Academic literature on the topic 'Hydroxy(tosyloxy)iodobenzene'

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Journal articles on the topic "Hydroxy(tosyloxy)iodobenzene"

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Kamal, Raj, Vipan Kumar, Ravinder Kumar, Sangeeta Saini, and Rajesh Kumar. "Oxidative Rearrangement via 1,2-Aryl Migration using Hydroxy(tosyloxy)iodobenzene in a Polar Aprotic Solvent." Synlett 31, no. 10 (2020): 959–64. http://dx.doi.org/10.1055/s-0040-1708010.

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A series of geminal β,β-ditosyloxy ketones were synthesized in moderate to good yields through hydroxy(tosyloxy)iodobenzene-mediated ditosyloxylation of readily accessible α,β-unsaturated ketones in a polar aprotic solvent. A mechanism has been proposed for the synthesis of the geminal β,β-ditosyloxy ketones, and entails an oxidative rearrangement involving a 1,2-aryl migration.
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Kawamura, Yasuhiko, Masashi Maruyama, Kazuyo Yamashita, and Masao Tsukayama. "Environmentally Benign Synthesis of Isoflavone Derivatives Using Polymer-Supported Hypervalent Iodine(III) Reagent." International Journal of Modern Physics B 17, no. 08n09 (2003): 1482–86. http://dx.doi.org/10.1142/s0217979203019198.

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Isoflavones are synthesized in one-pot manner by action of a hypervalent iodine (III) reagent, ⌊hydroxy(tosyloxy)iodo⌋benzene (HTIB, Koser's reagent) on 2'-benzoyloxychalcones in MeOH. A combined usage of iodobenzene diacetate (IBD)—p-toluenesulfonic acid (TsOH) is also effective for the same purpose. As an extension of those monomeric reagents, polymer-supported IBD (PSIBD, poly ⌊4-(diacetoxy)iodo⌋styrene) with TsOH works also well with merit of easy separation of isoflavones from the reaction mixture, no liberation of PhI, and reuse of the reagent.
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KUMAR, Parvin. "Solid State Oxidative Aromatization of Hantzsch 1,4-Dihydropyridines to Pyridines Using Iodobenzene Diacetate or Hydroxy(tosyloxy)iodobenzene." Chinese Journal of Chemistry 27, no. 8 (2009): 1487–91. http://dx.doi.org/10.1002/cjoc.200990250.

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Kumar, Rajesh, Nitya Sharma, and Om Prakash. "Hypervalent Iodine Reagents in the Synthesis of Flavonoids and Related Compounds." Current Organic Chemistry 24, no. 18 (2020): 2031–47. http://dx.doi.org/10.2174/1385272824999200420074551.

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Hypervalent iodine compounds have proved to be very useful reagents to bring about various oxidative transformations including (i) α-functionalization of carbonyl compounds, (ii) oxidation of phenols, and (iii) oxidative rearrangement of ketones and α,β- unsaturated ketones. These reactions find interesting applications in the development of newer and convenient approaches for the synthesis of flavonoids. This review focuses on the use of most common three hypervalent compounds, namely iodobenzene diacetate, [hydroxy(tosyloxy)iodo]benzene, and [bis-trifluoroacetoxy(iodo)]benzene in the synthes
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Jadhav, Ravindra D., Hitesh D. Mistry, Hashim Motiwala, et al. "A Facile One-Pot Synthesis of 3,5-Disubstituted Isoxazole Derivatives Using Hydroxy (Tosyloxy) Iodobenzene." Journal of Heterocyclic Chemistry 50, no. 4 (2013): 774–80. http://dx.doi.org/10.1002/jhet.1556.

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Jadhav, Ravindra D., Mistry Hitesh D. Mistry Hitesh D., Hashim Motiwala, et al. "ChemInform Abstract: A Facile One-Pot Synthesis of 3,5-Disubstituted Isoxazole Derivatives Using Hydroxy (Tosyloxy) Iodobenzene." ChemInform 44, no. 49 (2013): no. http://dx.doi.org/10.1002/chin.201349145.

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Xia, Min, and Zhen-Chu Chen. "Hypervalent Iodine in Synthesis XXXIII: Palladium-Catalyzed Cross-Coupling Reaction of Potassium Aryltrifluoroborates with Diaryliodonium Salts and Hydroxy(tosyloxy)iodobenzene." Synthetic Communications 29, no. 14 (1999): 2457–65. http://dx.doi.org/10.1080/00397919908086252.

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Vasudevan, Anita, and Gerald F. Koser. "Direct conversion of long-chain carboxamides to alkylammonium tosylates with hydroxy(tosyloxy)iodobenzene, a notable improvement over the classical Hofmann reaction." Journal of Organic Chemistry 53, no. 21 (1988): 5158–60. http://dx.doi.org/10.1021/jo00256a051.

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Xia, Min, and Zhen-Chu Chen. "ChemInform Abstract: Hypervalent Iodine in Synthesis. Part 33. Palladium-Catalyzed Cross-Coupling Reaction of Potassium Aryltrifluoroborates with Diaryliodonium Salts and Hydroxy(tosyloxy)iodobenzene." ChemInform 30, no. 35 (2010): no. http://dx.doi.org/10.1002/chin.199935109.

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Kumar, Parvin. "ChemInform Abstract: Solid State Oxidative Aromatization of Hantzsch 1,4-Dihydropyridines to Pyridines Using Iodobenzene Diacetate or Hydroxy(tosyloxy)iodobenzene." ChemInform 40, no. 52 (2009). http://dx.doi.org/10.1002/chin.200952160.

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Dissertations / Theses on the topic "Hydroxy(tosyloxy)iodobenzene"

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Pedrozo, Eliane Corrêa. "Reações de ésteres ß,Y-insaturados com tálio(III) e de 1,2-di-hidronaftalenos com iodo(III)." Universidade de São Paulo, 2006. http://www.teses.usp.br/teses/disponiveis/46/46135/tde-28112006-144242/.

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Esta dissertação apresenta um estudo sobre a contração de anel de ésteres ß,y-insaturados promovida por trinitrato de tálio (TTN) e de 1,2-di-hidronaftalenos promovida por hidroxi(tosiloxi)iodobenzeno (HTIB), também conhecido como reagente de Koser. Ambos estudos visaram à síntese de indanos funcionalizados. A reação de uma série de ésteres ß,y-insaturados (por exemplo 2-(3,4-di-hidronaftalen-1-il)-proprionato de etila) com TTN em ácido acético forneceu os correspondentes produtos de contração, formando indanos em bons rendimentos. A presença de grupos doadores de elétrons na posição 6 no anel
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