Academic literature on the topic 'Hydroxypyridine ligands'

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Journal articles on the topic "Hydroxypyridine ligands"

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Breit, Bernhard, and Wolfgang Seiche. "Self-assembly of bidentate ligands for combinatorial homogeneous catalysis based on an A-T base pair model." Pure and Applied Chemistry 78, no. 2 (January 1, 2006): 249–56. http://dx.doi.org/10.1351/pac200678020249.

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A new concept for generation of chelating ligand libraries for homogeneous metal complex catalysis based on self-assembly is presented. Thus, self-assembly of structurally simple monodentate ligands in order to give structurally more complex bidentate ligands is achieved employing hydrogen bonding. Based on this concept and on the 2-pyridone/hydroxypyridine tautomeric system, a new rhodium catalyst was identified which operated with excellent activity and regioselectivity upon hydroformylation of terminal alkenes. In order to generate defined unsymmetrical heterodimeric ligands, an A-T base pa
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Kremer, Marius, and Ulli Englert. "Zn and Ni complexes of pyridine-2,6-dicarboxylates: crystal field stabilization matters!" Acta Crystallographica Section E Crystallographic Communications 75, no. 6 (May 31, 2019): 903–11. http://dx.doi.org/10.1107/s2056989019007461.

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Six reaction products of ZnII and NiII with pyridine-2,6-dicarboxylic acid (H2Lig1), 4-chloropyridine-2,6-dicarboxylic acid (H2Lig2) and 4-hydroxypyridine-2,6-dicarboxylic acid (H2Lig3) are used to pinpoint the structural consequences of crystal field stabilization by an incomplete d shell. The pseudo-octahedral ZnII coordination sphere in bis(6-carboxypicolinato)zinc(II) trihydrate, [Zn(C7H4NO4)2]·3H2O or [Zn(HLig1)2]·3H2O, (1), is significantly less regular than that about NiII in the isostructural compound bis(6-carboxypicolinato)nickel(II) trihydrate, [Ni(C7H4NO4)2]·3H2O or [Ni(HLig1)2]·3H
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Bare, William D., Nathan H. Mack, J. N. Demas, and B. A. DeGraff. "pH-Dependent Photophysical Behavior of Rhenium Complexes Containing Hydroxypyridine Ligands." Applied Spectroscopy 58, no. 9 (September 2004): 1093–100. http://dx.doi.org/10.1366/0003702041959316.

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Oh, Yunghee, Chul Ho Lee, Burm Jong Lee, and Byoung Chul Shin. "Photoluminescent Europium Complexes with Oxygen and/or Nitrogen Donating Ligands." Key Engineering Materials 277-279 (January 2005): 966–71. http://dx.doi.org/10.4028/www.scientific.net/kem.277-279.966.

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The reaction of EuX3 ·nH2O (X=Cl¯ , NO3¯ ), a- pyridoin anion (P) and 2,2¢-dipyridylamine in ethanol solution yields a hydroxo complex, EuP2(OH) 2(H2O) 2, which is characterized by NMR, IR, and elemental analyses. Europium complexes coordinated by nitrogen donating ligands such as 2,2¢-dipyridylamine or 2¢-hydroxypyridine are unstable in solution and are prone to decompose to europium hydroxo complex and pyridinium amine salt. The UV and PL spectra of europium complexes are reported and a decomposition mechanism is proposed.
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Perdih, Franc. "Copper(II) bis(4,4,4-trifluoro-1-phenylbutane-1,3-dionate) complexes with pyridin-2-one, 3-hydroxypyridine and 3-hydroxypyridin-2-one ligands: molecular structures and hydrogen-bonded networks." Acta Crystallographica Section C Structural Chemistry 73, no. 11 (October 19, 2017): 960–67. http://dx.doi.org/10.1107/s2053229617014875.

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Copper(II) bis(4,4,4-trifluoro-1-phenylbutane-1,3-dionate) complexes with pyridin-2-one (pyon), 3-hydroxypyridine (hpy) and 3-hydroxypyridin-2-one (hpyon) were prepared and the solid-state structures of (pyridin-2-one-κO)bis(4,4,4-trifluoro-3-oxo-1-phenylbutan-1-olato-κ2 O,O′)copper(II), [Cu(C10H6F3O2)2(C5H5NO)] or [Cu(tfpb-κ2 O,O′)2(pyon-κO)], (I), bis(pyridin-3-ol-κO)bis(4,4,4-trifluoro-3-oxo-1-phenylbutan-1-olato-κ2 O,O′)copper(II), [Cu(C10H6F3O2)2(C5H5NO)2] or [Cu(tfpb-κ2 O,O′)2(hpy-κO)2], (II), and bis(3-hydroxypyridin-2-one-κO)bis(4,4,4-trifluoro-3-oxo-1-phenylbutan-1-olato-κ2 O,O′)coppe
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Pivarcsik, Tamás, Gábor Tóth, Nikoletta Szemerédi, Anita Bogdanov, Gabriella Spengler, Jakob Kljun, Jerneja Kladnik, Iztok Turel та Éva A. Enyedy. "Comparison of Solution Chemical Properties and Biological Activity of Ruthenium Complexes of Selected β-Diketone, 8-Hydroxyquinoline and Pyrithione Ligands". Pharmaceuticals 14, № 6 (27 травня 2021): 518. http://dx.doi.org/10.3390/ph14060518.

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In this work, the various biological activities of eight organoruthenium(II) complexes were evaluated to reveal correlations with their stability and reactivity in aqueous media. Complexes with general formula [Ru(η6-p-cymene)(X,Y)(Z)] were prepared, where (X,Y) represents either an O,O-ligand (β-diketone), N,O-ligand (8-hydroxyquinoline) or O,S-pyrithione-type ligands (pyrithione = 1-hydroxypyridine-2(1H)-thione) with Cl− or 1,3,5-triaza-7-phosphaadamantane (PTA) as a co-ligand (Z). The tested complexes inhibit the chlamydial growth on HeLa cells, and one of the complexes inhibits the growth
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Hejrani-Dalir, Ali, Masumeh Tabatabaee та Ali Sheibani. "Synthesis and crystal structure of 2-amino-3-hydroxypyridinium dioxido(pyridine-2,6-dicarboxylato-κ3O2,N,O6)vanadate(V) and its conversion to nanostructured V2O5". Acta Crystallographica Section C Structural Chemistry 71, № 2 (12 січня 2015): 89–92. http://dx.doi.org/10.1107/s2053229614027983.

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2-Amino-3-hydroxypyridinium dioxido(pyridine-2,6-dicarboxylato-κ3O2,N,O6)vanadate(V), (C5H7N2O)[V(C7H3NO4)O2] or [H(amino-3-OH-py)][VO2(dipic)], (I), was prepared by the reaction of VCl3with dipicolinic acid (dipicH2) and 2-amino-3-hydroxypyridine (amino-3-OH-py) in water. The compound was characterized by elemental analysis, IR spectroscopy and X-ray structure analysis, and consists of an anionic [VO2(dipic)]−complex and an H(amino-3-OH-py)+counter-cation. The VVion is five-coordinated by oneO,N,O′-tridentate dipic dianionic ligand and by two oxide ligands. Thermal decomposition of (I) in the
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Argibay-Otero, Saray, Rosa Carballo, and Ezequiel M. Vázquez-López. "Crystal structure offac-tricarbonylchloridobis(4-hydroxypyridine)rhenium(I)–pyridin-4(1H)-one (1/1)." Acta Crystallographica Section E Crystallographic Communications 73, no. 10 (September 29, 2017): 1551–54. http://dx.doi.org/10.1107/s2056989017013512.

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The asymmetric unit of the title compound, [ReCl(C5H5NO)2(CO)3]·C5H5NO, contains one molecule of the complexfac-[ReCl(4-pyOH)2(CO)3] (where 4-pyOH represents 4-hydroxypyridine) and one molecule of pyridin-4(1H)-one (4-HpyO). In the molecule of the complex, the Re atom is coordinated to two N atoms of the two 4-pyOH ligands, three carbonyl C atoms, in a facial configuration, and the Cl atom. The resulting geometry is slightly distorted octahedral. In the crystal structure, both fragments are associated by hydrogen bonds; two 4-HpyO molecules bridge between two molecules of the complex using the
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Jotani, Mukesh M., Hadi D. Arman, Pavel Poplaukhin та Edward R. T. Tiekink. "Bis(N,N-diethyldithiocarbamato-κ2S,S′)(3-hydroxypyridine-κN)zinc and bis[N-(2-hydroxyethyl)-N-methyldithiocarbamato-κ2S,S′](3-hydroxypyridine-κN)zinc: crystal structures and Hirshfeld surface analysis". Acta Crystallographica Section E Crystallographic Communications 72, № 12 (1 листопада 2016): 1700–1709. http://dx.doi.org/10.1107/s205698901601728x.

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The common feature of the molecular structures of the title compounds, [Zn(C5H10NS2)2(C5H5NO)], (I), and [Zn(C4H8NOS2)2(C5H5NO)], (II), are NS4donor sets derived fromN-bound hydroxypyridyl ligands and asymmetrically chelating dithiocarbamate ligands. The resulting coordination geometries are highly distorted, being intermediate between square pyramidal and trigonal bipyramidal for both independent molecules comprising the asymmetric unit of (I), and significantly closer towards square pyramidal in (II). The key feature of the molecular packing in (I) is the formation of centrosymmetric, dimeri
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Al-Saeedi, Sameerah, Laila Abdel-Rahman, Ahmed Abu-Dief, Shimaa Abdel-Fatah, Tawfiq Alotaibi, Ali Alsalme, and Ayman Nafady. "Catalytic Oxidation of Benzyl Alcohol Using Nanosized Cu/Ni Schiff-Base Complexes and Their Metal Oxide Nanoparticles." Catalysts 8, no. 10 (October 13, 2018): 452. http://dx.doi.org/10.3390/catal8100452.

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In this work, nanosized Cu and Ni Schiff-base complexes, namely ahpvCu, ahpnbCu, and ahpvNi, incorporating imine ligands derived from the condensation of 2-amino-3-hydroxypyridine, with either 3-methoxysalicylaldehyde (ahpv) or 4-nitrobenzaldehyde (ahpnb), were synthesized using sonochemical approach. The structure and properties of the new ligands and their complexes with Ni(II) and Cu(II) were determined via infrared (IR), nuclear magnetic resonance (NMR), electronic spectra (UV-Vis), elemental analysis (CHN), thermal gravimetric analysis (TGA), molar conductivity (Λm), and magnetic moment (
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Dissertations / Theses on the topic "Hydroxypyridine ligands"

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Farhad, Mohammad. "Studies on new trinuclear palladium compounds." Connect to full text, 2007. http://hdl.handle.net/2123/2477.

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Doctor of Philosophy(PhD)<br>The present study deals with the synthesis and characterization of six tri-palladium complexes code named MH3, MH4, MH5, MH6, MH7 and MH8 that contained two planaramine ligands bound to the central or each of the terminal metal ions. The activity of the compounds against human cancer cell lines: A2780, A2780cisR and A2780ZD0473R, cell uptake, levels of DNA-binding and nature of interaction with salmon sperm and pBR322 plasmid DNA have also been determined. Whereas cisplatin binds with DNA forming mainly intrastrand GG adduct that causes local bending of a DNA stran
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Book chapters on the topic "Hydroxypyridine ligands"

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of mixed ligand copper(II) bromo complex with 1-hydroxypyridine-2-thione." In Magnetic Properties of Paramagnetic Compounds, 164. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54237-8_81.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of copper(II) mixed ligand complex with thiophene-2-aldehyde thiosemicarbazone and 2-hydroxypyridine." In Magnetic Properties of Paramagnetic Compounds, 495. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54237-8_291.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of mixed ligand copper(II) chloro complex with 1-hydroxypyridine-2-thione and triphenylphosphine." In Magnetic Properties of Paramagnetic Compounds, 154–55. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54237-8_76.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of mixed ligand copper(II) bromo complex with 1-hydroxypyridine-2-thione and triphenylphosphine." In Magnetic Properties of Paramagnetic Compounds, 165–66. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54237-8_82.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of mixed ligand copper(II) chloro complex with 1-hydroxypyridine-2-thione and bis(diphenylphosphino)methane." In Magnetic Properties of Paramagnetic Compounds, 156–57. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54237-8_77.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of mixed ligand copper(II) bromo complex with 1-hydroxypyridine-2-thione and bis(diphenylphosphino) methane." In Magnetic Properties of Paramagnetic Compounds, 167–68. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54237-8_83.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of mixed ligand copper(II) chloro complex with 1-hydroxypyridine-2-thione and 1,2-bis(diphenylphosphino)ethane." In Magnetic Properties of Paramagnetic Compounds, 158–59. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54237-8_78.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of mixed ligand copper(II) chloro complex with 1-hydroxypyridine-2-thione and 1,2-bis(diphenylphosphino)propane." In Magnetic Properties of Paramagnetic Compounds, 160–61. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54237-8_79.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of mixed ligand copper(II) chloro complex with 1-hydroxypyridine-2-thione and 1,2-bis(diphenylphosphino)butane." In Magnetic Properties of Paramagnetic Compounds, 162–63. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54237-8_80.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of mixed ligand copper(II) bromo complex with 1-hydroxypyridine-2-thione and 1,2-bis(diphenylphosphino)ethane." In Magnetic Properties of Paramagnetic Compounds, 169–70. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54237-8_84.

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Conference papers on the topic "Hydroxypyridine ligands"

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Bare, William D., Nathan H. Mack, James N. Demas, and Benjamin A. DeGraff, Jr. "Highly efficient pH-induced intramolecular quenching of luminescence in rhenium complexes containing the hydroxypyridinde ligand." In Environmental and Industrial Sensing, edited by Tuan Vo-Dinh and Robert L. Spellicy. SPIE, 2001. http://dx.doi.org/10.1117/12.417357.

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