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Journal articles on the topic 'Interphase'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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1

Ghasem Zadeh Khorasani, Media, Anna-Maria Elert, Vasile-Dan Hodoroaba та ін. "Short- and Long-Range Mechanical and Chemical Interphases Caused by Interaction of Boehmite (γ-AlOOH) with Anhydride-Cured Epoxy Resins". Nanomaterials 9, № 6 (2019): 853. http://dx.doi.org/10.3390/nano9060853.

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Understanding the interaction between boehmite and epoxy and the formation of their interphases with different mechanical and chemical structures is crucial to predict and optimize the properties of epoxy-boehmite nanocomposites. Probing the interfacial properties with atomic force microscopy (AFM)-based methods, especially particle-matrix long-range interactions, is challenging. This is due to size limitations of various analytical methods in resolving nanoparticles and their interphases, the overlap of interphases, and the effect of buried particles that prevent the accurate interphase prope

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Lee, Sang Jin, Chung Hyo Lee, and Jong Hee Hwang. "Toughening of Ceramic Composite Designed by Silica-Based Transformation Weakening Interphases." Key Engineering Materials 287 (June 2005): 358–66. http://dx.doi.org/10.4028/www.scientific.net/kem.287.358.

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A new concept for achieving graceful failure in oxide composites is introduced. It is based on crack deflection in a weak interphase between a matrix and reinforcement (e.g. fiber), or in a laminated composite. The interphase can be phase transformation weakened by volume contraction and/or unit cell shape change. Microcracking induced by a displacive, crystallographic phase transformation in silica-based interphases resulted in increase in the toughness of the bulk composites. In the present study, mullite/cordierite laminates with b®a-cristobalite (SiO2) transformation weakened interphase, a

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3

Wang, Meng, and Xiaochen Hang. "Finite Element Analysis of Residual Stress Distribution Patterns of Prestressed Composites Considering Interphases." Materials 16, no. 4 (2023): 1345. http://dx.doi.org/10.3390/ma16041345.

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New finite element analysis procedures are developed in this study to obtain the precise stress distribution patterns of prestressed composites. Within the FEM procedures, an equivalent thermal method is modified to realize the prestress application, and a multi-step methodology is developed to consider coupling effects of polymer curing and prestress application. Thereafter, the effects of interphases’ properties, including the elastic modulus and coefficient of thermal expansion (CTE), on the stress distribution patterns are revealed. Analytical methods for residual stress prediction are mod

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Ferrara, Chiara, Riccardo Ruffo, and Piercarlo Mustarelli. "The Importance of Interphases in Energy Storage Devices: Methods and Strategies to Investigate and Control Interfacial Processes." Physchem 1, no. 1 (2021): 26–44. http://dx.doi.org/10.3390/physchem1010003.

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Extended interphases are playing an increasingly important role in electrochemical energy storage devices and, in particular, in lithium-ion and lithium metal batteries. With this in mind we initially address the differences between the concepts of interface and interphase. After that, we discuss in detail the mechanisms of solid electrolyte interphase (SEI) formation in Li-ion batteries. Then, we analyze the methods for interphase characterization, with emphasis put on in-situ and operando approaches. Finally, we look at the near future by addressing the issues underlying the lithium metal/el

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Bian, L. C., W. Liu, and J. Pan. "Probability of Debonding and Effective Elastic Properties of Particle-Reinforced Composites." Journal of Mechanics 33, no. 6 (2017): 789–96. http://dx.doi.org/10.1017/jmech.2017.4.

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AbstractIn this paper, the effective properties of particle-reinforced composites with a weakened interphase are investigated. The particle and interphase are regarded as an equivalent-inclusion, and the interphase zone around the particle is modeled as a linear elastic spring layer. A modified micro-mechanics model is proposed to obtain the effective elastic modulus. Moreover, a statistical debonding criterion is proposed to characterize the varying probability of the evolution of interphase debonding. Numerical examples are considered to illustrate the effect of imperfect interphases on the

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Lee, Sang Jin, and Sang Ho Lee. "High-Toughening Alumina Composites Weakened by Metastable Hexacelsian Interphases." Key Engineering Materials 345-346 (August 2007): 721–24. http://dx.doi.org/10.4028/www.scientific.net/kem.345-346.721.

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New laminate design for improved toughness in hexacelsian-alumina composite is introduced. The composite is based on crack deflection in a weak interphase in the alumina matrix and hexacelsian interphase. The strength and toughness of the laminated composite were studied both qualitatively by electronic microscopy and measuring flexure strength. The metastable hexacelsian interphases had partially microcracks to provide crack deflection in the composite, and the crack deflection noticeably proceeded along the meta-stable hexacelsian interphase. Load-deflection curve for the laminate showed imp

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7

Yoshida, Katsumi, Hiroyuki Akimoto, Akihiro Yamauchi, Toyohiko Yano, Masaki Kotani, and Toshio Ogasawara. "Interface Formation of Unidirectional SiC_f/SiC Composites by Electrophoretic Deposition Method." Key Engineering Materials 617 (June 2014): 213–16. http://dx.doi.org/10.4028/www.scientific.net/kem.617.213.

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C-and BN-interphases on SiC fibers for unidirectional SiCf/SiC composites were formed by EPD process, and their microstructure and mechanical properties were investigated. Whereas the C-SiCf/SiC composites showed a pseudo-ductile fracture behavior with large amount of fiber pullout, the BN-SiCf/SiC composites fractured in a brittle manner without fiber pullout in spite of sufficient thickness of BN interphase. It is inferred from the results of EDS that sintering additives would react with h-BN-interphase, and the interphase did not act effectively for toughening the SiCf/SiC composites.

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El Khoury, Diana, Richard Arinero, Jean-Charles Laurentie, Mikhaël Bechelany, Michel Ramonda, and Jérôme Castellon. "Electrostatic force microscopy for the accurate characterization of interphases in nanocomposites." Beilstein Journal of Nanotechnology 9 (December 7, 2018): 2999–3012. http://dx.doi.org/10.3762/bjnano.9.279.

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The unusual properties of nanocomposites are commonly explained by the structure of their interphase. Therefore, these nanoscale interphase regions need to be precisely characterized; however, the existing high resolution experimental methods have not been reliably adapted to this purpose. Electrostatic force microscopy (EFM) represents a promising technique to fulfill this objective, although no complete and accurate interphase study has been published to date and EFM signal interpretation is not straightforward. The aim of this work was to establish accurate EFM signal analysis methods to in

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9

Sancaktar, E., and P. Zhang. "Nonlinear Viscoelastic Modelling of the Fiber-Matrix Interphase in Composite Materials." Journal of Mechanical Design 112, no. 4 (1990): 605–19. http://dx.doi.org/10.1115/1.2912653.

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A nonlinear viscoelastic analysis of the carbon fiber-thermoset (or thermoplastic) matrix interphase is presented. The second order nonlinear partial differential equation governing the state of stress at the fiber-matrix interphase is solved by using an iterative scheme involving successive differentiation and Taylor expansions to satisfy the boundary conditions. Additional iteration is used for the case with nonlinear viscoelastic matrix material. The results reveal that the thickness and material properties of the interphase have strong influence in reducing the shear stress magnitudes and

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Singh, Manohar, and Jeewan Chandra Pandey. "Probing thermal conductivity of interphase in epoxy alumina nanocomposites." Polymers and Polymer Composites 30 (January 2022): 096739112210774. http://dx.doi.org/10.1177/09673911221077489.

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The objective of this research is to determine the thermal conductivity of the interphase in epoxy alumina nanocomposites. First, TPS 500 measures the thermal conductivity of epoxy alumina nanocomposite samples. Following that, a numerical model based on the finite element method was developed to estimate the effective thermal conductivity of epoxy alumina nanocomposites over a range of assumed interphase thermal conductivity values. Finally, an algorithm is devised to extract the interphase’s thermal conductivity by combining simulation and experiment results. Interphase was found to have sig

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11

Liu, Y. J., N. Xu, and J. F. Luo. "Modeling of Interphases in Fiber-Reinforced Composites Under Transverse Loading Using the Boundary Element Method." Journal of Applied Mechanics 67, no. 1 (1999): 41–49. http://dx.doi.org/10.1115/1.321150.

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In this paper, interphases in unidirectional fiber-reinforced composites under transverse loading are modeled by an advanced boundary element method based on the elasticity theory. The interphases are regarded as elastic layers between the fiber and matrix, as opposed to the spring-like models in the boundary element method literature. Both cylinder and square unit cell models of the fiber-interphase-matrix systems are considered. The effects of varying the modulus and thickness (including nonuniform thickness) of the interphases with different fiber volume fractions are investigated. Numerica

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12

Han, Yupei, Ajay Piriya Vijaya Kumar Saroja, Henry R. Tinker, and Yang Xu. "Interphases in the electrodes of potassium ion batteries." Journal of Physics: Materials 5, no. 2 (2022): 022001. http://dx.doi.org/10.1088/2515-7639/ac5dce.

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Abstract Rechargeable potassium-ion batteries (PIBs) are of great interest as a sustainable, environmentally friendly, and cost-effective energy storage technology. The electrochemical performance of a PIB is closely related to the reaction kinetics of active materials, ionic/electronic transport, and the structural/electrochemical stability of cell components. Alongside the great effort devoted in discovering and optimising electrode materials, recent research unambiguously demonstrates the decisive role of the interphases that interconnect adjacent components in a PIB. Knowledge of interphas

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13

Hu, An Jun, and Yi Nuo Li. "A Muti-Functional Artificial Interphase for Dendrite-Free Lithium Deposition." Key Engineering Materials 939 (January 25, 2023): 129–33. http://dx.doi.org/10.4028/p-9s9iqu.

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The solid electrolyte interphase (SEI) is the most intimate component affecting Li deposition in lithium metal anode (LMA). In order to guarantee the safety of LMA, the unstable intrinsic SEI needs to be replaced by the functional artificial interphase (ASEI). Herein, tailoring the interphases for realizing substantially enhanced lithium plating/striping behaviors (over 120 cycles for Li||Cu cells) is presented. This favorable ASEI containing Li3N component is in-situ fabricated by cycling after hexagonal boron nitride (h-BN) were coated on the LMA surface.

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14

Bender, B. A., and T. L. Jessen. "A comparison of the interphase development and mechanical properties of Nicalon and Tyranno SiC fiber-reinforced ZrTiO4 matrix composites." Journal of Materials Research 9, no. 10 (1994): 2670–76. http://dx.doi.org/10.1557/jmr.1994.2670.

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The differences in interphase development and mechanical properties between Nicalon and Tyranno fiber-reinforced ZrTiO4 matrix composites were assessed. The composites were reinforced with either uncoated or BN-coated fibers. The microstructure and interphase development were analyzed using scanning electron microscopy, transmission electron microscopy, and analytical electron microscopy. Mechanical behavior was characterized by strength and toughness measurements. Tyranno composites developed thinner interphases due to the differences in the structure and chemistry of the starting fiber resul

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El Khoury, D., V. Fedorenko, J. Castellon, et al. "Characterization of Dielectric Nanocomposites with Electrostatic Force Microscopy." Scanning 2017 (2017): 1–14. http://dx.doi.org/10.1155/2017/4198519.

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Nanocomposites physical properties unexplainable by general mixture laws are usually supposed to be related to interphases, highly present at the nanoscale. The intrinsic dielectric constant of the interphase and its volume need to be considered in the prediction of the effective permittivity of nanodielectrics, for example. The electrostatic force microscope (EFM) constitutes a promising technique to probe interphases locally. This work reports theoretical finite-elements simulations and experimental measurements to interpret EFM signals in front of nanocomposites with the aim of detecting an

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16

Khanna, Sanjeev K., P. Ranganathan, S. B. Yedla, R. M. Winter, and K. Paruchuri. "Investigation of Nanomechanical Properties of the Interphase in a Glass Fiber Reinforced Polyester Composite Using Nanoindentation." Journal of Engineering Materials and Technology 125, no. 2 (2003): 90–96. http://dx.doi.org/10.1115/1.1543966.

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Glass fiber reinforced polymer composites are widely used as structural materials. These two-component materials can be tailored to suit a large variety of applications. A better understanding of the properties of the fiber-matrix “interphase” can facilitate optimum design of the composite structure. The interphase is a microscopic region around the fiber and hence nano-scale investigation using nano-indentation techniques is appropriate to determine mechanical property variations within this region. In this study the atomic force microscope adapted with a commercial nanoindenter has been used

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17

Benveniste, Y., and G. Baum. "An interface model of a graded three-dimensional anisotropic curved interphase." Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences 463, no. 2078 (2006): 419–34. http://dx.doi.org/10.1098/rspa.2006.1777.

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A three-dimensional, generally curved, constant thickness interphase whose properties vary across its thickness is considered. This graded interphase is modelled by an interface that is located at its mid-surface and which comes now into direct contact with the media that were adjacent to it. The derivation is carried out in the setting of heat conduction, and appropriate jump conditions for the temperature and normal heat flux across the interface are derived, which characterize the interface model. The inhomogeneity of the interphase becomes a major motivation for its replacement by an inter

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Zanjani, Jamal Seyyed Monfared, and Ismet Baran. "Co-Bonded Hybrid Thermoplastic-Thermoset Composite Interphase: Process-Microstructure-Property Correlation." Materials 14, no. 2 (2021): 291. http://dx.doi.org/10.3390/ma14020291.

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Co-bonding is an effective joining method for fiber-reinforced composites in which a prefabricated part bonds with a thermoset resin during the curing process. Manufacturing of co-bonded thermoset-thermoplastic hybrid composites is a challenging task due to the complexities of the interdiffusion of reactive thermoset resin and thermoplastic polymer at the interface between two plies. Herein, the interphase properties of co-bonded acrylonitrile butadiene styrene thermoplastic to unsaturated polyester thermoset are investigated for different processing conditions. The effect of processing temper

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Zanjani, Jamal Seyyed Monfared, and Ismet Baran. "Co-Bonded Hybrid Thermoplastic-Thermoset Composite Interphase: Process-Microstructure-Property Correlation." Materials 14, no. 2 (2021): 291. http://dx.doi.org/10.3390/ma14020291.

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Co-bonding is an effective joining method for fiber-reinforced composites in which a prefabricated part bonds with a thermoset resin during the curing process. Manufacturing of co-bonded thermoset-thermoplastic hybrid composites is a challenging task due to the complexities of the interdiffusion of reactive thermoset resin and thermoplastic polymer at the interface between two plies. Herein, the interphase properties of co-bonded acrylonitrile butadiene styrene thermoplastic to unsaturated polyester thermoset are investigated for different processing conditions. The effect of processing temper

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20

Yang, Yang, Qi He, Hong-Liang Dai, et al. "Micromechanics-based analyses of short fiber-reinforced composites with functionally graded interphases." Journal of Composite Materials 54, no. 8 (2019): 1031–48. http://dx.doi.org/10.1177/0021998319873033.

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A micromechanical model for short fiber-reinforced composites (SFRCs) with functionally graded interphases and a systematic prediction scheme to determine the effective properties are presented. The matrix and the fibers are regarded to be linear elastic, isotropic, and homogeneous. Fibers are assumed to be ellipsoids coated perfectly by functionally graded interphases, which is supposed to be formed chemically or physically by the constituents near the interface. First, to analyze the grading interphase effect, layer-wise concept is followed to divide the functionally graded interphases into

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21

Yang, Xiao-Qing. "(Invited) An Inorganic-Rich but Low Lif Content Interphase for Fast Charging and Long Cycle Life Lithium Metal Batteries As Well As Evolution and Interplay of Lithium Metal Interphase Components." ECS Meeting Abstracts MA2024-02, no. 2 (2024): 286. https://doi.org/10.1149/ma2024-022286mtgabs.

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The first part of this presentation will be focused on An Inorganic-rich but No LiF Interphase for Fast Charging and Long Cycle Life Lithium Metal Batteries. Li metal battery (LMB) with Li metal anode and LiNi1-x-yMnxCoyO2 (NMC) cathode represents the next generation high energy density electrochemical energy storage devices. A major challenge facing LMB is finding an electrolyte that is capable of forming good interphases and enabling stable cycling. A common practice is fluorinating the electrolyte to generate anion-derived interphase rich in LiF. Electrolytes based on this strategy can lead

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Hernández-Díaz, David, Ricardo Villar-Ribera, Fernando Julián, Quim Tarrés, Francesc X. Espinach, and Marc Delgado-Aguilar. "Topography of the Interfacial Shear Strength and the Mean Intrinsic Tensile Strength of Hemp Fibers as a Reinforcement of Polypropylene." Materials 13, no. 4 (2020): 1012. http://dx.doi.org/10.3390/ma13041012.

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The strength of the interphase between the reinforcements and the matrix has a major role in the mechanical properties of natural fiber reinforced polyolefin composites. The creation of strong interphases is hindered by the hydrophobic and hydrophilic natures of the matrix and the reinforcements, respectively. Adding coupling agents has been a common strategy to solve this problem. Nonetheless, a correct dosage of such coupling agents is important to, on the one hand guarantee strong interphases and high tensile strengths, and on the other hand ensure a full exploitation of the strengthening c

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Vallat, M. F., S. Giami, and A. Coupard. "Elastomer-Elastomer Autohesion-Interphase Gradient of Elastic Modulus." Rubber Chemistry and Technology 72, no. 4 (1999): 701–11. http://dx.doi.org/10.5254/1.3538827.

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Abstract The effect of migration on the vulcanizing ingredients is considered when two sheets of carbon black reinforced polyisoprene are brought into contact. Two formulations (conventional and efficient ones) are chosen. The formation of macroscopic interphases on both sides of the interface is shown by measurements of local modulus by microindentation. The local concentration of sulfur is determined by energy dispersive X-ray analysis. Near the interface, the modulus is always higher than in the bulk of the sheets although the interfacial strength may be quite low. Co-crosslinking of the ch

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Vattathurvalappil, Suhail Hyder, Mahmoodul Haq, and Saratchandra Kundurthi. "Hybrid nanocomposites—An efficient representative volume element formulation with interface properties." Polymers and Polymer Composites 30 (January 2022): 096739112210846. http://dx.doi.org/10.1177/09673911221084651.

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Reinforcement of polymers with multiple inclusions of varying length scales and morphologies enable enhancement and tailorability of thermo-mechanical properties in resulting polymers. Computational material models can eliminate the trial-and-error approach of developing these hybrid reinforced polymers, enable prediction of interphase properties, and allow virtual exploration of design space. In this work, computational models, specifically representative volume elements were developed for acrylonitrile butadiene styrene polymer reinforced with nanoscale iron oxide particles and micro-scale s

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Lopez, Jeffrey. "Stabilizing Lithium Metal Anode and Conversion Cathode Interphases for High Energy Density Batteries." ECS Meeting Abstracts MA2024-02, no. 7 (2024): 801. https://doi.org/10.1149/ma2024-027801mtgabs.

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Lithium metal batteries offer great promise for higher energy density, but are presently limited by significant side reactions, poor quality deposition, and the potential to form hazardous dendrites. This is especially true when paired with conversion cathodes, which could potentially result in cells with specific energy > 700 Wh/kg. In this presentation, recent advances made toward high energy full cells will be discussed. A particular emphasis will be placed on the electrode-electrolyte interphases that form in these devices in high performance localized high concentration electrolytes (L

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Ko, Youngmin, Michael Baird, and Brett Helms. "Interphase Design by Localized Super-Concentrated Electrolyte for High-Voltage and High-Power Lithium Metal Batteries." ECS Meeting Abstracts MA2023-01, no. 2 (2023): 642. http://dx.doi.org/10.1149/ma2023-012642mtgabs.

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Batteries used in electric aircraft must deliver high-power on take-off and landing, providing in stride the ability to recharge at high voltage to make full use of the cathode capacity. Impedance rise associated with electrode–electrolyte interphases remains problematic with conventional electrolytes, resulting in unacceptable power fade. This is exacerbated when recharging cells at high voltage, which is where interphase generation remains poorly controlled. To address these issues, electrolyte design for high-voltage and high-power batteries should emphasize control over the interphase grow

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Geiss, Paul Ludwig, and Melanie Schumann. "Polymer Interphases in Adhesively Bonded Joints – Origin, Properties and Methods for Characterization." Materials Science Forum 941 (December 2018): 2249–54. http://dx.doi.org/10.4028/www.scientific.net/msf.941.2249.

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Chemically curing adhesives are formulations requiring reactions to convert from liquid to solid. Once cured, these adhesives carry the potential to create strong load bearing joints, resisting even severe detrimental service conditions. In adhesively bonded joints with chemically curing adhesives the term "interphase" relates to the adhesive volume adjacent to the surface of the adherent (interface), which generally will exhibit properties different from those of the adhesive bulk polymer. The properties of these interphases play an important role concerning the performance and durability of

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Borges, Catarina S. P., Eduardo A. S. Marques, Ricardo J. C. Carbas, et al. "Effect of the Interface/Interphase on the Water Ingress Properties of Joints with PBT-GF30 and Aluminum Substrates Using Silicone Adhesive." Polymers 15, no. 4 (2023): 788. http://dx.doi.org/10.3390/polym15040788.

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The aim of this work is to analyze the difference between silicone/composite and silicone/metal interphases, both in terms of water diffusion behavior and failure of the aged joints. For that, silicone joints with two different suhbstrates were prepared. The substrates were polybutylene terephthalate with 30% of short glass fiber (PBT-GF30) and 6082-T6 aluminum. It is assumed that the water uptake of the joints is equal to the water uptake of the substrate, adhesive, and interphase. Therefore, knowing the first three, the last could be isolated. To study the water diffusion behavior of the com

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ISHIDA, HATSUO. "Interphase Engineering." Sen'i Gakkaishi 44, no. 2 (1988): P56—P60. http://dx.doi.org/10.2115/fiber.44.2_p56.

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Herrington, C. S., and J. O. McGee. "Interphase cytogenetics." Neurochemical Research 15, no. 4 (1990): 467–74. http://dx.doi.org/10.1007/bf00969934.

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Rosy and Malachi Noked. "Multifunctional interphase." Nature Energy 3, no. 4 (2018): 253–54. http://dx.doi.org/10.1038/s41560-018-0114-3.

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Stanley, Michael W. "Interphase Cytogenetics." Advances in Anatomic Pathology 2, no. 3 (1995): 176–80. http://dx.doi.org/10.1097/00125480-199505000-00006.

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Kim, Jung-Hyun. "(Invited) Strategies for Enhancing the Stability of the Electrode-Electrolyte Interphase in Sulfide-Based Solid-State Batteries." ECS Meeting Abstracts MA2023-02, no. 1 (2023): 70. http://dx.doi.org/10.1149/ma2023-02170mtgabs.

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In recent years, all solid-state batteries (SSBs) have gained significant attention as the next-generation energy storage device due to their high energy density, improved safety, and enhanced stability. Sulfide-based solid electrolytes (SEs) have garnered significant attention among various inorganic materials for their exceptional properties, including high ionic conductivity and robust mechanical properties. These features make them promising candidates for SSBs, ensuring both manufacturability and long-term cycle life. For example, Li-argyrodites (e.g., Li6PS5X, and X = Cl, Br, I) and Na-t

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Baumgartner, Adi, Christy Ferlatte Hartshorne, Aris A. Polyzos, Heinz-Ulrich G. Weier, Jingly Fung Weier, and Ben O’Brien. "Full Karyotype Interphase Cell Analysis." Journal of Histochemistry & Cytochemistry 66, no. 8 (2018): 595–606. http://dx.doi.org/10.1369/0022155418771613.

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Aneuploidy seems to play not only a decisive role in embryonal development but also in tumorigenesis where chromosomal and genomic instability reflect a universal feature of malignant tumors. The cost of whole genome sequencing has fallen significantly, but it is still prohibitive for many institutions and clinical settings. No applied, cost-effective, and efficient technique has been introduced yet aiming at research to assess the ploidy status of all 24 different human chromosomes in interphases simultaneously, especially in single cells. Here, we present the selection of human probe DNA and

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Liu, Ziqi, and Jeffrey Lopez. "Operando FTIR Characterization of Interphases from Organosulfur Electrolytes in High Voltage Lithium-Ion Batteries." ECS Meeting Abstracts MA2024-02, no. 7 (2024): 943. https://doi.org/10.1149/ma2024-027943mtgabs.

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The widespread adoption of renewable energy storage technologies like electric vehicles and grid storage largely relies on the improvements of the energy density of the batteries inside those devices. Lithium-ion batteries (LIBs) are typically used for these applications due to their high energy density,[1] but the operating voltage of LIBs is limited by the electrochemical stability windows of the electrolyte. Resistive interphase layers form as a result of the breakdown of electrolyte molecules and limit LIB cycling stability. However, there is significant difficulty in the study and charact

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Saber-Samandari, Saeed, and Akbar Afaghi Khatibi. "The Effect of Interphase on the Elastic Modulus of Polymer Based Nanocomposites." Key Engineering Materials 312 (June 2006): 199–204. http://dx.doi.org/10.4028/www.scientific.net/kem.312.199.

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The elastic modulus of interphase in polymer based nanocomposites is investigated. A new three-dimensional unit cell model has been developed for modeling three constituent phases including particle, interphase and matrix. The elastic modulus of the interphase as a function of radius is then evaluated with the help of mathematical models. The average value of interphase elastic modulus is defined and the effect of interphase thickness and particle and matrix elastic modulus on interphase is investigated.

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Mikata, Yozo. "Stress Fields in a Continuous Fiber Composite With a Variable Interphase Under Thermo-Mechanical Loadings." Journal of Engineering Materials and Technology 116, no. 3 (1994): 367–77. http://dx.doi.org/10.1115/1.2904300.

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Stress fields in a continuous fiber composite with a variable interphase subjected to thermomechanical loadings are studied by using a four concentric circular cylinders model. An exact closed form solution is obtained for the stress field in the interphase in a series form using Frobenius method in a certain case. Numerical results are presented for FP fiber/Al 6061 composite with interphase, and carbon fiber/Al 6061 composite with interphase. It is found that the variableness of the thermoelastic constants in the interphase has significant effects on the stress distributions in the interphas

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Chen, Hsun-Yi, and Cindy Rusly. "Enhancing Performance of Lithium Sulfur Batteries with Electrode-Electrolyte Interphase Engineering." ECS Meeting Abstracts MA2024-02, no. 7 (2024): 1044. https://doi.org/10.1149/ma2024-0271044mtgabs.

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Batteries with high energy density are critical for the clean energy transition of human society. Lithium sulfur (Li-S) batteries with a high theoretical energy capacity is promising for applications such as electric vehicles. However, the commercialization obstacle of Li-S batteries lies on the shuttle effects of dissolved sulfur intermediates and formation of Li dendrite. In this work, we focus on engineering the electrode-electrolyte interphase with functionalized interlayers for enhanced performance of Li-S batteries. In particular, an amide-functionalized protection layer and a cellulose-

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Moradienayat, Monireh, Dania Olmos, and Javier González-Benito. "Airbrushed Polysulfone (PSF)/Hydroxyapatite (HA) Nanocomposites: Effect of the Presence of Nanoparticles on Mechanical Behavior." Polymers 14, no. 4 (2022): 753. http://dx.doi.org/10.3390/polym14040753.

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Nanocomposite films of polysulfone (PSF)—hydroxyapatite (HA) were prepared with a commercial airbrush. Structural, thermal, and mechanical characterization allows obtaining new information to understand the role of the nanofiller–polymer matrix interphase in the final performance of these materials in relation to its possible applications in the restoration of bones. Fourier-transform infrared spectroscopy shows that there are hardly any structural changes in the polymer when adding HA particles. From thermal analysis (differential scanning calorimetry and thermogravimetry), it can be highligh

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Tepavcevic, Sanja, Michael Counihan, Jungkuk Lee, et al. "Advancing Li-Transport in Composite Polymer Electrolytes with Functionalized LLZO Nanoparticles." ECS Meeting Abstracts MA2024-02, no. 8 (2024): 1145. https://doi.org/10.1149/ma2024-0281145mtgabs.

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The combination of Li+-conducting ceramics and polymers offers a new pathway to create better electrolytes for solid state batteries with both high ionic conductivity and good (electro)mechanical interfacial properties. Achieving synergy in Li transport between ion-conducting ceramic and polymer in a composite electrolyte has been proven to be difficult. The total Li-ion conductivity of the composite polymer electrolytes is still governed by the polymer matrix due to high interfacial resistance between the garnet particles and the PEO/LiTFSI matrix. We modeled our composite electrolytes with t

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Wang, Jian Fen, Matthias Weiling, Felix Pfeiffer, and Masoud Baghernejad. "Unveiling the Interfacial Composition of Li-Metal | Polymer Electrolytes during Lithium Plating-Stripping Employing Operando ATR-FTIR Spectroscopy." ECS Meeting Abstracts MA2024-02, no. 8 (2024): 1135. https://doi.org/10.1149/ma2024-0281135mtgabs.

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The Li-metal interphases formed in contact with solid-state (polymer) electrolytes (SSE) during electrochemical plating and stripping influences remarkably the lifespan and safety of solid-state batteries (SSBs). Effective interphases play a crucial role in impeding the continuous decomposition of electrolytes, the growth of dendrites, and consequently, enhancing the overall battery performance. However, the investigation of interphases of solid electrolytes remains a challenge, necessitating development of advanced techniques and methodologies. Moreover, highly sensitive instruments are deman

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Zhu, Da Sheng, and Bo Qin Gu. "Micromechanical Analysis of Single-Fiber Pull-Out Test of Fiber-Reinforced Viscoelastic Matrix Composites." Advanced Materials Research 399-401 (November 2011): 556–60. http://dx.doi.org/10.4028/www.scientific.net/amr.399-401.556.

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A micromechanical model for single-fiber pull-out test of fiber-reinforced viscoelastic matrix composites is established. It includes fiber, interphase and viscoelastic matrix. The formulas to calculate the fiber axial stress, the interphase shear stress, and the matrix axial and shear stress are obtained. Moreover, for Kevlar aramid fiber reinforced viscoelastic matrix composites, the influences of the interphase thickness, the fiber embedded length and volume fraction on the stress distributions of fiber and interphase is studied. Some analysis results show that, with the increase of normali

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Achenbach, J. D., and H. Zhu. "Effect of Interphases on Micro and Macromechanical Behavior of Hexagonal-Array Fiber Composites." Journal of Applied Mechanics 57, no. 4 (1990): 956–63. http://dx.doi.org/10.1115/1.2897667.

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The effect of interphase stiffness on microstresses and macromechanical behavior has been investigated for transverse loading of an hexagonal-array unidirectional fiber composite. The interphase is modeled by a layer which resists radial extension and circumferential shear deformation. Taking advantage of the periodicity of the medium, the states of stress, and deformation in a basic cell have been analyzed numerically by the use of the boundary element method. The circumferential tensile stress along the matrix side of the interphase and the radial stress in the interphase have been analyzed

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Chan, I. Tung, Tung Yang Chen, and Min Sen Chiu. "The Influence of Torsional-Rigidity Bounds for Composite Shafts with Specific Cross-Sections." Key Engineering Materials 462-463 (January 2011): 674–79. http://dx.doi.org/10.4028/www.scientific.net/kem.462-463.674.

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We consider the Saint-Venant torsion problem of composite shafts. Two different kinds of imperfect interfaces are considered. One models a thin interphase of low shear modulus and the other models a thin interphase of high shear modulus. The imperfect interfaces are characterized by parameters given in terms of the thickness and shear modulus of the interphases. Using variational principles, we derive rigorous bounds for the torsional rigidity of composite shafts with cross-sections of arbitrary shapes. The analysis is based on the construction of admissible fields in the inclusions and in the

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Zare, Yasser, and Kyong Yop Rhee. "Analysis of the Connecting Effectiveness of the Interphase Zone on the Tensile Properties of Carbon Nanotubes (CNT) Reinforced Nanocomposite." Polymers 12, no. 4 (2020): 896. http://dx.doi.org/10.3390/polym12040896.

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The establishment of interphase region around nanoparticles accelerates the percolating of carbon nanotubes (CNT) in polymer nanocomposites reinforced with CNT (PCNT), due to the linking productivity of interphase district before the physical connecting of nanoparticles. Therefore, the interphase is an important character in the networks of CNT in PCNT. Here, a simulation study is presented to investigate the interphase connection in the mechanical possessions of PCNT including tensile modulus and strength. A number of models comprising Takayanagi, Ouali, Pukanszky and Callister are developed

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Yu, Xiao Ming, Bin Zhang, Jia Min Shen, Yue Li, and Sai Sai Liu. "Simulation and Analysis on Fiber Reinforced Rubber Matrix Sealing Composite Based on Cohesive Zone Model." Materials Science Forum 953 (May 2019): 65–71. http://dx.doi.org/10.4028/www.scientific.net/msf.953.65.

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A finite element model on the single fiber pull-out test of short fiber reinforced rubber matrix sealing composites (SFRC) were established. The effects of the interphase properties on the interfacial stress distribution and initial debonding strain are investigated based on the cohesive zone model (CZM). The influences of interphase thicknesses and elastic modulus on the interfacial debonding behavior of SFRC are obtained. The results show that the interfacial initial debonding strain increases with the increasement of interphase thickness, and it decreases with the increasement of interphase

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Chang, Yan Jun, Zhuo Li, and Ke Shi Zhang. "Damage Evolution of the Interphase on C/SiC Composites with CZM Method." Applied Mechanics and Materials 166-169 (May 2012): 2847–50. http://dx.doi.org/10.4028/www.scientific.net/amm.166-169.2847.

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Considering thermal residual stress and initial matrix crack, the cylinder FEM analysis model for C/SiC tow was established. The cohesive element and damage criterions were introduced to simulation the initiation and propagation of interphase crack processes of C/SiC composites. The thermal residual stresses release with the initial matrix crack and the cracking on interphase. The interphase crack length was dominated by the performance of interphase. Analysis demonstrated that the CZM model can simulate well the thermal residual stress and the delamination of the interphase.

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Zhang, Changjun. "Hydroxyl-enabled interphase." Nature Energy 7, no. 7 (2022): 566. http://dx.doi.org/10.1038/s41560-022-01090-x.

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LeBrasseur, Nicole. "Migrating interphase DNA." Journal of Cell Biology 173, no. 3 (2006): 317a. http://dx.doi.org/10.1083/jcb.1733rr1.

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Freunberger, Stefan A. "Interphase identity crisis." Nature Chemistry 11, no. 9 (2019): 761–63. http://dx.doi.org/10.1038/s41557-019-0311-0.

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