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1

Silva, Ana L. R., Paula M. V. Gama, and Maria D. M. C. Ribeiro da Silva. "Influence of the functional groups −NH2, −OCH3, and −OH on the thermochemistry of indanes." Canadian Journal of Chemistry 97, no. 11 (2019): 788–94. http://dx.doi.org/10.1139/cjc-2019-0257.

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This work is a contribution to the thermochemical characterization of bicyclic hydrocarbons, reporting the study of six indane derivatives: 4-aminoindane, 5-aminoindane, 5-methoxyindane, 1-indanol, 2-indanol, and 5-indanol. The combustion calorimetry technique was used to measure the massic energy of combustion of each compound in the condensed state, which has been used to derive the corresponding standard (p° = 0.1 MPa) molar enthalpy of formation, at 298.15 K. The standard molar enthalpies of sublimation or vaporization of the compounds were determined by high-temperature Calvet microcalori
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2

Arnold, Donald R., Xinyao Du, and Kerstin M. Henseleit. "The effect of meta- and para-methoxy substitution on the reactivity of the radical cations of arylalkenes and alkanes. Radical ions in photochemistry. Part 26." Canadian Journal of Chemistry 69, no. 5 (1991): 839–52. http://dx.doi.org/10.1139/v91-124.

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The effect of meta- and para-methoxy substitution on the reactivity of some radical cations has been determined. The compounds chosen for study were 1-(3-methoxyphenyl)-1-phenylethylene (7), 1-(4-methoxyphenyl)-1-phenylethylene (8), 3-(3-methoxyphenyl)indene (9), 3-(4-methoxyphenyl)indene (10), methyl 2-(3-methoxyphenyl)-2-phenylethyl ether (11), methyl 2-(4-methoxyphenyl)-2-phenylethyl ether (12), cis- and trans-2-methoxy-1-(3-methoxyphenyl)indane (13), and cis- and trans-2-methoxy-1-(4-methoxyphenyl)indane (14). The radical cations of these compounds were generated by photosensitization (ele
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3

Abad, F., F. Álvarez, F. Fernández, X. García-Mera, and J. E. Rodríguez-Borges. "NEW CARBOCYCLIC NUCLEOSIDES DERIVED FROM INDAN." Nucleosides, Nucleotides and Nucleic Acids 20, no. 4-7 (2001): 1127–28. http://dx.doi.org/10.1081/ncn-100002503.

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4

Pio, Barbara, Harry R. Chobanian, Yan Guo, et al. "Design, synthesis and biological evaluation of indane derived GPR40 agoPAMs." Bioorganic & Medicinal Chemistry Letters 29, no. 14 (2019): 1842–48. http://dx.doi.org/10.1016/j.bmcl.2019.04.050.

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5

Deck, Paul A., and Carrie R. Maiorana. "Step−Growth Polymers Derived from Indene and Decafluorobiphenyl. A New Polymerization Mode for Indene." Macromolecules 34, no. 1 (2001): 9–13. http://dx.doi.org/10.1021/ma001424g.

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6

Darensbourg, Donald J., and Stephanie J. Wilson. "Synthesis of CO2-Derived Poly(indene carbonate) from Indene Oxide Utilizing Bifunctional Cobalt(III) Catalysts." Macromolecules 46, no. 15 (2013): 5929–34. http://dx.doi.org/10.1021/ma4013779.

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7

Kim, Ko Hoon, Se Hee Kim, Sunhong Park, and Jae Nyoung Kim. "Palladium-catalyzed synthesis of indane and cyclobuta[a]indenes from homoallylic alcohols derived from Baylis–Hillman adducts: base-dependent stereoselectivity for the benzylidene group in cyclobuta[a]indene." Tetrahedron 67, no. 19 (2011): 3328–36. http://dx.doi.org/10.1016/j.tet.2011.03.070.

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8

Abad, F., F. Alvarez, F. Fernandez, X. Garcia-Mera, and J. E. Rodriguez-Borges. "ChemInform Abstract: New Carbocyclic Nucleosides Derived from Indan." ChemInform 32, no. 49 (2010): no. http://dx.doi.org/10.1002/chin.200149213.

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9

Qian, Yimin, Karin Conde-Knape, Shawn D. Erickson, et al. "Potent MCH-1 receptor antagonists from cis-1,4-diaminocyclohexane-derived indane analogs." Bioorganic & Medicinal Chemistry Letters 23, no. 14 (2013): 4216–20. http://dx.doi.org/10.1016/j.bmcl.2013.05.017.

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10

Berezina, G. R., Yu G. Vorob'ev, and S. M. Vorob'eva. "Synthesis and Properties of Macroheterocycles Derived from an Indane-1,3-dione Analog." Russian Journal of General Chemistry 75, no. 12 (2005): 1946–48. http://dx.doi.org/10.1007/s11176-006-0019-x.

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11

Kim, Ko Hoon, Se Hee Kim, Sunhong Park, and Jae Nyoung Kim. "ChemInform Abstract: Palladium-Catalyzed Synthesis of Indane and Cyclobuta[a]indenes from Homoallylic Alcohols Derived from Baylis-Hillman Adducts: Base-Dependent Stereoselectivity for the Benzylidene Group in Cyclobuta[a]indene." ChemInform 42, no. 35 (2011): no. http://dx.doi.org/10.1002/chin.201135100.

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12

Vetica, Fabrizio, Stephen J. Bailey, Mukesh Kumar, et al. "Palladium-Catalyzed [3+2] Cycloaddition of Vinylaziridine and Indane-1,3-diones: Diastereo- and Enantioselective Access to Spiro-Pyrrolidines." Synthesis 52, no. 14 (2020): 2038–44. http://dx.doi.org/10.1055/s-0040-1707472.

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A mild and efficient palladium-catalyzed [3+2] cycloaddition of vinylaziridine and indane-1,3-diones has been realized. The resulting spiro-pyrrolidines were provided in excellent yields and, with the introduction of the leucine-derived phosphine ligand, moderate to good enantio­- and diastereoselectivities.
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13

Sarhan, A. A., E. M. Afsah, M. Y. Abdelaal, and M. R. Ibrahim. "Studies on the alkylation of polymer-supported ambident anion derived from indane-1,3-dione." Reactive and Functional Polymers 32, no. 3 (1997): 231–39. http://dx.doi.org/10.1016/s1381-5148(96)00086-7.

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14

Ajaz, Aida, Alicia C. Voukides, Katharine J. Cahill, Rajesh Thamatam, Sarah L. Skraba-Joiner, and Richard P. Johnson. "Microwave Flash Pyrolysis: C9H8 Interconversions and Dimerisations." Australian Journal of Chemistry 67, no. 9 (2014): 1301. http://dx.doi.org/10.1071/ch14238.

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The pyrolysis of 2-ethynyltoluene, indene, fluorene, and related compounds has been studied by sealed tube microwave flash pyrolysis (MFP), in concert with modelling of putative mechanistic pathways by density functional theory (DFT) computations. In the MFP technique, samples are admixed with graphite and subjected to intense microwave power (150–300 W) in a quartz reaction tube under a nitrogen atmosphere. The MFP reaction of 2-ethynyltoluene gave mostly indene, the product of a Roger Brown rearrangement (1,2-H shift to a vinylidene) followed by insertion. An additional product was chrysene,
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15

Sanchez, Cristina, and Robert A. McClelland. "The tamoxifen cation reacts to give indene products." Canadian Journal of Chemistry 78, no. 9 (2000): 1186–93. http://dx.doi.org/10.1139/v00-122.

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The tamoxifen carbocation (Ph(Ar)C=CPh-CH+-CH3, Ar = 4-Me2NCH2CH2OC6H4) is generated from acetate and sulfate precursors by SN1 ionization in water. The cation exists in (E) and (Z) forms which equilibrate before reaction. The major products are the α-hydroxytamoxifens Ph(Ar)C=CPh-CHOH-CH3, both (E) 64% and (Z) 29%, with the ratio independent of the configuration of the starting ester. Two minor products with a total yield of 7% account for the rest of the products. These have been characterized as indenes derived from intramolecular cyclization, a 4.5% yield of the indene derived from cycliza
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16

Davies, Ian W., Chris H. Senanayake, Robert D. Larsen, Thomas R. Verhoeven, and Paul J. Reider. "Application of indane-derived C2-symmetric bis(oxazolines) in two-point binding asymmetric Diels-Alder reactions." Tetrahedron Letters 37, no. 11 (1996): 1725–26. http://dx.doi.org/10.1016/0040-4039(96)00119-0.

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17

Vijayakumar, Chinnaswamy Thangavel, Thangadurai Periadurai, and Sarfaraz Alam. "Synthesis and Polymerization of Bismaleimide Derived from 5(6)-amino-1(4′-aminophenyl)-1,3,3′-trimethyl indane." Polymer-Plastics Technology and Engineering 48, no. 2 (2009): 141–51. http://dx.doi.org/10.1080/03602550802577320.

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18

Solà, Lluís, Anton Vidal-Ferran, Albert Moyano, Miquel A. Pericàs, and Antoni Riera. "New indane derived aminoalcohols as chiral ligands for the catalytic enantioselective addition of diethylzinc to aldehydes." Tetrahedron: Asymmetry 8, no. 10 (1997): 1559–68. http://dx.doi.org/10.1016/s0957-4166(97)00163-8.

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19

Kyaw, Myat, Shinsuki Mori, Nathaniel Dugos, Susan Roces, Arnel Beltran, and Shunsuke Suzuki. "Plasma-Enhanced Chemical Vapor Deposition of Indene for Gas Separation Membrane." ASEAN Journal of Chemical Engineering 19, no. 1 (2019): 47. http://dx.doi.org/10.22146/ajche.50874.

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Polyindene (PIn) membrane was fabricated onto a zeolite 5A substrate by using plasma-enhanced chemical vapor deposition (PECVD) at low temperature. Membrane characterization was done by taking Scanning Electron Microscopy (SEM) and FT-IR measurements and the new peak was found in the plasma-derived PIn film. Membrane performance was analyzed by checking permeability of pure gases (H2, N2, and CO2) through the membrane. PECVD-derived PIn membrane showed high gas barrier properties and selectivities of 8.2 and 4.0 for H2/CO2 and H2/N2, respectively, at room temperature
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20

Priebbenow, Daniel L., and Carol Hua. "Acyl silane directed Cp*Rh(iii)-catalysed alkylation/annulation reactions." Chemical Communications 57, no. 64 (2021): 7938–41. http://dx.doi.org/10.1039/d1cc03051e.

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21

García-Mera, Xerardo, Nerea Alonso, Olga Caamaño, et al. "Synthesis and Antiviral Activities of Novel Purinyl- and Pyrimidinyl­carbanucleosides Derived from Indan." Synthesis 2008, no. 12 (2008): 1845–52. http://dx.doi.org/10.1055/s-2008-1067091.

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22

Fernández, Franco, Xerardo García-Mera, Melvin Morales, José E. Rodríguez-Borges, and Eric De Clercq. "Synthesis and Cytostatic Activities of New 6-Substituted Purinylcarbonucleosides Derived from Indan." Synthesis 2002, no. 08 (2002): 1084–90. http://dx.doi.org/10.1055/s-2002-31956.

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23

Sharp, Hazel, Jackie Hollinshead, Barbara B. Bartholomew, Julius Oben, Alison Watson та Robert J. Nash. "Inhibitory Effects of Cissus quadrangularis L. Derived Components on Lipase, Amylase and α-Glucosidase Activity in vitro". Natural Product Communications 2, № 8 (2007): 1934578X0700200. http://dx.doi.org/10.1177/1934578x0700200806.

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The stems of Cissus quadrangularis L (Vitaceae) have been consumed for centuries throughout Asia and Africa as a culinary vegetable. The aqueous extract of C. quadrangularis stems and leaves contains flavonoids and stilbenes, which inhibit lipase, amylase and α-glucosidase and, therefore, might be, at least in part, related to the claimed anti-obesity activity of the plant. The enzyme inhibition activity is outlined of a novel flavonoid (3- O-α-L-rhamnopyranosylkaempferol) (2) and stilbene (3-(4-hydroxybenzylidene)-2-(2,5-dihydroxyphenyl)-1-(4-hydroxyphenyl)indane-4,6-diol) (7), four known str
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24

Wanibuchi, Kiyofumi, Kouichi Hosoda, Masato Ihara, et al. "Indene Compounds Synthetically Derived from Vitamin D Have Selective Antibacterial Action onHelicobacter pylori." Lipids 53, no. 4 (2018): 393–401. http://dx.doi.org/10.1002/lipd.12043.

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25

Davies, Ian W., Chris H. Senanayake, Robert D. Larsen, Thomas R. Verhoeven, and Paul J. Reider. "Application of a Ritter-type reaction to the synthesis of chiral indane-derived C2-symmetric bis(oxazolines)." Tetrahedron Letters 37, no. 6 (1996): 813–14. http://dx.doi.org/10.1016/0040-4039(95)02328-3.

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26

Chen, Qinfang, Yihao Pan, Dongxin Zhao, Weiran Yang, and Jing Zheng. "Construct indeno[1,2-b]oxepine or cis-cyclopropylacrylate by sulfur ylides." RSC Advances 10, no. 37 (2020): 21895–906. http://dx.doi.org/10.1039/d0ra03919e.

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For the first time, the [4 + 3] or [2 + 1] annulation of crotonate-derived sulfur ylides with arylidenemalononitrile or arylidene-1H-indene-1,3(2H)-dione is reported using Na<sub>2</sub>CO<sub>3</sub> as the base.
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27

Bucher, Götz, Gernot Heitmann, and Rainer Herges. "Thermochemistry and photochemistry of spiroketals derived from indan-2-one: Stepwise processes versus coarctate fragmentations." Beilstein Journal of Organic Chemistry 9 (August 15, 2013): 1668–76. http://dx.doi.org/10.3762/bjoc.9.191.

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Coarctate reactions are defined as reactions that include atoms at which two bonds are made and two bonds are broken simultaneously. In the pursuit of the discovery of new coarctate reactions we investigate the fragmentation reactions of cyclic ketals. Three ketals with different ring sizes derived from indan-2-one were decomposed by photolysis and pyrolysis. Particularly clean is the photolysis of the indan-2-one ketal 1, which gives o-quinodimethane, carbon dioxide and ethylene. The mechanism formally corresponds to a photochemically allowed coarctate fragmentation. Pyrolysis of the five-rin
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28

Rong, Zi-Qiang, Zhaoyuan Yu, Cheng Weng, et al. "Dynamic Kinetic Asymmetric Amination of Alcohols Assisted by Microwave: Stereoconvergent Access to Tetralin- and Indane-Derived Chiral Amines." ACS Catalysis 10, no. 16 (2020): 9464–75. http://dx.doi.org/10.1021/acscatal.0c02468.

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29

Bahajaj, Abood A., and John M. Vernon. "Formation of spiro indane derivatives from hydroxy lactams derived from N-(1-phenylethyl)-phthalimide and -pyridine-2,3-dicarboximide." Journal of the Chemical Society, Perkin Transactions 1, no. 10 (1996): 1041. http://dx.doi.org/10.1039/p19960001041.

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30

Tang, Fei, Ping Lan, Benoit Bolte, Martin G. Banwell, Jas S. Ward, and Anthony C. Willis. "Total Synthesis of (+)-Viridianol, a Marine-Derived Sesquiterpene Embodying the Decahydrocyclobuta[d]indene Framework." Journal of Organic Chemistry 83, no. 22 (2018): 14049–56. http://dx.doi.org/10.1021/acs.joc.8b02626.

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31

Fernandez, Franco, Xerardo Garcia-Mera, Malvin Morales, Jose E. Rodriguez-Borges, and Eric De Clercq. "ChemInform Abstract: Synthesis and Cytostatic Activities of New 6-Substituted Purinylcarbonucleosides Derived from Indan." ChemInform 33, no. 40 (2010): no. http://dx.doi.org/10.1002/chin.200240221.

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32

Kurosu, Michio, James R. Porter, and Michael A. Foley. "An efficient synthesis of indane-derived bis(oxazoline) and its application to hetero Diels–Alder reactions on polymer support." Tetrahedron Letters 45, no. 1 (2004): 145–48. http://dx.doi.org/10.1016/j.tetlet.2003.10.097.

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33

Englert, Ulli, Chunhua Hu, Albrecht Salzer та Elisabetta Alberico. "Conformationally Constrained Diphosphines Derived from (η6-(S)-1-(dimethylamino)indane)Cr(CO)3: Synthesis and Application in Enantioselective Hydrogenation". Organometallics 23, № 23 (2004): 5419–31. http://dx.doi.org/10.1021/om049628z.

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34

DAVIES, I. W., C. H. SENANAYAKE, R. D. LARSEN, T. R. VERHOEVEN, and P. J. REIDER. "ChemInform Abstract: Application of a Ritter-Type Reaction to the Synthesis of Chiral Indane-Derived C2-Symmetric Bis(oxazolines)." ChemInform 27, no. 21 (2010): no. http://dx.doi.org/10.1002/chin.199621135.

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35

Power, John D., Pierce Kavanagh, Gavin McLaughlin, et al. "Forensic analysis of P2P derived amphetamine synthesis impurities: identification and characterization of indene by-products." Drug Testing and Analysis 9, no. 3 (2016): 446–52. http://dx.doi.org/10.1002/dta.1944.

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36

Edwards, Oliver E., Austin M. Greaves, and Wing-Wah Sy. "Reactions of 1,2-dehydropyrrolidin-5-one with 1,3-dienes. Synthesis of dl-gephyrotoxin 223AB." Canadian Journal of Chemistry 66, no. 5 (1988): 1163–72. http://dx.doi.org/10.1139/v88-191.

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Evidence is presented that the regiospecific and often stereospecific pseudo-Diels–Alder reactions of 1,3-dienes with N-acyl immonium salts, derived from 5-ethoxy-2-pyrrolidinone, are stepwise reactions. 6,7-Dehydroindolizidinones, unsaturated lactam esters, and new indene and furan derivatives are described. A synthesis of dl-gephyrotoxin 223AB (indolizidine 223AB) from trans-1,3-heptadiene was achieved.
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37

Boitsov, Vitali M., Alexander V. Stepakov, Siqi Wang, et al. "Construction of Spiro[3-azabicyclo[3.1.0]hexanes] via 1,3-Dipolar Cycloaddition of 1,2-Diphenylcyclopropenes to Ninhydrin-Derived Azomethine Ylides." Synthesis 53, no. 12 (2021): 2114–32. http://dx.doi.org/10.1055/a-1360-9716.

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AbstractThe multi-component 1,3-dipolar cycloaddition of ninhydrin, α-amino acids (or peptides), and cyclopropenes for the synthesis of spirocyclic heterocycles containing both 3-azabicyclo[3.1.0]hexane and 2H-indene-1,3-dione motifs has been developed. This method provides easy access to 3-azabicyclo[3.1.0]hexane-2,2′-indenes with complete stereoselectivity and a high degree of atom economy under mild reaction conditions. A broad range of cyclopropenes and α-amino acids have been found to be compatible with the present protocol, which offers an opportunity to create a new library of biologica
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38

Roy, Suparna, and Venkatesh Piradhi. "Formal [2+1] Annulation (Spiro-Cyclopropanation) Reaction between Sulfur Ylides Derived from Baylis-Hillman Bromides and Arylidene Indane-1,3-Dione." ChemistrySelect 2, no. 21 (2017): 6159–62. http://dx.doi.org/10.1002/slct.201701221.

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39

Mor, Satbir, Savita Nagoria, Suchita Sindhu, Mohini Khatri, Gurdeep Sidhu, and Virender Singh. "Synthesis of Indane-Based 1,5-Benzothiazepines Derived from 3-Phenyl-2,3-dihydro-1H -inden-1-one and Antimicrobial Studies Thereof." Journal of Heterocyclic Chemistry 54, no. 6 (2017): 3282–93. http://dx.doi.org/10.1002/jhet.2948.

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40

Kutama, Ibrahim U., and Simon Jones. "Enantioselective Desymmetrization of Glutarimides Catalyzed by Oxazaborolidines Derived from cis-1-Amino-indan-2-ol." Journal of Organic Chemistry 80, no. 22 (2015): 11468–79. http://dx.doi.org/10.1021/acs.joc.5b02177.

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41

Kress, Michael H., Chunhua Yang, Nobuyoshi Yasuda, and E. J. J. Grabowski. "Stereoselective [2,3]-wittig rearrangement of (1S,2R)-1-amino-indan-2-ol derived amide enolates." Tetrahedron Letters 38, no. 15 (1997): 2633–36. http://dx.doi.org/10.1016/s0040-4039(97)00438-3.

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42

Cernicharo, J., M. Agúndez, C. Cabezas, et al. "Pure hydrocarbon cycles in TMC-1: Discovery of ethynyl cyclopropenylidene, cyclopentadiene, and indene." Astronomy & Astrophysics 649 (May 2021): L15. http://dx.doi.org/10.1051/0004-6361/202141156.

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We report the detection for the first time in space of three new pure hydrocarbon cycles in TMC-1: c-C3HCCH (ethynyl cyclopropenylidene), c-C5H6 (cyclopentadiene), and c-C9H8 (indene). We derive a column density of 3.1 × 1011 cm−2 for the first cycle and similar values, in the range (1−2) × 1013 cm−2, for the second and third. This means that cyclopentadiene and indene, in spite of their large size, are exceptionally abundant, only a factor of five less abundant than the ubiquitous cyclic hydrocarbon c-C3H2. The high abundance found for these two hydrocarbon cycles together with the high abund
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43

Kodama, Koichi, Shohei Yamaguchi, Shigetaka Hayano, et al. "Characterization and enantiomer separation of indene-derived hexacyclic hydrocarbon and its application as a chiral source." Tetrahedron 87 (May 2021): 132082. http://dx.doi.org/10.1016/j.tet.2021.132082.

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44

Morales-Verdejo, César, Iván Martínez-Díaz, Christopher Adams, et al. "New mono and bimetallic iron complexes derived from partially methylated s-indacene. Evidence of a trinuclear iron s-indacene complex." Polyhedron 69 (February 2014): 15–24. http://dx.doi.org/10.1016/j.poly.2013.11.023.

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45

Davis, Randall N., and Timothy D. Lash. "Preparation of stable fulvene and difulvene aldehydes from benzaldehydes and an indene-derived enamine: formation of novel indene-fused benzodiazepines and attempted syntheses of di- and tricarbaporphyrinoid systems." Tetrahedron 65, no. 48 (2009): 9935–43. http://dx.doi.org/10.1016/j.tet.2009.10.013.

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46

Gilmore, Nathan J., Simon Jones, and Mark P. Muldowney. "Synthetic Applicability andin SituRecycling of aB-Methoxy Oxazaborolidine Catalyst Derived fromcis-1-Amino-indan-2-ol." Organic Letters 6, no. 16 (2004): 2805–8. http://dx.doi.org/10.1021/ol048916o.

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47

Wechsler, Dominik, Gabriele Schatte, and Mark Stradiotto. "Synthesis, characterization, and catalytic application of a new chiral P,N-indene ligand derived from (R)-BINOL." Journal of Organometallic Chemistry 694, no. 12 (2009): 1943–47. http://dx.doi.org/10.1016/j.jorganchem.2009.02.015.

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48

Itte, Pushpavathi, M. K. Amshumali, and Mussavir Pasha, K.M. "Molecular Modeling, Geometry Optimization and Characterization of Bimetallic Complexes Derived from s-Indacene." Universal Journal of Chemistry 5, no. 3 (2017): 48–57. http://dx.doi.org/10.13189/ujc.2017.050302.

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49

Morales-Verdejo, César, Luciano Oehninger, Iván Martínez-Díaz, et al. "A new heterobimetallic manganese–rhodium carbonyl complex derived from partially alkylated s-indacene." Inorganica Chimica Acta 394 (January 2013): 132–39. http://dx.doi.org/10.1016/j.ica.2012.08.010.

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50

KRESS, M. H., C. YANG, N. YASUDA, and E. J. J. GRABOWSKI. "ChemInform Abstract: Stereoselective (2,3)-Wittig Rearrangement of (1S,2R)-1-Amino-indan-2- ol Derived Amide Enolates." ChemInform 28, no. 31 (2010): no. http://dx.doi.org/10.1002/chin.199731048.

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