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Relevant bibliographies by topics / Indole functionalization

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Journal articles

Academic literature on the topic 'Indole functionalization'

Author: Grafiati

Published: 4 June 2021

Last updated: 3 February 2022

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Journal articles on the topic "Indole functionalization"

1

Sharma, Upendra, Inder Kumar, and Rakesh Kumar. "Recent Advances in the Regioselective Synthesis of Indoles via C–H Activation/Functionalization." Synthesis 50, no. 14 (2018): 2655–77. http://dx.doi.org/10.1055/s-0037-1609733.

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Indole is an important heterocyclic motif that occurs ubiquitously in bioactive natural products and pharmaceuticals. Immense efforts have been devoted to the synthesis of indoles starting from the Fisher indole synthesis to the recently developed C–H activation/functionalization-based methods. Herein, we have reviewed the progress made on the regioselective synthesis of functionalized indoles, including 2-substituted, 3-substituted and 2,3-disusbstituted indoles, since the year 2010.1 Introduction2 Metal-Catalyzed Synthesis of 2-Substituted Indoles3 Metal-Catalyzed Synthesis of 3-Substituted

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2

Chen, Jing-Biao, and Yi-Xia Jia. "Recent progress in transition-metal-catalyzed enantioselective indole functionalizations." Organic & Biomolecular Chemistry 15, no. 17 (2017): 3550–67. http://dx.doi.org/10.1039/c7ob00413c.

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Recent progress on the transition-metal-catalyzed enantioselective functionalization reaction of indoles is reviewed, which is mainly focused on asymmetric indole alkylations, arylations, cycloaddition reactions, and other reactions.

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3

Zhang, Yong-Sheng, Xiang-Ying Tang, and Min Shi. "Divergent synthesis of indole-fused polycycles via Rh(ii)-catalyzed intramolecular [3 + 2] cycloaddition and C–H functionalization of indolyltriazoles." Organic Chemistry Frontiers 2, no. 11 (2015): 1516–20. http://dx.doi.org/10.1039/c5qo00216h.

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4

Trubitsõn, Dmitri, and Tõnis Kanger. "Enantioselective Catalytic Synthesis of N-alkylated Indoles." Symmetry 12, no. 7 (2020): 1184. http://dx.doi.org/10.3390/sym12071184.

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During the past two decades, the interest in new methodologies for the synthesis of chiral N-functionalized indoles has grown rapidly. The review illustrates efficient applications of organocatalytic and organometallic strategies for the construction of chiral α-N-branched indoles. Both the direct functionalization of the indole core and indirect methods based on asymmetric N-alkylation of indolines, isatins and 4,7-dihydroindoles are discussed.

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5

Osipov, Sergey, and Daria Vorobyeva. "Selective Synthesis of 2- and 7-Substituted Indole Derivatives via Chelation-Assisted Metallocarbenoid C–H Bond Functionalization." Synthesis 50, no. 02 (2017): 227–40. http://dx.doi.org/10.1055/s-0036-1591498.

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Functionally substituted indole derivatives are important intermediates for the synthesis of new potential drug candidates exhibiting strong bioactivities. Over the past few years, significant progress has been made in the direct C–H functionalization of the indole ring through the usage of metal-catalyzed intermolecular cross-coupling with diazo compounds. Directing group strategy provides a unique possibility for selective insertion of carbenes catalytically generated from diazo compounds into challenging indole C2–H and C7–H bonds. This short review summarizes recent advances in carbenoid f

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6

Nagaraju, Karre, and Dawei Ma. "Oxidative coupling strategies for the synthesis of indole alkaloids." Chemical Society Reviews 47, no. 21 (2018): 8018–29. http://dx.doi.org/10.1039/c8cs00305j.

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7

Kaldas, Sherif J., Alexandre Cannillo, Terry McCallum, and Louis Barriault. "Indole Functionalization via Photoredox Gold Catalysis." Organic Letters 17, no. 11 (2015): 2864–66. http://dx.doi.org/10.1021/acs.orglett.5b01260.

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8

Pirovano, Valentina. "Gold-Catalyzed Functionalization Reactions of Indole." European Journal of Organic Chemistry 2018, no. 17 (2018): 1925–45. http://dx.doi.org/10.1002/ejoc.201800125.

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9

Wu, Wang, Zhang, and Jin. "Urea-Derivative Catalyzed Enantioselective Hydroxyalkylation of Hydroxyindoles with Isatins." Molecules 24, no. 21 (2019): 3944. http://dx.doi.org/10.3390/molecules24213944.

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The enantioselective transformations of indoles preferentially take place in the more-reactive azole ring. However, the methods for the enantioselective functionalization of the indole benzene ring are scarce. In this paper, a series of bifunctional (thio)urea derivatives were used to organocatalyze the enantioselective Friedel−Crafts hydroxyalkylation of indoles with isatins. The resulting products were obtained in good yields (65–90%) with up to 94% enantiomer excess (ee). The catalyst type and the substrate scope were broadened in this methodology.

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10

Cai, Yan, Yuming Li, Minxuan Zhang, Jiaxin Fu та Zhiwei Miao. "Regioselective BF3·Et2O-catalyzed C–H functionalization of indoles and pyrrole with reaction of α-diazophosphonates". RSC Advances 6, № 73 (2016): 69352–56. http://dx.doi.org/10.1039/c6ra15329a.

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A regioselective synthesis of β-(3-indol)-β-aminophosphonates and β-(2-pyrrol)-β-aminophosphonates was developed through an intermolecular C–H insertion of α-diazophosphonates with indole and pyrrole derivatives catalyzed by BF<sub>3</sub>·Et<sub>2</sub>O.

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