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Journal articles on the topic 'Hypercrosslinked polystyrene'

Author: Grafiati

Published: 3 June 2025

Last updated: 31 July 2025

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1

Brovko, Roman V., Valentin Yu Doluda, Olga V. Lefedova, Ilya A. Tarasyuk, Dmitry V. Filippov, and Adele R. Latypova. "SYNTHEIS OF NI IMPREGNATED HYPERCROSSLINKED POLYSTERENE FOR CATALITIC HYDROGENATION OF D-GLUCOSE." IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA KHIMICHESKAYA TEKHNOLOGIYA 63, no. 5 (2020): 51–58. http://dx.doi.org/10.6060/ivkkt.20206305.6208.

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Development of efficient catalysts is in focus of modern chemical technology for production of fine chemicals. D-sorbitol is widely used as sweetener, food additive and fuel compound is typically produced by D-glucose hydrogenation over Ni-Reney catalyst. However, this catalyst is characterized by not sufficient stability and selectivity to D-sorbitol formation. The described study is devoted to synthesis of nickel containing hypercrosslinked polystyrene for D-glucose hydrogenation process. Hypercrosslinked polystyrene is one of the representatives of crosslinked polymers with rigid matrix app

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2

Tsyurupa, M. P., T. A. Mrachkovskaya, L. A. Maslova, et al. "Soluble intramolecularly hypercrosslinked polystyrene." Reactive Polymers 19, no. 1-2 (1993): 55–66. http://dx.doi.org/10.1016/0923-1137(93)90010-d.

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3

Yang, Yuwan, Bien Tan, and Colin D. Wood. "Solution-processable hypercrosslinked polymers by low cost strategies: a promising platform for gas storage and separation." Journal of Materials Chemistry A 4, no. 39 (2016): 15072–80. http://dx.doi.org/10.1039/c6ta05226f.

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4

Li, Yilin, Junjie Liu, Jingjing Kong, Ning Qi, and Zhiquan Chen. "Role of ultramicropores in the remarkable gas storage in hypercrosslinked polystyrene networks studied by positron annihilation." Physical Chemistry Chemical Physics 23, no. 24 (2021): 13603–11. http://dx.doi.org/10.1039/d1cp01867a.

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In this paper, hypercrosslinked polystyrene (HCLPS) networks were synthesized by radical bulk polymerization and Friedel–Crafts alkylation reactions using vinylbenzyl-co-divinylbenzene chloride (VBC-DVB) as the precursors.

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5

Shimanskaya, E., P. Guseva, and A. Stepacheva. "Anisole conversion using catalysts synthesized by hydrothermal method." Bulletin of Science and Practice 4, no. 12 (2018): 35–41. https://doi.org/10.5281/zenodo.2253033.

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This work is devoted to the study of conversion of anisole, as one of the lignin monomers, in the presence of catalysts synthesized by the hydrothermal method. Platinum and palladium catalyst deposited on the polymer matrix of hypercrosslinked polystyrene allowed achieving about 90% of anisole conversion. It was shown that during the conversion of anisole, cyclohexane, methylcyclohexane and phenol are the main products. The highest selectivity (approx. 88%) with respect to cyclohexane was shown by a platinum catalyst supported on hypercrosslinked polystyrene. The palladium catalyst showed lowe

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6

Tolmacheva, V. V., V. Yu Savinova, N. O. Goncharov, et al. "Sorption of Amphenicols on Magnetic Hypercrosslinked Polystyrene." Russian Journal of Physical Chemistry A 96, no. 6 (2022): 1268–72. http://dx.doi.org/10.1134/s0036024422060267.

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7

Tsyurupa, M. P., Z. K. Blinnikova, N. A. Proskurina, A. V. Pastukhov, L. A. Pavlova, and V. A. Davankov. "Hypercrosslinked polystyrene: The first nanoporous polymeric material." Nanotechnologies in Russia 4, no. 9-10 (2009): 665–75. http://dx.doi.org/10.1134/s1995078009090109.

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8

Kebets, Pavel A., and Pavel N. Nesterenko. "Zwitterion-exchange properties of sulfonated hypercrosslinked polystyrene." Mendeleev Communications 12, no. 4 (2002): 155–56. http://dx.doi.org/10.1070/mc2002v012n04abeh001622.

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9

Grzywiński, D., M. Szumski, and B. Buszewski. "Hypercrosslinked cholesterol-based polystyrene monolithic capillary columns." Journal of Chromatography A 1477 (December 2016): 11–21. http://dx.doi.org/10.1016/j.chroma.2016.11.023.

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10

Joseph, Roychen, Warren T. Ford, Shanmin Zhang, M. P. Tsyurupa, A. V. Pastukhov, and V. A. Davankov. "Solid-state13C-NMR analysis of hypercrosslinked polystyrene." Journal of Polymer Science Part A: Polymer Chemistry 35, no. 4 (1997): 695–701. http://dx.doi.org/10.1002/(sici)1099-0518(199703)35:4<695::aid-pola12>3.0.co;2-i.

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11

Wang, Zheng, Long Geng, Jiateng Zhao, Wenyuan Qiao, and Changhui Liu. "Comprehensive Utilization of Fossil Energy: Fabrication of Fire-Retardant Building Materials from Waste Plastic." Journal of Composites Science 8, no. 7 (2024): 266. http://dx.doi.org/10.3390/jcs8070266.

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As one of the most common fossil derivatives, plastics are widely used for their exceptional chemical stability, low density, and ease of processing. In recent years, there has been a significant increase in the production of waste plastics, coupled with a low recycling rate, resulting in serious environmental pollution. To enhance the use of waste plastics, this research synthesized flame-retardant materials from hypercrosslinked polystyrene with different molar fractions of flame retardants. Waste polystyrene foam was used as the raw material, while aniline, triphenylphosphine, and melamine

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12

Wu, Xiaoyu, Yi Liu, Yongfeng Liu, Duolong Di, Mei Guo, and Lei Zhao. "Synthesis, characterization, and adsorption properties of ionic liquid-modified hypercrosslinked polystyrene resins." RSC Advances 5, no. 89 (2015): 72601–9. http://dx.doi.org/10.1039/c5ra08273k.

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13

Filatova, A., V. Matveeva, E. Shimanskaya, and L. Mushinskii. "The kinetics of catalytic hydrogenation of nitrobenzene in the presence of Ru-containing catalysts." Bulletin of Science and Practice 4, no. 12 (2018): 89–95. https://doi.org/10.5281/zenodo.2254348.

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The process of catalytic hydrogenation of nitrobenzene is the most important chemical and technological process of obtaining aniline, which is used as a semi-product in the synthesis of polyurethanes, rubbers, various pharmaceuticals, pesticides, and herbicides. The paper presents the investigation of kinetics of catalytic hydrogenation of nitrobenzene to aniline in the presence of Ru-containing catalysts based on hypercrosslinked polystyrene. Nitrobenzene hydrogenation reaction was carried out in a six-point high-pressure steel reactor Series 5000 Multiple Reactor System (MRS). As a

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14

Andreeva, E. Yu, S. G. Dmitrienko, and Yu A. Zolotov. "Sorption of caffeine and theophylline on hypercrosslinked polystyrene." Moscow University Chemistry Bulletin 65, no. 1 (2010): 38–41. http://dx.doi.org/10.3103/s0027131410010050.

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15

Tsyuryupa, M. P., M. A. Papkov, and V. A. Davankov. "Internal stresses in hypercrosslinked polystyrene: Polarized optical studies." Polymer Science Series C 51, no. 1 (2009): 81–86. http://dx.doi.org/10.1134/s1811238209010135.

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16

Penner, N. A., and P. N. Nesterenko. "Anion-exchange ability of neutral hydrophobic hypercrosslinked polystyrene." Analytical Communications 36, no. 5 (1999): 199–201. http://dx.doi.org/10.1039/a902449b.

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17

Lazutin, A. A., A. A. Glagoleva, V. V. Vasilevskaya, and A. R. Khokhlov. "Computer synthesis of hypercrosslinked polystyrene: All-atom simulations." Low Temperature Physics 43, no. 2 (2017): 244–47. http://dx.doi.org/10.1063/1.4977588.

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18

Ferrante, Francesco, Fabrizio Lo Celso, and Dario Duca. "Construction and characterization of models of hypercrosslinked polystyrene." Colloid and Polymer Science 290, no. 14 (2012): 1443–50. http://dx.doi.org/10.1007/s00396-012-2704-0.

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19

Cao, Yanbing, Xiaoqi Fei, Xuanhao Wu, Haiqiang Wang, and Zhongbiao Wu. "Adsorption characteristics of dichloromethane-ethyl acetate/toluene vapor on a hypercrosslinked polystyrene adsorbent." RSC Advances 13, no. 22 (2023): 15165–73. http://dx.doi.org/10.1039/d3ra01754k.

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The adsorption characteristics of dichloromethane (DCM), toluene (MB), and ethyl acetate (EAC) vapors on hypercrosslinked polymeric resins (NDA-88) were studied. It showed that the NDA-88 exhibited promising adsorption and regeneration properties.

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20

Дмитриева, Анастасия Алексеевна, Елена Олеговна Щипанская, Антонина Анатольевна Степачёва, et al. "FUNCTIONALIZATION OF THE SURFACE OF HYPERCROSSLINKED POLYSTYRENE FOR CATALYST SYNTHESIS." Вестник Тверского государственного университета. Серия: Химия, no. 3(45) (October 18, 2021): 49–57. http://dx.doi.org/10.26456/vtchem2021.3.6.

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Нанесенные наноразмерные катализаторы широко используются в различных процессах химической технологии. При этом особые требования предъявляются к носителю, используемому при синтезе катализаторов. Сверхсшитые полимеры являются перспективными носителями, однако зачастую не имеют требуемых свойств (например, кислотности). Для придания дополнительных свойств возможно модифицировать поверхность полимеров различными веществами или функциональными группами. В данной работе проведено исследование способов модификации и веществ-предшественников кремнийсодержащей фазы для модификации поверхности сверхс

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21

Филатова, Анастасия Евгеньевна, Елена Игоревна Шиманская, Александрина Михайловна Сульман, and Ольга Валентиновна Гребенникова. "CATALYSTS BASED ON HYPERCROSSLINKED POLYSTYRENE FOR PROCESSING PLANT BIOMASS." Вестник Тверского государственного университета. Серия: Химия, no. 2(48) (July 7, 2022): 49–57. http://dx.doi.org/10.26456/vtchem2022.2.6.

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Создание высокоэффективных каталитических систем для промышленных процессов тесно связано с активным развитием современной химии. Повышение эффективности катализаторов возможно обеспечить путем направленного формирования частиц металлов, проявляющих высокую каталитическую активность. В связи с этим, актуальными являются проблемы получения каталитических систем с обеспечением контроля над размером металлосодержащих частиц; стабилизации частиц полимерами; изучения физико-химических свойств таких катализаторов; исследования кинетики реакции и установления особенностей механизмов протекания процес

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22

He, Chunqing, Takenori Suzuki, V. P. Shantarovich, Kenjiro Kondo, and Yasuo Ito. "Temperature dependence of ortho-positronium annihilation in hypercrosslinked polystyrene." Radiation Physics and Chemistry 68, no. 3-4 (2003): 511–14. http://dx.doi.org/10.1016/s0969-806x(03)00220-2.

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23

Sulman, E. M., M. E. Grigorev, V. Yu Doluda, et al. "Maltose hydrogenation over ruthenium nanoparticles impregnated in hypercrosslinked polystyrene." Chemical Engineering Journal 282 (December 2015): 37–44. http://dx.doi.org/10.1016/j.cej.2015.04.002.

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24

Sulman, E. M., A. A. Ivanov, V. S. Chernyavsky, et al. "Kinetics of phenol hydrogenation over Pd-containing hypercrosslinked polystyrene." Chemical Engineering Journal 176-177 (December 2011): 33–41. http://dx.doi.org/10.1016/j.cej.2011.05.044.

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25

Davankov, V. A., and M. P. Tsyurupa. "Structure and properties of porous hypercrosslinked polystyrene sorbents Styrosorb." Pure and Applied Chemistry 61, no. 11 (1989): 1881–88. http://dx.doi.org/10.1351/pac198961111881.

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26

Li, C., W. Che, S. Y. Liu, and G. Liao. "Hypercrosslinked microporous polystyrene: from synthesis to properties to applications." Materials Today Chemistry 29 (April 2023): 101392. http://dx.doi.org/10.1016/j.mtchem.2023.101392.

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27

Shimanskaya, Elena I., Esther M. Sulman, and Valentin Yu Doluda. "Catalytic synthesis of 2-methyl-1,4- naphthoquinone in 1%Au/HPS presence." Catalysis for Sustainable Energy 2, no. 1 (2016): 28–32. http://dx.doi.org/10.1515/cse-2015-0008.

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AbstractIn this paper, theoxidation process of 2 -methylnaphthalene to vitamin K3, using a gold catalyst systems will be discussed. This catalysis process is based on the hypercrosslinked polystyrene, synthesized by the impregnation with solutions of precursors − HAuCl4·2H2O and Ph3PAuCl. The use of gold catalyst system, which has been synthesized using Ph3PAuCl, allows to obtain the main product − 2-methyl-1,4-naphthoquinone − with 72% yield.

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28

Stepacheva, A., A. Simanova, A. Goncharova, D. Rud, A. Semenova, and N. Movsesyan. "Oil-crop biomass conversion using polymerstabilized catalysts." Bulletin of Science and Practice, no. 12 (December 11, 2017): 70–75. https://doi.org/10.5281/zenodo.1101157.

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Palladium-based catalysts supported on hypercrosslinked polystyrene were studied in the hydroconversion processes of oilseed biomass: (I) deoxygenation in a conventional solvent; (II) deoxygenation in supercritical hexane; (III) hydrogenation in toluene. It was shown that the highest selectivity towards the formation of target product, as well as the highest rate of stearic acid conversion in all the investigated processes, was observed using a 1% -Pd/HPS catalyst.

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29

Mushinskii, L., I. Navrotskaya, R. Brovko, and V. Doluda. "Study of Nitrobenzene Kinetic Particularities over Ni-containing Hypercrosslinked Polystyrene." Bulletin of Science and Practice 6, no. 4 (2020): 18–26. https://doi.org/10.33619/2414-2948/53/02.

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This paper presents a study of the kinetics of catalytic hydrogenation of nitrobenzene to aniline in the presence of Ni-containing catalysts based on super-crosslinked polystyrene. Aniline hydrogenation is a complex multi-stage process accompanied by the formation of a large number of both intermediate and by-products, including azobenzene, azoxybenzene, nitrosobenzene, phenylhydroxylamine and other substances. Therefor the study of the process kinetics is an important scientific and technical task necessary to increase the yield of the target product — aniline. The hydrogenation reactio

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30

Doluda, Valentin Yu, Viktoriya A. Strigina, Valentina G. Matveeva, Esfir M. Sul’man, and Natalia V. Lakina. "SYNTHESIS OF Pd-CONTAINING HYPERCROSSLINKED POLYSTYRENE AND RESEARCH OF ITS CATALYTIC PROPERTIES FOR FURFURAL HYDROGENATION." IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENIY KHIMIYA KHIMICHESKAYA TEKHNOLOGIYA 59, no. 4 (2018): 59. http://dx.doi.org/10.6060/tcct.20165904.5270.

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In this paper the results were presented on the study of physical-chemical and catalytic properties of Pd nanoparticles synthesized in hypercrosslinked polystyrene matrix with various methods allowing to obtain Pd particles of different sizes. Obtained samples were sudied with the methods of chemisorption of hydrogen, nitrogen adsorption, X-ray photoelectron spectroscopy. Synthesized catalysts were tested in the reaction of catalytic furfural hydrogenation. The dependence of the catalysts activity on their structural characteristics was determined.

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31

Mushinskii, L., I. Navrotskaya, R. Brovko, and V. Doluda. "Study of Nitrobenzene Kinetic Particularities over Ni-containing Hypercrosslinked Polystyrene." Bulletin of Science and Practice 6, no. 4 (2020): 18–26. http://dx.doi.org/10.33619/2414-2948/53/02.

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This paper presents a study of the kinetics of catalytic hydrogenation of nitrobenzene to aniline in the presence of Ni-containing catalysts based on super-crosslinked polystyrene. Aniline hydrogenation is a complex multi-stage process accompanied by the formation of a large number of both intermediate and by-products, including azobenzene, azoxybenzene, nitrosobenzene, phenylhydroxylamine and other substances. Therefor the study of the process kinetics is an important scientific and technical task necessary to increase the yield of the target product — aniline. The hydrogenation reaction of n

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32

Mironenko, N. V., T. A. Brezhneva, and V. F. Selemenev. "Kinetics of the sorption of triterpene saponin by hypercrosslinked polystyrene." Russian Journal of Physical Chemistry A 87, no. 3 (2013): 368–71. http://dx.doi.org/10.1134/s0036024413030175.

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33

Shiryaeva, V. E., T. P. Popova, A. A. Korolev, A. Yu Kanat’eva, and A. A. Kurganov. "Stationary Phase Based on Hypercrosslinked Polystyrene for Capillary Gas Chromatography." Russian Journal of Physical Chemistry A 94, no. 9 (2020): 1930–35. http://dx.doi.org/10.1134/s0036024420090253.

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34

Doluda, Valentin Yu, Johan Wärnå, Atto Aho, et al. "Kinetics of Lactose Hydrogenation over Ruthenium Nanoparticles in Hypercrosslinked Polystyrene." Industrial & Engineering Chemistry Research 52, no. 39 (2013): 14066–80. http://dx.doi.org/10.1021/ie401778y.

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35

Tsyurupa, M. P., O. G. Tarabaeva, A. V. Pastukhov, and V. A. Davankov. "Sorption of ions of heavy metals by neutral hypercrosslinked polystyrene." International Journal of Polymeric Materials 52, no. 5 (2003): 403–14. http://dx.doi.org/10.1080/00914030304926.

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36

Tolmacheva, Veronika V., Daniil I. Yarykin, Olga N. Serdiuk, Vladimir V. Apyari, Stanislava G. Dmitrienko, and Yury A. Zolotov. "Adsorption of catecholamines from their aqueous solutions on hypercrosslinked polystyrene." Reactive and Functional Polymers 131 (October 2018): 56–63. http://dx.doi.org/10.1016/j.reactfunctpolym.2018.07.005.

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37

Demirocak, Derviş Emre, Manoj K. Ram, Sesha S. Srinivasan, Ashok Kumar, D. Yogi Goswami, and Elias K. Stefanakos. "Spillover enhancement for hydrogen storage by Pt doped hypercrosslinked polystyrene." International Journal of Hydrogen Energy 37, no. 17 (2012): 12402–10. http://dx.doi.org/10.1016/j.ijhydene.2012.06.046.

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38

Pastukhov, A. V., S. F. Ginzburg, and V. A. Davankov. "ESR study of hypercrosslinked polystyrene carbonizate—organic solvent—oxygen systems." Russian Chemical Bulletin 55, no. 5 (2006): 852–59. http://dx.doi.org/10.1007/s11172-006-0342-8.

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39

Kiseleva, Maria G., Lubov’ V. Radchenko, and Pavel N. Nesterenko. "Ion-exchange properties of hypercrosslinked polystyrene impregnated with methyl orange." Journal of Chromatography A 920, no. 1-2 (2001): 79–85. http://dx.doi.org/10.1016/s0021-9673(01)00696-3.

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40

Šálek, Petr, Lucie Korecká, Daniel Horák, et al. "Immunomagnetic sulfonated hypercrosslinked polystyrene microspheres for electrochemical detection of proteins." Journal of Materials Chemistry 21, no. 38 (2011): 14783. http://dx.doi.org/10.1039/c1jm12475g.

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41

Pastukhov, A. V., T. A. Babushkina, V. A. Davankov, T. P. Klimova, and V. P. Shantarovich. "Water in nanopores of hypercrosslinked hydrophobic polystyrene at low temperatures." Doklady Physical Chemistry 411, no. 1 (2006): 305–8. http://dx.doi.org/10.1134/s0012501606110042.

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42

Davankov, V. A., A. V. Pastukhov, and M. P. Tsyurupa. "Unusual mobility of hypercrosslinked polystyrene networks: Swelling and dilatometric studies." Journal of Polymer Science Part B: Polymer Physics 38, no. 11 (2000): 1553–63. http://dx.doi.org/10.1002/(sici)1099-0488(20000601)38:11<1553::aid-polb160>3.0.co;2-l.

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43

Pastukhov, Alexander V., Maria P. Tsyurupa, and Vadim A. Davankov. "Hypercrosslinked polystyrene: A polymer in a non-classical physical state." Journal of Polymer Science Part B: Polymer Physics 37, no. 17 (1999): 2324–33. http://dx.doi.org/10.1002/(sici)1099-0488(19990901)37:17<2324::aid-polb4>3.0.co;2-b.

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44

Doluda, V., M. Grigorev, V. Matveeva, et al. "Evaluation of D-glucose Hydrogenation Catalysts Suability in Different Reactor Systems." MOLECULAR SCIENCES AND APPLICATIONS 1 (September 18, 2021): 53–57. http://dx.doi.org/10.37394/232023.2021.1.9.

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he samples of ruthenium impregnated in hypercrosslinked polystyrene and activated carbon were tested in D-glucose hydrogenation using butch reactor, shaker type reactor and fix bed reactor system to evaluate catalysts long term stability. Catalysts were characterized by nitrogen physisorption, X-Ray photoelectron spectroscopy, hydrogen chemisorption, X-Ray fluorescence analysis. Physicochemical changes of the studied catalysts are shown during catalysts stability investigation. A strong influence of the reactor type on catalysts stability in D-glucose hydrogenation is discussed.

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45

Ratvijitvech, Thanchanok, Michael Barrow, Andrew I. Cooper, and Dave J. Adams. "The effect of molecular weight on the porosity of hypercrosslinked polystyrene." Polymer Chemistry 6, no. 41 (2015): 7280–85. http://dx.doi.org/10.1039/c5py00668f.

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46

Aung, Pyae Phyo, Olga A. Veselova, and Irina D. Troshkina. "KINETICS OF SCANDIUM SORPTION BY IMPREGNATE CONTAINING PHOSPHINOXIDE." IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENIY KHIMIYA KHIMICHESKAYA TEKHNOLOGIYA 60, no. 8 (2017): 28. http://dx.doi.org/10.6060/tcct.2017608.5646.

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The kinetics of scandium sorption with impregnate-containing extractant – phosphine oxide based on hypercrosslinked polystyrene from nitric acid solutions was studied using a method of limited solution volume. A sample of sorbent obtained by impregnation contained 0.233 g extractant/g impregnate. Under batch conditions, the influence of temperature in the range 293-313 K on the kinetics of scandium sorption by impregnate was studied. It was revealed that the saturation of impregnate by scandium is established in 20-30 min. For the processing of integral kinetic scandium sorption curves, the ps

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47

Stepacheva, Antonina A., Oleg V. Manaenkov, Mariia E. Markova, et al. "Lignin Hydrogenolysis over Bimetallic Ni–Ru Nanoparticles Supported on SiO2@HPS." Catalysts 13, no. 5 (2023): 856. http://dx.doi.org/10.3390/catal13050856.

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Lignin obtained by hydrogenolysis of lignocellulose biomass is a prospective source of valuable green fuels and chemicals such as monophenols. One of the key factors in the chemical decomposition of lignin to monophenols is an efficient catalyst. Inert porous materials such as hypercrosslinked polymers are suitable catalytic supports for the immobilization of noble and transition metal nanoparticles. However, such polymers do not have acidic properties, which are crucial for catalyzing hydrolysis. In this work, we report novel, efficient catalysts for lignin hydrogenolysis to produce valuable

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48

Manaenkov, Oleg, and Olga Kislitsa. "Synthesis of Polymeric Sorbents with Magnetic Properties." International Journal of Chemical Engineering and Materials 1 (December 31, 2022): 25–29. http://dx.doi.org/10.37394/232031.2022.1.5.

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In this work, a procedure for the synthesis of polymeric sorbents based on hypercrosslinked polystyrene (HPS) with magnetic properties was developed. The technique is based on the reduction of iron salts with polyhydric alcohols at high temperature in an inert atmosphere. The resulting sorbents retain their original characteristics: an extended specific surface area, micro-mesoporous structure, acquiring magnetic properties, which makes it possible to use them as magnetically separable sorbents, supports for the active phase of heterogeneous catalytic systems etc.

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49

Дмитриева, А. А., С. Д. Емельянова, А. А. Степачёва, В. Г. Матвеева, and М. Г. Сульман. "Condition Influence on the Process of Anisole Supercritical Deoxygenation in the Presence of Pd-Catalyst." Сверхкритические Флюиды: Теория и Практика 17, no. 3(3) (2023): 51–59. http://dx.doi.org/10.34984/scftp.2022.17.3.006.

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Исследовано влияние температуры, давления и состава газовой фазы на процесс деоксигенации анизола в сверхкритическом н-гексане в присутствии палладиевого катализатора, нанесенного на сверхсшитый полистирол. Максимальный выход ароматических продуктов (бензола и толуола) получен при следующих условиях: температура 270 °С, начальное давление смеси азот-водород (20 об. % Н) 1,5 МПа. In the current work, the results of the study of the influence of pressure and temperature on the anisole deoxygenation process in supercritical n-hexane in the presence of Pd-containing catalyst supported on hypercros

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50

Tsyurupa, M. P., Z. K. Blinnikova, M. M. Il’in, et al. "Monodisperse microbeads of hypercrosslinked polystyrene for liquid and supercritical fluid chromatography." Russian Journal of Physical Chemistry A 89, no. 11 (2015): 2064–71. http://dx.doi.org/10.1134/s0036024415110217.

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