Academic literature on the topic 'Indolenines'

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Journal articles on the topic "Indolenines"

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Yang, Hua, Jie Li, Jun-An Xiao, Shu-Juan Zhao, and Hao-Yue Xiang. "Facile Construction of Pyrrolo[1,2-a]indolenine Scaffold via Dia­stereoselective [3+2] Annulation of Donor–Acceptor Cyclopropane with Indolenine." Synthesis 49, no. 18 (2017): 4292–98. http://dx.doi.org/10.1055/s-0036-1588876.

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A novel synthetic protocol for the assembly of pyrrolo[1,2-a]indolenine has been developed through a highly diastereoselective [3+2] annulation of 1,1-cyclopropanediesters with indolenines in the presence of catalytic Yb(OTf)3. This new strategy allows a facile construction of the multicyclic system with the flexible variation on the substituents in high yields (up to 86%) with excellent diastereoselectivities (>20:1 dr) in most cases.
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Suzuki, Tamie, Nilamber A. Mate, Arijit A. Adhikari, and John D. Chisholm. "Dialkylation of Indoles with Trichloroacetimidates to Access 3,3-Disubstituted Indolenines." Molecules 24, no. 22 (2019): 4143. http://dx.doi.org/10.3390/molecules24224143.

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2-Substituted indoles may be directly transformed to 3,3-dialkyl indolenines with trichloroacetimidate electrophiles and the Lewis acid TMSOTf. These reactions provide rapid access to complex indolenines which are present in a variety of complex natural products and medicinally relevant small molecule structures. This method provides an alternative to the use of transition metal catalysis. The indolenines are readily transformed into spiroindoline systems which are privileged scaffolds in medicinal chemistry.
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Chisholm, John, Arijit Adhikari, and Léa Radal. "Synthesis of 3,3′-Disubstituted Indolenines Utilizing the Lewis Acid Catalyzed Alkylation of 2,3-Disubstituted Indoles with Trichloroacetimidates." Synlett 28, no. 17 (2017): 2335–39. http://dx.doi.org/10.1055/s-0036-1588491.

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Trichloroacetimidates function as effective electrophiles for the selective C3-alkylation of 2,3-disubstituted indoles to provide 3,3′-disubstituted indolenines. These indolenines are common synthetic intermediates that are often utilized in the synthesis of complex molecules. Effective reaction conditions utilizing Lewis acid catalysts have been determined, and the scope of the reaction with respect to indole and imidate reaction partner has been investigated. This chemistry provides an alternative to base promoted and transition-metal-catalyzed methods that are more commonly utilized to acce
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Laronze, J. Y., J. Laronze, D. Patigny, and J. Lévy. "Methylene-indolines, indolenines and indoleniniums, XXI an indolenine approach to morphine related compounds." Tetrahedron Letters 27, no. 4 (1986): 489–92. http://dx.doi.org/10.1016/s0040-4039(00)85512-4.

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James, Michael J., Peter O'Brien, Richard J. K. Taylor, and William P. Unsworth. "Synthesis of Spirocyclic Indolenines." Chemistry - A European Journal 22, no. 9 (2015): 2856–81. http://dx.doi.org/10.1002/chem.201503835.

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Nawaz, Shah, Shiqiang Wei, Yue Huang, Wenyao Wang, Jingping Qu, and Baomin Wang. "Diastereoselective synthesis of indolenine-based spiro[pyrazolone-4,2′-pyrrolidine] scaffolds via 1,3-dipolar cycloaddition of 4-aminopyrazolones, aldehydes, and indolenines." Organic & Biomolecular Chemistry 19, no. 32 (2021): 6964–68. http://dx.doi.org/10.1039/d1ob01135a.

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Ramle, Abdul Qaiyum, Chee Chin Fei, Edward R. T. Tiekink, and Wan Jefrey Basirun. "Indoleninyl-substituted pyrimido[1,2-b]indazoles via a facile condensation reaction." RSC Advances 11, no. 40 (2021): 24647–51. http://dx.doi.org/10.1039/d1ra04372b.

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Alfano, Antonella Ilenia, Angela Zampella, Ettore Novellino, Margherita Brindisi, and Heiko Lange. "Harnessing interrupted Fischer in continuous flow: sustainable synthesis of (spiro)indolenine and (spiro)indoline privileged scaffolds." Reaction Chemistry & Engineering 5, no. 11 (2020): 2091–100. http://dx.doi.org/10.1039/d0re00329h.

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Fedoseev, Pavel, and Erik Van der Eycken. "Temperature switchable Brønsted acid-promoted selective syntheses of spiro-indolenines and quinolines." Chemical Communications 53, no. 55 (2017): 7732–35. http://dx.doi.org/10.1039/c7cc02580g.

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Huber, Florian, Joel Roesslein, and Karl Gademann. "Preparation of Indolenines via Nucleophilic Aromatic Substitution." Organic Letters 21, no. 8 (2019): 2560–64. http://dx.doi.org/10.1021/acs.orglett.9b00489.

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Dissertations / Theses on the topic "Indolenines"

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Fernando, Nilmi T. "Novel Near-Infrared Cyanine Dyes for Fluorescence Imaging in Biological Systems." Digital Archive @ GSU, 2011. http://digitalarchive.gsu.edu/chemistry_diss/57.

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Heptamethine cyanine dyes are attractive compounds for imaging purposes in biomedical applications because of their chemical and photophysical properties exhibited in the near-infrared region. A series of meso amino-substituted heptamethine cyanine dyes with indolenine, benz[e]indolenine and benz[c,d]indolenine heterocyclic moieties were synthesized and their spectral properties including fluorescence quntum yield were investigated in ethanol and ethanol/water mixture. Upon substitution with amines, the absorption maxima of the dyes shifted to the lower wavelength region (~600 nm), showed lar
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Hood, Tyler S. "Synthesis of α,β-Unstaurated N-Aryl Ketonitrones and Use as Precursors for Synthesis of C3-Quaternary Indolenines". Thesis, 2013. http://hdl.handle.net/1969.1/151056.

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Our group recently discovered and developed a diastereoselective reaction yielding C3-quaternary indolenines from the combination of α,β-unsaturated N-aryl ketonitrones and mono- or di-activated alkynes in toluene at 80 °C. This reaction builds a high level of complexity in a single step, and the C3-quaternary indolenines produced show promise as precursors to indole-containing molecules of biological and medicinal interest. However, we found our substrate scope was limited by the methods available for the synthesis of the α,β-unsaturated N-aryl ketonitrones necessary for the reaction. As a
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Wang, Chiang-Shen, and 王強昇. "Synthesis of Indolenine-Based Iridium Complexes, and Their Application on Organic Light-Emitting Devices." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/78220661274613450182.

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Book chapters on the topic "Indolenines"

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Horobin, R. W. "Polymethine dyes – 1. Cyanines, oxonols, benzimidazoles, indolenines and azamethines." In Conn’s Biological Stains. Taylor & Francis, 2020. http://dx.doi.org/10.1201/9781003076841-23.

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Conference papers on the topic "Indolenines"

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Sun, Shuqing, Ping Chen, Deshui Zheng, Tsuneki Okasaki, and Masaaki Hayami. "Optical and thermal properties of some indolenine cyanine dyes used as optical recording materials." In Photonics China '98, edited by Duanyi Xu and Seiya Ogawa. SPIE, 1998. http://dx.doi.org/10.1117/12.318488.

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