Academic literature on the topic 'Hydrolysis of Acetamide'

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Journal articles on the topic "Hydrolysis of Acetamide"

1

Xie, Jia-qing, Ya Zhang, Shu-lan Cai, Fang-zhen Li, and Fa-mei Feng. "Catalytic Capacity of Diaza-Crown Ether Lanthanum Complexes with Varied Ligands for Phosphate Ester Hydrolysis in Different Media." Progress in Reaction Kinetics and Mechanism 41, no. 4 (2016): 321–30. http://dx.doi.org/10.3184/146867816x14710833328904.

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Two diaza-crown ether compounds, 1,4,10,13-tetraoxa-7,16-diazacyclooctadecane (L0) and its derivative with double acetamide side arms 2,2'-(1,4,10,13-teteaoxa-7,16-diazacyclooctadecane-7,16-diyl)diacetamide (L), and the corresponding two lanthanum complexes were synthesised and characterised. The catalytic capacity of the lanthanum complexes was investigated for the hydrolysis of bis(4-nitrophenyl) phosphate ester (BNPP) in aqueous solution and in CTAB micelles. Kinetic studies show that the catalytic efficiency of complex LaL is obviously higher than that of complex LaL0, and introducing acet
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2

Ekler, Zsigmond, and Ferenc Dutka. "Chemical Reactivity and Safener Activity of Acetal Compounds." Zeitschrift für Naturforschung C 46, no. 9-10 (1991): 810–14. http://dx.doi.org/10.1515/znc-1991-9-1015.

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Abstract Although detailed examinations have been published on structure-activity relationships of herbicide safeners, only a few data are available on chemical reactivity-safener activity relationships. Chemical reactivity of acetamide type compounds as well as their safener activity against thiocarbamate herbicides change with the number of chlorine substituents in the order: non-chlorinated < monochloro < dichloro. Several compounds of another chemical group, acetals (e.g. MG-191, 2-dichloromethyl-2-methyl-1,3-dioxolane), are also effective safeners for thiocarbamate herbicides. Accor
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3

Berg, Gry Mine, Daniel J. Repeta, and Julie Laroche. "Dissolved Organic Nitrogen Hydrolysis Rates in Axenic Cultures of Aureococcus anophagefferens (Pelagophyceae): Comparison with Heterotrophic Bacteria." Applied and Environmental Microbiology 68, no. 1 (2002): 401–4. http://dx.doi.org/10.1128/aem.68.1.401-404.2002.

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ABSTRACT The marine autotroph Aureococcus anophagefferens (Pelagophyceae) was rendered axenic in order to investigate hydrolysis rates of peptides, chitobiose, acetamide, and urea as indicators of the ability to support growth on dissolved organic nitrogen. Specific rates of hydrolysis varied between 8 and 700% of rates observed in associated heterotrophic marine bacteria.
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4

Zikmundová, M., K. Drandarov, L. Bigler, M. Hesse, and C. Werner. "Biotransformation of 2-Benzoxazolinone and 2-Hydroxy-1,4-Benzoxazin-3-one by Endophytic Fungi Isolated from Aphelandra tetragona." Applied and Environmental Microbiology 68, no. 10 (2002): 4863–70. http://dx.doi.org/10.1128/aem.68.10.4863-4870.2002.

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ABSTRACT The biotransformation of the phytoanticipins 2-benzoxazolinone (BOA) and 2-hydroxy-1,4-benzoxazin-3-one (HBOA) by four endophytic fungi isolated from Aphelandra tetragona was studied. Using high-performance liquid chromatography-mass spectrometry, several new products of acylation, oxidation, reduction, hydrolysis, and nitration were identified. Fusarium sambucinum detoxified BOA and HBOA to N-(2-hydroxyphenyl)malonamic acid. Plectosporium tabacinum, Gliocladium cibotii, and Chaetosphaeria sp. transformed HBOA to 2-hydroxy-N-(2-hydroxyphenyl)acetamide, N-(2-hydroxyphenyl)acetamide, N-
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5

Lee, Ikchoon, Chang Kon Kim, and Hein Su Seo. "Theoretical studies on the acid hydrolysis of acetamide." Tetrahedron 42, no. 24 (1986): 6627–33. http://dx.doi.org/10.1016/s0040-4020(01)82101-3.

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6

Lee, Dong Soo, and Earnest F. Gloyna. "Hydrolysis and oxidation of acetamide in supercritical water." Environmental Science & Technology 26, no. 8 (1992): 1587–93. http://dx.doi.org/10.1021/es00032a015.

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7

Lee, Ikchoon, Chang Kon Kim, and Bon-Su Lee. "AM1 studies on the acid hydrolysis of acetamide." Journal of Physical Organic Chemistry 3, no. 6 (1990): 397–403. http://dx.doi.org/10.1002/poc.610030608.

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8

Nortrup, David A. "Determination of Residues of Alachlor and Related Herbicides in Crops by Liquid Chromatography with Electrochemical Detection." Journal of AOAC INTERNATIONAL 80, no. 5 (1997): 1104–10. http://dx.doi.org/10.1093/jaoac/80.5.1104.

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Abstract A method is described for determining residues of 3 acetamide herbicidesalachlor [2-chloro-N(2,6- diethylphenyl)-N(methoxymethyl)acetamide], acetochlor [2-chloro-N(2-ethyl-6-methylphenyl)-N (ethoxymethyl)acetamide), and butachlor [2-chloro-N(2,6-diethylphenyl)-N(butoxymethyl)- acetamide)by liquid chromatography (LC). Currently no published method determines metabolites from all 3 herbicides in crops. Strong-base hydrolysis after extraction of a test portion with water-acetonitrile results in the formation of 2,6- diethylaniline (DEA) and 2-(1-hydroxyethyl)-6-ethylaniline from alachlor
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9

Manohara, G. V., David Norris, M. Mercedes Maroto-Valer, and Susana Garcia. "Acetate intercalated Mg–Al layered double hydroxides (LDHs) through modified amide hydrolysis: a new route to synthesize novel mixed metal oxides (MMOs) for CO2 capture." Dalton Transactions 50, no. 21 (2021): 7474–83. http://dx.doi.org/10.1039/d1dt00602a.

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SEM images of MMOs derived from Mg–Al-acetate intercalated LDHs synthesized by acetamide hydrolysis with (a) Mg/Al = 3, (b) Mg/Al = 4 and their high temperature CO<sub>2</sub> capture capacity versus temperature (c) were obtained.
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10

Verspui, Göran, Gábor Besenyei, and Roger A. Sheldon. "Amide directed hydrocarboxylation of N-allylacetamide catalyzed by the aqueous Pd - tppts - Brønsted acid system (tppts = P(C6H4-m-SO3Na)3)1." Canadian Journal of Chemistry 79, no. 5-6 (2001): 688–92. http://dx.doi.org/10.1139/v01-068.

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The Pd - tppts - HOTs (tppts = P(C6H4-m-SO3Na)3, HOTs = p-toluenesulfonic acid) catalyzed hydrocarboxylation of N-allylacetamide in an aqueous medium afforded 4-acetamidobutyric acid and 3-acetamido-2-methylpropanoic acid under mild conditions, with a high regioselectivity towards the linear isomer. During the hydrocarboxylation an acid catalyzed hydrolysis of the amide moieties of both the substrate and the products took place, as well as the formation of acetamide and propanal, presumably via a Pd-catalyzed allylic substitution reaction of N-allylacetamide. The hydrolysis reaction was suppre
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