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Journal articles on the topic 'Hyper-Crosslinked polymers'

Author: Grafiati

Published: 8 June 2024

Last updated: 31 July 2025

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1

Rubin Pedrazzo, Alberto, Fabrizio Caldera, Marco Zanetti, Silvia Lucia Appleton, Nilesh Kumar Dahkar, and Francesco Trotta. "Mechanochemical green synthesis of hyper-crosslinked cyclodextrin polymers." Beilstein Journal of Organic Chemistry 16 (June 29, 2020): 1554–63. http://dx.doi.org/10.3762/bjoc.16.127.

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Cyclodextrin nanosponges (CD-NS) are nanostructured crosslinked polymers made up of cyclodextrins. The reactive hydroxy groups of CDs allow them to act as multifunctional monomers capable of crosslinking to bi- or multifunctional chemicals. The most common NS synthetic pathway consists in dissolving the chosen CD and an appropriate crosslinker in organic polar aprotic liquids (e.g., N,N-dimethylformamide or dimethyl sulfoxide), which affect the final result, especially for potential biomedical applications. This article describes a new, green synthetic pathway through mechanochemistry, in part

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2

Guo, Ziyang, Xiaodong Tian, Yan Song, et al. "Hard Carbons Derived from Phenyl Hyper-Crosslinked Polymers for Lithium-Ion Batteries." Coatings 13, no. 2 (2023): 421. http://dx.doi.org/10.3390/coatings13020421.

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Hyper-crosslinked polymers are attracting extensive attention owing to their ease of design and synthesis. Based on the flexibility of its molecular design, a hyper-crosslinked polymer with a π-conjugated structure and its derived carbon were synthesized by the Friedel–Crafts reaction. The polymer and its derived hard carbon material were characterized by FTIR, 13C NMR, Raman, BET, and other characterization tools. The electrochemical properties of both materials as anode electrodes of lithium-ion batteries were investigated. Benefiting from the highly cross-linked skeleton and conjugated stru

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3

Jeon, Hyo Jin, Dong Ok Kim, Jea Sung Park, et al. "Synthesis of Hyper Crosslinked Polymer Particle Having Hydroxyl Group." Polymer Korea 35, no. 1 (2011): 66–71. http://dx.doi.org/10.7317/pk.2011.35.1.66.

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4

Nikoshvili, L., A. Bertova, E. Sulman, and L. Kiwi-Minsker. "Hyper-crosslinked Polystyrene as a Support for Development of Hydrogenation Catalysts: Influence of Porosity." Bulletin of Science and Practice 5, no. 12 (2019): 47–53. http://dx.doi.org/10.33619/2414-2948/49/05.

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This paper is devoted to the prospects for the use of hyper-crosslinked polystyrene as a support for the development of catalysts for selective hydrogenation of alkynols for synthesis of fragrant substances and fat-soluble vitamins E and K. Various types of hyper-crosslinked polystyrene, characterized by different porosity, were used for the synthesis of palladium catalysts by wet-impregnation of polymers with palladium acetate. It was shown that in the case of C5 alkynol, the pore structure of the polymers does not significantly affect the observed catalytic activity, whereas for C10 and C20

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5

Jia, Ziyan, Jiannan Pan, Chen Tian, and Daqiang Yuan. "Twisted molecule-based hyper-crosslinked porous polymers for rapid and efficient removal of organic micropollutants from water." RSC Advances 8, no. 64 (2018): 36812–18. http://dx.doi.org/10.1039/c8ra04792h.

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6

Быков, Алексей Владимирович, and Галина Николаевна Демиденко. "THERMAL STABILITY AND POROSITY OF HYPER-CROSSLINKED AROMATIC POLYMERS." Вестник Тверского государственного университета. Серия: Химия, no. 2(40) (June 6, 2020): 62–72. http://dx.doi.org/10.26456/vtchem2020.2.8.

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В работе методами сопряженной с масс-спектрометрией термогравиметрии, физической адсорбции азота, инфракрасной спектроскопии диффузного отражения и рентгенофотоэлектронной спектроскопии проведено исследование изменений пористости и состава функциональных групп полимера MN270 в температурном диапазоне от 30 до 600С. В ходе исследования показано, что при разогреве ненаполненного металлами полимера его микропористая структура рушится при температурах ниже 300С, в то время как разрушение, связанное с деструкцией и деполимеризацией самой полимерной матрицы, происходит при температурах выше 350С. Th

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7

Ramirez-Vidal, Pamela, Fabián Suárez-García, Rafael L. S. Canevesi, et al. "Irreversible deformation of hyper-crosslinked polymers after hydrogen adsorption." Journal of Colloid and Interface Science 605 (January 2022): 513–27. http://dx.doi.org/10.1016/j.jcis.2021.07.104.

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8

Meng, Bo, Haiying Li, Shannon M. Mahurin, Honglai Liu, and Sheng Dai. "Hyper-crosslinked cyclodextrin porous polymer: an efficient CO2 capturing material with tunable porosity." RSC Advances 6, no. 111 (2016): 110307–11. http://dx.doi.org/10.1039/c6ra18307g.

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Several cyclodextrin (CD)-based hyper-crosslinked porous polymers (HCPPs) were designed and synthesized for selective CO<sub>2</sub> adsorption and storage. A feasible way to tailor the porosity of the materials was also established.

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9

Li, Haiying, Bo Meng, Shannon M. Mahurin, et al. "Carbohydrate based hyper-crosslinked organic polymers with –OH functional groups for CO2 separation." Journal of Materials Chemistry A 3, no. 42 (2015): 20913–18. http://dx.doi.org/10.1039/c5ta03213j.

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A class of novel hyper-crosslinked microporous polymers, based on green and renewable carbohydrates, was synthesized for carbon capture and storage with high CO<sub>2</sub>/N<sub>2</sub> selectivity by hydrogen bonding and dipole–quadrupole interactions.

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10

Fayemiwo, Kehinde A., Goran T. Vladisavljević, Seyed Ali Nabavi, et al. "Nitrogen-rich hyper-crosslinked polymers for low-pressure CO2 capture." Chemical Engineering Journal 334 (February 2018): 2004–13. http://dx.doi.org/10.1016/j.cej.2017.11.106.

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11

Setnickova, Katerina, Karel Jerabek, Tomas Strasak, et al. "Synthesis, Characterization, and Gas Adsorption Performance of Amine-Functionalized Styrene-Based Porous Polymers." Polymers 15, no. 1 (2022): 13. http://dx.doi.org/10.3390/polym15010013.

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In recent years, porous materials have been extensively studied by the scientific community owing to their excellent properties and potential use in many different areas, such as gas separation and adsorption. Hyper-crosslinked porous polymers (HCLPs) have gained attention because of their high surface area and porosity, low density, high chemical and thermal stability, and excellent adsorption capabilities in comparison to other porous materials. Herein, we report the synthesis, characterization, and gas (particularly CO2) adsorption performance of a series of novel styrene-based HCLPs. The m

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12

Luo, Yiqian, Yixuan Mei, Yang Xu, and Kun Huang. "Hyper-Crosslinked Porous Organic Nanomaterials: Structure-Oriented Design and Catalytic Applications." Nanomaterials 13, no. 18 (2023): 2514. http://dx.doi.org/10.3390/nano13182514.

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Hyper-crosslinked porous organic nanomaterials, especially the hyper-crosslinked polymers (HCPs), are a unique class of materials that combine the benefits of high surface area, porous structure, and good chemical and thermal stability all rolled into one. A wide range of synthetic methods offer an enormous variety of HCPs with different pore structures and morphologies, which has allowed HCPs to be developed for gas adsorption and separations, chemical adsorption and encapsulation, and heterogeneous catalysis. Here, we present a systematic review of recent approaches to pore size modulation a

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13

Lang, Mathias, Alexandra Schade, and Stefan Bräse. "Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction." Beilstein Journal of Organic Chemistry 12 (November 29, 2016): 2570–76. http://dx.doi.org/10.3762/bjoc.12.252.

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Herein we report the syntheses of two porous hyper-crosslinked polymers (HCPs) via thiol–yne reaction with rigid tetrahedral and pseudo-octahedral core structures. Sorption measurements with nitrogen gas at 77 K revealed BET-surface areas up to 650 m²/g. Those networks also showed a high thermal stability as well as insolubility in common organic solvents.

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14

Kim, Soobin, and Myungeun Seo. "Control of porosity in hierarchically porous polymers derived from hyper-crosslinked block polymer precursors." Journal of Polymer Science Part A: Polymer Chemistry 56, no. 8 (2018): 900–913. http://dx.doi.org/10.1002/pola.28966.

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15

Wang, Kewei, Liang Huang, Shumaila Razzaque, Shangbin Jin, and Bien Tan. "Fabrication of Hollow Microporous Carbon Spheres from Hyper-Crosslinked Microporous Polymers." Small 12, no. 23 (2016): 3134–42. http://dx.doi.org/10.1002/smll.201600256.

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16

Gokkus, Kutalmis. "New hyper-crosslinked polymers for enhanced CO2 adsorption: Synthesis and characterization." Sustainable Chemistry and Pharmacy 45 (June 2025): 102015. https://doi.org/10.1016/j.scp.2025.102015.

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17

Pei, Baoyou, Xiaoyan Xiang, Ting Liu, et al. "Preparation of Chloromethylated Pitch–Based Hyper–Crosslinked Polymers and An Immobilized Acidic Ionic Liquid as A Catalyst for the Synthesis of Biodiesel." Catalysts 9, no. 11 (2019): 963. http://dx.doi.org/10.3390/catal9110963.

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Hyper-crosslinking polymers and its immobilized acid ionic liquid catalyst were prepared using cheap pitch, as a monomer, through hyper-crosslinking reactions and allyl chloride, as a chlorine source, for chloromethylation and further grafting with imidazole and functionalizing with sulfonic acid. The polymers were characterized by FE-SEM, FTIR, TG, and nitrogen sorption. The grafting ratios of the chloromethylated pitch-based hyper-crosslinked polymer (HCPpitch–CH2–Cl) and immobilized acid ionic liquid [HCPpitch–Im–Pros][Tos] were 3.5 mmol/g and 3.0 mmol/g, and the BET specific surface areas

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18

Gatti, Giorgio, Mina Errahali, Lorenzo Tei, Maurizio Cossi, and Leonardo Marchese. "On the Gas Storage Properties of 3D Porous Carbons Derived from Hyper-Crosslinked Polymers." Polymers 11, no. 4 (2019): 588. http://dx.doi.org/10.3390/polym11040588.

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The preparation of porous carbons by post-synthesis treatment of hypercrosslinked polymers is described, with a careful physico-chemical characterization, to obtain new materials for gas storage and separation. Different procedures, based on chemical and thermal activations, are considered; they include thermal treatment at 380 °C, and chemical activation with KOH followed by thermal treatment at 750 or 800 °C; the resulting materials are carefully characterized in their structural and textural properties. The thermal treatment at temperature below decomposition (380 °C) maintains the polymer

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19

Tang, Cheng, Wenwen Yang, Zhijuan Zou, Fang Liao, Chunmei Zeng, and Kunpeng Song. "Facile Synthesis Hyper-Crosslinked PdFe Bimetallic Polymer as Highly Active Catalyst for Ullmann Coupling Reaction of Chlorobenzene." Polymers 15, no. 12 (2023): 2748. http://dx.doi.org/10.3390/polym15122748.

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The synthesis of efficient and sustainable heterogeneous Pd-based catalysts has been an active field of research due to their crucial role in carbon–carbon coupling reactions. In this study, we developed a facile and eco-friendly in situ assembly technique to produce a PdFe bimetallic hyper-crosslinked polymer (HCP@Pd/Fe) to use as a highly active and durable catalyst in the Ullmann reaction. The HCP@Pd/Fe catalyst exhibits a hierarchical pore structure, high specific surface area, and uniform distribution of active sites, which promote catalytic activity and stability. Under mild conditions,

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20

An, Wan-Kai, Shi-Jia Zheng, Hui-Xing Zhang, et al. "s-Tetrazine-functionalized hyper-crosslinked polymers for efficient photocatalytic synthesis of benzimidazoles." Green Chemistry 23, no. 3 (2021): 1292–99. http://dx.doi.org/10.1039/d0gc03719b.

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21

Luo, Xiaona, Jialin Shi, Hongyu Zhao, et al. "Biased adsorption of ethane over ethylene on low-cost hyper-crosslinked polymers." Journal of Solid State Chemistry 271 (March 2019): 199–205. http://dx.doi.org/10.1016/j.jssc.2018.12.061.

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22

Sadak, Ali Enis. "A comparative gas sorption study of dicarbazole-derived microporous hyper-crosslinked polymers." Microporous and Mesoporous Materials 311 (February 2021): 110727. http://dx.doi.org/10.1016/j.micromeso.2020.110727.

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23

Grätz, Sven, Sebastian Zink, Hanna Kraffczyk, Marcus Rose, and Lars Borchardt. "Mechanochemical synthesis of hyper-crosslinked polymers: influences on their pore structure and adsorption behaviour for organic vapors." Beilstein Journal of Organic Chemistry 15 (May 24, 2019): 1154–61. http://dx.doi.org/10.3762/bjoc.15.112.

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This study elucidates a mechanochemical polymerization reaction towards a hyper-crosslinked polymer as an alternative to conventional solvent-based procedures. The swift and solvent-free Friedel–Crafts alkylation reaction yields a porous polymer with surface areas of up to 1720 m2g−1 and pore volumes of up to 1.55 cm3g−1. The application of LAG (liquid-assisted grinding) revealed a profound impact of the liquid´s boiling point on the textural properties of the obtained polymer materials. Finally, the materials are characterized by vapour sorption experiments with benzene and cyclohexane.

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24

Wang, You, Yiwen Cao, Junjiang Zong, et al. "Acetamido-functionalized hyper-crosslinked polymers for efficient removal of phenol in aqueous solution." Separation and Purification Technology 287 (April 2022): 120566. http://dx.doi.org/10.1016/j.seppur.2022.120566.

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25

Xiong, Gang, Shan Gao, Qian Zhang, et al. "High porosity cyclotriphosphazene-based hyper-crosslinked polymers as efficient cationic dye MB adsorbents." Polymer 247 (April 2022): 124787. http://dx.doi.org/10.1016/j.polymer.2022.124787.

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26

Tian, Ke, Ting-Ting Zhu, Ping Lan, et al. "Massive Preparation of Coumarone-indene Resin-based Hyper-crosslinked Polymers for Gas Adsorption." Chinese Journal of Polymer Science 36, no. 10 (2018): 1168–74. http://dx.doi.org/10.1007/s10118-018-2127-6.

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27

Chen, Xiaoyi, Xinguo Chen, Yuanjie Fu, Jianqiang Zhang, Shenglong Hu, and Heming Luo. "Preparation and electrochemical characteristics of porous carbon composites originating from hyper-crosslinked polymers." Journal of Energy Storage 73 (December 2023): 108998. http://dx.doi.org/10.1016/j.est.2023.108998.

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28

Zhang, Xuewei, Jean-Christophe Daigle, and Karim Zaghib. "Comprehensive Review of Polymer Architecture for All-Solid-State Lithium Rechargeable Batteries." Materials 13, no. 11 (2020): 2488. http://dx.doi.org/10.3390/ma13112488.

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Solid-state batteries are an emerging option for next-generation traction batteries because they are safe and have a high energy density. Accordingly, in polymer research, one of the main goals is to achieve solid polymer electrolytes (SPEs) that could be facilely fabricated into any preferred size of thin films with high ionic conductivity as well as favorable mechanical properties. In particular, in the past two decades, many polymer materials of various structures have been applied to improve the performance of SPEs. In this review, the influences of polymer architecture on the physical and

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29

Chen, Dongyang, Shuai Gu, Yu Fu, et al. "Hyper-crosslinked aromatic polymers with improved microporosity for enhanced CO2/N2 and CO2/CH4 selectivity." New Journal of Chemistry 41, no. 14 (2017): 6834–39. http://dx.doi.org/10.1039/c7nj00919d.

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30

Shang, Qigao, Yuhao Cheng, Zhenpeng Gong, et al. "Constructing novel hyper-crosslinked conjugated polymers through molecular expansion for enhanced gas adsorption performance." Journal of Hazardous Materials 426 (March 2022): 127850. http://dx.doi.org/10.1016/j.jhazmat.2021.127850.

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31

Huang, Pu, Guozong Yue, Jiazhou Chen, et al. "Polyvinyl Alcohol (PVA)-based Hyper-crosslinked Polymers (HCPs) and Their Ultrahigh Iodine Adsorption Capacity." Chemistry Letters 49, no. 10 (2020): 1163–66. http://dx.doi.org/10.1246/cl.200245.

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32

Liu, Cong, Weihua Liu, Qianqian Wang, Chun Wang, and Qiuhua Wu. "Construction of novel hyper-crosslinked polymers with adjustable hydrophilicity for efficient extraction of nitroimidazoles." Journal of Chromatography A 1743 (February 2025): 465702. https://doi.org/10.1016/j.chroma.2025.465702.

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33

Tang, Cheng, Zhijuan Zou, Yufang Fu, and Kunpeng Song. "Highly Dispersed DPPF Locked in Knitting Hyper‐Crosslinked Polymers as Efficient and Recyclable Catalyst." ChemistrySelect 3, no. 21 (2018): 5987–92. http://dx.doi.org/10.1002/slct.201800610.

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34

Zong, Kai, Kejie Jiang, Xiaojun Bao, and Dongshun Deng. "Preparation of highly sulfonated hyper-crosslinked polymers as promising ammonia adsorbents with excellent performance." Journal of Environmental Chemical Engineering 13, no. 2 (2025): 116082. https://doi.org/10.1016/j.jece.2025.116082.

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35

Liang, Yawei, and Yibing Lu. "Synthesis, Catalysing and Application of Functional Carbon Dioxide-based Polymers." Highlights in Science, Engineering and Technology 6 (July 27, 2022): 202–10. http://dx.doi.org/10.54097/hset.v6i.962.

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CO2 has the characteristics of low chemical activity and dynamic stability, and it is difficult to activate. Despite of these difficulties, it has attracted increasing attention to make the most of CO2, which is a potentially renewable resource. CO2-based polymers have superior functions and a wide range of uses. the rational utilization of CO2 can not only alleviate the environmental problems caused by emissions, but also be a vital measure of human energy utilization. Meanwhile, in view of the low chemical activity of carbon dioxide, to achieve the synthesis of CO2-based polymer, the study o

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36

Wang, You, Yiwen Cao, Xu Zeng, Jianhan Huang, and You-Nian Liu. "Furan- and Thiophene-Modified Hyper-Crosslinked Polymers and Their Adsorption of Phenol from Aqueous Solution." Industrial & Engineering Chemistry Research 60, no. 2 (2021): 931–38. http://dx.doi.org/10.1021/acs.iecr.0c04784.

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37

Xia, Xiaochen, Peijian Sun, Xuehui Sun, et al. "Hyper-crosslinked polymers with controlled multiscale porosity for effective removal of benzene from cigarette smoke." e-Polymers 22, no. 1 (2021): 19–29. http://dx.doi.org/10.1515/epoly-2022-0006.

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Abstract A series of hyper-crosslinked polymers (HCPs) with connected hierarchical porous structures were synthesized from phenyl-based precursors of benzene (BEN), benzyl alcohol, aniline, biphenyl, and 1,3,5-triphenylbenzene (TPB) via the knitting method. The porous structures of the HCPs were greatly influenced by substituent groups and BEN ring number in the precursors. HCPs prepared from TPB had the largest surface area and pore volume with multiscale porosity. The porous structure of the HCPs could also be adjusted by the crosslinker amount. Insufficient crosslinking led to incomplete po

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38

Zong, Kai, Xiaojun Bao, Kejie Jiang, Mei Zhang, and Dongshun Deng. "Efficient adsorption of NH3 on Li salts@ hyper-crosslinked polymers: Equilibrium, kinetic, and thermodynamic analysis." Separation and Purification Technology 362 (July 2025): 131815. https://doi.org/10.1016/j.seppur.2025.131815.

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39

Fu, Zhenyu, Jizhen Jia, Jing Li, and Changkun Liu. "Transforming waste expanded polystyrene foam into hyper-crosslinked polymers for carbon dioxide capture and separation." Chemical Engineering Journal 323 (September 2017): 557–64. http://dx.doi.org/10.1016/j.cej.2017.04.090.

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40

Gao, Hui, Lei Ding, Hua Bai, and Lei Li. "Microporous Organic Polymers Based on Hyper-Crosslinked Coal Tar: Preparation and Application for Gas Adsorption." ChemSusChem 10, no. 3 (2017): 618–23. http://dx.doi.org/10.1002/cssc.201601475.

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41

Zhang, Ruina, Guokai Cui, Xiuqin Wang, et al. "Ionic liquid-based advanced porous organic hyper-crosslinked polymers (ILHCPs) for CO2 capture and conversion." Chemical Engineering Journal 489 (June 2024): 151102. http://dx.doi.org/10.1016/j.cej.2024.151102.

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42

Zhang, Hui, Ruitong Yin, and Chengdong Wang. "Recent advances of hyper-crosslinked porous polymers in environment related fields: synthesis, functionalization, and applications." Environmental Technology Reviews 14, no. 1 (2025): 427–57. https://doi.org/10.1080/21622515.2025.2485364.

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43

Gokkus, Kutalmis, Mursel Arici, Nesrin Sener, Cansel Tuncer, and S. Alper Akalin. "CO2 adsorption performance of novel polyaramid-based hyper-crosslinked polymers synthesized by the Friedel-Crafts." Polymer 324 (April 2025): 128254. https://doi.org/10.1016/j.polymer.2025.128254.

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44

Liu, Fenglei, Wenhao Fu, and Shuixia Chen. "Adsorption behavior and kinetics of CO 2 on amine‐functionalized hyper‐crosslinked polymer." Journal of Applied Polymer Science 137, no. 12 (2019): 48479. http://dx.doi.org/10.1002/app.48479.

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45

Cai, Yang, Xiangyu Wen, Yuwei Wang, et al. "Preparation of hyper-crosslinked polymers with hierarchical porous structure from hyperbranched polymers for adsorption of naphthalene and 1-naphthylamine." Separation and Purification Technology 266 (July 2021): 118542. http://dx.doi.org/10.1016/j.seppur.2021.118542.

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46

Yu-feng, Sun, Liu Zong-tang, Fei Zheng-hao, Li Zhen-xing, and Xing Rong. "Adsorption of Phenolic Compounds onto Tannic Acid Modified Hyper-crosslinked Adsorption Resin." Acta Polymerica Sinica 014, no. 1 (2014): 107–14. http://dx.doi.org/10.3724/sp.j.1105.2014.13165.

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47

Cai, Kaixing, Ping Liu, Tianxiang Zhao, Kai Su, Yi Yang, and Duan-Jian Tao. "Construction of hyper-crosslinked ionic polymers with high surface areas for effective CO2 capture and conversion." Microporous and Mesoporous Materials 343 (September 2022): 112135. http://dx.doi.org/10.1016/j.micromeso.2022.112135.

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48

Gu, Jiarui, Pingping Shao, Lan Luo, et al. "Microporous triazine-based ionic hyper-crosslinked polymers for efficient and selective separation of H2S/CH4/N2." Separation and Purification Technology 285 (March 2022): 120377. http://dx.doi.org/10.1016/j.seppur.2021.120377.

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49

Guo, Zengjing, Shuguang Ning, Shicheng Xu, Yongying Zhang, Yifan Dong, and Hongjing Han. "Tailoring Mesoporosity of Multi-Hydroxyls Hyper-Crosslinked Organic Polymers for Reinforced Ambient Chemical Fixation of CO2." Catalysts 14, no. 10 (2024): 707. http://dx.doi.org/10.3390/catal14100707.

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Ambient condition-determined chemical CO2 fixation affords great promise for remitting the pressure of CO2 release. The construction of a microporous environment easily captures CO2 molecules around the reactive sites of the catalyst to reinforce the reaction process. Herein, multi-hydroxyl-containing hyper-crosslinked organic polymers (HCPs-OH-n) are synthesized by the polymerization of 1,4-dichlorobenzyl (DCX) and m-trihydroxybenzene in the monosaccharide form in a Friedel–Crafts alkylation hypercrosslinking process (FCAHP). By tuning the DCX ratio in the FCAHP, the structural properties can

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50

Jia, Ziyan, Jiannan Pan, and Daqiang Yuan. "High Gas Uptake and Selectivity in Hyper-Crosslinked Porous Polymers Knitted by Various Nitrogen-Containing Linkers." ChemistryOpen 6, no. 4 (2017): 554–61. http://dx.doi.org/10.1002/open.201700073.

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