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1

Fang, Xiaosheng, Linfeng Hu, Changhui Ye, and Lide Zhang. "One-dimensional inorganic semiconductor nanostructures: A new carrier for nanosensors." Pure and Applied Chemistry 82, no. 11 (August 1, 2010): 2185–98. http://dx.doi.org/10.1351/pac-con-09-11-40.

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One-dimensional (1D) inorganic semiconductor nanostructures have witnessed an explosion of interest over the last decade because of advances in their controlled synthesis and unique property and potential applications. A wide range of gases, chemicals, biomedical nanosensors, and photodetectors have been assembled using 1D inorganic semiconductor nanostructures. The high-performance characteristics of these nanosensors are particularly attributable to the inorganic semiconducting nanostructure high surface-to-volume ratio (SVR) and its rationally designed surface. In this review, we provide a brief summary of the state-of-the-art research activities in the field of 1D inorganic semiconductor nanostructure-based nanosensors. Some perspectives and the outlook for future developments in this area are presented.
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2

Ríos-Silva, Mirtha, Myriam Pérez, Roberto Luraschi, Esteban Vargas, Claudia Silva-Andrade, Jorge Valdés, Juan Marcelo Sandoval, Claudio Vásquez, and Felipe Arenas. "Anaerobiosis favors biosynthesis of single and multi-element nanostructures." PLOS ONE 17, no. 10 (October 7, 2022): e0273392. http://dx.doi.org/10.1371/journal.pone.0273392.

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Herein we report the use of an environmental multimetal(loid)-resistant strain, MF05, to biosynthesize single- or multi-element nanostructures under anaerobic conditions. Inorganic nanostructure synthesis typically requires methodologies and conditions that are harsh and environmentally hazardous. Thus, green/eco-friendly procedures are desirable, where the use of microorganisms and their extracts as bionanofactories is a reliable strategy. First, MF05 was entirely sequenced and identified as an Escherichia coli-related strain with some genetic differences from the traditional BW25113. Secondly, we compared the CdS nanostructure biosynthesis by whole-cell in a design defined minimal culture medium containing sulfite as the only sulfur source to obtain sulfide reduction from a low-cost chalcogen reactant. Under anaerobic conditions, this process was greatly favored, and irregular CdS (ex. 370 nm; em. 520–530 nm) was obtained. When other chalcogenites were tested (selenite and tellurite), only spherical Se0 and elongated Te0 nanostructures were observed by TEM and analyzed by SEM-EDX. In addition, enzymatic-mediated chalcogenite (sulfite, selenite, and tellurite) reduction was assessed by using MF05 crude extracts in anaerobiosis; similar results for nanostructures were obtained; however Se0 and Te0 formation were more regular in shape and cleaner (with less background). Finally, the in vitro nanostructure biosynthesis was assessed with salts of Ag, Au, Cd, and Li alone or in combination with chalcogenites. Several single or binary nanostructures were detected. Our results showed that MF05 is a versatile anaerobic bionanofactory for different types of inorganic NS. synthesis.
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3

Escudero, Alberto, Carolina Carrillo-Carrión, Elena Romero-Ben, Ana Franco, Christian Rosales-Barrios, Mª Carmen Castillejos, and Noureddine Khiar. "Molecular Bottom-Up Approaches for the Synthesis of Inorganic and Hybrid Nanostructures." Inorganics 9, no. 7 (July 17, 2021): 58. http://dx.doi.org/10.3390/inorganics9070058.

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Chemical routes for the synthesis of nanostructures are fundamental in nanoscience. Among the different strategies for the production of nanostructures, this article reviews the fundamentals of the bottom-up approaches, focusing on wet chemistry synthesis. It offers a general view on the synthesis of different inorganic and hybrid organic–inorganic nanostructures such as ceramics, metal, and semiconductor nanoparticles, mesoporous structures, and metal–organic frameworks. This review article is especially written for a wide audience demanding a text focused on the basic concepts and ideas of the synthesis of inorganic and hybrid nanostructures. It is styled for both early researchers who are starting to work on this topic and also non-specialist readers with a basic background on chemistry. Updated references and texts that provide a deeper discussion and describing the different synthesis strategies in detail are given, as well as a section on the current perspectives and possible future evolution.
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4

Tian, Yan, Zekun Guo, Tong Zhang, Haojian Lin, Zijuan Li, Jun Chen, Shaozhi Deng, and Fei Liu. "Inorganic Boron-Based Nanostructures: Synthesis, Optoelectronic Properties, and Prospective Applications." Nanomaterials 9, no. 4 (April 3, 2019): 538. http://dx.doi.org/10.3390/nano9040538.

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Inorganic boron-based nanostructures have great potential for field emission (FE), flexible displays, superconductors, and energy storage because of their high melting point, low density, extreme hardness, and good chemical stability. Until now, most researchers have been focused on one-dimensional (1D) boron-based nanostructures (rare-earth boride (REB6) nanowires, boron nanowires, and nanotubes). Currently, two-dimensional (2D) borophene attracts most of the attention, due to its unique physical and chemical properties, which make it quite different from its corresponding bulk counterpart. Here, we offer a comprehensive review on the synthesis methods and optoelectronics properties of inorganic boron-based nanostructures, which are mainly concentrated on 1D rare-earth boride nanowires, boron monoelement nanowires, and nanotubes, as well as 2D borophene and borophane. This review paper is organized as follows. In Section I, the synthesis methods of inorganic boron-based nanostructures are systematically introduced. In Section II, we classify their optical and electrical transport properties (field emission, optical absorption, and photoconductive properties). In the last section, we evaluate the optoelectronic behaviors of the known inorganic boron-based nanostructures and propose their future applications.
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5

Xu, Hui, Yuci Xu, Xinchang Pang, Yanjie He, Jaehan Jung, Haiping Xia, and Zhiqun Lin. "A general route to nanocrystal kebabs periodically assembled on stretched flexible polymer shish." Science Advances 1, no. 2 (March 2015): e1500025. http://dx.doi.org/10.1126/sciadv.1500025.

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Assembling nanoparticles into one-dimensional (1D) nanostructures with precisely controlled size and shape renders the exploration of new properties and construction of 1D miniaturized devices possible. The physical properties of such nanostructures depend heavily on the size, chemical composition, and surface chemistry of nanoparticle constituents, as well as the close proximity of adjacent nanoparticles within the 1D nanostructure. Chemical synthesis provides an intriguing alternative means of creating 1D nanostructures composed of self-assembled nanoparticles in terms of material diversity, size controllability, shape regularity, and low-cost production. However, this is an area where progress has been slower. We report an unconventional yet general strategy to craft an exciting variety of 1D nanonecklace-like nanostructures comprising uniform functional nanodiscs periodically assembled along a stretched flexible polymer chain by capitalizing on judiciously designed amphiphilic worm-like diblock copolymers as nanoreactors. These nanostructures can be regarded as organic-inorganic shish-kebabs, in which nanodisc kebabs are periodically situated on a stretched polymer shish. Simulations based on self-consistent field theory reveal that the formation of organic-inorganic shish-kebabs is guided by the self-assembled elongated star-like diblock copolymer constituents constrained on the highly stretched polymer chain.
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6

Rao, C. N. R., Ved Varun Agrawal, Kanishka Biswas, Ujjal K. Gautam, Moumita Ghosh, A. Govindaraj, G. U. Kulkarni, K. P. Kalyanikutty, Kripasindhu Sardar, and S. R. C. Vivekchand. "Soft chemical approaches to inorganic nanostructures." Pure and Applied Chemistry 78, no. 9 (January 1, 2006): 1619–50. http://dx.doi.org/10.1351/pac200678091619.

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Chemical approaches have emerged as the preferred means to synthesize nanostructures of various inorganic materials due to superior control over size, shape, and surface functionality. This article provides an overview of the contributions made in the authors' laboratory toward the synthesis of nanocrystals, nanowires, nanotubes, nanowalls, and other nanostructures of several inorganic materials. Thus, thiolized monodisperse metal nanocrystals have been obtained by a ligand exchange process and the stability of their 2D assemblies studied. Nanocrystals of pure CoO and ReO3 have been synthesized, for the first time, employing a one-pot solvothermal technique. The solvothermal method has also been used to obtain organic soluble nanocrystals of semiconducting materials such as CdS, CdSe, and GaN. Inorganic nanowires and nanotubes have been prepared by several soft chemical routes, including surfactant-assisted synthesis and hydrogel templating. A simple reaction between elemental Se and Te with NaBH4 in water has been utilized to obtain nanowires of Se and Te. We also describe the nebulized spray pyrolysis (NSP) technique to synthesize carbon nanotubes and nanowires of metals and III-V nitride semiconductors with improved yields. An important new technique for preparing nanocrystalline films of materials is by the reaction of the metal precursors in the organic layer at the interface of two immiscible liquids, with appropriate reagents. Nanocrystalline films of metals, alloys, and semiconductors and ultra-thin single-crystalline films of metal chalcogenides and oxides have been obtained by this technique. Apart from these, we discuss single precursor routes to iron sulfide, GeSe2, and III-V nitride nanostructures as well as the first synthesis of GaS and GaSe nanowalls and nanotubes obtained through exfoliation by laser irradiation and thermal treatment.
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7

Ho, Ghim Wei, and Andrew See Weng Wong. "Aqueous Synthesis towards Vertically-Aligned and Selective Pattern of ZnO Nanostructures Arrays." Advanced Materials Research 67 (April 2009): 7–12. http://dx.doi.org/10.4028/www.scientific.net/amr.67.7.

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For any future cost-effective applications of inorganic nanostructures in particular hybrid photovoltaic cell, solution processable and selective printable of inorganic nanomaterials is essential. The patterning and growth of highly ordered arrays of crystalline ZnO inorganic nanostructures use simple soft lithography technique and mild reaction conditions; both low in temperature and free from harmful organic additives. Variable yet controllable anisotropic growth of ZnO nanowires has been demonstrated on the transferred patterns of ZnO nanocystals.
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8

Ren, Haoqi, Jie Cui, and Shaodong Sun. "Water-guided synthesis of well-defined inorganic micro-/nanostructures." Chemical Communications 55, no. 64 (2019): 9418–31. http://dx.doi.org/10.1039/c9cc04293h.

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9

Jan, Jeng Shiung, Po Jui Chen, and Yu Han Ho. "Synthesis of Gold Nanoparticle/Silica Nanostructures." Materials Science Forum 688 (June 2011): 321–25. http://dx.doi.org/10.4028/www.scientific.net/msf.688.321.

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A novel approach is proposed to prepare organic-inorganic composite tubular structure by mineralizing silica and/or gold nanoparticle in the LbL assembled polypeptide multilayers films. Mesoporous silica (m-SiO2) and gold nanoparticle/mesoporous silica (Au NP/m-SiO2) tubes were prepared by subsequent calcination. The LbL assembled poly-L-lysine (PLL)/poly-L-tyrosine (PLT) multilayer film within the inner pores of polycarbonate templates acts as both a mineralizing agent and template for the formation of these materials. The as-prepared mesoporous SiO2and Au NP/m-SiO2tubes have well-defined structures. Gold nanoparticles with size smaller than 8 nm were immobilized in the silica network and the as-prepared Au NP/m-SiO2tubes exhibit good catalytic activity towards the reduction of p-nitrophenol. This approach may provide a facile and general method to synthesize organic-inorganic and metal-oxide nanocomposites with different composition and structures.
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10

Cai, Jiabai, and Shunxing Li. "Photocatalytic Treatment of Environmental Pollutants using Multilevel- Structure TiO2-based Organic and Inorganic Nanocomposites." Current Organocatalysis 7, no. 3 (November 30, 2020): 161–78. http://dx.doi.org/10.2174/2213337207999200701214637.

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Nanostructured materials often exhibit unique physical properties, such as fast carrier transport, subwavelength optical waveguiding, and a high surface-area-to-volume ratio. When the size of a material is reduced to nanoscale dimensions, its physical and chemical properties can change dramatically. In addition, nanostructures offer exciting new opportunities for environmental applications. In this review, we aim to provide an up-to-date summary of recent research related to multifunctional TiO2-based inorganic and organic semiconductor nanomaterials, covering both their synthesis and applications. After a brief introduction of the definition and classification of TiO2-based inorganic and organic semiconductor nanomaterial structures, we discuss various application strategies, such as sewage treatment, heavy metal removal, and the oxidation of alcohols to the corresponding aldehydes. In our previous work, we fabricated a variety of TiO2-based hollow spheres using a diverse range of materials from inorganic semiconductors to organic semiconductors and applied these structures as photocatalysts. Further, the development of these nanostructures may enable numerous applications in the field of environmental technology.
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11

Azam, Anum, and Danielle Tullman-Ercek. "Type-III secretion filaments as scaffolds for inorganic nanostructures." Journal of The Royal Society Interface 13, no. 114 (January 2016): 20150938. http://dx.doi.org/10.1098/rsif.2015.0938.

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Nanostructured materials exhibit unique magnetic, electrical and catalytic properties. These characteristics are determined by the chemical composition, size and shape of the nanostructured components, which are challenging to modulate on such small size scales and to interface with living cells. To address this problem, we are using a self-assembling filament protein, PrgI, as a scaffold for bottom-up inorganic nanostructure synthesis. PrgI is a small protein (80 amino acids) that oligomerizes to form the type-III secretion system needle of Salmonella enterica . We demonstrate that purified PrgI monomers also spontaneously self-assemble into long filaments and that high-affinity peptide tags specific for attachment to functionalized particles can be integrated into the N-terminal region of PrgI. The resulting filaments selectively bind to gold, whether the filaments are assembled in vitro , sheared from cells or remain attached to live S. enterica cell membranes. Chemical reduction of the gold-modified PrgI variants results in structures that are several micrometres in length and which incorporate a contiguous gold surface. Mutant strains with genomically incorporated metal-binding tags retain the secretion phenotype. We anticipate that self-assembled, cell-tethered protein/metal filamentous structures have applications in sensing and energy transduction in vivo .
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12

Zhai, Tianyou, Liang Li, Ying Ma, Meiyong Liao, Xi Wang, Xiaosheng Fang, Jiannian Yao, Yoshio Bando, and Dmitri Golberg. "One-dimensional inorganic nanostructures: synthesis, field-emission and photodetection." Chemical Society Reviews 40, no. 5 (2011): 2986. http://dx.doi.org/10.1039/c0cs00126k.

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13

Buck, Matthew R., and Raymond E. Schaak. "Emerging Strategies for the Total Synthesis of Inorganic Nanostructures." Angewandte Chemie International Edition 52, no. 24 (April 22, 2013): 6154–78. http://dx.doi.org/10.1002/anie.201207240.

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14

Selvakumar, R., N. Seethalakshmi, P. Thavamani, Ravi Naidu, and Mallavarapu Megharaj. "Recent advances in the synthesis of inorganic nano/microstructures using microbial biotemplates and their applications." RSC Adv. 4, no. 94 (2014): 52156–69. http://dx.doi.org/10.1039/c4ra07903e.

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15

Khatami, Mehrdad, Hajar Q. Alijani, Farideh Mousazadeh, Nooshin Hashemi, Zahra Mahmoudi, Samaneh Darijani, Mehdi Bamorovat, Alireza Keyhani, Meghdad Abdollahpour-Alitappeh, and Fariba Borhani. "Calcium carbonate nanowires: greener biosynthesis and their leishmanicidal activity." RSC Advances 10, no. 62 (2020): 38063–68. http://dx.doi.org/10.1039/d0ra04503a.

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16

Bettini, Simona, Michela Ottolini, Donato Valli, Rosanna Pagano, Chiara Ingrosso, Maarten Roeffaers, Johan Hofkens, Ludovico Valli, and Gabriele Giancane. "Synthesis and Characterization of Gold Chiral Nanoparticles Functionalized by a Chiral Drug." Nanomaterials 13, no. 9 (April 30, 2023): 1526. http://dx.doi.org/10.3390/nano13091526.

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Inorganic chiral nanoparticles are attracting more and more attention due to their peculiar optical properties and potential biological applications, such as bioimaging, therapeutics, and diagnostics. Among inorganic chiral nanoparticles, gold chiral nanostructures were demonstrated to be very interesting in this context, with good physical chemical stability and also the possibility to decorate the surface, improving biomedical application as the interaction with the bio-systems. Gold (Au) nanostructures were synthesized according to a seed-mediated procedure which envisages the use of cetyltrimethylammonium bromide (CTAB) as the capping agent and L- and D-cysteine to promote chirality. Au nanostructures have been demonstrated to have opposite circular dichroism signals depending on the amino acid enantiomer used during the synthesis. Then, a procedure to decorate the Au surface with penicillamine, a drug used for the treatment of Wilson’s disease, was developed. The composite material of gold nanoparticles/penicillamine was characterized using electron microscopy, and the penicillamine functionalization was monitored by means of UV-Visible, Raman, and infrared spectroscopy, highlighting the formation of the Au–S bond. Furthermore, electron circular dichroism was used to monitor the chirality of the synthesized nanostructures and it was demonstrated that both penicillamine enantiomers can be successfully bonded with both the enantiomers of the gold nanostructures without affecting gold nanoparticles’ chirality. The effective modification of nanostructures’ surfaces via penicillamine introduction allowed us to address the important issue of controlling chirality and surface properties in the chiral nano-system.
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17

Susha, N., K. Nandakumar, and Swapna S. Nair. "Enhanced photoconductivity in CdS/betanin composite nanostructures." RSC Advances 8, no. 21 (2018): 11330–37. http://dx.doi.org/10.1039/c7ra13116j.

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The synthesis is described of inorganic/organic hybrid nanostructured composites based on CdS/betanin with enhanced photoconductivity due to the transfer of photogenerated electrons from the conduction band of betanin to the conduction band of CdS.
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18

Lackinger, Markus. "Synthesis on inert surfaces." Dalton Transactions 50, no. 29 (2021): 10020–27. http://dx.doi.org/10.1039/d1dt00058f.

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Intriguing covalent nanostructures are synthesized on solid surfaces. While important reactions proceed exclusively on metal surfaces, light-induced couplings or deposition of pre-activated monomers pave the road to synthesis on inert surfaces.
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19

Vitiello, Giuseppe, Brigida Silvestri, and Giuseppina Luciani. "Learning from Nature: Bioinspired Strategies Towards Antimicrobial Nanostructured Systems." Current Topics in Medicinal Chemistry 18, no. 1 (March 22, 2018): 22–41. http://dx.doi.org/10.2174/1568026618666180206101129.

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Microbial contamination still remains a major issue of the modern era, due to the widespread of drug-resistant pathogens. This has prompted researchers to come up with novel antimicrobial systems that could overcome antibiotic-resistance. In this context, nature can provide inestimable source of inspiration to design high-performance multifunctional materials with potent activity against drug-resistant pathogens. Actually, integrating the bio-inspired-approach with nanotechnology can provide cutting-edge solutions for drug-resistant infections. In this context, this review will examine recent advances in the development of bio-inspired antimicrobial nanostructures. Advantages of bioinspired approach to nanomaterials over conventional routes have been highlighted. Generally, bionspired synthesis can be carried out either by mimicking the functions of natural materials/ structures or by mimicking the biological processes employed to produce substances or materials. The review provides an overview of both strategies as applied to the synthesis of inorganic, organic as well as hybrid nanostructures. Antimicrobial efficacy and biological properties of these systems have been highlighted. Antimicrobial and antibiofouling nanostructured surfaces are also discussed.
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20

Nah, Yoonseo, Dohyub Jang, and Dong Ha Kim. "Block copolymer micelles enable facile synthesis of organic–inorganic perovskite nanostructures with tailored architecture." Chemical Communications 57, no. 15 (2021): 1879–82. http://dx.doi.org/10.1039/d0cc06935c.

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21

Volkov, V. L., and G. S. Zakharova. "V3O7 · H2O oxide nanostructures: Synthesis and study." Russian Journal of Inorganic Chemistry 54, no. 11 (November 2009): 1704–7. http://dx.doi.org/10.1134/s0036023609110047.

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22

Liang, Hai-Wei, Shuo Liu, and Shu-Hong Yu. "Controlled Synthesis of One-Dimensional Inorganic Nanostructures Using Pre-Existing One-Dimensional Nanostructures as Templates." Advanced Materials 22, no. 35 (July 29, 2010): 3925–37. http://dx.doi.org/10.1002/adma.200904391.

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23

Kalpanadevi, K., C. R. Sinduja, and R. Manimekalai. "Synthesis and Structural Characterization of CdFe2O4 Nanostructures." International Journal of Nanoscience 16, no. 04 (August 2017): 1750002. http://dx.doi.org/10.1142/s0219581x17500028.

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The synthesis of CdFe2O4 nanoparticles has been achieved by a simple thermal decomposition method from the inorganic precursor, [CdFe2(cin)3(N2H[Formula: see text]], which was obtained by a simple precipitation method from the corresponding metal salts, cinnamic acid and hydrazine hydrate. The precursor was characterized by hydrazine and metal analyses, infrared spectral analysis and thermo gravimetric analysis. On appropriate annealing, [CdFe2(cin)3(N2H[Formula: see text]] yielded CdFe2O4 nanoparticles. The XRD studies showed that the crystallite size of the particles was 13[Formula: see text]nm. The results of HRTEM studies also agreed well with those of XRD. SAED pattern of the sample established the polycrystalline nature of the nanoparticles. SEM images displayed a random distribution of grains in the sample.
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24

Mandracci, Pietro, and Paola Rivolo. "Recent Advances in the Plasma-Assisted Synthesis of Silicon-Based Thin Films and Nanostructures." Coatings 13, no. 6 (June 10, 2023): 1075. http://dx.doi.org/10.3390/coatings13061075.

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Silicon-based thin films and nanostructures are of paramount importance in a wide range of applications, including microelectronics, photovoltaics, large area sensors, and biomedicine. The wide accessibility of silicon and its relatively low cost have driven a continuous improvement of technology based on this element. Plasma technology has been widely used for the synthesis of coatings and nanostructures based on silicon. Moreover, it has made a fundamental contribution to continuous improvement of the physicochemical properties of silicon-based materials and allows the synthesis of nanometric structures with well-defined shapes and morphologies. In this work, we have reviewed the most interesting developments in plasma-assisted processes for the synthesis of Si-based materials, both inorganic and organic, in the last five years. Special attention has been paid to new techniques, or modifications of already-existing ones, that open up new possibilities for the synthesis of materials with new properties, as well as nanostructures with novel characteristics.
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25

Tartaj, Pedro, and Jose M. Amarilla. "Porous inorganic nanostructures with colloidal dimensions: synthesis and applications in electrochemical energy devices." Chem. Commun. 50, no. 17 (2014): 2077–88. http://dx.doi.org/10.1039/c3cc49090d.

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26

Pei, Yuchen, Raghu V. Maligal-Ganesh, Chaoxian Xiao, Tian-Wei Goh, Kyle Brashler, Jeffrey A. Gustafson, and Wenyu Huang. "An inorganic capping strategy for the seeded growth of versatile bimetallic nanostructures." Nanoscale 7, no. 40 (2015): 16721–28. http://dx.doi.org/10.1039/c5nr04614a.

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27

KHOMUTOV, G. B., M. N. ANTIPINA, A. N. SERGEEV-CHERENKOV, A. A. RAKHNYANSKAYA, M. ARTEMYEV, D. KISIEL, R. V. GAINUTDINOV, A. L. TOLSTIKHINA, and V. V. KISLOV. "ORGANIZED PLANAR NANOSTRUCTURES VIA INTERFACIAL SELF-ASSEMBLY AND DNA TEMPLATING." International Journal of Nanoscience 03, no. 01n02 (February 2004): 65–74. http://dx.doi.org/10.1142/s0219581x04001821.

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The methods are presented for fabrication of new nanoscale-organized planar inorganic nanostructures, ultrathin polymeric and nanocomposite films on solid substrates with incorporated nanosized functional and structural building blocks. The methods are based on interfacial synthesis and self-assembly, DNA templating and scaffolding. Ultimately thin monomolecular and multilayer ordered stable polymeric and nanocomposite films containing incorporated ligand-stabilized gold nanoclusters, interfacially in-film grown metallic ( Au , Pd ) nanoparticles and organized low-dimensional nanostructures were formed. N-alkylated derivatives of poly(4-vinilpyridine) were synthesized and used as water-insoluble amphiphilic polycations to form organized polymeric Langmuir monolayers and novel planar DNA/amphiphilic polycation complexes at the air–aqueous DNA solution interface. The extended net-like and quasi-circular toroidal condensed conformations of deposited planar DNA/amphiphilic polycation complexes were obtained in dependence on the amphiphilic polycation monolayer state during the DNA binding. Planar DNA/amphiphilic polycation complexes were used as nanotemplates for fabrication of organized planar bio-organic–inorganic hybrid nanostructures with ordered nanophase inorganic components (quasi-one-dimensional arrays of semiconductor (CdS) and iron oxide nanoparticles and nanorods) organized in planar matrix of deposited DNA/amphiphilic polycation complex film. The formed nanostructures were characterized by atomic force microscopy and transmission electron microscopy techniques.
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28

Forde, Aaron, Talgat Inerbaev, and Dmitri Kilin. "Role of Cation-Anion Organic Ligands for Optical Properties of Fully Inorganic Perovskite Quantum Dots." MRS Advances 3, no. 55 (2018): 3255–61. http://dx.doi.org/10.1557/adv.2018.552.

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ABSTRACTApplication of lead-halide perovskite nanostructures for photovoltaic and light emitting applications depends on fashion of the surface termination. The reasonable choice of surface ligands for perovskite nanostructures prevent formation of trap states and contribute to chemical stability, wide opening of the bandgap, and intensity of absorption and photoluminescence of perovskite nanostructures. This work provides atomistic arguments for dual ligand protocol of surface passivation of fully inorganic perovskite quantum dots with fully organic ligands being a mix of cations (ethyl-ammonium) and anions (acetic) in nearly equal proportions. Computed binding energies of either individual ligands or anion-cation pairs demonstrate high stability in comparison to thermal energy and are concluded to be favourable choice in synthesis of colloidal perovskite quantum dots for light emitting applications.
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Jangu, Surendra, Biraj Kanta Satpathy, Mula Raju, Chacko Jacob, and Debabrata Pradhan. "Synthesis of V-shaped MnO2 nanostructure and its composites with reduced graphene oxide for supercapacitor application." Dalton Transactions 50, no. 20 (2021): 6878–88. http://dx.doi.org/10.1039/d1dt00422k.

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30

Lamberti, Francesco, Chiara Mazzariol, Federico Spolaore, Riccardo Ceccato, Luigi Salmaso, and Silvia Gross. "Design of Experiment: A Rational and Still Unexplored Approach to Inorganic Materials’ Synthesis." Sustainable Chemistry 3, no. 1 (March 6, 2022): 114–30. http://dx.doi.org/10.3390/suschem3010009.

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This review was devoted to outlining the use and potential increasing application of the Design of Experiment (DoE) approach to the rational and planned synthesis of inorganic nanomaterials, with a particular focus on polycrystalline nanostructures (metal and alloys, oxides, chalcogenides, halogenides, etc.) produced by sustainable wet chemistry routes based on a multi-parameter experimental landscape. After having contextualised the stringent need for a rational approach to inorganic materials’ synthesis, a concise theoretical background on DoE is provided, focusing on its statistical basis, shortly describing the different sub-methodologies, and outlining the pros and cons of each. In the second part of the review, a wider section is dedicated to the application of DoE to the rational synthesis of different kinds of chemical systems, with a specific focus on inorganic materials.
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Zhang, Guodong, Yadong Xiao, Nian Liu, Cong Liu, and Bing Yang. "Controllable SHS Synthesis of ZnO Nanostructures." Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 45, no. 3 (August 26, 2014): 433–36. http://dx.doi.org/10.1080/15533174.2013.819908.

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32

Logar, Manca, Boštjan Jančar, Aleksandar Rečnik, and D. Suvorov. "POLYELECTROLYTE MULTILAYER TEMPLATE ASSISTED IN-SITU SYNTHESIS OF THE INORGANIC NANOSTRUCTURES." Contemporary Materials 1, no. 1 (July 2, 2010): 4–18. http://dx.doi.org/10.5767/anurs.cmat.100101.en.004l.

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Rossner, Christian, and Andreas Fery. "Planet–satellite nanostructures from inorganic nanoparticles: from synthesis to emerging applications." MRS Communications 10, no. 1 (December 20, 2019): 112–22. http://dx.doi.org/10.1557/mrc.2019.163.

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Sangsefidi, Fatemeh Sadat, Mahdiyeh Esmaeili-Zare, and Masoud Salavati-Niasari. "Hydrothermal synthesis and characterization of HgS nanostructures assisted by inorganic precursor." Journal of Industrial and Engineering Chemistry 28 (August 2015): 197–201. http://dx.doi.org/10.1016/j.jiec.2015.02.014.

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35

Buck, Matthew R., and Raymond E. Schaak. "ChemInform Abstract: Emerging Strategies for the Total Synthesis of Inorganic Nanostructures." ChemInform 44, no. 37 (August 22, 2013): no. http://dx.doi.org/10.1002/chin.201337184.

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Zhai, Tianyou, Liang Li, Ying Ma, Meiyong Liao, Xi Wang, Xiaosheng Fang, Jiannian Yao, Yoshio Bando, and Dmitri Golberg. "ChemInform Abstract: One-Dimensional Inorganic Nanostructures: Synthesis, Field-Emission and Photodetection." ChemInform 42, no. 30 (June 30, 2011): no. http://dx.doi.org/10.1002/chin.201130227.

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37

Amgar, Daniel, Sigalit Aharon, and Lioz Etgar. "Inorganic and Hybrid Organo-Metal Perovskite Nanostructures: Synthesis, Properties, and Applications." Advanced Functional Materials 26, no. 47 (October 18, 2016): 8576–93. http://dx.doi.org/10.1002/adfm.201603752.

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38

Barra, Ana, Cláudia Nunes, Eduardo Ruiz-Hitzky, and Paula Ferreira. "Green Carbon Nanostructures for Functional Composite Materials." International Journal of Molecular Sciences 23, no. 3 (February 6, 2022): 1848. http://dx.doi.org/10.3390/ijms23031848.

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Carbon nanostructures are widely used as fillers to tailor the mechanical, thermal, barrier, and electrical properties of polymeric matrices employed for a wide range of applications. Reduced graphene oxide (rGO), a carbon nanostructure from the graphene derivatives family, has been incorporated in composite materials due to its remarkable electrical conductivity, mechanical strength capacity, and low cost. Graphene oxide (GO) is typically synthesized by the improved Hummers’ method and then chemically reduced to obtain rGO. However, the chemical reduction commonly uses toxic reducing agents, such as hydrazine, being environmentally unfriendly and limiting the final application of composites. Therefore, green chemical reducing agents and synthesis methods of carbon nanostructures should be employed. This paper reviews the state of the art regarding the green chemical reduction of graphene oxide reported in the last 3 years. Moreover, alternative graphitic nanostructures, such as carbons derived from biomass and carbon nanostructures supported on clays, are pointed as eco-friendly and sustainable carbonaceous additives to engineering polymer properties in composites. Finally, the application of these carbon nanostructures in polymer composites is briefly overviewed.
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Ji, Yongqiang, Minqiang Wang, Zhi Yang, Hengwei Qiu, Hui Wang, Muhammad Amin Padhiar, Yun Zhou, Jialin Dang, Nikolai V. Gaponenko, and Arshad Saleem Bhatti. "A versatile approach for shape-controlled synthesis of ultrathin perovskite nanostructures." Dalton Transactions 50, no. 9 (2021): 3308–14. http://dx.doi.org/10.1039/d0dt04203j.

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40

Semchenko, G. D., and E. S. Gevorkyan. "Consolidated Nanocomposite Materials with the Defined Properties." Advances in Science and Technology 91 (October 2014): 24–31. http://dx.doi.org/10.4028/www.scientific.net/ast.91.24.

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Application of modern ways of ceramic materials’ consolidation and association of synthesis methods of organic and inorganic chemistry, sol-gel method and mechanochemistry, allowing to control processes of synthesis of the defined phases at molecular level, gives the chance to create highly effective composite materials. It is known that properties of composites on the basis of refractory compounds become dimensionally dependent at reduction of the particles’ size to several interatomic distances in one, two or three dimensions . Obtaining of durable nanostructural ceramics on the basis of ZrO2 with substantial increase of mechanical properties can be realized by creation of material with fine homogeneous structure, on the basis of powders of nonoxygen compounds when strength properties and crack resistance increase at creation of –intra and –inter nanostructures. In work results of creation of the consolidated nanomaterials and composite ceramics with usage of the peculiarities set forth above for synthesis of precursors of powders and the defined phases that self-reinforce ceramic matrixes have been presented.
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Abbas, Mohamed, Sri RamuluTorati, Shawl Asif Iqbal, and CheolGi Kim. "A novel and rapid approach for the synthesis of biocompatible and highly stable Fe3O4/SiO2 and Fe3O4/C core/shell nanocubes and nanorods." New Journal of Chemistry 41, no. 7 (2017): 2724–34. http://dx.doi.org/10.1039/c6nj03697j.

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Pellegrino, Giovanna, Sabrina Carola Carroccio, Francesco Ruffino, Guglielmo G. Condorelli, Giuseppe Nicotra, Vittorio Privitera, and Giuliana Impellizzeri. "Polymeric platform for the growth of chemically anchored ZnO nanostructures by ALD." RSC Advances 8, no. 1 (2018): 521–30. http://dx.doi.org/10.1039/c7ra11168a.

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The synthesis of hybrid nano-composites in which an inorganic layer is grown on a polymeric surface via chemical bonds, is a challenging goal for many applications from photocatalysis, to sensing and optoelectronics.
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Liang, Hai-Wei, Shuo Liu, and Shu-Hong Yu. "ChemInform Abstract: Controlled Synthesis of One-Dimensional Inorganic Nanostructures Using Pre-Existing One-Dimensional Nanostructures as Templates." ChemInform 41, no. 45 (October 14, 2010): no. http://dx.doi.org/10.1002/chin.201045228.

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Rawal, Ishpal, Ravi Kant Tripathi, and O. S. Panwar. "Easy synthesis of organic–inorganic hybrid nanomaterials: study of DC conduction mechanism for light dependent resistors." RSC Advances 6, no. 37 (2016): 31540–50. http://dx.doi.org/10.1039/c5ra27774d.

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45

Nieto-Argüello, Alfonso, Alejandro Torres-Castro, Rafael Villaurrutia-Arenas, Juan J. Martínez-Sanmiguel, María Ujué González, José Miguel García-Martín, and Jorge L. Cholula-Díaz. "Green synthesis and characterization of gold-based anisotropic nanostructures using bimetallic nanoparticles as seeds." Dalton Transactions 50, no. 46 (2021): 16923–28. http://dx.doi.org/10.1039/d1dt02804a.

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46

Janairo, Jose Isagani B., and Kazuyasu Sakaguchi. "Synthesis of Bimetallic PdAg Nanoparticles through an Oligomerization- Controlled Biomineralization Peptide." Materials Science Forum 928 (August 2018): 77–82. http://dx.doi.org/10.4028/www.scientific.net/msf.928.77.

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Peptide – mediated biomineralization is an emerging and promising biomimetic approach for the synthesis of nanomaterials. This nature – inspired technique of producing inorganic nanostructures depends on the biomineralization peptide to control the shape and morphology of the prevailing inorganic nanostructure. One of the challenges in peptide – mediated biomineralization is controlling the 3D arrangement and orientation of the peptide. Recently, we have developed a peptide platform that can specify and direct the geometric arrangement and spatial orientation of the biomineralization peptide. The peptide platform is composed of two segments: a metal binding sequence, and the tetramerization domain of the tumor suppressor p53 protein, which acts as the oligomerization control element. The resulting fusion peptide exhibits a spatially – fixed and well – controlled assembly of the palladium binding sequence. This present study demonstrates the utility and efficacy of this peptide platform to bimetallic materials. Monodispersed 5 nm bimetallic PdAg nanoparticles were synthesized using the oligomerization – controlled biomineralization peptide. The synthesis was carried out in an aqueous environment, void of harsh reagents. When other fusion biomineralization peptides were used to synthesize bimetallic PdAg nanoparticles, less ordered nanoparticles were yielded. The results highlight the importance of controlled assembly on bimetallic nanoparticle formation through biomineralization. The presented method offers a straightforward manner of creating monodispersed and extremely small nanoparticles, which are useful in a wide array of applications.
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Leprince-Wang, Yamin, Guangyin Jing, and Basma El Zein. "Novel ZnO-Based Nanostructures: Synthesis, Characterization and Applications." Crystals 13, no. 2 (February 16, 2023): 338. http://dx.doi.org/10.3390/cryst13020338.

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The Special Issue “Novel ZnO-Based Nanostructures: Synthesis, Characterization and Applications” is a collection of 13 papers, including 3 review papers and 10 original articles dedicated to both experimental research works and numerical simulations on ZnO nanostructures [...]
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48

Bettini, Simona, Valentina Bonfrate, Ludovico Valli, and Gabriele Giancane. "Paramagnetic Functionalization of Biocompatible Scaffolds for Biomedical Applications: A Perspective." Bioengineering 7, no. 4 (November 28, 2020): 153. http://dx.doi.org/10.3390/bioengineering7040153.

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The burst of research papers focused on the tissue engineering and regeneration recorded in the last years is justified by the increased skills in the synthesis of nanostructures able to confer peculiar biological and mechanical features to the matrix where they are dispersed. Inorganic, organic and hybrid nanostructures are proposed in the literature depending on the characteristic that has to be tuned and on the effect that has to be induced. In the field of the inorganic nanoparticles used for decorating the bio-scaffolds, the most recent contributions about the paramagnetic and superparamagnetic nanoparticles use was evaluated in the present contribution. The intrinsic properties of the paramagnetic nanoparticles, the possibility to be triggered by the simple application of an external magnetic field, their biocompatibility and the easiness of the synthetic procedures for obtaining them proposed these nanostructures as ideal candidates for positively enhancing the tissue regeneration. Herein, we divided the discussion into two macro-topics: the use of magnetic nanoparticles in scaffolds used for hard tissue engineering for soft tissue regeneration.
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Biswas, Subhajit, Soumitra Kar, and Subhadra Chaudhuri. "Synthesis and Characterization of Zinc Sulfide Nanostructures." Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 36, no. 1 (March 2006): 33–36. http://dx.doi.org/10.1080/15533170500471417.

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50

Simonenko, T. L., V. A. Bocharova, N. P. Simonenko, E. P. Simonenko, V. G. Sevastyanov, and N. T. Kuznetsov. "Hydrothermal Synthesis of Hierarchical CoMoO4 Nanostructures." Russian Journal of Inorganic Chemistry 66, no. 11 (November 2021): 1633–38. http://dx.doi.org/10.1134/s0036023621110176.

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