Academic literature on the topic 'Immiscible electrolytes'

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Journal articles on the topic "Immiscible electrolytes"

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Cho, Sung-Ju, Gwan Yeong Jung, Su Hwan Kim, et al. "Monolithic heterojunction quasi-solid-state battery electrolytes based on thermodynamically immiscible dual phases." Energy & Environmental Science 12, no. 2 (2019): 559–65. http://dx.doi.org/10.1039/c8ee01503a.

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Ruiz-Martín, Désirée, Daniel Moreno-Boza, Rebeca Marcilla, Marcos Vera, and Mario Sánchez-Sanz. "Mathematical modelling of a membrane-less redox flow battery based on immiscible electrolytes." Applied Mathematical Modelling 101 (August 25, 2021): 96–110. https://doi.org/10.1016/j.apm.2021.08.020.

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We present a mathematical model to study the steady-state performance of a membrane-less reversible redox flow battery formed by two immiscible electrolytes that spontaneously form a liquid-liquid system separated by a well defined interface. The model assumes a two-dimensional battery with two coflowing electrolytes and flat electrodes at the channel walls. In this configuration, the analysis of the far downstream solution indicates that the interface remains stable in all the parameter range covered by this study. To simplify the description of the problem, we use the dilute soluti
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Pechberty, Clément, Sofia Reiner, and Patrik Johansson. "Dual Electrolyte Design for Lithium-Ion Batteries." ECS Meeting Abstracts MA2023-02, no. 2 (2023): 298. http://dx.doi.org/10.1149/ma2023-022298mtgabs.

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Lithium-ion batteries (LIBs) are today the most used energy storage for portable electronics and electric vehicles – but are laden with concerns of materials scarcity and availability. The development of high-voltage cobalt-free cathode active materials such as LiNi0.5Mn1.5O4 (LNMO) represents one promising route for next-generation LIBs due to their combination of high capacity and low cost. Combining LNMO with conventional LIB electrolytes based on carbonate solvents, however, typically leads to severe capacity fading due to a range of different degradation mechanisms1, not the least due to
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Reiner, Sofia, Clément Pechberty, Julia Maibach, and Patrik Johansson. "Lithium-Ion Battery Electrolyte Miscibility Studied By Spectroscopy." ECS Meeting Abstracts MA2023-02, no. 2 (2023): 314. http://dx.doi.org/10.1149/ma2023-022314mtgabs.

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Interfaces, interphases, and surfaces are of immense interest to the battery research community since the key reactions and much of the kinetics that determine the performance of the cell occur there. While solid/liquid and solid/solid interfaces have been thoroughly studied, liquid/liquid interfaces have attracted much less attention. Here we target the liquid/liquid interfaces between two liquid electrolytes, employed to create dual electrolyte batteries. The grand idea is that based on two either chemically or mechanically immiscible electrolytes we can expand the overall electrochemical st
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Samec, Zdeněk. "Dynamic electrochemistry at the interface between two immiscible electrolytes." Electrochimica Acta 84 (December 2012): 21–28. http://dx.doi.org/10.1016/j.electacta.2012.03.118.

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Tarantseva, K. R., M. I. Yakhkind, A. K. Mishra, M. A. Marynova, E. A. Polyanskova, and A. A. Goryacheva. "Systems of two immiscible liquids for a new type of membraneless fuel cells using renewable fuel." E3S Web of Conferences 161 (2020): 01062. http://dx.doi.org/10.1051/e3sconf/202016101062.

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Systems of two immiscible liquids are proposed for a new type of membraneless fuel cells using renewable fuel, in which the stationary phase boundary carries out a role of membrane. These systems consist of water, alcohol (preferable ethanol) and a number of electrolytes (salts and bases) leading to the layering of aqueous alcohol. In such systems top phase has significant alcohol content and insignificant electrolyte content, bottom phase has significant electrolyte content and insignificant alcohol content. To study the layering conditions in these systems, binodal curves were plotted for th
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Vanýsek, Petr, and Irma C. Hernandez. "Ion Transport across a Microscopic Interface between two Immiscible Electrolytes." Journal of The Electrochemical Society 137, no. 9 (1990): 2763–68. http://dx.doi.org/10.1149/1.2087068.

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Navalpotro, Paula, Santiago Enrique Ibañez, Eduardo Pedraza, and Rebeca Marcilla. "Towards Totally Aqueous Membrane-Free Flow Batteries: Fundamentals and Challenges." ECS Meeting Abstracts MA2023-02, no. 4 (2023): 808. http://dx.doi.org/10.1149/ma2023-024808mtgabs.

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The implementation of renewable energies (solar, wind, etc) is driven the development of new energy storage systems that can mitigate their inherent intermittency solving the mismatch between the energy demand and production. Among different systems, electrochemical energy storage devices stand out due to their efficiency, flexibility and modularity. Specifically, Redox Flow Batteries (RFB) are the unique type of battery able to decouple energy and power densities which makes them versatile and adaptable to different applications. Nevertheless, although they are commercially available, their i
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Efaw, Corey M., Qisheng Wu, Ningshengjie Gao, et al. "Understanding Solvation Structures of Localized High-Concentration Electrolytes Used for Li-Metal Batteries." ECS Meeting Abstracts MA2023-01, no. 1 (2023): 437. http://dx.doi.org/10.1149/ma2023-011437mtgabs.

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Liquid electrolytes in batteries are typically treated as macroscopically homogeneous ionic transport media, despite having complex chemical composition and atomistic solvation structures, thus leaving a knowledge gap of microstructural characteristics. A promising electrolyte system design has recently been developed with the title of a localized high-concentration electrolyte (LHCE). These electrolytes are a summation of three components – a charge-carrying salt, a solvent that solvates the salt, and a diluent that is highly immiscible with the salt. This creates the perception of a high-con
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Asami, Ryosuke, Mahito Atobe, and Toshio Fuchigami. "Electropolymerization of an Immiscible Monomer in Aqueous Electrolytes Using Acoustic Emulsification." Journal of the American Chemical Society 127, no. 38 (2005): 13160–61. http://dx.doi.org/10.1021/ja0546931.

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Dissertations / Theses on the topic "Immiscible electrolytes"

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Wiles, M. C. "The behaviour of affinity dyes at the interface of immiscible electrolytes." Thesis, University of Southampton, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.382976.

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Cheng, Yufei. "Electrochemistry at the interface between two immiscible electrolyte solutions." Thesis, University of Liverpool, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.316502.

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Velazquez-Manzanares, Miguel. "Charge transfer across the interface of two immiscible electrolyte solutions." Thesis, University of Liverpool, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.366988.

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Brown, Alan R. "Photoelectrochemical processes at the interface between two immiscible electrolyte solutions." Thesis, University of Edinburgh, 1992. http://hdl.handle.net/1842/12836.

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This thesis is devoted to the photoelectrochemical characterisation of the interface between two immiscible electrolyte solutions. A number of new phenomena are reported and analysed. These include photoinitiated ion transfer, photosensitised ion transfer, interfacial photoanation of the [Ru(bpy)<SUB>3</SUB>]<SUP>2</SUP>+ ion and photoinitiated electron transfer. This last phenomenon takes place between the luminescent state of the [Ru(bpy)<SUB>3</SUB>]<SUP>2</SUP>+ ion and 7,7,8,8-tetracyanoquinodimethane, across the water/1,2-dichloroethane interface. A novel technique is presented to examin
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Lamichhane, Hum Bahadur. "Characterisation of Insulin at the Interface Between Two Immiscible Electrolyte Solutions." Thesis, Curtin University, 2019. http://hdl.handle.net/20.500.11937/80108.

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The behaviour of insulin was characterised at the interface between the two immiscible electrolyte solutions (ITIES). Electroadsorbed insulin was subjected to study by Fourier transform infrared and Raman spectroscopy, to understand any secondary structure changes following electroadsorption. Following electroadsorption, insulin showed secondary structure changes which varied with the aqueous insulin concentration. At higher concentration, significant proportions of combined ß-sheet and irregular helix structures were found, while a-helical forms were dominant at lower concentration. Raman spe
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Agyekum, Isaac. "Electrochemical Studies of Reactions in Small Volumes Less Than 1 Femto Litres." Digital Commons @ East Tennessee State University, 2011. https://dc.etsu.edu/etd/1316.

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Electrochemical methods have been used to study electron transfer reactions at the interface between an aqueous phase of less than 1 femto liters in volume and a bulk organic phase. The small aqueous phase is formed at the end of a slightly recessed platinum electrode. When a negative potential is applied between the Pt electrode and the aqueous phase, Ru(NH3)63+ in the aqueous phase could be reduced to Ru(NH3)62+. Because the volume of the aqueous phase is very small, the electrochemically formed Ru(NH3)62+ could instantly reach the interface between the aqueous phase and the organic phase wh
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Book chapters on the topic "Immiscible electrolytes"

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Koryta, J. "Electrolysis at the Interface Between Two Immiscible Electrolyte Solutions." In The Interface Structure and Electrochemical Processes at the Boundary Between Two Immiscible Liquids. Springer Berlin Heidelberg, 1987. http://dx.doi.org/10.1007/978-3-642-71881-6_2.

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Kotov, Nicholas A., and Michael G. Kuzmin. "Photoelectrochemical Effect at the Interface Between Two Immiscible Electrolyte Solutions." In Liquid-Liquid Interfaces. CRC Press, 2020. http://dx.doi.org/10.1201/9781003068778-10.

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Kakiuchi, Takashi. "Partition Equilibrium of Ionic Components in Two Immiscible Electrolyte Solutions." In Liquid-Liquid Interfaces. CRC Press, 2020. http://dx.doi.org/10.1201/9781003068778-1.

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Koczorowski, Zbigniew. "Galvani and Volta Potentials at the Interface Separating Immiscible Electrolyte Solutions." In The Interface Structure and Electrochemical Processes at the Boundary Between Two Immiscible Liquids. Springer Berlin Heidelberg, 1987. http://dx.doi.org/10.1007/978-3-642-71881-6_5.

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Indenbom, Andrej V. "The double layer at the interface between two immiscible electrolyte solutions." In Capillarity Today. Springer Berlin Heidelberg, 1991. http://dx.doi.org/10.1007/3-540-54367-8_54.

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De Armond, M. Keith, and Anna H. De Armond. "Excited State Electron Transfer at the Interface of Two Immiscible Electrolyte Solutions." In Liquid-Liquid Interfaces. CRC Press, 2020. http://dx.doi.org/10.1201/9781003068778-11.

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Samec, Zdeněk, and Vladimir Mareček. "Study of the Electrical Double Layer at the Interface Between Two Immiscible Electrolyte Solutions by Impedance Measurements." In The Interface Structure and Electrochemical Processes at the Boundary Between Two Immiscible Liquids. Springer Berlin Heidelberg, 1987. http://dx.doi.org/10.1007/978-3-642-71881-6_7.

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Schmickler, Wolfgang. "Introduction." In Interfacial Electrochemistry. Oxford University Press, 1996. http://dx.doi.org/10.1093/oso/9780195089325.003.0006.

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Electrochemistry is an old science: There is good archaeological evidence that an electrolytic cell was used by the Parthans (250 B.C. to 250 A.D.), probably for electroplating, though a proper scientific investigation of electrochemical phenomena did not start before the experiments of Volta and Galvani. The meaning and scope of electrochemical science has varied throughout the ages: For a long time it was little more than a special branch of thermodynamics; later attention turned to electrochemical kinetics. During recent decades, with the application of various surface-sensitive techniques
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Duroudier, Jean-Paul. "Laws Governing the Transfer of Material and Heat Between Two Immiscible Fluids Electrolytes and their Diffusion." In Thermodynamics. Elsevier, 2016. http://dx.doi.org/10.1016/b978-1-78548-176-5.50004-2.

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"Interfaces Between Two Immiscible Electrolyte Solutions." In Fundamentals of Electrochemistry. John Wiley & Sons, Inc., 2005. http://dx.doi.org/10.1002/047174199x.ch32.

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Conference papers on the topic "Immiscible electrolytes"

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Merletti, German, Salim Al Hajri, Michael Rabinovich, Russell Farmer, Mohamed Bennis, and Carlos Torres-Verdín. "Assessment of True Formation Resistivity and Water Saturation in Deeply Invaded Tight-Gas Sandstones Based on the Combined Numerical Simulation of Mud-Filtrate Invasion and Resistivity Logs." In 2022 SPWLA 63rd Annual Symposium. Society of Petrophysicists and Well Log Analysts, 2022. http://dx.doi.org/10.30632/spwla-2022-0030.

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The process of mud-filtrate invasion involves immiscible fluid displacement and salt mixing between mud-filtrate and formation fluids in porous and permeable rocks. Consequently, the post-invasion spatial distribution of fluids and electrolyte concentration around the borehole affects resistivity measurements with different depths of investigation (DOI). In the presence of deep mud-filtrate invasion, the assessment of water saturation in the uninvaded zone based on the deep resistivity log can be inaccurate. Deep and electrically conductive filtrate invasion coupled with shoulder-bed effects c
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