Academic literature on the topic 'HR-ToF-AMS'

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Journal articles on the topic "HR-ToF-AMS"

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Qi, Lu, Mindong Chen, Giulia Stefenelli, et al. "Organic aerosol source apportionment in Zurich using an extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF-MS) – Part 2: Biomass burning influences in winter." Atmospheric Chemistry and Physics 19, no. 12 (2019): 8037–62. http://dx.doi.org/10.5194/acp-19-8037-2019.

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Abstract. Real-time, in situ molecular composition measurements of the organic fraction of fine particulate matter (PM2.5) remain challenging, hindering a full understanding of the climate impacts and health effects of PM2.5. In particular, the thermal decomposition and ionization-induced fragmentation affecting current techniques has limited a detailed investigation of secondary organic aerosol (SOA), which typically dominates OA. Here we deploy a novel extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF-MS) during winter 2017 in downtown Zurich, Switzerland, which o
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Stefenelli, Giulia, Veronika Pospisilova, Felipe D. Lopez-Hilfiker, et al. "Organic aerosol source apportionment in Zurich using an extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF-MS) – Part 1: Biogenic influences and day–night chemistry in summer." Atmospheric Chemistry and Physics 19, no. 23 (2019): 14825–48. http://dx.doi.org/10.5194/acp-19-14825-2019.

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Abstract. Improving the understanding of the health and climate impacts of aerosols remains challenging and is restricted by the limitations of current measurement techniques. Detailed investigation of secondary organic aerosol (SOA), which is typically the dominating fraction of the organic aerosol (OA), requires instrumentation capable of real-time, in situ measurements of molecular composition. In this study, we present the first ambient measurements by a novel extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF-MS). The EESI-TOF-MS was deployed along with a high-r
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Lee, Berto P., Yong Jie Li, Richard C. Flagan, Charles Lo, and Chak K. Chan. "Sizing Characterization of the Fast-Mobility Particle Sizer (FMPS) Against SMPS and HR-ToF-AMS." Aerosol Science and Technology 47, no. 9 (2013): 1030–37. http://dx.doi.org/10.1080/02786826.2013.810809.

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Bhattu, Deepika, S. N. Tripathi, and Abhishek Chakraborty. "Deriving aerosol hygroscopic mixing state from size-resolved CCN activity and HR-ToF-AMS measurements." Atmospheric Environment 142 (October 2016): 57–70. http://dx.doi.org/10.1016/j.atmosenv.2016.07.032.

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Rollins, A. W., J. L. Fry, J. F. Hunter, et al. "Elemental analysis of aerosol organic nitrates with electron ionization high-resolution mass spectrometry." Atmospheric Measurement Techniques 3, no. 1 (2010): 301–10. http://dx.doi.org/10.5194/amt-3-301-2010.

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Abstract. Four hydroxynitrates (R(OH)R'ONO2) representative of atmospheric volatile organic compound (VOC) oxidation products were synthesized, nebulized and sampled into an Aerodyne High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS). The resulting mass spectrum was used to evaluate calibration factors for elemental analysis of organic nitrates by AMS, and to determine the distribution of nitrogen in the detected fragments in a search for an AMS signature of organic nitrates. We found that 30% of the detected nitrogen mass is in the NO+ and NO2+ fragments, 12% at NHx+ fragme
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Rollins, A. W., J. L. Fry, J. F. Hunter, et al. "Elemental analysis of aerosol organic nitrates with electron ionization high-resolution mass spectrometry." Atmospheric Measurement Techniques Discussions 2, no. 5 (2009): 2781–807. http://dx.doi.org/10.5194/amtd-2-2781-2009.

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Abstract. Four hydroxynitrates (R(OH)R'ONO2) representative of atmospheric volatile organic compound (VOC) oxidation products were synthesized, nebulized and sampled into an Aerodyne High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS). The resulting mass spectrum was used to evaluate calibration factors for elemental analysis of organic nitrates by AMS, and to determine the distribution of nitrogen in the detected fragments in a search for an AMS signature of organic nitrates. We find that 30% of the detected nitrogen mass is in the NO+ and NO2+ fragments, 12% at NHx+ fragmen
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Xu, L., S. Suresh, H. Guo, R. J. Weber, and N. L. Ng. "Aerosol characterization over the southeastern United States using high resolution aerosol mass spectrometry: spatial and seasonal variation of aerosol composition, sources, and organic nitrates." Atmospheric Chemistry and Physics Discussions 15, no. 7 (2015): 10479–552. http://dx.doi.org/10.5194/acpd-15-10479-2015.

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Abstract. We deployed a High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) and an Aerosol Chemical Speciation Monitor (ACSM) to characterize the chemical composition of submicron non-refractory particles (NR-PM1) in the southeastern US. Measurements were performed in both rural and urban sites in the greater Atlanta area, GA and Centreville, AL for approximately one year, as part of Southeastern Center of Air Pollution and Epidemiology study (SCAPE) and Southern Oxidant and Aerosol Study (SOAS). Organic aerosol (OA) accounts for more than half of NR1 mass concentration regar
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Xu, L., S. Suresh, H. Guo, R. J. Weber, and N. L. Ng. "Aerosol characterization over the southeastern United States using high-resolution aerosol mass spectrometry: spatial and seasonal variation of aerosol composition and sources with a focus on organic nitrates." Atmospheric Chemistry and Physics 15, no. 13 (2015): 7307–36. http://dx.doi.org/10.5194/acp-15-7307-2015.

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Abstract. We deployed a High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) and an Aerosol Chemical Speciation Monitor (ACSM) to characterize the chemical composition of submicron non-refractory particulate matter (NR-PM$_{1}$) in the southeastern USA. Measurements were performed in both rural and urban sites in the greater Atlanta area, Georgia (GA), and Centreville, Alabama (AL), for approximately 1 year as part of Southeastern Center for Air Pollution and Epidemiology study (SCAPE) and Southern Oxidant and Aerosol Study (SOAS). Organic aerosol (OA) accounts for more than h
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Ma, Mutian, Laura-Hélèna Rivellini, YuXi Cui, et al. "Elemental analysis of oxygenated organic coating on black carbon particles using a soot-particle aerosol mass spectrometer." Atmospheric Measurement Techniques 14, no. 4 (2021): 2799–812. http://dx.doi.org/10.5194/amt-14-2799-2021.

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Abstract. Chemical characterization of organic coatings is important to advance our understanding of the physio-chemical properties and environmental fate of black carbon (BC) particles. The soot-particle aerosol mass spectrometer (SP-AMS) has been utilized for this purpose in recent field studies. The laser vaporization (LV) scheme of the SP-AMS can heat BC cores gradually until they are completely vaporized, during which organic coatings can be vaporized at temperatures lower than that of the thermal vaporizer (TV) used in a standard high-resolution time-of-flight aerosol mass spectrometer (
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Jensen, Louise N., Manjula R. Canagaratna, Kasper Kristensen та ін. "Temperature and volatile organic compound concentrations as controlling factors for chemical composition of <i>α</i>-pinene-derived secondary organic aerosol". Atmospheric Chemistry and Physics 21, № 15 (2021): 11545–62. http://dx.doi.org/10.5194/acp-21-11545-2021.

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Abstract. This work investigates the individual and combined effects of temperature and volatile organic compound precursor concentrations on the chemical composition of particles formed in the dark ozonolysis of α-pinene. All experiments were conducted in a 5 m3 Teflon chamber at an initial ozone concentration of 100 ppb and initial α-pinene concentrations of 10 and 50 ppb, respectively; at constant temperatures of 20, 0, or −15 ∘C; and at changing temperatures (ramps) from −15 to 20 and from 20 to −15 ∘C. The chemical composition of the particles was probed using a high-resolution time-of-fl
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Dissertations / Theses on the topic "HR-ToF-AMS"

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Vesin, Aude. "Suivi temportel des niveaux de concentration en atmosphère intérieure lors de l'application d'insecticides ménagers." Thesis, Aix-Marseille, 2013. http://www.theses.fr/2013AIXM4710/document.

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L'étude du comportement dynamique des substances actives pendant l'épandage de produits insecticides ménagers commerciaux dans les atmosphères intérieures nécessite le développement et l'adaptation de procédures analytiques de mesure en ligne ayant une résolution temporelle élevée. Un HS-PTR-MS et un HR-ToF-AMS ont par conséquent été utilisés pour mesurer les contaminants à la fois en phase gazeuse et particulaire. Les substances actives ciblées par cette étude appartiennent à la famille des pyréthrinoïdes, présentes dans différentes formulations commerciales du type diffuseurs électriques et
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Faber, Peter [Verfasser]. "Chemische und physikalische Charakterisierung von Aerosolpartikeln aus besonderen anthropogenen Emissionsquellen : ein integrativer Ansatz mittels online (HR-ToF-AMS)- und komplementärer offline (ATR-FTIR-Spektroskopie)-Analytik / Peter Faber." Mainz : Universitätsbibliothek Mainz, 2015. http://d-nb.info/1071827197/34.

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