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Journal articles on the topic 'Hot metal desulphurization'

Author: Grafiati

Published: 3 June 2025

Last updated: 31 July 2025

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1

Cao, Tong You, Wei Sun, and Kai Liu. "Effects of Operation Parameters on Desulphurization of Hot Metal with Passive Magnesium and Calcium Oxide in CSP Plant of WISCO." Advanced Materials Research 402 (November 2011): 132–37. http://dx.doi.org/10.4028/www.scientific.net/amr.402.132.

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The effects of operation parameters on desulphurization of hot metal with passive magnesium and calcium oxide injection in CSP plant of WISCO. have been studied in this paper. On basis of industrial optimization trials’ results on hot metal desulphurization, the original desulphurization process had been modified. Through the new-developed desulphurization process, desulfurizer consumptions have been decreased a lot by 40% with passive magnesium and 34% with lime respectively. Economical profits can be seen from the desulphurization process.

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2

Zeng, Jian Hua, Hong Pan, Yuan Chao Feng, Min Zhang, Shen Xiang Yang, and Li Gang Li. "Study on Sulfur Control Technology for Non-Oriented Electrical Steel." Advanced Materials Research 602-604 (December 2012): 351–55. http://dx.doi.org/10.4028/www.scientific.net/amr.602-604.351.

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In cognizance of the problems of low desulphurization rate for hot metal, large sulfur-recovery in converter, as well as high sulfur content in products when producing non-oriented electrical steel with vanadium-content hot metal, countermeasures have been carried out. Sulfur content in non-oriented electrical steel is decreased obviously with the study on technologies of desulphurization for hot metal with vanadium & titanium, sulfur-recovery control in converter, and desulphurization in RH refining process as well. The results of industrial tests show that the rate of w（S）≤0.008 % is as

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3

Shapovalov, A. "The use of statistical modelling to justify a rational technology of steel production in the conditions of JSC Ural Steel." Bulletin of Science and Practice, no. 11 (November 14, 2017): 227–35. https://doi.org/10.5281/zenodo.1048455.

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In the conditions of JSC Ural Steel, the most costly technological task in the production of high-quality steel is to provide the required sulfur content. The analysis of the sulfur removal in the production of high-quality steel in the technological conditions of JSC Ural Steel was performed. An increase in the sulfur content of the pig iron at 0,007-0,010% of the tapping from the blast furnace until used in an electric arc furnace was founded. The need for preliminary hot metal desulphurization before pouring in the electric arc furnace was justified. The method of calculating the cost of ho

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4

Shevchenko, A. F., and I. A. Manachin. "Main conditions of rational technological solutions of injection processes for ladle desulphurization of hot metal by various dispersed reagents." Ferrous Metallurgy. Bulletin of Scientific , Technical and Economic Information 1, no. 11 (2018): 13–20. http://dx.doi.org/10.32339/0135-5910-2018-11-13-20.

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Application of dispersed reagents in hot metal ladle treatment processes enabled for solving a wide range of tasks of increasing metal products quality and improving technical and economic indices of metal smelting processes. But there are reserves of existing technologies improving, since during their application a whole number of peculiarities of heat- and mass exchange processes, having place in ladle at wide range of parameters and refining conditions, are not taken into consideration. Therefore, elaboration of conceptions about exchange processes mechanisms at different reagents injection

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5

Barron, Miguel A., Joan Reyes, and Dulce Y. Medina. "Operational Costs of Hot Metal Desulphurization Processes." Open Journal of Business and Management 08, no. 05 (2020): 2326–36. http://dx.doi.org/10.4236/ojbm.2020.85143.

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6

Han, Yong Hui, Da Qing Cang, and Wen Bin Dai. "Optimization of Co-Injection Desulfurization of Vanadium Bearing Hot Metal." Key Engineering Materials 744 (July 2017): 239–43. http://dx.doi.org/10.4028/www.scientific.net/kem.744.239.

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The desulphurization process parameters of vanadium bearing hot metal were optimized. It is found that it has the best desulfurization effect in 100t hot metal ladle, when the lance position is 280mm, the ratio of lime to Mg is 3:1, and the Mg injection rate is 9kg/min. The Si and Ti content of hot metal can increase the activity of S. With the increase of Si and Ti content of hot metal, the final sulfur content has a reduction trend. When the content of Si and Ti is lower than 0.35%, the final sulfur content of hot metal increases, and the hit rate decreases. The effect of hot metal temperatu

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7

Barron, Miguel A., Dulce Y. Medina, and Joan Reyes. "A Straightforward Mathematical Model of Hot Metal Desulphurization." Open Journal of Applied Sciences 10, no. 06 (2020): 318–27. http://dx.doi.org/10.4236/ojapps.2020.106024.

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8

Rastogi, Ravi, Kalyanmoy Deb, Brahma Deo, and Rob Boom. "Genetic adaptive search model of hot metal desulphurization." Steel Research 65, no. 11 (1994): 472–78. http://dx.doi.org/10.1002/srin.199401196.

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9

Lubyanoi, D. A., S. A. Fomkin, A. V. Kukharenko, D. D. Lubyanoi, A. V. Markidonov, and Yu N. Soina-Kutishcheva. "Regarding a technology of Sulphur removal in acidic induction furnaces." Ferrous Metallurgy. Bulletin of Scientific , Technical and Economic Information 75, no. 6 (2019): 689–94. http://dx.doi.org/10.32339/0135-5910-2019-6-689-694.

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Sulphurremoval is a rather complicated metallurgical task, which require implementation of new energy-saving technologies, including metal desulphurization in induction furnaces. Results of analysis of different methods of metal desulphurization in the acidic induction furnaces. A technology of hot metal refining with Sulphurremoval by basic slags by extraction mechanism in the acidic induction furnaces proposed, tested and implemented at several plants. The essence of the xtraction mechanism applied to desulphurization method is as follows: particles of calcic slag involved by electromagnetic

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10

Li, Lin, Jun Yu Mu, Xiang Long Meng, Yong Qi Li, and Jie Peng. "Experimental Research on Influencing Factors of Melting Reduction for High-Phosphorus Titanomagnetite Pellets." Advanced Materials Research 962-965 (June 2014): 775–79. http://dx.doi.org/10.4028/www.scientific.net/amr.962-965.775.

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Reduction of high-phosphorus titanomagnetite was studied for future comprehensive utilization of resource. Experimental temperature (T), burden alkalinity (CaO/SiO2) and carbon-oxygen ratio (C/O) had an influence on the content of [P] and [S] in hot metal. Highest dephosphorization rate in hot metal appeared at C/O=1, high temperature was beneficial to desulphurization, but not for dephosphorization. High CaO/SiO2may decrease the content of [P] and [S]. C/O and CaO/SiO2had great influence on the content of [P] and [S] in hot metal.

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11

Zou, Zongshu, Yousheng Zou, Libing Zhang, and Nan Wang. "Mathematical Model of Hot Metal Desulphurization by Powder Injection." ISIJ International 41, Suppl (2001): S66—S69. http://dx.doi.org/10.2355/isijinternational.41.suppl_s66.

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12

de Souza Costa, S. L., E. Pacelli Meireles de Araújo, I. Lopes Alves, and J. Lima de Siqueira. "Optimizing the hot metal desulphurization process with the usage of rotating lance." Revue de Métallurgie 103, no. 12 (2006): 531–36. http://dx.doi.org/10.1051/metal:2006120.

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13

Shevchenko, A. F., I. A. Manachin, B. V. Dvoskin, et al. "Increase of desulphurization potential of technological systems of hot metal injection desulphurization by various reagents." Ferrous Metallurgy. Bulletin of Scientific , Technical and Economic Information 75, no. 11 (2019): 1237–43. http://dx.doi.org/10.32339/0135-5910-2019-11-1237-1243.

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14

Panteleev, V. V., K. B. Pykhteeva, M. V. Polovets, K. V. Mironov, and S. A. Zagainov. "Analysis of hot metal desulfurization methods efficiency during titanomagnetite processing." Ferrous Metallurgy. Bulletin of Scientific , Technical and Economic Information 76, no. 6 (2020): 543–49. http://dx.doi.org/10.32339/0135-5910-2020-6-543-549.

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To make high-quality steel, it is necessary to ensure low sulfur content in the hot metal entering a steelmaking shop. The task to obtain low sulfur metal can be solved either during blast furnace smelting or its ladle desulfurization immediately after tapping out of blast furnace. Under conditions of JSC EVRAZ NTMK, the ladle desulfurization of vanadium hot metal is not applied, since it leads to a loss of vanadium. Is explained by the fat, that calcium oxide forms with V2O5 a strong calcium vanadate (3СаО·V2O5), which makes the process of vanadium recovery during further slag processing more

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15

Li, Ming Hui, De Gang Ouyang, Shan He Zhu, Wei Luo, and Hai Qing Wang. "Physical Simulation of KR Stirring Desulphurization in Special-Shaped Ladle." Advanced Materials Research 512-515 (May 2012): 2537–42. http://dx.doi.org/10.4028/www.scientific.net/amr.512-515.2537.

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According to the theory research results of KR stirring mixing performance, a special-shaped ladle for KR stirring was designed, and the physical simulation experiment on conventional circular and special-shaped hot metal ladles were done. The experiment results indicate that : to the circular ladle, the designed special-shaped ladle significantly improves the mixing performance of KR stirring desulphurization; the operation principle for special-shaped ladle improving desulphurization dynamic condition is that the designed axisymmetric special-shaped section make a certain distance between th

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16

Ma, Wenjun, Haibo Li, Jun Zhang, Yang Cui, and Liang Sun. "Influence of clogging of a T-shaped desulfurization lance on the flow field in a hot metal ladle." Metallurgical Research & Technology 116, no. 3 (2019): 301. http://dx.doi.org/10.1051/metal/2018092.

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Lance injected desulphurization become ineffective when injection ports become obstructed. In this work, the difference of the flow fields between single and double hole injection was investigated by numerical simulations. When one of the openings in a T-shaped injection lance is blocked, a dead zone occurs in the ladle over approximately 1/4th of the volume, and there is not an active flow field on the surface of clogging side. To decrease clogging, industrial experiments examining different diameter lances were carried out. The results showed that clogging can be reduced by increasing the in

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17

SHIWAKU, Kiyoshi, Syozo KAWASAKI, Akimitsu KAMIMORI, Matsuhide AOKI, and Kiminori HAJIKA. "Sequential Dephosphorization and Desulphurization of Hot Metal by Newly Developed Pretreatment Furnace." Tetsu-to-Hagane 73, no. 11 (1987): 1567–74. http://dx.doi.org/10.2355/tetsutohagane1955.73.11_1567.

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18

Barannik, Ivan A., V. A. Aleksandrov, A. M. Bashmakov, and A. F. Shevchenko. "Specific Features of Magnesium and Its Alloy Application for Hot Metal Desulphurization." Materials Science Forum 488-489 (July 2005): 877–80. http://dx.doi.org/10.4028/www.scientific.net/msf.488-489.877.

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19

Datta, Amlan, Mavoori Hareesh, Prem Kumar Kalra, Brahma Deo, and Rob Boom. "Adaptive neural net (ANN) models for desulphurization of hot metal and steel." Steel Research 65, no. 11 (1994): 466–71. http://dx.doi.org/10.1002/srin.199401195.

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20

Wang, Laixin, Shengli Wu, Mingyin Kou, Binbin Du, Yanan Lu, and Kai Gu. "Improving the Desulphurization in COREX Process by Adjusting the Hot Metal Chemical Composition." Metallurgical and Materials Transactions B 49, no. 1 (2017): 89–97. http://dx.doi.org/10.1007/s11663-017-1111-9.

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21

Kim, Seong-Woo, Sung-Mo Jung, Chang-Hee Rhee, and Sang-Chul Shim. "Effects of Mn ore on the Dephosphorization and Desulphurization in Hot Metal Pretreatment." steel research international 75, no. 4 (2004): 229–34. http://dx.doi.org/10.1002/srin.200405949.

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22

Isaenko, G. E., V. N. Titov, E. A. Andreeva, V. A. Kobelev, A. G. Nechkin, and D. A. Chernavin. "Estimation of hot metal desulfurization by intermediate and final blast-furnace slag when using pellets of different basicity in blast-furnace charge." Ferrous Metallurgy. Bulletin of Scientific , Technical and Economic Information 79, no. 7 (2023): 559–65. http://dx.doi.org/10.32339/0135-5910-2023-7-559-565.

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n the process of blast-furnace smelting, up to 90% of coke sulfur is captured by the iron ore charge, accumulating in hot metal in the amount that was absorbed from the gas phase. Desulphurization of cast iron occurs when it interacts first with the intermediate, and at the final stage, with the final blast-furnace slag. In this regard, it is of interest to evaluate the desulfurizing properties of the intermediate and final slag, which affect the sulfur content in hot metal. Melting mixtures of pellets of different basicity and sinter in a blast furnace leads to the formation of primary and in

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23

Yang, Annika Fang, Andrey Karasev, and Pär Göran Jönsson. "Effect of Nepheline Syenite on Iron Losses in Slags during Desulphurization of Hot Metal." steel research international 87, no. 5 (2015): 599–607. http://dx.doi.org/10.1002/srin.201500154.

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24

Deo, Brahma, Amlan Datta, Basant Kukreja, Ravi Rastogi, and Kalyanmoy Deb. "Optimization of back propagation algorithm and GAS-assisted ANN models for hot metal desulphurization." Steel Research 65, no. 12 (1994): 528–33. http://dx.doi.org/10.1002/srin.199401206.

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25

Coudure, J. M., and G. A. Irons. "The Effect of Calcium Carbide Particle Size Distribution on the Kinetics of Hot Metal Desulphurization." ISIJ International 34, no. 2 (1994): 155–63. http://dx.doi.org/10.2355/isijinternational.34.155.

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26

Schürmann, Eberhard, and Hans-Martin Delhey. "Thermodynamics of desulphurization reactions during the treatment of hot metal with calcium and calcium compounds." Steel Research 61, no. 2 (1990): 64–71. http://dx.doi.org/10.1002/srin.199000302.

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27

Schürmann, Eberhard, Hans-Martin Delhey, and Peter Kniep. "Reactions of calcium carbide with calcium carbonate and calcium hydroxide during desulphurization of hot metal." Steel Research 61, no. 5 (1990): 204–11. http://dx.doi.org/10.1002/srin.199000333.

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28

Dou, Jin Xiao, Jiang Long Yu, Chao Ling Song, and Feng Kui Yin. "A Review on Research of Carbonaceous and Carbon-Supported Sorbents for Flue Gas Desulfurization." Applied Mechanics and Materials 295-298 (February 2013): 1497–501. http://dx.doi.org/10.4028/www.scientific.net/amm.295-298.1497.

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The development of flue gas desulphurization technologies and the control and reduction of SO2 pollution from coal combustion have become a hot research topic due to environmental concerns. Carbonaceous and carbon supported desulfurizing sorbents have highly porous structures, large specific surface area and low production costs and can be widely used as desulfurizer. This paper provides a comprehensive review of carbonaceous and carbon-based desulfurizing sorbents, including active components, compositions of raw gas and effects of process operation conditions. It can be concluded that the us

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29

Cwudziński, Adam, Jan Falkus, and Angelika Podolska-Loska. "Numerical, Physical, and Industrial Investigations on Hot Metal Desulphurization—From Macromixing Conditions to Reaction Rate Phenomena." Materials 17, no. 23 (2024): 5858. http://dx.doi.org/10.3390/ma17235858.

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The efficiency of the hot metal pretreatment process plays a very important role in achieving high-quality and low-cost advanced steel. From macromixing phenomena obtained by numerical modeling and physical experiments to compound interaction databases from industry trials, the Authors compared fundamental relationships from the literature with their own laboratory results and plant data. A simple numerical model based on the LES turbulence approach was well-validated by water modeling. Hence for a 300-ton ladle, the mixing time and mixing power were predicted. Finally, the mass transfer contr

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30

Niekerk, W. H. Van, and R. J. Dippenaar. "Thermodynamic Aspects of Na2O and CaF2 Containing Lime-based Slags Used for the Desulphurization of Hot-metal." ISIJ International 33, no. 1 (1993): 59–65. http://dx.doi.org/10.2355/isijinternational.33.59.

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31

Sivak, B. A., A. V. Protasov, and L. A. Smirnov. "Review of methods of slag removal from melt surface in hot metal and steel ladles." Ferrous Metallurgy. Bulletin of Scientific , Technical and Economic Information 76, no. 12 (2020): 1243–52. http://dx.doi.org/10.32339/0135-5910-2020-12-1243-1252.

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The removal of slag from melt surface of hot metal and steel ladles is a necessary condition to provide a deep desulphurization and dephosphorization of hot metal and steel in the process of their processing. A review of methods of slag skimming presented, mainly based on slag mechanical shoveling and its removal out of ladles by vacuum sucking. It was shown, that manipulators design for the slag skimming working instrument moving depends on the production scale, mass of the processed heats, amount and properties of the slag to be removed, production process intensity and ecological requiremen

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32

Park, No-Kuk, Dong-Hwal Lee, Jong-Dae Lee, Won‐Chul Chang, Si-Ok Ryu, and Tae-Jin Lee. "Effects of reduction of metal oxide sorbents on reactivity and physical properties during hot gas desulphurization in IGCC." Fuel 84, no. 17 (2005): 2158–64. http://dx.doi.org/10.1016/j.fuel.2005.06.004.

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33

Grillo, F. F., J. L. Coleti, J. R. Oliveira, J. A. S. Tenório, E. Junca, and D. C. R. Espinosa. "Use of Computational Thermodynamics in the Analysis of Hot Metal Desulphurization with Slags Based on Marble Waste and Sodalite." MATERIALS TRANSACTIONS 57, no. 8 (2016): 1332–38. http://dx.doi.org/10.2320/matertrans.m2016016.

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34

Park, No-Kuk, Jong Dae Lee, Tae Jin Lee, Si Ok Ryu, and Chih Hung Chang. "The preparation of a high surface area metal oxide prepared by a matrix-assisted method for hot gas desulphurization." Fuel 84, no. 17 (2005): 2165–71. http://dx.doi.org/10.1016/j.fuel.2005.06.010.

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35

KAWAHARA, Masayasu, Toshiharu MITSUO, Yutaka SASSA, and Kazuhiko KATOH. "Effects of Calcination Conditions on the Reactivity of Burnt Lime whih Water and on the Desulphurization Reaction of Hot Metal." Tetsu-to-Hagane 75, no. 3 (1989): 462–69. http://dx.doi.org/10.2355/tetsutohagane1955.75.3_462.

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36

Chomiak, M., J. Trawczyński, and M. Zawadzki. "Effect of cobalt (nickel) oxide on the properties of zinc–titanium sorbents for high temperature desulphurization of model coal gas." Brazilian Journal of Chemical Engineering 38, no. 3 (2021): 605–16. http://dx.doi.org/10.1007/s43153-021-00129-y.

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AbstractZn–Ti–Co(Ni) sorbents for H2S removal from model hot coal were prepared and characterized. Effects of cobalt (Co) and nickel (Ni) on the sorbents texture, structure, H2S sorption capacity and regeneration properties were determined. TiO2 formed mixed metal oxides with CoO and NiO in the fresh sorbents, while TiO2 and nanocrystalline sulfides of Zn, Co, Ni were found in sulphided ones. The oxidative regeneration of sulphided sorbents re-formed mixed oxides. Sorption capacity of studied materials increased along with an increase of the amount of added Co (Ni) and also with the number of

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37

BAN-YA, Shiro, Mitsutaka HINO, Retsu NAGABAYASHI, and Osamu TERAYAMA. "Dephosphorization and Desulphurization of Hot Metal with CaO-Al₂O₃-Fe_xO_yFlux." Tetsu-to-Hagane 75, no. 1 (1989): 66–73. http://dx.doi.org/10.2355/tetsutohagane1955.75.1_66.

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38

Kislyakov, Volodymyr, Lavr Molchanov, Ivan Manachyn, Artem Pokhvalityi, and Olena Chubina. "COMPARATIVE ANALYSIS OF REAGENTS FOR COMPLEX TREATMENT OF CAST IRON." Collection of scholarly papers of Dniprovsk State Technical University (Technical Sciences) 2, no. 45 (2024): 9–18. https://doi.org/10.31319/2519-2884.45.2024.1.

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The aim of this work is to summarize the results of using various reagents for the comprehensive removal of impurities from molten cast iron. A comparative analysis of the effectiveness of different reagents for cast iron refining was conducted. The use of soda slag as a reagent was tested at the industrial level in a 140-ton hot metal ladle, and the results of experimental treatments were presented. A technology for comprehensive cast iron refining using the CaO-FeO-Na2CO3 reagent system was considered, which is based on the interaction of these components with molten cast iron. Possible chem

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39

Yang, Yindong, Paul Wu, George Men, and Alex McLean. "Hot Metal Desulphurization Using Waste Residues from the Aluminum Industry." High Temperature Materials and Processes 31, no. 4-5 (2012). http://dx.doi.org/10.1515/htmp-2012-0089.

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40

Mazumdar, Dipak, and Stavros Argyropoulos. "Discussion on “Numerical Study of Desulphurization Behavior during Kanbara Reactor Hot Metal Treatment”." Metallurgical and Materials Transactions B, April 1, 2022. http://dx.doi.org/10.1007/s11663-022-02489-3.

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41

Wang, Qiang, Shuyuan Jia, Fangguan Tan, et al. "Response to “Discussion on “Numerical Study of Desulphurization Behavior During Kanbara Reactor Hot Metal Treatment””." Metallurgical and Materials Transactions B, March 11, 2022. http://dx.doi.org/10.1007/s11663-022-02490-w.

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42

"Efficiency of hot metal desulphurization in the production of high quality steel at JSC "Ural Steel"." Russian Internet Journal of Industrial Engineering 1, no. 1 (2013): 34–37. http://dx.doi.org/10.24892/rijie/20130105.

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43

"06/01121 The preparation of a high surface area metal oxide prepared by a matrix-assisted method for hot gas desulphurization." Fuel and Energy Abstracts 47, no. 3 (2006): 170. http://dx.doi.org/10.1016/s0140-6701(06)81125-2.

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