Academic literature on the topic 'Indole Palladium catalysts'

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Journal articles on the topic "Indole Palladium catalysts"

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Ayesha, Muhammad Bilal, Nasir Rasool, et al. "Synthesis of Indoles via Intermolecular and Intramolecular Cyclization by Using Palladium-Based Catalysts." Catalysts 11, no. 9 (2021): 1018. http://dx.doi.org/10.3390/catal11091018.

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As part of natural products or biologically active compounds, the synthesis of nitrogen-containing heterocycles is becoming incredibly valuable. Palladium is a transition metal that is widely utilized as a catalyst to facilitate carbon-carbon and carbon-heteroatom coupling; it is used in the synthesis of various heterocycles. This review includes the twelve years of successful indole synthesis using various palladium catalysts to establish carbon-carbon or carbon-nitrogen coupling, as well as the conditions that have been optimized.
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Li, Kangkang, Junhao Ye, Zhen Wang, Hongliang Mu, and Zhongbao Jian. "Indole-bridged bisphosphine-monoxide palladium catalysts for ethylene polymerization and copolymerization with polar monomers." Polymer Chemistry 11, no. 15 (2020): 2740–48. http://dx.doi.org/10.1039/d0py00100g.

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Novel indole-based C–N-bridged bisphosphine-monoxide palladium catalysts enable ethylene polymerization with completely different activities and molecular weights and copolymerization with polar comonomers.
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Iwatsuki, Satoshi, Takuya Suzuki, Syogo Tanooka, Tatsuo Yajima, and Yuichi Shimazaki. "Kinetic studies on cyclopalladation in palladium(II) complexes containing an indole moiety." Pure and Applied Chemistry 86, no. 2 (2014): 151–61. http://dx.doi.org/10.1515/pac-2014-5020.

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Abstract Various Pd–C complexes have been developed to date, affording deep insights into the reaction intermediates in useful catalytic reactions in organic syntheses. Cyclopalladation is one of the most famous Pd–C bond formation reactions to generate the palladacycles. Indole is an electron-rich aromatic ring involved in the side chain of an essential amino acid, tryptophan (Trp), and Trp and its derivatives are important in biological systems, such as electron transfer in protein, cofactors for conversion of biological molecules and so on. Pd catalysts are also useful for syntheses of such
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Kimyashov, Alexander A., Alexander V. Syromolotov, and Dmitry S. Ryashincev. "Study of Buchwald-Hartwig reaction with catalysts based on monovalent copper." Butlerov Communications 58, no. 4 (2019): 62–65. http://dx.doi.org/10.37952/roi-jbc-01/19-58-4-62.

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Many natural substances and drugs includes N-aryl-substituted heterocycles. These substances can be synthesized in various conditions, one of which is the amination of Buchwald-Hartwig. In this reaction formation of N-substituted anilines was observed as the resalt of the interaction between aryl halides and tin amides in palladium catalysis condition. It was discovered by Buchwald and Hartwig in 1994. In 1996, toxic amides of tin and P(o-Tol)3 were replaced by amines and chelating diphosphines. Due to high yields and good reproducibility, Buchwald-Hartwig amination is the attractive method fo
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Ryashentseva, M. A. "A preparative synthesis of indole by dehydrogenation of 4,5,6,7-tetrahydroindole over catalysts with a low palladium content." Russian Chemical Bulletin 42, no. 10 (1993): 1756–57. http://dx.doi.org/10.1007/bf00697060.

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Peng, Yiyuan, Xinglin Ye, Jian Huang, Zhihong Deng, and Jianjun Yuan. "Palladium-Catalyzed Cross-Coupling Reactions of 4-Tosyl­oxyquinazolines with Indoles: An Efficient Approach to 4-(1H-Indol-1-yl)quinazolines." Synthesis 53, no. 02 (2020): 383–90. http://dx.doi.org/10.1055/s-0040-1707356.

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In this paper, exploration of our continuous interests on late-stage derivation of quinozaline core is described. A wide array of 4-(1H-indol-1-yl)quinazolines were obtained in good to excellent yields through palladium-catalyzed cross-coupling of 4-tosyloxyquinazolines with indole derivatives under mild reaction conditions.
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Jiang, Guangbin, Guang Yang, Xinqiang Liu, Shoucai Wang, and Fanghua Ji. "Palladium-catalyzed sequential acylation/annulation of indoles with acyl chlorides using primary amine as the directing group." New Journal of Chemistry 45, no. 1 (2021): 104–9. http://dx.doi.org/10.1039/d0nj04406g.

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Chang, Chieh-Yu, Yu-Huan Lin, and Yen-Ku Wu. "Palladium-catalyzed N1-selective allylation of indoles with allylic alcohols promoted by titanium tetraisopropoxide." Chemical Communications 55, no. 8 (2019): 1116–19. http://dx.doi.org/10.1039/c8cc09817d.

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Prasad Tulichala, R. N., and K. C. Kumara Swamy. "Palladium-catalysed decarboxylative nitrile insertion via C–H activation or self-coupling of indole-2-carboxylic acids: a new route to indolocarbolines and triindoles." Chemical Communications 51, no. 60 (2015): 12008–11. http://dx.doi.org/10.1039/c5cc03160e.

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Liu, Xian-Rong, and Yan-Ling Zhou. "Crystal structure of 1-methyl-3-[2,2,2-trifluoro-1-(1-methyl-1H-indol-3-yl)-1-phenylethyl]-1H-indole." Acta Crystallographica Section E Structure Reports Online 70, no. 11 (2014): o1156. http://dx.doi.org/10.1107/s1600536814021916.

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The title compound, C26H21F3N2, was prepared by the palladium-catalysed reaction of (2,2,2-trifluoroethyl)benzene with 1-methyl-1H-indole. The dihedral angle between the planes of the indole-ring systems is 52.13 (6)° and theN-methyl groups point away from each other. Three short intramolecular C—H...F contacts are observed.
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Dissertations / Theses on the topic "Indole Palladium catalysts"

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Clawson, Ronald W. "The synthesis of 3-ethoxyindoles, koniamborine, salviadione and studies toward fistulosin utilizing palladium-catalyzed reductive N-heteroannulation." Morgantown, W. Va. : [West Virginia University Libraries], 2007. https://eidr.wvu.edu/etd/documentdata.eTD?documentid=5425.

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Thesis (Ph. D.)--West Virginia University, 2007.<br>Title from document title page. Document formatted into pages; contains xxiv, 282 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 166-179).
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Hubbard, Jeremiah W. "Novel synthesis of 3,4-fused indoles." Morgantown, W. Va. : [West Virginia University Libraries], 2001. http://etd.wvu.edu/templates/showETD.cfm?recnum=2209.

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Thesis (M.S.)--West Virginia University, 2001.<br>Title from document title page. Document formatted into pages; contains xi, 70, 76 p. : ill. Includes abstract. Includes bibliographical references (p. 67-70).
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Turner, Michael R. "Novel palladium catalyzed synthesis of 3-substituted indoles and its application toward the total synthesis of indolactam V." Morgantown, W. Va. : [West Virginia University Libraries], 2000. http://etd.wvu.edu/templates/showETD.cfm?recnum=1585.

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Thesis (M.S.)--West Virginia University, 2000.<br>Title from document title page. Document formatted into pages; contains ix, 51, 28 p. : ill. Includes abstract. Includes bibliographical references (p. 49-51).
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Dacko, Christopher Andrew. "The synthesis of tryptophan derivatives, 2- and/or 3-substituted indoles, progress toward dilemmaones A-C, and synthetic studies towards fistulosin via palladium-catalyzed reductive N-heteroannulation." Morgantown, W. Va. : [West Virginia University Libraries], 2009. http://hdl.handle.net/10450/10403.

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Thesis (Ph. D.)--West Virginia University, 2009.<br>Title from document title page. Document formatted into pages; contains xxvi, 324 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 186-198).
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Gorugantula, Sobha Priyadarshini. "Syntheses of fused pyrroloheterocycles, isatins, approach towards the indole fragment of nosiheptide and a base-mediated formation of 3-hydroxycarbazoles." Morgantown, W. Va. : [West Virginia University Libraries], 2009. http://hdl.handle.net/10450/10483.

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Thesis (Ph. D.)--West Virginia University, 2009.<br>Title from document title page. Document formatted into pages; contains xx, 242 p. : ill. Includes abstract. Includes bibliographical references (p. 137-145).
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Banini, Serge R. "Palladium-catalyzed syntheses of indoles, pyrroloindoles, quinolines a base-mediated formation of N-alkoxyindoles, and progress toward the first total synthesis of echinosulfone A /." Morgantown, W. Va. : [West Virginia University Libraries], 2008. https://eidr.wvu.edu/etd/documentdata.eTD?documentid=5710.

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Thesis (Ph. D.)--West Virginia University, 2008.<br>Title from document title page. Document formatted into pages; contains xv, 275 p. : ill. Includes abstract. Includes bibliographical references (p. 107-113).
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Lopez, Suarez Laura. "Tetra-substituted olefin synthesis using palladium-catalysed C-H activation." Thesis, University of Edinburgh, 2012. http://hdl.handle.net/1842/5869.

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In an effort to obtain more efficient and greener chemical transformations, a substantial amount of research interest has been directed towards the use of arene C-H bonds as functional groups. Hydroarylation of alkynes through direct functionalisation of C-H bonds has been studied in recent years leading to the development of high-yielding metal-mediated processes. The main aim of the current work is the addition of a third component in the hydroarylation of alkynes trough C-H activation, in order to achieve a second C-C bond formation. Attempts at palladium-catalysed three-component reaction
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Batail, Nelly. "La catalyse au palladium pour l'obtention d'indoles fonctionnalisés : application à une synthèse monotope d'indoloquinones par catalyse hétérogène." Phd thesis, Université Claude Bernard - Lyon I, 2010. http://tel.archives-ouvertes.fr/tel-00713118.

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Depuis le début des années 1990, l'hétéroannélation de Larock est apparue comme une méthode de choix pour obtenir, en une seule étape, des indoles 2,3-disubstitués. Cependant, bien qu'efficace, certains inconvénients restaient associés à cette stratégie comme l'utilisation d'un système catalytique homogène associé à l'emploi de sels. Pour cette raison, nous avons développé une nouvelle méthodologie sans sels ou additifs par catalyse hétérogène. Différents catalyseurs commerciaux ou faciles d'accès (Pd/C ou [Pd]/NaY) ainsi que de nouveaux complexes au palladium immobilisés sur SBA-15 ont été te
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Hodgkinson, Roy. "Synthesis of indoles and azaindoles via copper/palladium catalysed tandem C-N bond coupling." Thesis, University of Oxford, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.504479.

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Cusati, Giuseppe. "La catalyse hétérogène au palladium en chimie fine : une étude sur la synthèse " one-pot " de stilbènes et bibenzyles : application à la synthèse de styrènes et aryl-indoles." Phd thesis, Université Claude Bernard - Lyon I, 2009. http://tel.archives-ouvertes.fr/tel-00876267.

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Les synthèses " one pot " multi-étapes efficaces et éco-compatibles ont été envisagées pour la synthèse de molécules potentiellement bioactives tels que les systèmes bis(bibenzyliques) et leurs précurseurs stilbéniques ou bibenzyliques par catalyse hétérogène au palladium. Une synthèse " one-pot " impliquant une réaction de couplage de Heck suivie d'une hydrogénation des stilbènes ainsi formés a été mise au point en présence de Pd/C. Cette stratégie c'est révélée être limitée lors de l'application à des substrats désactivés et stériquement encombrées. Couplée au manque de disponibilité commerc
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Book chapters on the topic "Indole Palladium catalysts"

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Seibel, Zara M., and Tristan H. Lambert. "Construction of Alkylated Stereocenters." In Organic Synthesis. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780190646165.003.0035.

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Hirohisa Ohmiya and Masaya Sawamura at Hokkaido University reported (Angew. Chem. Int. Ed. 2013, 52, 5350) the copper-catalyzed, γ-selective allylation of terminal alkyne 1 to produce the chiral skipped enyne 3 with high ee. A method to synthe­size asymmetric skipped diene 6 via copper-catalyzed allylic allylation of diene 4 was developed (Chem. Commun. 2013, 49, 3309) by Ben L. Feringa at the University of Groningen. Prof. Feringa also disclosed (J. Am. Chem. Soc. 2013, 135, 2140) the regi­oselective and enantioselective allyl–allyl coupling of bromide 7 with allyl Grignard under Cu catalysis in the presence of phosphoramidite 8. James P. Morken of Boston College reported (Org. Lett. 2013, 15, 1432) the cross-coupling of allylboronate 11 with a mixture of alkenes 10a,b under palladium catalysis to produce diene 13 with high ee. Jian Liao at the Chengdu Institute of Biology Chinese Academy of Sciences and the University of Chinese Academy of Sciences reported (Angew. Chem. Int. Ed. 2013, 52, 4207) the palladium-catalyzed allylic alkylation of indole using the chi­ral bis(sulfoxide) phosphine ligand 15. Yi-Xia Jia at the Zhejiang University of Technology reported (J. Am. Chem. Soc. 2013, 135, 2983) the enantioselective alkyl­ation of indole to produce the trifluoromethyl adduct 19 using nickel catalysis in the presence of bisoxazoline ligand 18. Sarah E. Reisman at the California Institute of Technology disclosed (J. Am. Chem. Soc. 2013, 135, 7442) the reductive cross-coupling of acid chloride 20 and benzyl chloride 21 using a nickel complex with bisoxazoline ligand 22 and manganese(0) as reductant. Ilan Marek at the Technion-Israel Institute of Technology reported (Angew. Chem. Int. Ed. 2013, 52, 5333) a method for the construction of all-carbon quaternary stereocenters, such as the one present in aldehyde 25, using a diastereoselective car­bometallation of cyclopropene 24 followed by oxidation and ring opening. Switching from methyl Grignard and copper iodide to MeCuCNLi reverses the diastereoselec­tivity of the carbometallation and allows access to the opposite enantiomer. Matthew S. Sigman at the University of Utah reported (J. Am. Chem. Soc. 2013, 135, 6830) the redox–relay oxidative Heck arylation of alkenyl alcohol 27 with boronic acid 26 using a palladium catalyst and pyridine oxazole ligand 28 to produce the γ-substituted aldehyde 29.
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