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Journal articles on the topic 'Inorganic-organic hybrid compounds'

Author: Grafiati

Published: 4 June 2021

Last updated: 6 September 2023

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1

Matsui, Takashi, Mitsuyasu Kawahara, Kenjiro Teshima, Masahiro Rikukawa, and Kohei Sanui. "Novel Organic-Inorganic Hybrid Compounds Containing Alkyldiammonium Salts." Molecular Crystals and Liquid Crystals 376, no. 1 (January 1, 2002): 89–94. http://dx.doi.org/10.1080/713738452.

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2

Luo, Dawei, Jian Zhang, Yu Liang, Jianling Ni, Fangming Wang, and Wei Liu. "New Copper Bromide Organic-Inorganic Hybrid Molecular Compounds with Anionic Inorganic Core and Cationic Organic Ligands." Crystals 12, no. 1 (December 23, 2021): 19. http://dx.doi.org/10.3390/cryst12010019.

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Here, organic-inorganic hybrid molecular compounds based on copper(I) bromide have been synthesized by slow-diffusion method. The inorganic modules of these two structures are Cu2Br42− anion, and the inorganic modules are coordinated to cationic organic ligands via Cu-N coordinative bonds. Both of these compounds are luminescent, emitting green emissions under UV excitation.

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3

Mizusawa, K., K. Kikuchi, Y. Takeoka, M. Rikukawa, and K. Sanui. "Architecture and surface morphology of organic-inorganic hybrid compounds." Synthetic Metals 137, no. 1-3 (April 2003): 907–8. http://dx.doi.org/10.1016/s0379-6779(02)01025-1.

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4

Kracke, Andreas, Carsten von Hänisch, and Nina Kramer. "Hybrid Cage Compounds with Organic and Inorganic Building Blocks." European Journal of Inorganic Chemistry 2012, no. 18 (May 14, 2012): 2975–79. http://dx.doi.org/10.1002/ejic.201200384.

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5

Stock, Norbert, Christian Jargstorff, and Steffanie Wriedt. "Two New Crystalline Organogermanate-Based Inorganic-Organic Hybrid Compounds." Zeitschrift für anorganische und allgemeine Chemie 637, no. 5 (February 21, 2011): 572–77. http://dx.doi.org/10.1002/zaac.201000406.

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6

SUGAHARA, Yoshiyuki. "Chemical processes employing inorganic layered compounds for inorganic and inorganic^|^ndash;organic hybrid materials." Journal of the Ceramic Society of Japan 122, no. 1427 (2014): 523–29. http://dx.doi.org/10.2109/jcersj2.122.523.

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7

Chujo, Yoshiki, and Ryo Tamaki. "New Preparation Methods for Organic–Inorganic Polymer Hybrids." MRS Bulletin 26, no. 5 (May 2001): 389–92. http://dx.doi.org/10.1557/mrs2001.92.

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Nano-ordered composite materials consisting of organic polymers and inorganic compounds have been attracting attention for their use in creating high-performance or high-functionality polymeric materials. The term “polymer hybrid” describes blends of organic and inorganic components with molecular-level dispersions.

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8

Wang, Dong-Yan, Xue-Li Hou, and Xue-Nan Li. "Isostructural organic–inorganic hybrid compounds: triethylcholine tribromidocadmate and triethylcholine tribromidomercurate." Acta Crystallographica Section C Structural Chemistry 71, no. 8 (July 25, 2015): 728–32. http://dx.doi.org/10.1107/s2053229615013303.

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In order to search for new anionic architectures and develop useful organic–inorganic hybrid materials in halometallate systems, two new crystalline organic–inorganic hybrid compounds have been prepared,i.e. catena-poly[triethyl(2-hydroxyethyl)azanium [[bromidocadmate(II)]-di-μ-bromido]], {(C8H20NO)[CdBr3]}n, (1), andcatena-poly[triethyl(2-hydroxyethyl)azanium [[bromidomercurate(II)]-di-μ-bromido]], {(C8H20NO)[HgBr3]}n, (2), and the structures determined by X-ray diffraction analysis. The compounds are isostructural, crystallizing in the space groupP21/n. The metal centres are five-coordinated by bromide anions, giving a slightly distorted trigonal–bipyramidal geometry. The crystal structures consist of one-dimensional edge-sharing chains ofMBr5trigonal bipyramids, between which triethylcholine counter-cations are intercalated. O—H...Br hydrogen-bonding interactions are present between the cations and anions.

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9

Fan, Le-Qing, Xin Jin, Dong-Xu Li, Chong-Bin Tian, and Ji-Huai Wu. "[Pb3Cu2I10(phen)4]n: a novel organic–inorganic hybrid ferromagnetic semiconductor." Dalton Transactions 46, no. 43 (2017): 14738–41. http://dx.doi.org/10.1039/c7dt03237d.

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10

Li, Ying, Han-Ying Li, Kai-Chi Chang, Hsiu-Mei Lin, and Chih-Min Wang. "Recent developments in organic–inorganic hybrid metal phosphates and phosphites." Dalton Transactions 50, no. 29 (2021): 10014–19. http://dx.doi.org/10.1039/d1dt01016f.

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This frontier article highlights recent advances in synthesis and characterization of organic–inorganic hybrid metal phosphates and phosphites. The synthetic strategies and structural stabilities of hybrid composites blended with stable crystalline compounds are presented.

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11

Choi, Hansol, and Jihoon Choi. "Detection of Volatile Organic Compounds (VOCs) using Organic-Inorganic Hybrid Perovskite Nanoparticles." Korean Journal of Materials Research 30, no. 10 (October 31, 2020): 515–21. http://dx.doi.org/10.3740/mrsk.2020.30.10.515.

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12

Ptak, Maciej, Adam Sieradzki, Mantas Šimėnas, and Mirosław Maczka. "Molecular spectroscopy of hybrid organic–inorganic perovskites and related compounds." Coordination Chemistry Reviews 448 (December 2021): 214180. http://dx.doi.org/10.1016/j.ccr.2021.214180.

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13

Dolbecq, Anne, Eddy Dumas, Cédric R. Mayer, and Pierre Mialane. "Hybrid Organic−Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications." Chemical Reviews 110, no. 10 (October 13, 2010): 6009–48. http://dx.doi.org/10.1021/cr1000578.

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14

Dui, Xue-Jing, Xiao-Yuan Wu, Jian-Zhen Liao, Teng Teng, Wei-Ming Wu, and Wen-Bin Yang. "Photocatalytic properties of two POM-templated organic–inorganic hybrid compounds." Inorganic Chemistry Communications 56 (June 2015): 112–15. http://dx.doi.org/10.1016/j.inoche.2015.04.007.

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15

D, Krisha, M. Chamundeeswari, and K. Tamilarasan. "Hybrid Composite Photocatalysts Membrane System For Industrial Water Treatment And Renewable Energy Applications." ECS Transactions 107, no. 1 (April 24, 2022): 19069–76. http://dx.doi.org/10.1149/10701.19069ecst.

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A combination between the composite photocatalyst and membrane system towards the development of hybrid process for various applications especially in water treatment and renewable energy synthesis. These hybrid processes overcome many of the difficulties that are associated with conventional methods and promote process intensification. The hybrid photocatalytic membrane process could reduce the downstream process and also degrade the toxic compound in the waste water. Effluent waste water generated from industrial and domestic process, it consists of complex organic compounds such as lignin, phenolic compounds, pectin, proteins and minerals etc. The effluent containing organic dyes and phenolic compounds releases toxic materials into aquo system poses environmental concern. The traditional effluent treatment very challenge process due to consist mixture of organic and inorganic pollutants such as lignin, resins, tannins, chlorinated phenol, waxes and heavy metals etc. Recently, many industries planning to reuse treated water for economic reasons and environmental protection.

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16

Varela Caselis, J. L., R. Agustín Serrano, and E. Rubio Rosas. "Preparation and Characterization of Epoxy-Silica Coatings Using Rhodamine 6G as Dye." MRS Proceedings 1613 (2014): 45–51. http://dx.doi.org/10.1557/opl.2014.157.

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ABSTRACTIt has been found that the hybrid materials are a compatible matrix for numerous organic compounds, such as organic dyes, laser dyes, and compounds that exhibit photo-chromic behavior and many more The epoxy-silica system seems to be an excellent matrix for organic dyes and a hybrid material suitable for to be used as coating on glass substrates with good adhesion properties. This work presents a systematic study of the effects of the different amount of using rhodamine 6G as dye on the structure and properties of epoxy–silica hybrids coatings synthesized by the sol-gel process. We have taken advantage on the high solubility of organic dyes in a hybrid organic–inorganic epoxy resin–silica (epoxy–SiO2) matrix to obtain homogeneous, hard and high optical quality red color films on glass substrates. The effects of the content of rhodamine 6 G on the optical and thermal properties of epoxy-silica hybrid films were also examined. Epoxy resin DER 332 cured with an amine (4,4 diamino diphenyl methane) was used as organic component and tetraethyl orthosilicate (TEOS) was used as precursor of the inorganic component. The results showed that at a concentration of rhodamine 0.05% coatings retain adhesion properties similar to coatings without colorant and the coatings are uniform and free of defects. These coatings have the potential to be used as filters and ornamental coatings.

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17

Xu, Li-Jie, Wen-Zhe Zhou, Li-Yuan Zhang, Bin Li, Hong-Ying Zang, Yong-Hui Wang, and Yang-Guang Li. "Organic–inorganic hybrid assemblies based on Ti-substituted polyoxometalates for photocatalytic dye degradation." CrystEngComm 17, no. 19 (2015): 3708–14. http://dx.doi.org/10.1039/c4ce02505a.

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18

Sousa, Rui P. C. L., Rita B. Figueira, Bárbara R. Gomes, Sara Sousa, R. Cristina M. Ferreira, Susana P. G. Costa, and M. Manuela M. Raposo. "Hybrid Sol–Gel Matrices Doped with Colorimetric/Fluorimetric Imidazole Derivatives." Nanomaterials 11, no. 12 (December 15, 2021): 3401. http://dx.doi.org/10.3390/nano11123401.

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Organic–inorganic hybrids (OIH) are materials that can be easily synthesized by the sol–gel method and combine the advantages of organic and inorganic moieties within a single polymeric matrix. Imidazole derivatives are versatile organic compounds that can change their optical properties with the variation of pH due to the protonation or deprotonation of the nitrogen atoms. This work reports the preparation of different OIHs doped with different contents of two imidazole compounds (3a,b). The obtained materials were characterized structurally by FTIR, and the dielectric properties were studied by electrochemical impedance spectroscopy. The optical properties were studied by UV-Vis absorption and fluorescence spectroscopies. The FTIR analysis showed that the presence of the imidazole does not change the structural properties of the matrices. The normalized resistance values obtained for the doped matrices ranged between 8.57 and 9.32 Ω cm2, all being higher than the undoped matrix. The σ ranged between 9.49 and 10.28 S cm−1, being all higher than the pure OIH samples. Compound 3a showed a maximum absorption peak at 390 nm, which is present in the OIH spectra, proving the presence of the compound. In the case of compound 3b, a maximum absorption wavelength at 412 nm was found, and the compound peak was not clear, which may indicate that an interaction between the compound and the matrix occurred. A synergetic effect between the intrinsic emission of the matrix and the fluorescence of 3a is found on the OIH-doped matrices.

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19

Enferadi-Kerenkan, A., A. Gandon, and T. O. Do. "Novel tetra-propyl/butylammonium encapsulated Keggin-type polyoxotungstates: synthesis, structural characterization, and catalytic capability in oxidative cleavage of unsaturated fatty acids." Dalton Transactions 47, no. 4 (2018): 1214–22. http://dx.doi.org/10.1039/c7dt04469k.

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20

Merghes, Petru, Gheorghe Ilia, Iosif Hulka, Vlad Chiriac, Narcis Varan, and Vasile Simulescu. "The Influence of Boron on the Structure and Properties of Hybrid Compounds Containing Zirconium and Phosphorus." Gels 8, no. 10 (October 17, 2022): 667. http://dx.doi.org/10.3390/gels8100667.

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In the present work, novel organic–inorganic hybrid materials containing boron, zirconium, and phosphorus were synthesized at different molar ratios, using the sol–gel method, starting from zirconyl chloride hexa-hydrate, triethyl borate, and phenyl phosphonic acid as the precursors. The sol–gel process is used for the first time in the present work in order to obtain organic–inorganic hybrids (or the so-called inorganic polymers) containing together boron, zirconium, and phosphorus. The sol–gel syntheses were performed at room temperature in ethanol. Zirconium containing compounds are already well known for their applications in medicine in restorative or prosthetic devices, including dental implants, knee and hip replacements, middle-ear ossicular chain reconstruction, and so on. Zirconium is a strong transition metal, which started to replace hafnium and titanium in the last decade in important applications. On the other hand, boron has the capability (similar to carbon) to form stable covalently bonded molecular networks. In addition to this capability, boron also offers mixed metallic and nonmetallic properties, because of its place on the periodic table, at the border between metals and nonmetals. Boron is responsible for the higher thermal stability of synthesized hybrid compounds. In the structure of those hybrid compounds, zirconium, boron, and phosphorus atoms are always connected via an oxygen atom, by P-O-Zr, Zr-O-Zr, or Zr-O-B bridges.

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21

Bouguerra, Manel, Adel Mahroug, Agata Wróbel, Damian Trzybiński, Krzysztof Woźniak, and Mohamed Belhouchet. "Physico-chemical study of new supramolecular-architectured hybrid organic–inorganic sulfates incorporating diammoniumdiphenylsulfone cations." RSC Advances 11, no. 42 (2021): 26368–78. http://dx.doi.org/10.1039/d1ra03696c.

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22

Parbhakar, Swati, Reetam Kaushik, and Firasat Hussain. "Synthesis and characterization of self-assembled inorganic–organic hybrid arsenotungstates." Acta Crystallographica Section C Structural Chemistry 74, no. 12 (November 30, 2018): 1561–68. http://dx.doi.org/10.1107/s2053229618014171.

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A series of 12 inorganic–organic hybrid 4f-substituted arsenotungstates decorated with 3d-based complexes along with acetate bridging, viz. {[Cu2(H2O)(1,10-phen)2(μ-CH3COO)2]4[Ln2(H2O)2(μ-CH3COO)2(α-AsW11O39)2]}2− (LnIII = Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu), have been synthesized. These compounds were isolated using a one-pot synthetic strategy with copper, lanthanoid, trilacunary arsenotungstate and 1,10-phenanthroline as precursors. They were characterized using various analytical techniques, such as single-crystal X-ray diffraction (SC-XRD), powder XRD (PXRD), Fourier transform IR (FT–IR) spectroscopy, UV–Vis spectroscopy and thermogravimetric analysis (TGA). In all these compounds, a dinuclear Ln2(ac)2 moiety is sandwiched between two monolacunary [AsW11O39]7− polyoxometalates (POMs), where the Ln2(ac)2 moiety is comprised of two acetate ligands in a μ-κO,O′:κO fashion. Moreover, the anion is decorated by a copper–phenanthroline–acetate complex through a terminal O atom of the polyanion.

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23

Yue, Cheng-Yang, Na Lin, Lu Gao, Ying-Xue Jin, Zhao-Yang Liu, Yao-Yao Cao, Sha-Sha Han, Xi-Kai Lian, Bing Hu, and Xiao-Wu Lei. "Organic cation directed one-dimensional cuprous halide compounds: syntheses, crystal structures and photoluminescence properties." Dalton Transactions 48, no. 27 (2019): 10151–59. http://dx.doi.org/10.1039/c9dt01460h.

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24

Rodrigues, Marieli Oliveira, Victória Goulart Isoppo, Angélica Venturini Moro, and Fabiano Severo Rodembusch. "Photoactive organic-inorganic hybrid materials: From silylated compounds to optical applications." Journal of Photochemistry and Photobiology C: Photochemistry Reviews 51 (June 2022): 100474. http://dx.doi.org/10.1016/j.jphotochemrev.2021.100474.

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25

Hei, Xiuze, Yang Fang, Simon J. Teat, Colin Farrington, Megan Bonite, and Jing Li. "Copper(I) iodide-based organic–inorganic hybrid compounds as phosphor materials." Zeitschrift für Naturforschung B 76, no. 10-12 (October 5, 2021): 759–64. http://dx.doi.org/10.1515/znb-2021-0126.

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Abstract Two photoluminescent copper(I) iodide inorganic-organic hybrid materials have been synthesized and structurally characterized as 1D-Cu2I2(bpoe)2 (1) and 1D-Cu2I2(bbtpe-m)2 (2) (bpoe = 1,2-bis(pyridin-3-yloxy)ethane, bbtpe-m = 1,1′-(3-methylpentane-1,5-diyl)bis(1H-benzo[1,2,3]triazole). Both are chain-like structures composed of Cu2I2 rhomboid dimers connected by bidentate ligands. Their emission colors range from cyan to yellow with relatively high internal quantum yields in the solid state. The tunable band gap and emission color is achieved by varying the LUMO energies of the ligands. The structures are robust and remain stable up to T = 260 °C, and coupled with their efficient and adjustable luminescence, facile synthesis, and non-toxic nature, these compounds demonstrate potential as rare earth element (REE)-free phosphors.

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26

Bauer, E. M., C. Bellitto, M. Colapietro, S. A. Ibrahim, M. R. Mahmoud, G. Portalone, and G. Rigini. "Co(II)n-alkyl phosphonates: examples of hybrid organic-inorganic compounds." Acta Crystallographica Section A Foundations of Crystallography 61, a1 (August 23, 2005): c358. http://dx.doi.org/10.1107/s010876730508476x.

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27

Moreno, Yanko, Andrés Vega, Svetlana Ushak, Ricardo Baggio, Octavio Peña, Eric Le Fur, Jean-Yves Pivan, and Evgenia Spodine. "Magnetic properties of phosphate-bridged copper(ii) organic–inorganic hybrid compounds." J. Mater. Chem. 13, no. 9 (2003): 2381–87. http://dx.doi.org/10.1039/b212463g.

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28

Joniaková, D., R. Gyepes, E. Rakovský, P. Schwendt, L’ Žúrková, J. Marek, and Z. Mička. "Structural variability of copper-1,10-phenanthroline–oxovanadate hybrid inorganic–organic compounds." Polyhedron 25, no. 13 (September 2006): 2491–502. http://dx.doi.org/10.1016/j.poly.2006.02.020.

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29

Ghosh, Saurabh, Domenico Di Sante, and Alessandro Stroppa. "Strain Tuning of Ferroelectric Polarization in Hybrid Organic Inorganic Perovskite Compounds." Journal of Physical Chemistry Letters 6, no. 22 (November 5, 2015): 4553–59. http://dx.doi.org/10.1021/acs.jpclett.5b01806.

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30

Hu, Bing, Guo-Dong Zou, Mei-Ling Feng, and Xiao-Ying Huang. "Inorganic–organic hybrid compounds based on novel lanthanide-antimony oxohalide nanoclusters." Dalton Transactions 41, no. 33 (2012): 9879. http://dx.doi.org/10.1039/c2dt30563a.

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31

Sahoo, Trilochan, Uchenna A. Anene, Sanjeev K. Nayak, and S. Pamir Alpay. "Electronic and optical properties of zinc based hybrid organic-inorganic compounds." Materials Research Express 7, no. 3 (March 9, 2020): 035701. http://dx.doi.org/10.1088/2053-1591/ab7ac4.

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32

Yang, Ming-Xing, Shen Lin, Xiao-Hua Chen, Ming-Hong Luo, and Jiao-Hua Liu. "Two organic–inorganic hybrid compounds constructed from 12-tungstovanadate and bipyridine." Journal of Coordination Chemistry 63, no. 3 (November 19, 2009): 406–17. http://dx.doi.org/10.1080/00958970903431704.

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33

Silverio, Fabiano, Márcio José dos Reis, Jairo Tronto, and João Barros Valim. "Removal of aliphatic amino acids by hybrid organic–inorganic layered compounds." Applied Surface Science 253, no. 13 (April 2007): 5756–61. http://dx.doi.org/10.1016/j.apsusc.2006.12.040.

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34

Andrade-Espinoza, Beatriz A., Gregorio G. Carbajal-Arizaga, Selma Rivas-Fuentes, Karla Nuño, José Benito Pelayo-Vázquez, and Jenny Arratia-Quijada. "Synthesis of Organic-Inorganic Hybrid Material with a Synergistic Interface as a Release Agent for Free Acid β-Hydroxy-β-Methyl Butyrate." Journal of Nanomaterials 2021 (December 6, 2021): 1–12. http://dx.doi.org/10.1155/2021/3060539.

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We report the preparation and characterization of a new organic-inorganic hybrid system composed of type-I collagen and ZnAl layered double hydroxide (LDH) particles loaded with β-hydroxy-β-methyl butyrate (HMB) by coprecipitation reaction. X-ray diffraction (peaks well agree with those reported in the literature), infrared spectroscopy (stretching bonds for both organic-inorganic compounds), and X-ray photoelectron spectroscopy confirmed the hybrid system retained HMB in the carboxylate form, and a small fraction turned to the acid form. In both cases, the HMB molecules are assembled to the LDH surface. The hybrid compound results in improved thermal stability for HMB and collagen, as shown by thermal analysis. Scanning electron microscopy data reflects different arrangements from LDH sheets with interesting physicochemical properties since LDH and collagen protect free HMB and make it more bioavailable and functional. In vitro studies as part of high-throughput screening strategies indicated that LDH hybrids reduced cell viability around 75-90%, which is an acceptable viability value because of the L6 cell line susceptibility. However, all new nanomaterials must be carefully analyzed by different toxicity tests because a single test does not evaluate complete physiological compartments.

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35

Yagishita, Sadahiro, Akiko Himegi, Ken Kanazashi, Tomomi Ohishi, Ryuta Ishikawa, Tomohiko Hamaguchi, and Satoshi Kawata. "Structural transformations of layered structures constructed from Cu(ii)–chloranilate monomer compounds." Dalton Transactions 46, no. 9 (2017): 2966–73. http://dx.doi.org/10.1039/c6dt04867f.

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36

Meng, Xin, Zhi-Bo Liu, Ke Xu, Lei He, Yu-Zhen Wang, Ping-Ping Shi, and Qiong Ye. "Metal regulated organic–inorganic hybrid ferroelastic materials: [(CH₃)₃CN(CH₃)₂CH₂F]₂[MBr₄] (M = Cd and Zn)." Inorganic Chemistry Frontiers 9, no. 8 (2022): 1603–8. http://dx.doi.org/10.1039/d1qi01533h.

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Two organic–inorganic hybrid compounds [(CH3)3CN(CH3)2CH2F]2[MBr4] (M = Cd and Zn) undergo ferroelastic phase transitions. The substitution of metal center Cd with Zn of inorganic anions regulate the ferroelastic phase transitions.

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Merghes, Petru, Narcis Varan, Gheorghe Ilia, Iosif Hulka, and Vasile Simulescu. "A SEM-EDX Study on the Structure of Phenyl Phosphinic Hybrids Containing Boron and Zirconium." Gels 9, no. 9 (September 1, 2023): 706. http://dx.doi.org/10.3390/gels9090706.

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The SEM-EDX method was used to investigate the structure and morphology of organic–inorganic hybrids containing zirconium, boron and phosphorus compounds, synthesized by the sol–gel method. We started by using, for the first time together, zirconyl chloride hexa-hydrate (ZrOCl2·6H2O), phenyl phosphinic acid and triethyl borate as precursors and reagents, at different molar ratios. The obtained hybrids showed a very high thermal stability and are not soluble in water or in organic solvents. As a consequence, such hybrid solid materials are suitable for applications at high temperatures. The obtained hybrids have complex 3D structures and form organic–inorganic networks containing Zr-O-Zr, Zr-O-P and Zr-O-B bridges. Such organic–inorganic networks are also expected to form supramolecular structures and to have many potential applications in different fields of great interest such as catalysis, medicine, agriculture, energy storage, fuel cells, sensors, electrochemical devices and supramolecular chemistry.

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38

Telysheva, Galina, Tatiana Dizhbite, Lilija Jashina, Anna Andersone, Alexander Volperts, Jevgenija Ponomarenko, and Nina Mironova-Ulmane. "Synthesis of lignin-based inorganic/organic hybrid materials favorable for detoxification of ecosystem components." BioResources 4, no. 4 (August 1, 2009): 1276–84. http://dx.doi.org/10.15376/biores.4.4.1276-1284.

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Combination of lignin matrices (including those modified with silicon oligomers or quaternary ammonium compounds) and such inorganic building blocks as copper and manganese cations (Cu2+, Mn2+) made it possible to synthesize novel hybrid organic-inorganic materials. The synthesized hybrid materials were characterized with significantly increased (2-9 times) values of specific surface area in comparison with those for non-modified and Si-modified precursor matrices. The Cu2+-containing hybrid materials differed by enhanced sorption capacity towards proteins and bacteria.

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39

Guo, Yuan-Yuan, Lin-Jie Yang, and Philip Lightfoot. "Three New Lead Iodide Chain Compounds, APbI3, Templated by Molecular Cations." Crystals 9, no. 12 (November 24, 2019): 616. http://dx.doi.org/10.3390/cryst9120616.

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The crystal structures of three new hybrid organic-inorganic lead halide compounds [IqH]PbI3, [4MiH]PbI3, and [BzH]PbI3 ([IqH+] = isoquinolinium, [4MiH+] = 4-methylimidazolium, [BzH+] = benzotriazolium) have been determined by single crystal x-ray diffraction. All three compounds have the same generic formula as perovskite, ABX3, but adopt a rare non-perovskite structure built from one dimensional (1D) edge-sharing octahedral chains. The bandgap of each compound was investigated by solid UV-Vis spectra. In comparison with previously reported hybrid compounds containing the same type of octahedral chains, [C10H7CH2NH3]Pbl3 and (C7H7N2)PbI3, all three new compounds have lower bandgaps (<2.4 ev), indicating that they may be promising for photovoltaic application.

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40

Seesaard, Thara, Chadinee Thippakorn, Teerakiat Kerdcharoen, and Sumana Kladsomboon. "A hybrid electronic nose system for discrimination of pathogenic bacterial volatile compounds." Analytical Methods 12, no. 47 (2020): 5671–83. http://dx.doi.org/10.1039/d0ay01255f.

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41

Mukundam, Vanga, Kunchala Dhanunjayarao, Ching-Nan Chuang, Dun-Yen Kang, Man-kit Leung, Kuo-Huang Hsieh, and Krishnan Venkatasubbaiah. "Design, synthesis, photophysical and electrochemical properties of 2-(4,5-diphenyl-1-p-aryl-1H-imidazol-2-yl)phenol-based boron complexes." Dalton Transactions 44, no. 22 (2015): 10228–36. http://dx.doi.org/10.1039/c5dt00867k.

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42

You, Xiuli, Jiaojiao Yao, and Zhenhong Wei. "Tin based organic–inorganic hybrid semiconductors with reversible phase transition and dielectric anomaly." Dalton Transactions 49, no. 21 (2020): 7252–57. http://dx.doi.org/10.1039/d0dt01401j.

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Two discrete tin based organic–inorganic hybrid compounds [(FMBA)₂SnX₆] (X = Cl and Br) showed reversible phase transition and dielectric anomaly above 400 K which were originated from the order-disorder of a fluorine-substituted organic amine.

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Wang, Zhongxia, Xing-Hui Lv, Yu-Ling Liu, Yang Lu, Hai-Peng Chen, and Jia-Zhen Ge. "Prominent dielectric transitions in layered organic–inorganic hybrids: (isoamyl-ammonium)2CdX4 (X = Cl and Br)." Inorganic Chemistry Frontiers 4, no. 8 (2017): 1330–36. http://dx.doi.org/10.1039/c7qi00270j.

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Lassoued, Mohamed Saber, Yuan-Chao Pang, Qian-Wen Li, Xinkai Ding, Bo Jiao, Hua Dong, Guijiang Zhou, et al. "Stable two-dimensional lead iodide hybrid materials for light detection and broadband photoluminescence." Materials Chemistry Frontiers 6, no. 1 (2022): 71–77. http://dx.doi.org/10.1039/d1qm01247a.

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Li, Xiao, Liu Yang, Chao Qin, Fu-Hong Liu, Liang Zhao, Kui-Zhan Shao, and Zhong-Min Su. "POM-based inorganic–organic hybrid compounds: synthesis, structures, highly-connected topologies and photodegradation of organic dyes." RSC Advances 5, no. 73 (2015): 59093–98. http://dx.doi.org/10.1039/c5ra09339b.

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Four new polyoxovanadate-based organic–inorganic hybrid materials have been synthesized under hydrothermal conditions through self-assembly. Their thermal stabilities and photocatalytic activities were also investigated.

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Guo, Hai-Yang, Hui Qi, Xiao Zhang, and Xiao-Bing Cui. "First Organic–Inorganic Hybrid Compounds Formed by Ge-V-O Clusters and Transition Metal Complexes of Aromatic Organic Ligands." Molecules 27, no. 14 (July 11, 2022): 4424. http://dx.doi.org/10.3390/molecules27144424.

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Three compounds based on Ge-V-O clusters were hydrothermally synthesized and characterized by IR, UV-Vis, XRD, ESR, elemental analysis and X-ray crystal structural analysis. Both [Cd(phen)(en)]2[Cd2(phen)2V12O40Ge8(OH)8(H2O)]∙12.5H2O (1) and [Cd(DETA)]2[Cd(DETA)2]0.5[Cd2(phen)2V12O41Ge8(OH)7(0.5H2O)]∙7.5H2O (2) (1,10-phen = 1,10-phenanthroline, en = ethylenediamine, DETA = diethylenetriamine) are the first Ge-V-O cluster compounds containing aromatic organic ligands. Compound 1 is the first dimer of Ge-V-O clusters, which is linked by a double bridge of two [Cd(phen)(en)]2+. Compound 2 exhibits an unprecedented 1-D chain structure formed by Ge-V-O clusters and [Cd2(DETA)2]4+ transition metal complexes (TMCs). [Cd(en)3]{[Cd(η2-en)2]3[Cd(η2-en)(η2-μ2-en)(η2-en)Cd][Ge6V15O48(H2O)]}∙5.5H2O (3) is a novel 3-D structure which is constructed from [Ge6V15O48(H2O)]12− and four different types of TMCs. We also synthesized [Zn2(enMe)3][Zn(enMe)]2[Zn(enMe)2(H2O)]2[Ge6V15O48(H2O)]∙3H2O (4) and [Cd(en)2]2{H8[Cd(en)]2Ge8V12O48(H2O)}∙6H2O (5) (enMe = 1,2-propanediamine), which have been reported previously. In addition, the catalytic properties of these five compounds for styrene epoxidation have been assessed.

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Mirković, Miljana, Muge Sari Yilmaz, Ljiljana Kljajević, Vladimir Pavlović, Marija Ivanović, Dunja Djukić, and Tarik Eren. "Design of PEI and Amine Modified Metakaolin-Brushite Hybrid Polymeric Composite Materials for CO2 Capturing." Polymers 15, no. 7 (March 27, 2023): 1669. http://dx.doi.org/10.3390/polym15071669.

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In this paper, the properties of organic-inorganic hybrid polymer materials, which were synthesized from an aluminosilicate inorganic matrix with the addition of brushite and aminosilane grafted on one side and PEI covalently bonded composites on the other side, were examined. The synthesized organic-inorganic hybrid polymers were examined in terms of a structural, morphological, thermo-gravimetric, and adsorption-desorption analysis and also as potential CO2 capturers. The structural and phase properties as well as the percentage contents of the crystalline and amorphous phase were determined by the X-ray diffraction method. The higher content of the amorphous phase in the structure of hybrid polymers was proven in metakaolin and metakaolin-brushite hybrid samples with the addition of amino silane and with 1,000,000 PEI in a structure. The DRIFT method showed the main band changes with the addition of an organic phase and inorganic matrix. Microstructural studies with the EDS analysis showed a uniform distribution of organic and inorganic phases in the hybrid geopolymers. The thermo-gravimetric analysis showed that organic compounds are successfully bonded to inorganic polymer matrix, while adsorption-desorption analysis confirmed that the organic phase completely covered the surface of the inorganic matrix. The CO2 adsorption experiments showed that the amine-modified composites have the higher capture capacity, which is 0.685 mmol·g−1 for the GM10 sample and 0.581 mmol·g−1 for the BGM10 sample, with 1,000,000 PEI in the structure.

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Wang, Guan-E., Gang Xu, Ming-Sheng Wang, Li-Zhen Cai, Wen-Hua Li, and Guo-Cong Guo. "Semiconductive 3-D haloplumbate framework hybrids with high color rendering index white-light emission." Chemical Science 6, no. 12 (2015): 7222–26. http://dx.doi.org/10.1039/c5sc02501j.

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Gu, Jingmin, Lei Zhang, Xiaofeng Yuan, Ya-Guang Chen, Xiuzhu Gao, and Dong Li. "Synthesis and Antibacterial Activity of Polyoxometalates with Different Structures." Bioinorganic Chemistry and Applications 2018 (December 9, 2018): 1–6. http://dx.doi.org/10.1155/2018/9342326.

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A new inorganic-organic hybrid compound, [{Cu(phen)2}2(H4W12O40)], was synthesized, and its crystal structure was determined. The Keggin anion H4W12O404− was grafted with two coordination units {Cu(phen)2}, forming an electrically neutral molecule. The antibacterial activity of several polyoxometalate compounds with different anionic structures including the new compound was studied. The results show that the compound 1 can inhibit the growth of Enterococcus faecalis FA2 strains and that antibacterial activity of the polyoxometalate compounds is dependent with component elements of POM but is less relative with the anion structures.

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Nashrah, Nisa, Rosy Amalia Kurnia Putri, Early Zahwa Alharissa, Wail Al Zoubi, and Young Gun Ko. "Hybrid Organic-Inorganic Materials on Metallic Surfaces: Fabrication and Electrochemical Performance." Metals 11, no. 7 (June 29, 2021): 1043. http://dx.doi.org/10.3390/met11071043.

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In recent years, hybrid organic-inorganic (HOI) materials have attracted massive attention as they combine the unique properties of organic and inorganic compounds. In this review, we focus on the formation of HOI materials and their electrochemical performance that can be controlled by microstructural design depending upon their chemical composition. This overview outlines the recent strategies of preparing HOI materials on metallic surface via wet-electrochemical systems, such as plasma electrolysis (PE) and dip chemical coating (DCC). The corresponding electrochemical behavior for short and long term exposures is also summarized.

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