Academic literature on the topic 'Intercalation mechanism'

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Journal articles on the topic "Intercalation mechanism"

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Ding, Shu Li, B. H. Xu, Q. F. Liu, and Y. Z. Sun. "Preparation of Nano-Kaolinite and Mechanism." Advanced Materials Research 204-210 (February 2011): 1217–20. http://dx.doi.org/10.4028/www.scientific.net/amr.204-210.1217.

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With potassium acetate as an intercalation agent, kaolinite-potassium acetate(KAc) intercalation complexes was prepared. Afterwards, nano-kaolinite was successfully made through exfoliated intercalation complexes using power ultrasonic. The intermediate and final products were characterized by X-ray diffraction(XRD), infrared spectroscopy(IR), laser particle size analyzer, and scanning electron microscope (SEM). The results show that intercalation of KAc into kaolinite resulted in a crystal space expansion, from a basal spacing of 7.14Ǻ to 14.20 Ǻ, and the intercalation rate was about 80%. KAc
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Xia, Hua, and Sheng Hui Zhang. "Synthesis, Characterization and Mechanism of Benzamide Intercalated Kaolinite by Replacement Method." Applied Mechanics and Materials 420 (September 2013): 222–29. http://dx.doi.org/10.4028/www.scientific.net/amm.420.222.

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Kaolinite/benzamide complex was prepared by displacement reaction of a kaolinite/dimethylsulphoxide (DMSO) intercalation complex with melted benzamide. The whole process was recorded by powder X-ray diffractometry (PXRD) and Fourier-transformed infrared spectroscopy (FTIR). Those PXRD and FT-IR indicated that there are two stages in the process of melted benzamide replacing intercalation. The first stage is the deintercalation of DMSO molecules in the kaolinite/dimethylsulphoxide intercalation complex. And the second stage is the melted benzamide intercalation.
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Monaco, Regina R. "Capture of a Transition State Using Molecular Dynamics: Creation of an Intercalation Site in dsDNA with Ethidium Cation." Journal of Nucleic Acids 2010 (2010): 1–4. http://dx.doi.org/10.4061/2010/702317.

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The mechanism of intercalation and the ability of double stranded DNA (dsDNA) to accommodate a variety of ligands in this manner has been well studied. Proposed mechanistic steps along this pathway for the classical intercalator ethidium have been discussed in the literature. Some previous studies indicate that the creation of an intercalation site may occur spontaneously, with the energy for this interaction arising either from solvent collisions or soliton propagation along the helical axis. A subsequent 1D diffusional search by the ligand along the helical axis of the DNA will allow the lig
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Nisar, Umair, R. A. Shakoor, Rachid Essehli, et al. "Sodium intercalation/de-intercalation mechanism in Na4MnV(PO4)3 cathode materials." Electrochimica Acta 292 (December 2018): 98–106. http://dx.doi.org/10.1016/j.electacta.2018.09.111.

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Kaghazchi, Payam. "Mechanism of Li intercalation into Si." Applied Physics Letters 102, no. 9 (2013): 093901. http://dx.doi.org/10.1063/1.4794825.

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Koudriachova, Marina V. "Mechanism of lithium intercalation in titanates." Journal of Solid State Electrochemistry 14, no. 4 (2008): 549–53. http://dx.doi.org/10.1007/s10008-008-0654-8.

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Yan, Dong, Shaozhuan Huang, Yew Von Lim, et al. "Stepwise Intercalation-Conversion-Intercalation Sodiation Mechanism in CuInS2 Prompting Sodium Storage Performance." ACS Energy Letters 5, no. 12 (2020): 3725–32. http://dx.doi.org/10.1021/acsenergylett.0c02049.

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Wu, Yuhan, Yang Xu, Yueliang Li, et al. "Unexpected intercalation-dominated potassium storage in WS2 as a potassium-ion battery anode." Nano Research 12, no. 12 (2019): 2997–3002. http://dx.doi.org/10.1007/s12274-019-2543-0.

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Abstract Unexpected intercalation-dominated process is observed during K+ insertion in WS2 in a voltage range of 0.01–3.0 V. This is different from the previously reported two-dimensional (2D) transition metal dichalcogenides that undergo a conversion reaction in a low voltage range when used as anodes in potassium-ion batteries. Charge/discharge processes in the K and Na cells are studied in parallel to demonstrate the different ion storage mechanisms. The Na+ storage proceeds through intercalation and conversion reactions while the K+ storage is governed by an intercalation reaction. Owing t
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Wang, Yaowu, Pengcheng Hao, Jianping Peng, and Yuezhong Di. "Mechanism of aluminum carbide formation in aluminum electrolysiscells." Journal of Mining and Metallurgy, Section B: Metallurgy, no. 00 (2020): 23. http://dx.doi.org/10.2298/jmmb190514023w.

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The formation and dissolution of aluminum carbide is considered the primary factor affecting the life of aluminum electrolysis cells. Herein, the characteristics of sodium-graphite intercalation compounds (Na-GICs)were measured and the formation mechanism of Al4C3duringthe aluminum electrolysis process was experimentally studied. The Na-GIC characteristics and the products of aluminum and Na-GIC reactions were investigated by Raman spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy and scanning electron microscopy. The results showed that graphite can react with the sodium metal
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Kajiyama, Satoshi, Lucie Szabova, Keitaro Sodeyama, et al. "Sodium-Ion Intercalation Mechanism in MXene Nanosheets." ACS Nano 10, no. 3 (2016): 3334–41. http://dx.doi.org/10.1021/acsnano.5b06958.

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Dissertations / Theses on the topic "Intercalation mechanism"

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Borralleras, Mas Pere. "Intercalation mechanism of polycarboxylate-based superplasticizers into montmorillonite clays." Doctoral thesis, Universitat Politècnica de Catalunya, 2019. http://hdl.handle.net/10803/667977.

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The presence of clays in the sands used for concrete production interferes with the development of the fluidity of concrete, producing an instantaneous slump loss just after batching and the premature loss of fluidity. This interference occurs with all types of additives and clays but is especially problematic when combining sands containing expansive clays such as montmorillonites with new-generation high water-reducer/superplasticizer admixtures based on polycarboxylate polymers (PCE). Water-reducers based on PCE polymers offer much better performance than traditional superplasticizers ba
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Soares, Adrien. "Batteries Lithium-ion innovantes, spécifiques pour le stockage de l'énergie photovoltaïque." Thesis, Montpellier 2, 2012. http://www.theses.fr/2012MON20206/document.

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Le travail de thèse, présenté dans ce mémoire, est consacré à l'étude de nouveaux matériaux d'électrode pour batterie lithium-ion pour le stockage d'énergie photovoltaïque. Ce type de production d'énergie impose de nombreuses intermittences de charge, des non synchronisations entre les périodes de production et de consommation, etc. L'objectif est d'évaluer le comportement de différents types de matériau d'électrode dans des batteries soumises à des profils de charge photovoltaïque pour ensuite sélectionner les plus adaptés à ce stockage spécifique d'énergie. Les matériaux choisis, Li4Ti5O12,
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Bulmer, John Simmons. "Temperature and Frequency Dependent Conduction Mechanisms Within Bulk Carbon Nanotube Materials." Wright State University / OhioLINK, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=wright1290546481.

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Rommel, Stefan Verfasser], Richard [Akademischer Betreuer] Weihrich, Arno [Akademischer Betreuer] [Pfitzner, and Frank-Michael [Akademischer Betreuer] Matysik. "Synthesis and characterization of nano- and microcrystalline ternary MAX-Materials (M = Ni, Co; A = Li, In, Sn, Pb, Tl; X = S, Se, PO4) Diffusion/Intercalation of metals into binaries as mechanism of formation and application as electrode materials / Stefan Rommel ; Richard Weihrich, Arno Pfitzner, Frank-Michael Matysik." Regensburg : Universitätsbibliothek Regensburg, 2016. http://d-nb.info/1130155153/34.

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Williams, Gareth R. "Cation-ordered layered double hydroxides : formation mechanisms, new materials, and intercalation chemistry." Thesis, University of Oxford, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.419434.

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Mortemard, de boisse Benoit. "Etudes structurales et électrochimiques des matériaux NaxMn1-yFeyO2 et NaNiO2 en tant qu’électrode positive de batteries Na-ion." Thesis, Bordeaux, 2014. http://www.theses.fr/2014BORD0370/document.

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Ce travail présente les études électrochimiques et structurales menées sur deux systèmes : P2/O3-NaxMn1-yFeyO2 et O’3-NaxNiO2 utilisés en tant que matériaux d’électrode positive pour batteries Na-ion.Concernant le système P2/O3-NaxMn1-yFeyO2, l’étude par diffraction des rayons X menée in situ pendantla charge de batteries a montré de nombreuses transitions structurales. Que leur structure soit de type P2ou O3, les matériaux présentent une phase distordue pour les taux d’intercalation (x) les plus élevés etune phase très peu ordonnée pour les taux d’intercalation les moins élevés. Entre ces deu
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Léon, Pascale. "Etudes de relations structure-activite dans la serie des dimeres de 7h-pyridocarbazole, agents antitumoraux bis-intercalants de l'adn." Paris 6, 1987. http://www.theses.fr/1987PA066487.

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Jourdan, Muriel. "Les lésions abasiques de l'ADN : étude par RMN et interaction avec des drogues." Université Joseph Fourier (Grenoble ; 1971-2015), 1998. http://www.theses.fr/1998GRE10255.

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Notre travail s'inscrit dans le cadre de l'etude par resonance magnetique nucleaire (rmn) d'une des lesions majeures de l'adn : le site abasique. Celui-ci resulte de la perte d'une base nucleique conduisant a la formation du 2-desoxyribose ou de sa forme oxyde, la 2-desoxyribonolactone. La 2-desoxyribonolactone fait l'objet de nombreux travaux mais reste une lesion mal connue, tant d'un point de vue chimique, biologique que structural. Nous avons determine par rmn et modelisation moleculaire, la premiere structure d'un oligonucleotide contenant cette lesion. Par comparaison avec la structure d
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VILAREM, PUIG MARIE-JOSE. "Etude des mecanismes d'activite cytotoxique et moleculaire du bd-40, une aza-ellipticine douee de pouvoir antitumoral." Paris 6, 1987. http://www.theses.fr/1987PA066219.

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Demonchaux, Patrice. "Recherche d'agents radioprotecteurs : synthèse et mécanisme d'action de composés de type intercalant-aminothiol." Grenoble 1, 1988. http://www.theses.fr/1988GRE10016.

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Les intercalants utilises sont des amino-9 chloro-6 methoxy-2 acridines des amino-4 chloro-7 quinoleines et des amino-4 chloro-7 methyl-1 quinoleiniums sur lesquels ont ete introduites des chaines analogues a celles de la cysteamine et du wr 2727; etude de l'affinite de ces composes avec l'adn
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Book chapters on the topic "Intercalation mechanism"

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Andreev, A., K. Kirilov, V. Ivanova, L. Prahov, and E. Manova. "Catalytic Oxidation of Sulphide Ions on MoS2 by Intercalation Mechanism." In Chemical Physics of Intercalation II. Springer US, 1993. http://dx.doi.org/10.1007/978-1-4615-2850-0_42.

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Tontegode, Alexander Ya. "Intercalation by K, Cs, Ba, Pt, Si and C Atoms of the Graphite Monolayer on the Surface of Metals and its Mechanism." In Chemical Physics of Intercalation II. Springer US, 1993. http://dx.doi.org/10.1007/978-1-4615-2850-0_35.

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Kosova, N. V. "Mechanochemical Synthesis of Intercalation Lithium Transition-Metal Oxide Compounds: Some Aspects Of Mechanism." In New Trends in Intercalation Compounds for Energy Storage. Springer Netherlands, 2002. http://dx.doi.org/10.1007/978-94-010-0389-6_39.

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Chen, Zhenlin, and Nanqi Huang. "Analysis of Failure Mechanism of Slopes with a Horizontal Weak Intercalation Under Earthquakes." In Advancing Culture of Living with Landslides. Springer International Publishing, 2017. http://dx.doi.org/10.1007/978-3-319-53498-5_77.

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Mukherjee, Arnab, Richard Lavery, Biman Bagchi, and James T. Hynes. "Simulation Study of the Molecular Mechanism of Intercalation of the Anti-Cancer Drug Daunomycin into DNA." In Springer Series in Chemical Physics. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-02306-4_7.

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Guérard, Daniel, and Philippe Lagrange. "Intercalation mechanisms in the polylayered ternary compounds of graphite with electron donors." In Chemical Physics of Intercalation. Springer US, 1987. http://dx.doi.org/10.1007/978-1-4757-9649-0_19.

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Giessen, B. C., and R. S. Markiewicz. "Description of the Tl, Pb and Bi Cuprate High-Tc Superconductors (HTSC’s) as Intercalation Compounds and Classification of all HTSC’s According to Doping Mechanism." In Superconductivity and Applications. Springer US, 1990. http://dx.doi.org/10.1007/978-1-4684-7565-4_33.

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Vikhrenko, V. S., G. S. Bokun, and Y. G. Groda. "Thermodynamics and Kinetics of Lattice Gases: Statistical Mechanics Perspective." In New Trends in Intercalation Compounds for Energy Storage. Springer Netherlands, 2002. http://dx.doi.org/10.1007/978-94-010-0389-6_66.

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Otter, Albin, Christopher C. Hanstock, George Kotovych, et al. "Molecular Recognition of DNA Binding Agents: High-Field 1H and 3 1P One- and Two-Dimensional NMR Studies on the 1:1 Intercalation Complexes of Mitoxantrone with Selected Oligodeoxyribonucleotides." In Mechanisms of DNA Damage and Repair. Springer US, 1986. http://dx.doi.org/10.1007/978-1-4615-9462-8_22.

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Imanishi, N., T. Horiuchi, A. Hirano, and Y. Takeda. "Lithium intercalation mechanism of iron cyanocomplex." In Studies in Surface Science and Catalysis. Elsevier, 2001. http://dx.doi.org/10.1016/s0167-2991(01)82240-0.

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Conference papers on the topic "Intercalation mechanism"

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Massey, Cameron, Geoffrey McKnight, Ping Liu, and William Barvosa-Carter. "Graphite Intercalation Compounds as Actuation Materials." In ASME 2004 International Mechanical Engineering Congress and Exposition. ASMEDC, 2004. http://dx.doi.org/10.1115/imece2004-61155.

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The intrinsic electrochemical behavior of Graphite Intercalated Compounds (GICs) during formation offers the potential for high-force, high-strain solid-state actuation applications. To explore this behavior we submitted a “model” system, highly-oriented pyrolytic graphite (HOPG)/sulfuric acid (H2SO4), to axial compressive loads from 0 to 8 MPa, and measured the intercalation response in terms of voltage and displacement. We observed strains greater than 30% between 2 and 6 MPa, confirming the potential of GIC formation as a viable actuating mechanism. Further studies are planned in order to p
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Yang, Shuting, Lijun Liu, and Qingzhang Lu. "Studies on Intercalation/Deintercalation Mechanism of High Polymer Modified Graphite Anode for Lithium Ion Battery." In Proceedings of the 7th Asian Conference. WORLD SCIENTIFIC, 2000. http://dx.doi.org/10.1142/9789812791979_0057.

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Geier, Sebastian M., Peter Wierach, Thorsten Mahrholz, and Michael Sinapius. "Polypyrrole-Coated Carbon Nanotube-Arrays: The Missing Link Between Bucky-Paper Actuation and CNT-Array Actuation." In ASME 2017 Conference on Smart Materials, Adaptive Structures and Intelligent Systems. American Society of Mechanical Engineers, 2017. http://dx.doi.org/10.1115/smasis2017-3975.

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The actuation mechanisms of cnt-based materials are still controversially discussed. It is not common sense whether it is a macroscopic volume effect caused by ion intercalation or electrostatic repulsion of equally charged cnts or a nanoscopic effect of filled electron anti-bonding orbitals of the carbon atom or interactions with ions docking on the carbon surface. In the presented paper arrays of highly aligned multi-walled carbon nanotubes (mwcnts) are used which are stabilized by a polypyrrole-coating. The samples are tested along the cnt-orientation and in perpendicular mode to analyze th
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Heckner, Karl H., and Annette Rothe. "Intercalation mechanisms and time dependencies of work parameters of electrochromic layers." In Optical Materials Technology for Energy Efficiency and Solar Energy Conversion XIII, edited by Volker Wittwer, Claes G. Granqvist, and Carl M. Lampert. SPIE, 1994. http://dx.doi.org/10.1117/12.185432.

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Senderovich, Shai, David Jones, Alfred Ajami, and Fiona McLaughlin. "Abstract 3665: The novel DNA intercalator amonafide (AS1413), disrupts the cell cycle by mechanisms distinct from those of Topo II inhibitors daunorubicin and etoposide." In Proceedings: AACR 101st Annual Meeting 2010‐‐ Apr 17‐21, 2010; Washington, DC. American Association for Cancer Research, 2010. http://dx.doi.org/10.1158/1538-7445.am10-3665.

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