Academic literature on the topic 'Hydrolysis of triterpene'

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Journal articles on the topic "Hydrolysis of triterpene"

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K., S. Mukherjee, Brahmachari G., Chatterjee D., and Mukherjee P. "Triterpene from Adiantum lunulactum." Journal of Indian Chemical Societ Vol. 78, May 2001 (2001): 267–68. https://doi.org/10.5281/zenodo.5878466.

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Department of Chemistry, Visva-Bharati, Santiniketan-731 235, India <em>Manuscript received 19 January 2000, revised 21 December 2000, accepted 26 December 2000</em> The petrol extract of the whole plants of<em> Adiantum lunulactum</em> has yielded a new hopane triterpene. 3&beta;-acetoxyl-21<em>&alpha;</em>-<em>H-</em>hop-22(29)ene.
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Oleszek, Wiesław, Marian Jurzysta, Stanisław Burda, and Michał Płoszyński. "Triterpene saponins of Trigonella monspeliaca L." Acta Societatis Botanicorum Poloniae 56, no. 2 (2014): 281–85. http://dx.doi.org/10.5586/asbp.1987.027.

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The triterpene saponin fraction was isolated from &lt;em&gt;Trigonella monspeliaca&lt;/em&gt; tops. It consisted of ten saponosides, three of which were determined to be medicagenic acid glycosides, the other seven - soyasapogenol glucosides. Acid hydrolysis of the saponin fraction yielded medicagenic acid, soyasapogenol B and its artifacts soyasapogenol C, D and F. These data consitute the first report on the occurence of medicagenic acid and soyasapogenol glycosides in the genus &lt;em&gt;Trigonella&lt;/em&gt;.
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Reina, Robert J., Kevin D. White, and Edwin G. E. Jahngen. "Validated Method for Quantitation and Identification of 4,4-Desmethylsterols and Triterpene Diols in Plant Oils by Thin-Layer Chromatography–High Resolution Gas Chromatography–Mass Spectrometry." Journal of AOAC INTERNATIONAL 80, no. 6 (1997): 1272–80. http://dx.doi.org/10.1093/jaoac/80.6.1272.

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Abstract Alkaline hydrolysis was performed on a series of different vegetable oils. The unsaponifiable lipid matter was extracted with ethyl ether, and the class of 4,4-desmethylsterols (sterols) plus the triterpene diols (diols) erythrodiol, uvaol, and betulinol were isolated by thin-layer chromatography. A validated method using the acetate derivatives of sterols instead of their silyl ethers is presented. The acetate derivatives were analyzed by high resolution gas chromatography (HRGC). Retention time, precision, recovery studies, and absolute response factors were calculated for these est
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Kwon, Jaeyoung, Keebeom Ko, Lijun Zhang, Dong Zhao, Hyun Ok Yang, and Hak Cheol Kwon. "An Autophagy Inducing Triterpene Saponin Derived from Aster koraiensis." Molecules 24, no. 24 (2019): 4489. http://dx.doi.org/10.3390/molecules24244489.

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Autophagy is an important self-degradative mechanism that plays a key role in treating neurodegeneration diseases. This research aimed at discovering bioactive compounds from Aster koraiensis. A new triterpene saponin, astersaponin I (1), was isolated from the EtOH extract of A. koraiensis. The structure of 1 was characterized by spectroscopic methods, ECD calculation, and acid hydrolysis. The biochemical analysis showed that compound 1 significantly increased the expression of microtubule-associated protein 1A/1B light chain 3B (LC3-II) expression in SH-SY5Y cells, which indicates the inducti
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Ying, Q. L., A. R. Rinehart, S. R. Simon, and J. C. Cheronis. "Inhibition of human leucocyte elastase by ursolic acid. Evidence for a binding site for pentacyclic triterpenes." Biochemical Journal 277, no. 2 (1991): 521–26. http://dx.doi.org/10.1042/bj2770521.

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Several pentacyclic triterpenoid metabolites of plant origin are inhibitors of hydrolysis of both synthetic peptide substrates and elastin by human leucocyte elastase (HLE). Ursolic acid, the most potent of these compounds, has an inhibition constant of 4-6 microM for hydrolysis of peptide substrates in phosphate-buffered saline. With tripeptide and tetrapeptide substrates, the inhibition is purely competitive, whereas with a shorter dipeptide substrate the inhibition is non-competitive, suggesting that ursolic acid interacts with subsite S3 of the extended substrate-binding domain in HLE, but
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Kuroda, Minpei, Takaaki Shizume, and Yoshihiro Mimaki. "New Acylated Triterpene Glycosides from the Roots of Polygala tenuifolia." Natural Product Communications 9, no. 3 (2014): 1934578X1400900. http://dx.doi.org/10.1177/1934578x1400900326.

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Two new and five known acylated triterpene glycosides were isolated from the MeOH extract of the roots of Polygala tenuifolia. Based on extensive spectroscopic analysis, including 2D NMR experiments, and the results of alkaline hydrolysis, the structures of the new compounds were assigned as 3β-[(β-D-glucopyranosyl)oxy]–2β,27-dihydroxyolean-12-ene-23,28-dioic acid 28- O-β-D-apiofuranosyl-(1→3)-[β-D-galactopyranosyl-(1→4)-β-D-xylopyranosyl-(1→4)]-α-L-rhamnopyranosyl-(1→2)-3- O-( E)-3,4,5-trimethoxycinnamoyl-β-D-fucopyranosyl ester (1) and 3β-[(β-D-glucopyranosyl)oxy]–2β,27-dihydroxyolean-12-ene
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Konuspayev, Saparkali, Batiha Kassenova, Zauresh Akhatova, and Roza Nurbaeva. "Alkaline hydrolysis of wool fat (lanolin) in a medium of proton and aprotic solvents." Chemical Bulletin of Kazakh National University, no. 1 (March 30, 2018): 4–9. http://dx.doi.org/10.15328/cb978.

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The raw material being studied is the woolen fat of the sheep of the Edilbay fine-fleece and Kazakh arkharomeric fine-fleece, which is excreted when washing wool in primary wool processing plants (PWP) in the regions of Kazakhstan, such as Semipalatinsk, Aktyubinsk, Zhambyl and Tokmak. Earlier we obtained anhydrous lanolin from the fat of various factories of the PWP. In both cases, positive results were obtained and a certificate of compliance of anhydrous lanolin FS RK was obtained. In terms of its chemical composition, wool fat is a mixture of C10-C16 carboxylic acid esters with aliphatic,
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Astudillo, Luis, Margarita Gutiérrez, Luisa Quesada, Aurelio San-Martín, Luis Espinoza, and Patricio Peñailillo. "New Diterpenes from Azorella spinosa." Natural Product Communications 9, no. 1 (2014): 1934578X1400900. http://dx.doi.org/10.1177/1934578x1400900104.

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Two new diterpenes,2-acetoxy-13-hydroxy-mulin-11-ene and 2-acetoxy-mulin-11, 13-diene, have been isolated from the aerial parts of Azorella spinosa and their structures determined by spectroscopic and conventional chemical methods. Furthermore, 2, 13-dihydroxy-mulin-11-ene was obtained using a basic hydrolysis of the first compound. Two diterpenes reported for other Azorella species have also been found, namely mulinolic acid and 13β-hydroxyazorellane, as well as the triterpene lactone of ursolic acid, quercetin, and 7-hydroxycoumarin. The compounds were evaluated using antibacterial, antioxid
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Yokosuka, Akihito, Tomoki Iguchi, Maki Jitsuno, and Yoshihiro Mimaki. "Structure and Cytotoxicity of Novel Lignans and Lignan Glycosides from the Aerial Parts of Larrea tridentata." Molecules 26, no. 20 (2021): 6186. http://dx.doi.org/10.3390/molecules26206186.

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Previously, the authors conducted phytochemical investigations of the aerial parts of Larrea tridentata and reported triterpene glycosides and lignan derivatives. In continuation of the preceding studies, 17 lignans and lignan glycosides (1–17) were isolated, including seven new compounds (1–7). Herein, the structure of the new compounds was determined based on spectroscopic analysis and enzymatic hydrolysis. The cytotoxicity of 1–17 against HL-60 human promyelocytic leukemia cells was examined. Compounds 4–11 and 14–16 were cytotoxic to HL-60 cells, with IC50 values in the range of 2.7–17 μM.
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Nguyen, Hoang Sa, Ha Thanh Nguyen, Van Loc Tran, et al. "Synthesis of hybrid compounds of 24-nor-lupane triterpene and amino acids via C-28 amide linkage." Hue University Journal of Science: Natural Science 132, no. 1B (2023): 43–47. http://dx.doi.org/10.26459/hueunijns.v132i1b.6810.

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Betulinic acid derivatives exhibit different biological activity against diversified targets, such as anticarcinogenic activity in experimental animals, anti-HIV, antihyperglycemia, and anti-inflammatory in humans. In this work, we investigated the synthetic procedure of 24-nor-3-oxo-20(29)-lupen-28-oic acid (1) derivatives. Starting from compound 1 and L-leucine methyl ester, we proceeded with amidification, reduction, and hydrolysis under basic conditions. Finally, three hybrid compounds were successfully synthesised and elucidated with spectral means.
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Dissertations / Theses on the topic "Hydrolysis of triterpene"

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Tripoteau, Ludovic. "Valorisation des coproduits de l'holothurie Cucumaria frondosa par l'étude d'extraits bioactifs et approche écotoxicologique des métabolites secondaires relargués en situation de stress." Thesis, Lorient, 2015. http://www.theses.fr/2015LORIS368/document.

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La transformation des produits marins génère d’importantes quantités de rejets. La majorité est transformée pour des applications de masse avec une faible valeur ajoutée. Au Nouveau Brunswick, 85 000 tonnes de produits marins sont transformés annuellement et la moitié est peu ou pas valorisée, c’est le cas de l’holothurie Cucumaria frondosa. Face aux différentes pressions de leur environnement, et notamment la prédation, ces invertébrés marins ont évolué en développant des métabolites d’une large chimiodiversité, ce qui en fait d’excellents candidats pour le développement de substances naturel
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Book chapters on the topic "Hydrolysis of triterpene"

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Taber, Douglass F. "The Corey Synthesis of (+)-Lupeol." In Organic Synthesis. Oxford University Press, 2013. http://dx.doi.org/10.1093/oso/9780199965724.003.0086.

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The total synthesis of lupeol was one of the crowning achievements of the Robinson annulation/ reductive alkylation approach to stereocontrolled polycarbocyclic construction developed by Gilbert Stork (J. Am. Chem. Soc. 1971, 93, 4945). It is a measure of the progress of organic synthesis since that time that E. J. Corey of Harvard University could devise (J. Am. Chem. Soc. 2009, 131, 13928) an enantioselective synthesis of (+)-lupeol 3 that could be carried out by a single colleague. The key step in the synthesis was the Lewis acid–mediated cyclization of 1 to 2. The preparation of 1 began wi
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