Academic literature on the topic 'Hydriolic acid'

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Journal articles on the topic "Hydriolic acid"

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Liu, Zhengchun, Alessandro Granata, Xinhua Shen, and Arthur S. Perlin. "Reactions of hydriodic acid with aldonolactones and n-alkanolactones. Interconversions between lactones and iodocarboxylic acids." Canadian Journal of Chemistry 70, no. 7 (July 1, 1992): 2081–88. http://dx.doi.org/10.1139/v92-264.

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Aldonolactones containing from four to eight carbon atoms, and lactones of the related monohydroxy-n-alkanoic acids, were subjected to reaction with 57% hydriodic acid at 125 °C. As in the classical studies of Kiliani, the reduction of D-glycero-D-ido-heptono-1,4-lactone yielded mainly γ-heptanolactone. Analogously, the corresponding γ-alkanolactones were obtained as major products from the 1,4-lactones of the D-xylono-, D-allono-, and D-erythro-L-talo-octono configuration. Monoiodo-n-alkanoic acids were also formed in admixture with the lactones in all of these reactions. D-Erythrono-1,4-lactone was unique among the aldonolactones in that it led only to an acid, i.e., 3-iodo-n-butanoic acid. The latter was also the product of the non-reductive reaction of hydriodic acid with β-butyrolactone whereas, by contrast, γ-butyrolactone afforded 4-iodobutanoic acid. Among compounds in the five to eight carbon series, it was found that under conditions close to equilibrium the ratio of lactone to iodoacid decreased progressively with the length of the carbon chain; e.g., in the 4 h reactions of γ-valero-, γ-capro-, γ-heptano-, and γ-octanolactone, the ratios were 2.4, 1.2, 0.2, and 0.1, respectively. An accompanying characteristic of these reactions is a progression in the number of isomeric iodoacids formed. Whereas γ-valerolactone was accompanied by 4-iodopentanoic acid, there were two isomers (4- and 5-) of iodohexanoic acid, three monoiodo- (including 6-iodo-) heptanoic acids, and four (including 7-iodo-) octanoic acids. In all instances, the isomer substituted at the penultimate carbon was major. An interplay of several individual reactions, including ring-opening displacements, eliminations–additions, and rearrangements, as well as a probable influence of entropy changes on the lactone-acid equilibria, appear to account largely for these observations.
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Oksuz, Melik, and H. Yildirim Erbil. "Wet-spun graphene filaments: effect of temperature of coagulation bath and type of reducing agents on mechanical & electrical properties." RSC Advances 8, no. 31 (2018): 17443–52. http://dx.doi.org/10.1039/c8ra02325e.

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Greenberg, Fred H. "Reaction of Dibenzoylethylene with Hydriodic Acid." Journal of Chemical Education 77, no. 4 (April 2000): 505. http://dx.doi.org/10.1021/ed077p505.

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Ardo, Shane, Sang Hee Park, Emily L. Warren, and Nathan S. Lewis. "Unassisted solar-driven photoelectrosynthetic HI splitting using membrane-embedded Si microwire arrays." Energy & Environmental Science 8, no. 5 (2015): 1484–92. http://dx.doi.org/10.1039/c5ee00227c.

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HODOTSUKA, Masatoshi, Xiaoyong YANG, and Hiroyuki OKUDA. "ICONE15-10169 STUDY ON VAPOR-LIQUID EQUILIBRIUM OF HYDRIODIC ACID FOR THERMOCHEMICAL HYDROGEN PRODUCTION IS PROCESS." Proceedings of the International Conference on Nuclear Engineering (ICONE) 2007.15 (2007): _ICONE1510. http://dx.doi.org/10.1299/jsmeicone.2007.15._icone1510_71.

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Dobmeier, Michael, Josef M. Herrmann, Dieter Lenoir, and Burkhard König. "Reduction of benzylic alcohols and α-hydroxycarbonyl compounds by hydriodic acid in a biphasic reaction medium." Beilstein Journal of Organic Chemistry 8 (March 2, 2012): 330–36. http://dx.doi.org/10.3762/bjoc.8.36.

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The synthetic protocol for the reduction of alcohols to hydrocarbons by using hydriodic acid, first described by Kiliani more than 140 years ago, was improved to be more applicable to organic synthesis. Instead of a strongly acidic, aqueous solution, a biphasic toluene–water reaction medium was used, which allowed the conversion of primary, secondary and tertiary benzylic alcohols, in good yields and short reaction times, into the corresponding hydrocarbons. Red phosphorous was used as the stoichiometric reducing agent. Keto, ester, amide or ether groups are tolerated, and catalytic amounts of hydriodic acid (0.2 equiv) in the presence of 0.6 equiv phosphorous are sufficient to achieve conversion.
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Zhu, Weiguang, Guoqing Xin, Yiping Wang, Xin Min, Tiankai Yao, Wenqian Xu, Minghao Fang, Sufei Shi, Jian Shi, and Jie Lian. "Tunable optical properties and stability of lead free all inorganic perovskites (Cs2SnIxCl6−x)." Journal of Materials Chemistry A 6, no. 6 (2018): 2577–84. http://dx.doi.org/10.1039/c7ta10040j.

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Cs2SnIxCl6−x perovskites were synthesized using hydriodic acid as an iodine source, and the color scheme displays a tunable band gap with varying I/Cl ratios.
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Onuki, Kaoru, Gab-Jin Hwang, and Saburo Shimizu. "Electrodialysis of hydriodic acid in the presence of iodine." Journal of Membrane Science 175, no. 2 (August 2000): 171–79. http://dx.doi.org/10.1016/s0376-7388(00)00415-4.

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Lionelli, G. T., E. J. Pickus, J. G. Bray, W. T. Lawrence, and R. A. Korentager. "Myoglobinuria and Hypocalcemia After a Superficial Hydriodic Acid Burn." Journal of Burn Care & Rehabilitation 22, no. 5 (September 2001): 341–45. http://dx.doi.org/10.1097/00004630-200109000-00009.

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Miethchen, Ralf, Andreas Schmidt, Katharina Neitzel, Manfred Michalik, Thomas Pundt, and Wolfgang Ruth. "Concentrated hydriodic acid in simultaneous deprotections of multifunctional inositols." Carbohydrate Research 340, no. 4 (March 2005): 741–48. http://dx.doi.org/10.1016/j.carres.2004.11.031.

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Dissertations / Theses on the topic "Hydriolic acid"

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Ng, Dixon C. "Wood liquefaction with hydriodic acid." Thesis, McGill University, 1985. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=65993.

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Ladanowski, Catherine. "Liquefaction of wood with hydriodic acid in a continuous reactor." Thesis, McGill University, 1986. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=66221.

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Darwiche, Ali. "Membranes zéolithiques de type MFI pour l'extraction et la séparation de l'hydrogène." Thesis, Mulhouse, 2010. http://www.theses.fr/2010MULH3174.

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Cette étude se situe dans le cadre des recherches menées par le CEAEA sur la production massive d'hydrogène, sans émission de gaz à effet de serre, via un cycle thermo-chimique de décomposition de l'eau couplé à une source de chaleur à haute température d'origine nucléaire. Dans le cas particulier du cycle dit« Iode-Soufre», on doit extraire H2 à partir d'un mélange H2/HI/H20 très corrosif, opération pour laquelle des procédés membranaires ont été proposés. L'objectif de ce travail est le développement de membranes zéolithiques de type MFI susceptibles d'être utilisées dans ce contexte. Nous présentons les différents matériaux utilisés, la méthodologie de synthèse de couches minces de Silicalite-1 et de ZSM-5 synthétisée sans structurant organique, les techniques de caractérisation des membranes. Une étude cinétique nous a permis d'optimiser et de contrôler les conditions d'obtention de ces couches minces déposées sur des substrats tubulaires en Ti02 et plans en Al2O3-α. De nombreuses expériences de perméation ont été réalisées, pour des gaz simples (H2, He, Ar, N 2, C02, SF6) et des mélanges gazeux (H2/H20/Ar) et (H2/H20/HI/Ar). Les effets de la température, de la pression amont, de l'épaisseur et de la longueur de la couche mince ainsi que du gaz vecteur ont été étudiés en détail. Il apparaît que la présence de molécules d'H20 dans le système joue un rôle prépondérant sur la perméation des autres molécules
In the general context of massive and "carbon free" hydrogen production studies, the aim of this work was the development of zeolitic MFI membranes for hydrogen extraction and separation. The methodology of synthesis, the membranes characterization techniques as well as the permeation experimental setup are presented. Optimization and control of the elaboration of Ti02 supported Silicalite-1 and template free ZSM-5 membranes have been reached. Details of the full kinetic study that we performed are given. Numerous permeation experiments, involving pure gas (H2, He, Ar, N2, C02, SF6) and mixtures (H2/H20/Ar) and (H2/H 20/HI/Ar) have been carried on. The effects of temperature, feed pressure, thickness and length of the membranes, as well as the role of the sweeping gas have been emphasized. In the case of gas mixtures, the presence of H20 molecules appears to be a predominant factor
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陳志安. "Iodination with Potassium Permanganate/ Hydriodic Acid/ Acetonitrile Reagent." Thesis, 1994. http://ndltd.ncl.edu.tw/handle/94956554273408418076.

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碩士
國立臺灣師範大學
化學學系
82
Homogeneous solution of potassium permanganate/hydriodic acid/acetonitrile has been found as a mild iodination reagent. At room temperture or below, using a molar ratio of KMnO4: HI: substrate at 1:5:4 aryliodination was completed within twelve hours for various aromatic amines, monosubstituted products were obtained in good yeilds (71-78%).   This reagent is also applicable for the iodination of alkynes. With the molar ratio of KMnO4:HI:substrate of 3:25:10 at 60℃, addition to alkynes took place and the diiodo-substituted alkenes were obtained in yields of 65% to 87%. Contrary to the results obtained from iodine addtion to alkynes, this reaction is stereospecific. Terminal alkynes gave only (E)-diiodo-substituted alkenes and internal alkynes led only to the (Z) diiodo-substituted alkenes. The stereochemistry of the products were determined by comparison of the 13C nuclear magnetic resonance data with known compounds and also by reported by R. A. Hollins.   The KMnO4/HBr/CH3CN is useful for the α-brominatin of carbonyl compounds. Monobrominated compounds were obtained as the major products in good yeilds (42-92%). For the 1, 3-dicarbonyl compounds, reaction could be completed within twenty minutes, leading to high yield of α-brominated products.
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Books on the topic "Hydriolic acid"

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Bell, James Munsie. The compensation method of determining the rate of oxidation of hydrogen iodide. Toronto: [s.n.], 1995.

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The induction by ferrous salts of the reaction between chromic and hydriodic acids. [Toronto]: University library ; pub. by the Librarian, 1995.

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Book chapters on the topic "Hydriolic acid"

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Heisig, G. B., O. C. Frykholm, E. R. Caley, and M. G. Burford. "Hydriodic Acid." In Inorganic Syntheses, 157–62. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132326.ch54.

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Foster, L. S., H. G. Nahas, and Edgar E. Lineken. "Hydriodic Acid: Regeneration of Oxidized Solutions." In Inorganic Syntheses, 210–12. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132333.ch65.

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Härtinger, S. "Cleavage with Hydriodic Acid." In Chlorine, Bromine, and Iodine, 1. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-035-00521.

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Härtinger, S. "Iodination with Hydriodic Acid." In Chlorine, Bromine, and Iodine, 1. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-035-00537.

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Härtinger, S., and M. Härtinger. "Synthesis from Haloalkanes with Hydriodic Acid." In Chlorine, Bromine, and Iodine, 1. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-035-00501.

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Gwyther, J. R., and D. J. Turner. "68. Volatility of hydriodic acid in steam." In Water chemistry of nuclear reactor systems 5, 1: 289–294. Thomas Telford Publishing, 1989. http://dx.doi.org/10.1680/wconrs5v1.15470.0043.

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Härtinger, S. "Iodination with Metal Iodides and Acid as a Source of Hydriodic Acid." In Chlorine, Bromine, and Iodine, 1. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-035-00538.

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Conference papers on the topic "Hydriolic acid"

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Terada, Atsuhiko, Jin Iwatsuki, Hirokaki Takegami, Shinji Kubo, Nariaki Sakaba, and Kaoru Onuki. "Research and Development on Hydrogen Production by Thermochemical Water-Splitting IS Process." In Fourth International Topical Meeting on High Temperature Reactor Technology. ASMEDC, 2008. http://dx.doi.org/10.1115/htr2008-58088.

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A project using the High Temperature Engineering Test Reactor (HTTR) is being proceeded at the Japan Atomic Energy Agency (JAEA), which aims to develop technologies of nuclear production of hydrogen to meet its massive demand in future. The HTTR with thermal power of 30MW is the Japanese high-temperature gas-cooled reactor (HTGR), built and operated at the site of the Oarai Research & Development Center of JAEA. Under the HTTR project, JAEA has been conducting research and development on thermochemical IS process aiming to reach its final goal of demonstrating the nuclear hydrogen production by an HTTR-IS system. The IS process is a chemical process composed of three reactions, i.e. hydrogen iodide decomposition, sulfuric acid decomposition, and production of hydrogen iodide and sulfuric acid. JAEA completed one-week continuous hydrogen production using a glass-made bench-scale test apparatus equipped with an automatic control system in 2004, where the hydrogen production rate was about 30 NL/hr. Based on the successful test, present activity focuses on the development of components to be used in the corrosive process environments and, also, of technologies to realize high thermal efficiency of hydrogen production. This paper describes present status of the activities such as conceptual design of a test plant driven by sensible heat of helium gas heated by an electric heater simulating the HTTR, and component tests for service in the corrosive environments of high temperature sulfuric acid. Also, R&D results are described on glass lining technologies and a reliability evaluation of components made of SiC ceramics, which are promising candidates for application to, e.g. the sulfuric acid decomposer and the hydriodic acid distillation column.
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