Academic literature on the topic 'Hydrogen evolution reaction'

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Journal articles on the topic "Hydrogen evolution reaction"

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Jeon, Dasom, Jinwoo Park, Changhwan Shin, Hyunwoo Kim, Ji-Wook Jang, Dong Woog Lee, and Jungki Ryu. "Superaerophobic hydrogels for enhanced electrochemical and photoelectrochemical hydrogen production." Science Advances 6, no. 15 (April 2020): eaaz3944. http://dx.doi.org/10.1126/sciadv.aaz3944.

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The efficient removal of gas bubbles in (photo)electrochemical gas evolution reactions is an important but underexplored issue. Conventionally, researchers have attempted to impart bubble-repellent properties (so-called superaerophobicity) to electrodes by controlling their microstructures. However, conventional approaches have limitations, as they are material specific, difficult to scale up, possibly detrimental to the electrodes’ catalytic activity and stability, and incompatible with photoelectrochemical applications. To address these issues, we report a simple strategy for the realization of superaerophobic (photo)electrodes via the deposition of hydrogels on a desired electrode surface. For a proof-of-concept demonstration, we deposited a transparent hydrogel assembled from M13 virus onto (photo)electrodes for a hydrogen evolution reaction. The hydrogel overlayer facilitated the elimination of hydrogen bubbles and substantially improved the (photo)electrodes’ performances by maintaining high catalytic activity and minimizing the concentration overpotential. This study can contribute to the practical application of various types of (photo)electrochemical gas evolution reactions.
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Chen, Ziyao, Huai Qin Fu, Mengyang Dong, Yu Zou, Porun Liu, and Huijun Zhao. "Hydrogen Spillover in Electrochemical Hydrogen Evolution Reaction." General Chemistry 8, no. 3-4 (2022): 220007. http://dx.doi.org/10.21127/yaoyigc20220007.

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Eftekhari, Ali. "Electrocatalysts for hydrogen evolution reaction." International Journal of Hydrogen Energy 42, no. 16 (April 2017): 11053–77. http://dx.doi.org/10.1016/j.ijhydene.2017.02.125.

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Li, Hao, Zhien Zhang, and Zhijian Liu. "Non-Monotonic Trends of Hydrogen Adsorption on Single Atom Doped g-C3N4." Catalysts 9, no. 1 (January 14, 2019): 84. http://dx.doi.org/10.3390/catal9010084.

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To estimate the reaction free energies of the hydrogen evolution reaction (HER) on under-coordinated metallic sites, density function theory (DFT) calculations are usually employed to calculate the hydrogen adsorption energy with an “only-one-hydrogen-adsorption” model, assuming that adsorption with one hydrogen is the most thermodynamically favorable situation during catalysis. In this brief report, we show that on many single atom sites, adsorption of more than one hydrogen is sometimes even more thermodynamically favorable, with the presence of two or three hydrogens resulting in lower adsorption energies. These interesting non-monotonic trends indicate that modeling HER and other hydrogen-related reactions on under-coordinated sites should also consider the numbers of hydrogen being adsorbed at the same site, otherwise the results could deviate from real experimental situations.
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Lin, Shiru, Haoxiang Xu, Yekun Wang, Xiao Cheng Zeng, and Zhongfang Chen. "Directly predicting limiting potentials from easily obtainable physical properties of graphene-supported single-atom electrocatalysts by machine learning." Journal of Materials Chemistry A 8, no. 11 (2020): 5663–70. http://dx.doi.org/10.1039/c9ta13404b.

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The oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER) are three critical reactions for energy-related applications, such as water electrolyzers and metal–air batteries.
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Wu, Hengbo, Jie Wang, Wei Jin, and Zexing Wu. "Recent development of two-dimensional metal–organic framework derived electrocatalysts for hydrogen and oxygen electrocatalysis." Nanoscale 12, no. 36 (2020): 18497–522. http://dx.doi.org/10.1039/d0nr04458j.

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Developing efficient and low-cost electrocatalysts with unique nanostructures is of great significance for improved electrocatalytic reactions, including the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR).
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Sui, Chenxi, Kai Chen, Liming Zhao, Li Zhou, and Qu-Quan Wang. "MoS2-modified porous gas diffusion layer with air–solid–liquid interface for efficient electrocatalytic water splitting." Nanoscale 10, no. 32 (2018): 15324–31. http://dx.doi.org/10.1039/c8nr04082f.

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The formation and adsorption of bubbles on electrodes weaken the efficiency of gas evolution reactions such as the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) by hindering proton transfer and consuming nucleation energy.
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Yu, Xiaomei, Wei Shi, Jiajiao Wei, Tiantian Liu, Yuanyuan Li, Mengyuan He, Zhengyu Wei, et al. "Green fabrication of ultrafine N-Mo x C/CoP hybrids for boosting electrocatalytic water reduction." Nanotechnology 35, no. 6 (November 22, 2023): 065704. http://dx.doi.org/10.1088/1361-6528/ad0985.

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Abstract Developing non-noble-metal electrocatalysts for hydrogen evolution reactions with high activity and stability is the key issue in green hydrogen generation based on electrolytic water splitting. It has been recognized that the stacking of large CoP particles limits the intrinsic activity of as-synthesized CoP catalyst for hydrogen evolution reaction. In the present study, N-Mo x C/CoP-0.5 with excellent electrocatalytic activity for hydrogen evolution reaction was prepared using N-Mo x C as decoration. A reasonable overpotential of 106 mV (at 10 mA cm−2) and a Tafel slope of 59 mV dec−1 in 1.0 M KOH solution was achieved with N-Mo x C/CoP-0.5 electrocatalyst, which exhibits superior activity even after working for 37 h. Uniformly distributed ultrafine nanoclusters of the N-Mo x C/CoP-0.5 hybrids could provide sufficient interfaces for enhanced charge transfer. The effective capacity of the hydrogen evolution reaction could be preserved in the complex, and the enlarged electrocatalytic surface area could be expected to offer more active sites for the reaction.
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Dong, Ying, Jing Li, and Xiao-Yu Yang. "Cu catalysts detour hydrogen evolution reaction." Matter 5, no. 8 (August 2022): 2537–40. http://dx.doi.org/10.1016/j.matt.2022.06.057.

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Stanković, S., B. N. Grgur, B. Jović, N. Krstajić, O. Pavlović, and M. Vojnović. "Hydrogen Evolution Reaction from EDTA Solutions." Materials Science Forum 413 (September 2002): 185–90. http://dx.doi.org/10.4028/www.scientific.net/msf.413.185.

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Dissertations / Theses on the topic "Hydrogen evolution reaction"

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Zhou, Leyao. "Electroless Deposited Transitional Metal Phosphide for Oxygen/Hydrogen Evolution Reactions." University of Akron / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=akron1522333083629295.

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Karimi, Shervedani Reza. "Kinetics of hydrogen evolution reaction on Ni-Me-P electrodes." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/nq26382.pdf.

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Shervedani, Reza Karimi. "Kinetics of hydrogen evolution reaction on Ni-Me-P electrodes." Thèse, Sherbrooke : Université de Sherbrooke, 1997. http://savoirs.usherbrooke.ca/handle/11143/4954.

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Luo, Lin. "Novel Nanostructure Electrocatalysts for Oxygen Reduction and Hydrogen Evolution Reactions." University of the Western Cape, 2019. http://hdl.handle.net/11394/7315.

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Philosophiae Doctor - PhD
The widespread use of fossil energy has been most convenient to the world, while they also cause environmental pollution and global warming. Therefore, it is necessary to develop clean and renewable energy sources, among which, hydrogen is considered to be the most ideal choice, which forms the foundation of the hydrogen energy economy, and the research on hydrogen production and fuel cells involved in its production and utilization are naturally a vital research endeavor in the world. Electrocatalysts are one of the key materials for proton exchange member fuel cells (PEMFCs) and water splitting. The use of electrocatalysts can effectively reduce the reaction energy barriers and improve the energy conversion efficiency.
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Wright, Edward Anthony. "A study of the hydrogen evolution reaction on platinum group metals." Thesis, University of Exeter, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.414258.

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Lee, Heung Chan. "Magnetic field effects on electron transfer reactions: heterogeneous photoelectrochemical hydrogen evolution and homogeneous self exchange reaction." Diss., University of Iowa, 2010. https://ir.uiowa.edu/etd/2562.

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Magnetic field effects (MFE) on electrochemical systems have been of interest to researchers for the past 60 years. MFEs on mass transport, such as magnetohydrodynamics and magnetic field gradients effects are reported, but MFEs on electron transfer kinetics have been rarely investigated. Magnetic modification of electrodes enhances electron transfer kinetics under conditions of high concentrations and low physical diffusion conditions, as shown by Leddy and coworkers. Magnetic microparticles embedded in an ion exchange polymer (e.g., Nafion) applied to electrode surfaces. Rates of electron transfer reactions to diffusing redox probes and to adsorbates are markedly enhanced. This work reports MFEs on hydrogen evolution on illuminated p-Si; MFEs on hydrogen evolution on noncatalytic electrodes; a model for MFEs on homogeneous self-exchange reactions; and a convolution based voltammetric method for film modified electrodes. First, a MFE on the photoelectrochemical hydrogen evolution reaction (HER) at p-Si semiconductors is demonstrated. The HER is an adsorbate reaction. Magnetic modification reduces the energetic cost of the HER by 400 - 500 mV as compared to Nafion modified electrodes and by 1200 mV as compared to unmodified p-Si. Magnetically modified p-Si achieves 6.2 % energy conversion efficiency. Second, from HER on noncatalytic electrodes, the MFE on photoelectrochemical cells arises from improved heterogeneous electron transfer kinetics. On glassy carbon electrodes, magnetic modification improves heterogeneous electron transfer rate constant, k₀,for HER 80,000 fold. Third, self exchange reaction rates are investigated under magnetic modification for various temperatures, outersphere redox probes, and magnetic particles. Arrhenius analyses of the rate constants collected from the experiments show a 30 - 40 % decrease in activation energy at magnetically modified electrodes. A kinetic model is established based on transition state theory. The model includes pre-polarization and electron nuclear spin polarization steps and characterizes a majority of the experimental results. Lastly, a convolution technique for modified with uniform films electrodes is developed and coded in Matlab (mathematical software) for simple and straightforward analysis of Nafion modified electrodes.
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Zou, Yu. "Supported Composite Electrocatalysts for Energy Conversion Applications." Thesis, Griffith University, 2022. http://hdl.handle.net/10072/417198.

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Increasing energy demand and environmental awareness have promoted the development of efficient and environment-friendly hydrogen technologies. Water electrolysis (2𝐻2𝑂→2𝐻2+𝑂2) is a promising way to store renewable electricity generated by solar or wind energy into chemical fuel in the form of H2. Water electrolysis is comprised of a hydrogen evolution reaction (HER) on the cathode and an oxygen evolution reaction (OER) on the anode. For both HER and OER, highly catalytic active electrocatalysts are required to lower the overpotentials and to speed up the sluggish kinetics. To date, noble metal catalysts are still the most efficient electrocatalysts for these two reactions, but their high cost and low abundance on Earth limit the scalable application of water electrolysis. Therefore, investigation of alternative catalysts with low cost and high electrocatalytic activity is urgently needed. This thesis focuses on alkaline electrocatalytic HER, as well as related reactions such as OER, and hydrazine oxidation(HzOR)-assistant HER. In terms of material design, the components are introduced to improve conductivity and mass transfer, as well as boost the intrinsic catalytic activity. Moreover, the mechanism was investigated through exploring the link between structure and performance, as well using density functional theory (DFT) calculations. The first two experimental chapters employed a two-dimensional (2D) material, MXene, as support. In Chapter 2, ruthenium single atoms were incorporated onto ultrathin Ti3C2Tx MXene nanosheets to unlock its electrocatalytic activity. The RuSA@Ti3C2Tx presented a 1 A cm−2 HER current density with an over potential of 425.7 mV, outperforming the commercial Pt/C benchmark. Operando Raman test under HER potential showed the different protonation level between RuSA@Ti3C2Tx and Ti3C2Tx, suggesting the different hydrogen absorption energy of the oxygen terminal on the Ti3C2Tx basal plane. Finally, the theoretical calculations confirmed that the RuSA not only facilitates water dissociation, but also modulates the hydrogen After increasing the Ru content and conducting electroreduction, RuTi alloy nanoclusters were constructed on the surface of Ti3C2Tx. Surprisingly, the RuTi@Ti3C2Tx showed better performance in HER, and excellent hydrazine oxidation reaction (HzOR) performance. The overpotential to attain a current density of 10 mA cm−2 for HER was only 14 mV, lower than that of the commercial Pt/C. The HzOR catalytic activity also outperformed most reported work. In addition, the overall hydrazine spitting was conducted in an H-type electrolytic cell, demonstrating superior thermodynamic advantage and good stability. Defect-abundant active carbon (AC-DCD) as support was prepared by the hydrothermal reaction with dicyanamide. Then, the Ru nanoparticles were grown on the surface. Compared to the catalyst with pristine AC as support prepared under same conditions, Ru600@AC-DCD presented a larger electrochemical special area with strain-abundant Ru nanoparticles. Ru600@AC-DCD delivered excellent HER performance in alkaline media, and good catalytic properties in acidic and neutral media. Finally, another novel metal@carbon composite, Ni nanoparticles encapsulated in graphite carbon layers, was synthesized by directly annealing the Ni-imidazole framework precursors at 350 °C in H2/Ar. By tuning the annealing time under H2/Ar flow, Ni nanoparticles with different crystalline phases were synthesized. These Ni@C samples are di-function electrocatalysts for HER and OER in alkaline condition. The mixed-phase catalyst mix2-Ni@C delivered the highest activity to catalyze HER, while the pure hcp phase catalyst hcp-Ni@C showed best OER activity. This work provided a practical method to prepare low-cost difunctional electrocatalysts for overall water electrolysis. In summary, the thesis innovatively contributes to the knowledge in material science and water electrolysis in the aspects of: (i) designing novel supported composite electrocatalysts with high catalytic activity for HER, OER, and HzOR; (ii) monitoring the changing of surface terminal by operando Raman spectroscopy to verify the HER mechanism; (iii) development of metal nanostructures, like RuTi alloy, hcp phase Ni and mixed-phase Ni, via facile methods, and investigation of their unique properties; and (iv) application of large current HER and exploration of the kinetics under different potentials.
Thesis (PhD Doctorate)
Doctor of Philosophy (PhD)
School of Environment and Sc
Science, Environment, Engineering and Technology
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Xing, Shihui. "Rational design of bi-transition metal oxide electrocatalysts for hydrogen and oxygen evolutions." Thesis, Queensland University of Technology, 2021. https://eprints.qut.edu.au/209307/1/Shihui_Xing_Thesis.pdf.

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This thesis mainly focuses on the rational design and preparation of bi-transition metal oxide materials for high-performance electrochemical catalysis, such as hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). To address the challenges of sluggish kinetics and large overpotentials in HER and OER, the effective strategy of morphology engineering, introducing a secondary metal element and supporting on carbon-based materials were carried out and discussed.
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Anthony, David M. "Effects of cyclic current modulation on cathode materials for the hydrogen evolution reaction." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape11/PQDD_0003/MQ40982.pdf.

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Smale, Simon. "Study of the hydrogen evolution reaction on platinum and platinum group metal surfaces." Thesis, Cardiff University, 2008. http://orca.cf.ac.uk/54760/.

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The hydrogen evolution reaction (HER) has been examined on a variety of Pt and Pt-group metal surfaces to investigate the rate of the reaction. Pt stepped single crystal surfaces were investigated in relation to the HER using cyclic voltammetry, linear sweep voltammetry and multi-frequency AC voltammetry. It was found that the hydrogen evolution reaction activity did not show a dependence on the structure of single crystal platinum electrode surfaces. Thick films of Au, Rh and Pd were deposited onto Pt {111} and successfully annealed to give pseudomorphic surfaces of the bulk metal. The aim of such measurements was to investigate whether strains within the crystal lattice of these films would result in enhanced HER activity. None of the surfaces investigated showed significant HER enhancement. Rather, results similar to those observed using the bulk metals were obtained. Rough Ir and Pt deposits on Pt{111} were also investigated. Enhanced HER activity was observed on these surfaces. This enhancement was interpreted in terms of the structural arrangement of the Ir and Pt deposits. For Pd films on Pt {111} (0 < fVPd < 2 monolayers) it was observed that Pt dominated the HER kinetics for Pd coverages up to one monolayer and was still influential on the HER at two monolayers of Pd. Similarly Pd-Pt surface alloys also showed that Pd had little or no influence on the HER kinetics even with 75 % Pd in the surface layer. Possible mechanisms for this behaviour have been proposed, in particular, the role of subsurface hydrogen in HER on Pt is discussed.
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Books on the topic "Hydrogen evolution reaction"

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Cheuk, Roger. Sputtering nickel and nickel-molybdenum as electrocatalysts for the hydrogen evolution reaction. Ottawa: National Library of Canada, 1995.

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Anthony, David M. Effects of cyclic current modulation on cathode materials for the hydrogen evolution reaction. Ottawa: National Library of Canada, 1998.

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Lian, Ke. The electrocatalytic behaviour of Ni-Co alloys for the hydrogen evolution reaction in alkaline solution. Ottawa: National Library of Canada, 1990.

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Sinanan, Anson R. Nickel-based amorphous alloys with Cr/V additions for the hydrogen evolution reaction in alkaline solution. Ottawa: National Library of Canada, 2001.

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A, Lorenz R., Weber C. F, U.S. Nuclear Regulatory Commission. Division of Safety Issue Resolution., and Oak Ridge National Laboratory, eds. Iodine evolution and pH control. Washington, DC: Division of Safety Issue Resolution, Office of Nuclear Regulatory Research, U.S. Nuclear Regulatory Commission, 1992.

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Yung, Y. L. Quantitative understanding of the cycles of oxidized and reduced sulfur on Venus: Final technical report for NAG 2-764 from California Institute of Technology, period covered March 1, 1992 through February 28, 1994. [Washington, DC: National Aeronautics and Space Administration, 1994.

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Book chapters on the topic "Hydrogen evolution reaction"

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Krstajic, Nedeljko. "Hydrogen Evolution Reaction." In Encyclopedia of Applied Electrochemistry, 1039–44. New York, NY: Springer New York, 2014. http://dx.doi.org/10.1007/978-1-4419-6996-5_403.

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Thomas, Siby, Minu Mathew, K. P. Priyanka, and Dickson D. Babu. "MoS2 for Hydrogen Evolution Reaction." In Materials Horizons: From Nature to Nanomaterials, 231–55. Singapore: Springer Nature Singapore, 2024. https://doi.org/10.1007/978-981-97-7367-1_13.

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Ghouri, Zafar Khan. "Electrocatalyst Design for Hydrogen Evolution Reaction." In SpringerBriefs in Energy, 21–39. Cham: Springer Nature Switzerland, 2024. http://dx.doi.org/10.1007/978-3-031-73442-7_3.

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Li, Guangfu, and Mu Pan. "Electrocatalytic Oxygen Evolution Reaction in Acid Media." In Green Hydrogen Production by Water Electrolysis, 138–57. Boca Raton: CRC Press, 2024. http://dx.doi.org/10.1201/9781003368939-7.

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Rhimi, Baker, and Zhifeng Jiang. "Dual-Atom Catalysts for Hydrogen Evolution Reaction." In Atomically Precise Electrocatalysts for Electrochemical Energy Applications, 283–98. Cham: Springer Nature Switzerland, 2024. http://dx.doi.org/10.1007/978-3-031-54622-8_16.

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Xue, Qi, Yuanzhen Zhou, Juan Bai, and Jun Mei. "Multi-atom Catalysts for Hydrogen Evolution Reaction." In Atomically Precise Electrocatalysts for Electrochemical Energy Applications, 299–314. Cham: Springer Nature Switzerland, 2024. http://dx.doi.org/10.1007/978-3-031-54622-8_17.

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Sharma, Vaishali, and Aman Mahajan. "Single-Atom Catalysts for Hydrogen Evolution Reaction." In Atomically Precise Electrocatalysts for Electrochemical Energy Applications, 261–81. Cham: Springer Nature Switzerland, 2024. http://dx.doi.org/10.1007/978-3-031-54622-8_15.

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Zhao, Bin, and Siran Xu. "Carbon-Based Nanomaterials for Hydrogen Evolution Reaction." In Carbon-Based Nanomaterials for Energy Conversion and Storage, 123–46. Singapore: Springer Nature Singapore, 2022. http://dx.doi.org/10.1007/978-981-19-4625-7_6.

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Thiyagarajan, Natarajan, Nithila A. Joseph, and Manavalan Gopinathan. "Noble-Metal-Free Nanoelectrocatalysts for Hydrogen Evolution Reaction." In Nanostructured Materials for Energy Related Applications, 73–120. Cham: Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-030-04500-5_4.

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Chen, Linxuan. "Molybdenum Disulfide Nanosheets for Efficient Hydrogen Evolution Reaction." In The 2021 International Conference on Machine Learning and Big Data Analytics for IoT Security and Privacy, 962–66. Cham: Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-89511-2_135.

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Conference papers on the topic "Hydrogen evolution reaction"

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Minamimoto, Hiro, Daiki Sato, and Kei Murakoshi. "Isotopic hydrogen evolution reaction by plasmonic electrochemistry." In Optical Manipulation and Structured Materials Conference, edited by Takashige Omatsu, Hajime Ishihara, Keiji Sasaki, and Kishan Dholakia. SPIE, 2020. http://dx.doi.org/10.1117/12.2573789.

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Poimenidis, Ioannis, Nikandra Papakosta, Michael Tsanakas, Argyro Klini, Maria Farsari, Michalis Konsolakis, Stavros D. Moustaizis, and Panagiotis A. Loukakos. "Laser-nanostructured substrates for enhanced hydrogen evolution reaction." In Nanoscale and Quantum Materials: From Synthesis and Laser Processing to Applications 2024, edited by Andrei V. Kabashin, Maria Farsari, and Masoud Mahjouri-Samani. SPIE, 2024. http://dx.doi.org/10.1117/12.3003827.

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Reyes-Mesa, David, Albert Gallego-Gamo, Axel Guinard, Adelina Vallribera, Albert Granados, Roser Pleixats, and Carolina Gimbert-Suriñach. "Tunable Covalent Organic Frameworks for the Light-induced Hydrogen Evolution Reaction." In The Future of Hydrogen: Science, Applications and Energy Transition. València: FUNDACIO DE LA COMUNITAT VALENCIANA SCITO, 2024. http://dx.doi.org/10.29363/nanoge.hfuture.2024.023.

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Zhang, Yanfeng. "Electrocatalytic hydrogen evolution reaction of MX2 and MX2 heterostructures." In Nano-Micro Conference 2017. London: Nature Research Society, 2017. http://dx.doi.org/10.11605/cp.nmc2017.01025.

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Azmi, Nur Suhaily, Mohd Nazree Derman, and Zuraidawani Che Daud. "Hydrogen Evolution Reaction of AC Anodized Stainless Steel 304L." In 2023 IEEE International Conference on Sensors and Nanotechnology (SENNANO). IEEE, 2023. http://dx.doi.org/10.1109/sennano57767.2023.10352445.

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Hsieh, Shu Huei, Lilun Chang, and Wenjauh Chen. "Pt-MoSx/Graphene Nanocomposite for the Hydrogen Evolution Reaction." In 2015 6th International Conference on Manufacturing Science and Engineering. Paris, France: Atlantis Press, 2015. http://dx.doi.org/10.2991/icmse-15.2015.229.

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Nguyen, Tri Khoa, Jong-Won Yun, and Yong Soo Kim. "Electrocatalytic hydrogen evolution reaction based on reduced graphene oxide:Pt nanocomposite." In 2016 11th International Forum on Strategic Technology (IFOST). IEEE, 2016. http://dx.doi.org/10.1109/ifost.2016.7884184.

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Muthamizh, S., V. Narayanan, and R. Jayavel. "Hydrogen evolution reaction with transition metal molybdate as cathode material." In DAE SOLID STATE PHYSICS SYMPOSIUM 2018. AIP Publishing, 2019. http://dx.doi.org/10.1063/1.5113392.

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Lai, Lianfeng, Kongqiang Ye, Minglin Li, Jing Luo, Bo Wu, and Zhiying Ren. "Prediction of Strain Effect on Hydrogen Evolution Reaction on VMO-SLMOS2 *." In 2019 IEEE 19th International Conference on Nanotechnology (IEEE-NANO). IEEE, 2019. http://dx.doi.org/10.1109/nano46743.2019.8993908.

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Sui, Wubin, Curtis Guild, Junkai He, Andrew Meguerdichian, Ran Miao, and Steven L. Suib. "An Advanced Hierarchical MoS2/Mn for High Performance Hydrogen Evolution Reaction." In 2017 International Conference on Material Science, Energy and Environmental Engineering (MSEEE 2017). Paris, France: Atlantis Press, 2017. http://dx.doi.org/10.2991/mseee-17.2017.66.

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Reports on the topic "Hydrogen evolution reaction"

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Wilmont, Martyn, Greg Van Boven, and Tom Jack. GRI-96-0452_1 Stress Corrosion Cracking Under Field Simulated Conditions I. Chantilly, Virginia: Pipeline Research Council International, Inc. (PRCI), November 1997. http://dx.doi.org/10.55274/r0011963.

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Electrochemical measurements have been performed on polished and mill scaled steel samples. The solutions investigated have included carbonate bicarbonate mixtures of varying pH as well as solutions of neutral pH such as NS4. Results indicate that the mechanism of corrosion associated with the carbonate bicarbonate environments involves passive film formation. No such passivation is observed for solutions associated with neutral pH SCC. Electrochemical corrosion rates measured on polished steel specimens exposed to NS4 solutions in the pH range 5 to 6.8 were in the region of 5 x 10e-1 to 1 x 10e-2 mm/s. However, rates obtained on mill scaled surfaces went much lower and in the region of 5 x 10e-10 mm/s. Field determined crack propagation rates are estimated to be in the region of 2 x 10e-8 mm/s. Whilst the laboratory determined corrosion rates are lower than the field propagation rate it should be remembered that the laboratory rates were obtained on unstressed specimens. The application of load would be expected to increase the corrosion rate and may indicate that stress focused dissolution process may be sufficient to explain the propagation of neutral pH stress corrosion cracks. However, as hydrogen evolution is the most likely cathodic reaction involved in the mechanism of neutral pH SCC the role of hydrogen in the crack propagation mechanism may also be important.
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Hair. L52003 Application of the Crack Layer Theory for Understanding and Modeling of SCC in High Pressure. Chantilly, Virginia: Pipeline Research Council International, Inc. (PRCI), August 2003. http://dx.doi.org/10.55274/r0010893.

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A stochastic features of SCC colony, such as corrosion pit distribution, SC crack initiation from the pits and SC crack aspect ratio, SC crack cluster formation, SC cluster interaction and instability, are observed and characterized. A concept of a single crack equivalent to a cluster of cracks is introduced to simplify computational work on clusters evolution and instability. Various criteria of equivalence for different stages of clusters evolution are discussed. An accelerated test with a number of accelerating factors has been designed and performed for simulation of individual SC crack growth. Corrosion products at each stage of single crack propagation are investigated by means of Raman and FTIR analysis. The crack layer theory is adopted for modeling of SC crack growth. It provides the formalism for modeling of the effect of such processes as electro-chemical reactions, hydrogen embrittlement, and mechanical loading rates on crack growth rate. Finally, a computer simulation of SC crack growth was performed and validated by the available set of experimental data.
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