies of heteronuclear coordination complexes." Thesis, University of Sheffield, 2014. http://etheses.whiterose.ac.uk/7365/.

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This thesis is primarily concerned with the synthesis and characterisation of heterometallic polynuclear coordination structures, but also contains host-guest studies of mononuclear complexes. Chapter One consists of an introduction to self-assembly and supramolecular chemistry. Recent examples of coordination cages are given along with previous work from the Ward group. An introduction to recent efforts in the field of heterometallic supramolecular chemistry is also given. Chapter Two describes the use of a series of mononuclear Ru(II) complexes to act as models for the vertices of coordinati

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21

Chretien, Michelle N. "Photochemical, photophysical, and photobiological studies of zeolite guest-host complexes." Thesis, University of Ottawa (Canada), 2005. http://hdl.handle.net/10393/29205.

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This thesis focuses on the photochemistry and photophysics of a variety of zeolite complexes, from catalysts to sunscreens. The first chapter describes the preparation and photophysical and photochemical characterization of two new photocatalytic materials. The catalysts are based on a multi-component zeolite, host-guest complex and the interaction between components was probed using time-resolved spectroscopic techniques. The catalytic efficiency, in terms of the ability to photodegrade biological contaminants, was also investigated. These studies were performed with the aim of developing eff

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22

Tošner, Zdeněk. "NMR investigations of host-guest complexes and their dynamic properties /." Stockholm : Prague : Division of physical chemistry, Stockholm University ; Charles University, 2005. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-347.

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23

Streb, Carsten. "Functional polyoxometalate assemblies : from host-guest complexes to porous frameworks." Thesis, University of Glasgow, 2008. http://theses.gla.ac.uk/120/.

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The host-guest chemistry of two sets of isopolyoxometalate clusters is investigated. In particular the binding modes of cationic alkali and alkali earth metals through coordinative interactions with the cluster anions {Mo36} and {W36} were compared and contrasted. It was shown that the ionic radii of the cations are crucial in the isolation of discrete molecules or infinite 3D frameworks. Crystal engineering allowed the introduction of organic amine guest molecules by the formation of a set of intermolecular interactions between the cluster anions and the amine cations. In addition it was show

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24

Lacy, Stephen Michael. "Redox-active cyclophane host molecules for the inclusion of cationic and neutral guest species." Thesis, University of Oxford, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.333410.

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25

Löffler, Susanne. "Host-Guest Chemistry of Acridone-based Coordiantion Cages." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2018. http://hdl.handle.net/11858/00-1735-0000-002E-E415-6.

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26

Yasmin, Ananya. "Investigation of Host Guest Inclusion Complexations and Diverse Interactions of Some Industrially and Biologically Potent Molecules in Assorted Phases by Physicochemical Methodologies." Thesis, University of North Bengal, 2019. http://ir.nbu.ac.in/handle/123456789/2854.

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27

Holman, K. Travis. "The host-guest chemistry of new members in the cyclotriveratrylene family of cavitands /." free to MU campus, to others for purchase, 1998. http://wwwlib.umi.com/cr/mo/fullcit?p9924887.

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28

Chiba, Yusuke. "Template Synthesis of Structure-Controlled Porphyrin Tubes and Those Inclusion and Optical Properties." Kyoto University, 2018. http://hdl.handle.net/2433/232050.

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29

Bradbury, Adam John, and babradbury@optusnet com au. "METAL ION ACTIVATED ANION SENSORS." Flinders University. School of Chemistry Physics and Earth Sciences, 2007. http://catalogue.flinders.edu.au./local/adt/public/adt-SFU20080319.125059.

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A series of new, octadentate, fluorescent, macrocyclic ligands have been prepared with a view to using them to study aromatic anion sequestration. The eight-coordinate Cd(II) complexes of the ligands have been shown capable of acting as receptors for a range of aromatic oxoanions. This has been demonstrated by perturbation of both 1H NMR chemical shift values and the anthracene derived fluorescence emission intensity as the potential guest anion and the host are combined. Non-linear least squares regression analysis of the resulting titration curves leads to the determination of binding consta

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30

Canuto, Holly Corianda. "Investigation by solid-state NMR into the dynamics of organometallic and host-guest complexes." Thesis, University of Oxford, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.270339.

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31

Lam, Ho-chuen, and 林浩銓. "Design, synthesis and host-guest chemistry of rhodamine derivatives and their transition metal complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2012. http://hdl.handle.net/10722/198806.

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New classes of luminescent transition metal complexes, including the systems of rhenium(I) tricarbonyl diimine, cyclometalated iridium(III) diimine, cyclometalated rhodium(III) diimine, ruthenium(II) diimine and ruthenium(II) terpyridine complexes tethered with rhodamine moieties, have been synthesized. The X-ray crystal structure of one of the cyclometalated rhodium(III) diimine complexes with rhodamine pendants, [Rh(SPLC2N2)(ppy)2](PF6) has been determined. The molecular structure of [Rh(SPLC2N2)(ppy)2](PF6) showed a distorted octahedral geometry and the rhodamine moiety was found in a spiro

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32

Farabi, Shiva. "Luminescent assemblies based on surface active transition metal complexes and supramolecular host-guest systems." Thesis, University of Birmingham, 2012. http://etheses.bham.ac.uk//id/eprint/3833/.

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Miniaturisation of devices and components is becoming increasingly important in the field of molecular devices. The design of multicomponent supramolecular systems that undergo photoinduced energy or electron transfer processes has been well recognised in view of its potential for development of nanosized molecular devices for solar energy conversion and components in photonic devices. Consequently research has expanded to the properties of monolayers formed from rather simple organic molecules to biological systems and metal complexes. In the present approach, surface active Ru(II) and Os(II)

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33

Cametti, Massimo. "Salophen-Uranyl Complexes as Supramolecular Receptors." Doctoral thesis, La Sapienza, 2005. http://hdl.handle.net/11573/917517.

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34

Waymark, Christopher Peter. "Studies towards a novel synthetic receptor for small peptides." Thesis, University of Southampton, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.294980.

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35

Hulushe, Siyabonga Theophillus. "Guest inclusion behaviour of zirconium(IV)- based polycarboxylate complexes: a study of metal-organic frameworks." Thesis, Rhodes University, 2018. http://hdl.handle.net/10962/63710.

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36

Biplab, Rajbanshi. "Investigation of host- guest inclusion complexation of some biologically potent molecules and solvent consequences of some food preservations with the manifestation of synthesis, characterization and innovative applications." Thesis, University of North Bengal, 2020. http://ir.nbu.ac.in/handle/123456789/3963.

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37

裴雍蓮 and Yung-lin Pui. "Syntheses, luminescence studies and host-guest chemistry of d10 and d6metal complexes containing diimine and/or chalcogenolate ligand." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2000. http://hub.hku.hk/bib/B43894367.

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38

Pui, Yung-lin. "Syntheses, luminescence studies and host-guest chemistry of d10 and d6 metal complexes containing diimine and/or chalcogenolate ligand." Click to view the E-thesis via HKUTO, 2000. http://sunzi.lib.hku.hk/hkuto/record/B43894367.

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39

Yip, Sung-kong, and 葉崇江. "Design, synthesis, characterization and luminescence properties of alkynylgold(I) complexes: strategies towardssupramolecular architectures and host guest chemistry." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2005. http://hub.hku.hk/bib/B31941734.

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40

Symmers, Paul Robert. "Synthesis and properties of kinetically robust metallosupramolecular tetrahedra." Thesis, University of Edinburgh, 2014. http://hdl.handle.net/1842/10003.

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The fascinating field of molecular capsules has recently begun to see the creation of structures that, medicated by the encapsulation of guest molecules within their central cavity, are able to change the properties or reactivity of the substrate. The current capsule designs are however, prone to exchange of either part or whole ligands. This exchange or the capsule's subsequent disassembly can lead to loss of the cavity or modification of their external properties, and is a barrier to their more widespread application, a problem this work seeks to address by creating more a robust capsule str

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41

Martínez, Agramunt Víctor. "Nickel and palladium supramolecular organometallic complexes based on NHC-ligands with polyaromatic moieties for host-guest chemistry studies." Doctoral thesis, Universitat Jaume I, 2020. http://dx.doi.org/10.6035/14104.2020.366143.

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Se ha obtenido una nueva familia de cuatro Complejos Organometálicos Supramoleculares (SOCs) basados en pireno. Dentro de los cuales se ha desarrollado un nuevo receptor de PAH, capaz de discernir entre los diferentes PAH en función de su forma, tamaño, y número de electrones-pi. Hemos desarrollado una estrategia eficiente para la extracción de PAH, que son compuestos tóxicos y carcinogénicos, en disolventes orgánicos. Paralelamente, se han obtenido dos receptores de fulereno, capaces de adaptar su tamaño a la forma del fulereno. Debido a la mayor afinidad respecto a un fulereno específico, mo

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42

Yip, Sung-kong. "Design, synthesis, characterization and luminescence properties of alkynylgold(I) complexes strategies towards supramolecular architectures and host guest chemistry /." Click to view the E-thesis via HKUTO, 2005. http://sunzi.lib.hku.hk/hkuto/record/B31941734.

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43

Tang, Pui-ling, and 鄧佩玲. "Synthesis, luminescence and host-guest chemistry of mono- and dinuclear platinum(II) complexes of pyridyl and diphosphine ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2002. http://hub.hku.hk/bib/B31243654.

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44

Tang, Pui-ling. "Synthesis, luminescence and host-guest chemistry of mono- and dinuclear platinum(II) complexes of pyridyl and diphosphine ligands /." Hong Kong : University of Hong Kong, 2002. http://sunzi.lib.hku.hk/hkuto/record.jsp?B25155040.

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45

He, Xiaoming. "Design, synthesis and characterization of alkynyl- and thiolato- gold (I) complexes with various receptor groups for host-guest chemistry." Click to view the E-thesis via HKUTO, 2010. http://sunzi.lib.hku.hk/hkuto/record/B43571979.

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46

Li, Chi-kwan. "Gold(I) and Gold(II) phosphine complexes exhibiting weak AuI ... AuI interactions and unsupported AuII-AuII bonds : syntheses, spectroscopy, host-guest chemistry and reactivity studies /." Hong Kong : University of Hong Kong, 2002. http://sunzi.lib.hku.hk/hkuto/record.jsp?B25155295.

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47

Coupry, Damien E., Matthew A. Addicoat, and Thomas Heine. "Explicit treatment of hydrogen bonds in the universal force field: Validation and application for metal-organic frameworks, hydrates, and host-guest complexes." AIP Publishing, 2017. https://ul.qucosa.de/id/qucosa%3A21499.

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A straightforward means to include explicit hydrogen bonds within the Universal Force Field (UFF) is presented. Instead of treating hydrogen bonds as non-bonded interaction subjected to electrostatic and Lennard-Jones potentials, we introduce an explicit bond with a negligible bond order, thus maintaining the structural integrity of the H-bonded complexes and avoiding the necessity to assign arbitrary charges to the system. The explicit hydrogen bond changes the coordination number of the acceptor site and the approach is thus most suitable for systems with under-coordinated atoms, such as man

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48

Li, Chi-kwan, and 李志君. "Gold(I) and Gold(II) phosphine complexes exhibiting weak AuI... AuI interactions and unsupported AuII-AuII bonds: syntheses, spectroscopy, host-guest chemistry and reactivity studies." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2002. http://hub.hku.hk/bib/B31243332.

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49

Shields, Dylan J. "Photochemistry of Organic Azides, Quinones, and Peroxides in Solution, Crystals, Super Molecular Complexes and Cryogenic Matrices." University of Cincinnati / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=ucin157441745178423.

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50

Galstyan, Anzhela [Verfasser], Bernhard [Akademischer Betreuer] Lippert, and Jens [Gutachter] Müller. "Discrete supramolecular metal complexes : Synthesis, structures, host-guest chemistry with anions, and DNA binding properties / Anzhela Galstyan. Betreuer: Bernhard Lippert. Gutachter: Jens Müller." Dortmund : Universitätsbibliothek Dortmund, 2011. http://d-nb.info/1103472453/34.

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