Academic literature on the topic 'Immiscibility Gap'

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Journal articles on the topic "Immiscibility Gap"

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Mende, Tamás, and András Roósz. "Calculation of the Immiscibility Gap by ESTPHAD Method." Materials Science Forum 659 (September 2010): 423–28. http://dx.doi.org/10.4028/www.scientific.net/msf.659.423.

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By using the thermodynamic equations, the ESTPHAD (Estimation of Phase Diagrams) method developed by us has been made suitable for calculating the immiscibility gap of monotectic systems. 2 special parameters were introduced in the basic equation of ESTPHAD which ensure the description of the characteristics of monotectic curve on the basis of the boundary conditions created by us. By means of the monotectic ESTPHAD equation, the equations of separation temperatures of monotectic parts in the Zn-Bi and Al-Bi systems were calculated (with an accuracy of +/- 10K) on the basis of the reference da
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Ban, Takayuki, Shigeo Hayashi, Atsuo Yasumori, and Kiyoshi Okada. "Calculation of metastable immiscibility region in the Al2O3–SiO2 system." Journal of Materials Research 11, no. 6 (1996): 1421–27. http://dx.doi.org/10.1557/jmr.1996.0178.

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Metastable liquid-liquid immiscibility region in the Al2O3–SiO2 system was calculated by a regular solution model using three sets of liquidus data from the stable phase diagrams reported. These calculations indicated that the immiscibility region was richer in Al2O3 composition than those reported before. A miscibility gap calculated using the liquidus data reported by Klug et al. [F. J. Klug, S. Prochazka, and R. H. Doremus, J. Am. Ceram. Soc. 70, 750 (1987)] (model A) ranged from 2.6 to 71 mol % Al2O3 at around 1000 °C, which was the most compatible result with the idea that metastable pseu
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Plevachuk, Yu, V. Filippov, V. Kononenko, et al. "Investigation of the miscibility gap region in liquid Ga–Pb alloys." International Journal of Materials Research 94, no. 9 (2003): 1034–39. http://dx.doi.org/10.1515/ijmr-2003-0187.

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Abstract The miscibility gap of the Ga–Pb system has been investigated by different experimental methods and techniques. Viscosity, acoustic and electrical conductivity measurements were carried out through the entire immiscibility region. Possible reasons of revealed discrepancies in the absolute values of the phase separation temperatures are discussed in relation with peculiarities of the experimental methods employed. The shape of the miscibility gap has been analysed.
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Bergermann, Armin, Martin French, and Ronald Redmer. "Gibbs-ensemble Monte Carlo simulation of H2–H2O mixtures." Physical Chemistry Chemical Physics 23, no. 22 (2021): 12637–43. http://dx.doi.org/10.1039/d1cp00515d.

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The miscibility gap in H<sub>2</sub>–H<sub>2</sub>O mixtures is investigated by conducting Gibbs-ensemble Monte Carlo simulations. Our results indicate that H<sub>2</sub>–H<sub>2</sub>O immiscibility regions may have a significant impact on the structure and evolution of ice giant planets.
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Arefiev, Anton V., Anton Shatskiy, Altyna Bekhtenova, and Konstantin D. Litasov. "Phonolite-Carbonatite Liquid Immiscibility at 3–6 GPa." Minerals 13, no. 3 (2023): 443. http://dx.doi.org/10.3390/min13030443.

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Liquid immiscibility plays an important role in the formation of carbonatites and associated alkaline Si-undersaturated magmas. Experiments in the sodium carbonate-aluminosilicate systems suggest that the carbonate-silicate miscibility gap is limited by crustal and shallow mantle pressures (up to 2.5 GPa). Unlike in the potassium-rich carbonate-aluminosilicate systems, the carbonate-silicate miscibility gap was established at pressures of 3.5–6 GPa. It is therefore interesting to elucidate the immiscibility range under intermediate pressures, corresponding to 100–200 km depths. Here we conduct
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Constant, Kristen Persels, Jonq-Ren Lee, and Yet-Ming Chiang. "Microstructure development in furfuryl resin-derived microporous glassy carbons." Journal of Materials Research 11, no. 9 (1996): 2338–45. http://dx.doi.org/10.1557/jmr.1996.0297.

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The processing of microporous glassy carbon derived from furfuryl alcohol and ethylene glycol mixtures has been studied, with emphasis on understanding and controlling microstructure development. It is shown that this system exhibits a polymerization-dependent miscibility gap, and that the carbon microstructure is determined by phase separation in the liquid state. Variations in carbon microstructure with composition and thermal history can be understood in terms of the time-dependent immiscibility and resulting phase separation.
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Takei, Takahiro, Yoshikazu Kameshima, Atsuo Yasumori, and Kiyoshi Okada. "Calculation of metastable immiscibility region in the Al2O3–SiO2 system using molecular dynamics simulation." Journal of Materials Research 15, no. 1 (2000): 186–93. http://dx.doi.org/10.1557/jmr.2000.0030.

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The metastable immiscibility region in the Al2O3–SiO2 system was calculated by conventional thermodynamic equations using thermodynamic parameters obtained from molecular dynamics simulation. The calculated miscibility gap has a consolute temperature of around 1500 °C at the critical composition of about 20 mol% Al2O3 and spreads more widely towards the Al2O3-rich composition side than the SiO2-rich side. The calculated miscibility gap in this study showed a fair agreement with that reported by Ban et al. [T. Ban, S. Hayashi, A. Yasumori, and K. Okada, J. Mater. Res. 11, 1421 (1996)] calculate
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Ilatovskaia, M., and O. Fabrichnaya. "Liquid Immiscibility and Thermodynamic Assessment of the Al2O3–TiO2–SiO2 System." Journal of Phase Equilibria and Diffusion 43, no. 1 (2022): 15–31. http://dx.doi.org/10.1007/s11669-021-00935-4.

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AbstractPhase equilibria in the TiO2–SiO2 system have been studied experimentally using DTA and SEM/EDX. The thermodynamic parameters for the TiO2–SiO2 system have been assessed considering new experimental data of the present work and from the literature. Moreover, the miscibility of the liquid in the Al2O3–TiO2–SiO2 system has been studied at 2013 K in air and shrinkage of the miscibility gap at 3.8 mol% Al2O3 has been demonstrated. The experimental data obtained in the present work and literature as well as the thermodynamic databases for the binary Al2O3–TiO2, TiO2–SiO2, and Al2O3–SiO2 sys
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Janovszky, Dóra, and Kinga Tomolya. "Designing Amorphous/Crystalline Composites by Liquid-Liquid Phase Separation." Materials Science Forum 790-791 (May 2014): 473–78. http://dx.doi.org/10.4028/www.scientific.net/msf.790-791.473.

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The Cu-Zr-Ag system is characterized by a miscibility gap. The liquid separates into Ag-rich and Cu-Zr rich liquids. Yttrium was added to the Cu-Zr-Ag and Cu-Zr-Ag-Al systems and its influence on liquid immiscibility was studied. This alloying element has been chosen to check the effect of the heat of mixing between silver and the given element. In the case of Ag-Y system it is highly negative (-29 kJ/mol). The liquid becomes immiscible in the Cu-Zr-Ag-Y system. To the effect of Y addition the quaternary liquid decomposed into Ag-Y rich and Cu-Zr rich liquids. The Y addition increased the fiel
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Taglialavore, A. P., W. M. Kriven, and S. H. Risbud. "Microstructural development of rapidly solidified, phase-separated SiO2-Al2O3 glass." Proceedings, annual meeting, Electron Microscopy Society of America 44 (August 1986): 442–43. http://dx.doi.org/10.1017/s042482010014378x.

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A metastable miscibility gap has been shown to exist oyer much of the SiO2(s) -mullite(s) phase field by various indirect methods. The various proposed boundaries of this liquid-liquid immiscibility region, however, significantly disagree in their widths and critical point positions. The overall aim of our research is to directly determine the miscibility gap boundaries by using TEM/EDS on suitably equilibrated phases of rapidly solidified SiO2-Al2O3 glass. Rapid solidification by roller quenching (∼106°C/sec) and by ice- water quenching (~1035°C/sec) was used so that a wide range of compositi
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Dissertations / Theses on the topic "Immiscibility Gap"

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Lutsyk, V. I., and A. E. Zelenaya. "Ternary Systems for the Liquid Immiscibility Gap Technology." Thesis, Sumy State University, 2013. http://essuir.sumdu.edu.ua/handle/123456789/35368.

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The computer models for T-x-y diagrams with the mono- and invariant monotectic equilibrium, and monovariant syntectic equilibrium by means of kinematical simulation of phase regions boundaries are considered. The effect of syntectic equilibrium changing for monotectic one is investigated with the material balances visualization. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/35368
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Book chapters on the topic "Immiscibility Gap"

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Hedenquist, Jeffrey W., Yukihiro Matsuhisa, Elji Izawa, Noel C. White, Werner F. Giggenbach, and Masahiro Aoki. "Economic Geology and the Bulletin of the Society of Economic Geologists." In Epithermal Gold Mineralization and Modern Analogues, Kyushu, Japan. Society of Economic Geologists, 2001. http://dx.doi.org/10.5382/gb.34.10.

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Abstract The Nansatsu district of southern Kyushu has been the site of calc-alkaline volcanism for the last 10 m.y., shifting eastward with time. Associated hydrothermal activity followed deposition of the volcanic host rocks by about 0.5 m.y. and was characterized by interaction of magmatic fluids with meteoric water under epithermal conditions, resulting in the formation of high sulfidation Cu-Au deposits at Kasuga, Iwato, and Akeshi. The orebodies consist of &amp;gt;95 wt percent SiO2 and result from leaching of the original andesite lava and pyroclastic flows by acid chloride-sulfate water
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Conference papers on the topic "Immiscibility Gap"

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Akhtar, M., M. Shevchenko, and E. Jak. "Overview of the experimental phase equilibria studies of the Ni-Sn-S, Cu-Sb-S, Cu-Sn-S, Fe-Sb-As and Fe-Sn-As systems." In 12th International Conference of Molten Slags, Fluxes and Salts (MOLTEN 2024) Proceedings. Australasian Institute of Mining and Metallurgy (AusIMM), 2024. http://dx.doi.org/10.62053/wtuw4662.

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This article presents an overview of the experimental phase equilibria studies of S-containing systems (Ni-Sn-S, Cu-Sb-S, and Cu-Sn-S) and As-containing systems (Fe-Sb-As and Fe-Sn-As). These systems improve the prediction capabilities of FactSage in a 20-component ‘Cu2O’-PbO-ZnO-FeO-Fe2O3-CaO-SiO2-S-(Al2O3-MgO-CrO-Cr2O3-Na2O)-(As, Sn, Sb, Bi, Ag, Au, Ni, Co) system for complex pyrometallurgical operations during both refining and recycling. Experiments involved equilibration at predetermined temperatures (300–1200°C) with or without preheating, followed by rapid quenching in a brine. Quenched
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Gu, Peiwen, Guobao Shi, Kemei Cao, and Jiayun Wang. "Research on IVR-Relevant Phenomena of Material Thermodynamic Interaction and Corium Pool Configuration." In 2017 25th International Conference on Nuclear Engineering. American Society of Mechanical Engineers, 2017. http://dx.doi.org/10.1115/icone25-66969.

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In-Vessel Retention (IVR), which arrests relocated molten core materials in the vessel during severe accident, has been singled out as an appealing accident management approach to many reactors. The heat transfer imposed by in-vessel corium is a vital part for IVR success considering the difficulty of significantly altering ex-vessel CHF. For a given decay power, corium pool configuration determines the heat flux profile along the vessel wall, which may produce uncertainties associated with IVR strategy. In this paper, a thermodynamic tool is employed to study the corium pool configurations by
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Alo, R. G., S. H. Normann, M. F. Alam, R. H. Abdul Rani, and M. B. Mappy. "Repair of Production Packer Leaks Riglessly Using Thermosetting Resin." In SPE Symposium - Well Integrity Management. SPE, 2024. http://dx.doi.org/10.2118/220574-ms.

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Abstract Leaks through the production packer, which serves as a primary barrier can compromise well integrity. Traditional methods to restore packer integrity typically entail costly workover operations, necessitating the deployment of a rig to replace the upper completion. This paper presents a cost-effective solution utilizing thermosetting resin, offering an economically viable alternative for remediating packer leaks without the need for heavy workover rigs. The method employs gravity-feeding of thermosetting resin through the annular fluids to seal leaks located often thousands of meters
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Cruz, Felipe, Sidi Mamoudou, and Ali Tinni. "The Impact of Gas-Oil Miscibility on Oil Recovery During Huff-and-Puff EOR in Organic-Rich Shales." In SPE Annual Technical Conference and Exhibition. SPE, 2022. http://dx.doi.org/10.2118/210028-ms.

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Abstract Injection pressure is a key parameter in the design of a Huff-and-Puff EOR process in organic-rich shales. Reservoir engineering studies have shown that injection pressure and miscibility play a role during Huff-and-Puff EOR. However, during field implementation, the injection pressure is often limited by the number of compressors and in several cases, the gas injected might not reach sufficient pressure to achieve a state of complete miscibility with the oil. These scenarios lead to a condition of partial miscibility or immiscibility which impacts the efficiency of the recovery mecha
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