Academic literature on the topic 'Intramolecular cyclialkylation'

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Journal articles on the topic "Intramolecular cyclialkylation"

1

Ali, A. Khalaf, and A. Albar Hassan. "Modern Friedel-Crafts chemistry. Part-26. A facile synthesis of trans-2-methyl-1-phenylindan via rearranged intramolecular cyclialkylation of 1,2-diphenyl-2-methyl-2-propanol under Friedel-Crafts conditions." Journal of India Chemical Society Vol 81, Jun 2004 (2004): 518–21. https://doi.org/10.5281/zenodo.5833496.

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department of Chemistry, Faculty of Science, Assiut University, Assiut, Egypt <em>Fax</em> : 91-542-2307547 Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia <em>Manuscript received 28 January 2003. revised 28 October 2003, accepted 12 January 2004</em> 1,2-Diphenyl-2-methyl-2-propanol (1) was prepared by two alternative Grignard methods. Treatment of 1 with AICI<sub>3</sub>, AICI<sub>3</sub>/CH<sub>3</sub>NO<sub>2</sub> or K10&nbsp;&nbsp;clay catalyst in benzene, toluene or dichloromethane solvent at varying temperatures for varying times gave<em> tr
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2

El-Aal, Hassan A. K. Abd, and Ali A. Khalaf. "Friedel–Crafts Chemistry. Part 39. Unprecedented Facile Route to the Synthesis of Benzo[b][1]benzazepines via Intramolecular Friedel–Crafts Cyclialkylations." Australian Journal of Chemistry 66, no. 6 (2013): 635. http://dx.doi.org/10.1071/ch12548.

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A series of six pharmaceutically promising 5,6-dihydro-11H-benzo[b][1]benzazepine derivatives (1c–h) were cleanly prepared by Friedel–Crafts cyclialkylations of nitrogen-containing alkanols in the presence of AlCl3, 85 % H2SO4 or polyphosphoric acid catalysts. The precursor alkanols (13a–f) were readily prepared by reaction of two synthesized carboxylic acid esters (12a, b) with different Grignard reagents. Also, two dibenzo[b,f]azepinones (15a, b) were prepared by Friedel–Crafts cycliacylation and reduced to the corresponding 5,6-dihydro-11H-benzo[b][1]benzazepines (1a, b). Overall, this appr
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Abd El-Aal, Hassan Abdou Kotb, and Ali Ali Khalaf. "Modern Friedel-Crafts Chemistry. Part 38. Facile Synthesis of Acenaphthenes via Direct and Rearranged Intramolecular Friedel-Crafts Cyclialkylations of Intermediate Carbinols." Polycyclic Aromatic Compounds 33, no. 4 (2013): 331–46. http://dx.doi.org/10.1080/10406638.2013.781041.

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4

Abd El-Aal, Hassan A. K., and Ali A. Khalaf. "ChemInform Abstract: Friedel-Crafts Chemistry. Part 39. Unprecedented Facile Route to the Synthesis of Benzo[b][1]benzazepines via Intramolecular Friedel-Crafts Cyclialkylations." ChemInform 44, no. 52 (2013): no. http://dx.doi.org/10.1002/chin.201352197.

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5

"Friedel-Crafts chemistry. Part 55. Competing indan versus tetralin ring formations during Friedel-Crafts intramolecular cyclialkylations of some selected di-, tri- and tetraphenylated alkanols." Assiut University Journal of Multidisciplinary Scientific Research 47, no. 2 (2018): 66–80. http://dx.doi.org/10.21608/aunj.2018.221247.

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