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1

Cao, Huaqiang. Synthesis and Applications of Inorganic Nanostructures. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2017. http://dx.doi.org/10.1002/9783527698158.

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2

Rao, C. N. R. Essentials of inorganic materials synthesis. Hoboken, New Jersey: Wiley, 2014.

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3

Berridge, Timothy Edward. The synthesis and characterisation of hybrid nanostructures containing both organic and inorganic regions. Birmingham: University of Birmingham, 1998.

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4

Alain, Tressaud, ed. Functionalized inorganic fluorides: Synthesis, characterization & properties of nanostructured solids. Hoboken, N.J: Wiley, 2010.

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5

Sohn, Hong Yong. Chemical vapor synthesis of inorganic nanopowders. Hauppauge, N.Y: Nova Science Publishers, 2011.

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6

Aresta, M., and Angela Dibenedetto. Inorganic micro- and nanomaterials: Synthesis and characterization. Berlin: Walter de Gruyter GmbH & Co. KG, 2013.

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7

Nicola, Hüsing, ed. Synthesis of inorganic materials. Weinheim: Wiley-VCH, 2000.

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8

Eduardo, Ruiz-Hitzky, Ariga Katsuhiko 1962-, and Lvov Yuri 1952-, eds. Bio-inorganic hybrid nanomaterials: Strategies, syntheses, characterization and applications. Weinheim: Wiley-VCH, 2008.

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9

Winterer, Markus. Nanocrystalline Ceramics: Synthesis and Structure. Berlin, Heidelberg: Springer Berlin Heidelberg, 2002.

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10

Nazario, Martin, ed. Carbon nanotubes and related structures: Synthesis, characterization, functionalization, and applications. Weinheim: Wiley-VCH, 2010.

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11

Rapid production of micro- and nano-particles using superficial water. Heidelberg: Springer, 2010.

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12

Cao, Huaqiang. Synthesis and Applications of Inorganic Nanostructures. Wiley & Sons, Incorporated, John, 2017.

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13

Cao, Huaqiang. Synthesis and Applications of Inorganic Nanostructures. Wiley & Sons, Limited, John, 2017.

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14

Cao, Huaqiang. Synthesis and Applications of Inorganic Nanostructures. Wiley & Sons, Incorporated, John, 2017.

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15

Cao, Huaqiang. Synthesis and Applications of Inorganic Nanostructures. Wiley & Sons, Incorporated, John, 2017.

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16

Cao, Huaqiang. Synthesis and Applications of Inorganic Nanostructures. Wiley-VCH Verlag GmbH, 2017.

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17

Rao, C. N. R., and Kanishka Biswas. Essentials of Inorganic Materials Synthesis. Wiley & Sons, Incorporated, John, 2015.

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18

Rao, C. N. R., and Kanishka Biswas. Essentials of Inorganic Materials Synthesis. Wiley & Sons, Incorporated, John, 2015.

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19

Rao, C. N. R., and Kanishka Biswas. Essentials of Inorganic Materials Synthesis. Wiley & Sons, Limited, John, 2015.

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20

Li, Jing, and Xiao-Ying Huang. Nanostructured crystals: An unprecedented class of hybrid semiconductors exhibiting structure-induced quantum confinement effect and systematically tunable properties. Edited by A. V. Narlikar and Y. Y. Fu. Oxford University Press, 2017. http://dx.doi.org/10.1093/oxfordhb/9780199533053.013.16.

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This article describes the structure-induced quantum confinement effect in nanostructured crystals, a unique class of hybrid semiconductors that incorporate organic and inorganic components into a single-crystal lattice via covalent (coordinative) bonds to form extended one-, two- and three-dimensional network structures. These structures are comprised of subnanometer-sized II-VI semiconductor segments (inorganic component) and amine molecules (organic component) arranged into perfectly ordered arrays. The article first provides an overview of II-VI and III-V semiconductors, II-VI colloidal quantum dots, inorganic-organic hybrid materials before discussing the design and synthesis of I-VI-based inorganic-organic hybrid nanostructures. It also considers the crystal structures, quantum confinement effect, bandgaps, and optical properties, thermal properties, thermal expansion behavior of nanostructured crystals.
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21

Dibenedetto, Angela, and Michele Aresta. Inorganic Micro- and Nanomaterials: Synthesis and Characterization. de Gruyter GmbH, Walter, 2013.

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22

Thomas, Sabu, Sneha Mohan, Nandakumar Kalarikkal, and Samuel Oluwatobi Oluwafemi. Synthesis of Inorganic Nanomaterials: Advances and Key Technologies. Elsevier Science & Technology, 2018.

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23

Thomas, Sabu, Oluwatobi Samuel Oluwafemi, Nandakumar Kalarikkal, and Sneha Mohan Bhagyaraj. Synthesis of Inorganic Nanomaterials: Advances and Key Technologies. Elsevier Science & Technology, 2018.

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24

Tressaud, Alain. Functionalized Inorganic Fluorides: Synthesis, Characterization and Properties of Nanostructured Solids. Wiley & Sons, Incorporated, John, 2010.

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25

Tressaud, Alain. Functionalized Inorganic Fluorides: Synthesis, Characterization and Properties of Nanostructured Solids. Wiley & Sons, Limited, John, 2010.

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26

Solution Synthesis of Inorganic Films and Nanostructured Materials: Volume 1449. Materials Research Society, 2012.

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27

Ariga, Katsuhiko, Eduardo Ruiz-Hitzky, and Yuri M. Lvov. Bio-Inorganic Hybrid Nanomaterials: Strategies, Synthesis, Characterization and Applications. Wiley & Sons, Limited, John, 2008.

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28

Ariga, Katsuhiko, Eduardo Ruiz-Hitzky, Yuri M. Lvov, and Eduardo Ruiz-Hitzky. Bio-Inorganic Hybrid Nanomaterials: Strategies, Synthesis, Characterization and Applications. Wiley & Sons, Incorporated, John, 2008.

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29

Hüsing, Nicola, and Katharina Landfester. Inorganic Nanomaterials: An Introduction to Synthesis, Characterization and Self-Assembly. Wiley & Sons, Incorporated, John, 1991.

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30

Inorganic Micro- And Nanomaterials: Synthesis and Characterization. De Gruyter, Inc., 2013.

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31

(Editor), Eduardo Ruiz-Hitzky, Katsuhiko Ariga (Editor), and Yuri M. Lvov (Editor), eds. Bio-inorganic Hybrid Nanomaterials: Strategies, Syntheses, Characterization and Applications. Wiley-VCH, 2008.

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32

Solution Synthesis of Inorganic Functional Materials - Films, Nanoparticles, and Nanocomposites: Volume 1547. Cambridge University Press, 2013.

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33

Electronic Organic and Inorganic Hybrid Nanomaterials Vol. 1359: Synthesis, Device Physics and Their Applications. Materials Research Society, 2011.

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34

Panigrahi, Muktikanta, and Arpan Kumar Nayak. Polyaniline based Composite for Gas Sensors. IOR PRESS, 2021. http://dx.doi.org/10.34256/ioriip212.

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In this research work, we have demonstrated the synthesis, spectroscopic characteristics, thermal behaviour and DC conductivity of a few nanostructured composites, substituted conducting polymers (ICPs) and composites of ICPs. The physical properties of aforementioned composites are significantly changed by the doping with HCl, H2SO4, HNO3, H3PO4, or acrylic acid. The charge transport properties of these polymeric materials have been studied in detail because of their potential application in gas sensors. In the current work, varieties of conducting polymer based materials such as PANI-ES/Cloisite 20A nanostructured composite, acrylic acid (AA) doped PANI polymer, N-substituted conducting polyaniline polymer, DL−PLA/PANI-ES composites, poly methyl methacrylate (PMMA) based polyaniline composite, and inorganic acid doped polyaniline are sucessfuly synthesized using aniline/aniline hydrochloride as precursors in acidic medium. Particularly, AA based synthesised PANI polymer was found with higher solubility The spectroscopic, thermal stability, enthalpy of fusion, room temperature DC conductivity and temperature dependent DC conductivity measurements with and without magnetic was carried out with as-synthesized materials. The FTR/ATR−FTIR spectra indicated the presence of different functional groups in the as-prepared composite materials. The UV−Visible absorption spectroscopic analysis showed the presence of polaron band suggesting PANI-ES form. The Room temperature DC conductivity, temperature variation DC conductivity (in presence and absence of magnetic field), and magnetoresistance (MR) of as-prepared conducting polyaniline based were analysed. The highest room temperature DC conductivity value was obtained from H2SO4 doped based composite materials and all prepared conductive composites were followed ohms law. The low temperature DC conductivity was carried out in order to study the semiconducting nature of prepared materials. The Mott type VRH model was found to be well fitted the conductivity data and described the density of states at the Fermi level which is constant in this temperature range. From MR plots, a negative MR was observed, which described the quantum interference effect on hopping conduction. We discuss different gas analytes i.e., NO2, LPG, H2, NH3, CH4, and CO of conducting polymer based materials.
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