Relevant bibliographies by topics / Intramolecular migration

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  1. Journal articles
  2. Dissertations / Theses
  3. Book chapters
  4. Conference papers

Academic literature on the topic 'Intramolecular migration'

Author: Grafiati
Published: 5 June 2025
Last updated: 1 August 2025

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Journal articles on the topic "Intramolecular migration"

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Yasui, Yoshizumi. "Intramolecular Palladium Migration." Journal of Synthetic Organic Chemistry, Japan 66, no. 3 (2008): 251–52. http://dx.doi.org/10.5059/yukigoseikyokaishi.66.251.

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Loncke, Paul G., Timothy A. Gadosy, and Gilles H. Peslherbe. "A theoretical study of the mechanism of 1,2-migrations in methoxysiloxycarbene." Canadian Journal of Chemistry 80, no. 3 (2002): 302–14. http://dx.doi.org/10.1139/v02-013.

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Intramolecular rearrangements of methoxysiloxycarbene (CH3OCOSiH3) have been investigated by means of ab initio molecular orbital theory and hybrid density functional theory calculations. Particular attention was paid to 1,2-silyl migration from oxygen to the carbene carbon, and to the analogous 1,2-methyl migration for comparison. A combination of frontier molecular orbital (FMO) theory, natural bond orbital (NBO) analysis, and the theory of atoms in molecules (AIM) were used to shed light on the mechanistic details of these rearrangements. The present analyses clearly indicate that 1,2-silyl
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Wang, Min, Zhen Wu, Bo Zhang, and Chen Zhu. "Azidoheteroarylation of unactivated olefins through distal heteroaryl migration." Organic Chemistry Frontiers 5, no. 12 (2018): 1896–99. http://dx.doi.org/10.1039/c8qo00301g.

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J. Poziomek, Edward, Shekhar Munavalli, and Fu-Lian Hsu. "Novel Intramolecular Nitrogen to Carbon Double Migration." HETEROCYCLES 26, no. 1 (1987): 23. http://dx.doi.org/10.3987/r-1987-01-0023.

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Ji, Meishan, Jiajia Yu, and Chen Zhu. "Cyanotrifluoromethylthiolation of unactivated dialkyl-substituted alkynes via cyano migration: synthesis of trifluoromethylthiolated acrylonitriles." Chemical Communications 54, no. 50 (2018): 6812–15. http://dx.doi.org/10.1039/c8cc01189c.

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Wang, Na, Jian Wang, Yu-Long Guo, et al. "Oximinotrifluoromethylation of unactivated alkenes under ambient conditions." Chemical Communications 54, no. 64 (2018): 8885–88. http://dx.doi.org/10.1039/c8cc05186k.

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Tasgin, Dilek Isik, and Canan Unaleroglu. "N-phosphorylation of pyrroles: An intramolecular migration reaction." Tetrahedron Letters 59, no. 20 (2018): 1955–57. http://dx.doi.org/10.1016/j.tetlet.2018.04.022.

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Ji, Meishan, Zhen Wu, Jiajia Yu, Xiaobing Wan, and Chen Zhu. "Cyanotrifluoromethylthiolation of Unactivated Olefins through Intramolecular Cyano Migration." Advanced Synthesis & Catalysis 359, no. 11 (2017): 1959–62. http://dx.doi.org/10.1002/adsc.201700218.

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Barisic, Damir, Jakob Lebon, Cäcilia Maichle-Mössmer, and Reiner Anwander. "Pentadienyl migration and abstraction in yttrium aluminabenzene complexes including a single-component catalyst for isoprene polymerization." Chemical Communications 55, no. 49 (2019): 7089–92. http://dx.doi.org/10.1039/c9cc02857a.

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Lee, Katarzyna N., Zhen Lei, Cristian A. Morales-Rivera, Peng Liu, and Ming-Yu Ngai. "Mechanistic studies on intramolecular C–H trifluoromethoxylation of (hetero)arenes via OCF3-migration." Organic & Biomolecular Chemistry 14, no. 24 (2016): 5599–605. http://dx.doi.org/10.1039/c6ob00132g.

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Dissertations / Theses on the topic "Intramolecular migration"

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Burke, Edmund William Dwerryhouse. "Isolation, identification and chemical modification of Narcissus alkaloids." Thesis, University of Manchester, 2016. https://www.research.manchester.ac.uk/portal/en/theses/isolation-identification-and-chemical-modification-of-narcissus-alkaloids(7fcf6ef2-c9da-4760-89ac-d275433e66dc).html.

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Galanthamine is one of only a few drugs that is licenced for the treatment of Alzheimer's disease. It is manufactured through an inefficient synthetic process or extracted from members of the Amaryllidaceae plant family. In this work a range of structurally related alkaloids was semisynthesised from galanthamine and used as standards to assist with the search for alkaloids that may make a good starting point in the semisynthesis of galanthamine. The search was targeted on the effluent from the production line of Alzeim Ltd., a company that extracted galanthamine from members of the Narcissus g
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Book chapters on the topic "Intramolecular migration"

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Hayashi, Yoshio, Yuri Yamazaki, Mariusz Skwarczynski, et al. "Application of Intramolecular Migration Reaction in Peptide Chemistry to Chemical Biology, Chemical Pharmaceutics and Medicinal Chemistry." In Advances in Experimental Medicine and Biology. Springer New York, 2009. http://dx.doi.org/10.1007/978-0-387-73657-0_223.

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Yamazaki, Takashi, Kenji Mizutani, and Tomoya Kitazume. "Efficient Synthetic Routes to Chiral 6-Deoxy-6,6,6-trifluorosugars via Intramolecular 1,2-O,O-Silyl Migration." In ACS Symposium Series. American Chemical Society, 1996. http://dx.doi.org/10.1021/bk-1996-0639.ch008.

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Zhang, L. "Intramolecular Acyl Migration." In Compounds of Groups 12 and 11 (Zn, Cd, Hg, Cu, Ag, Au). Georg Thieme Verlag KG, 2011. http://dx.doi.org/10.1055/sos-sd-103-00028.

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Harwood, Laurence M. "Electrophilic rearrangements." In Polar Rearrangements. Oxford University Press, 1992. http://dx.doi.org/10.1093/hesc/9780198556701.003.0005.

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This chapter deals with electrophilic rearrangements in which a group migrates formally as cationic species. It mentions the intramolecular electrophilic rearrangement which has four electrons involved in the transition state, of which one pair is accommodated in an antibonding orbital of the migrating species. It also describes the anionic migration terminus that acts as the nucleophile. The chapter considers the interaction of the highest occupied molecular orbital (HOMO) with the lowest unoccupied molecular orbital (LUMO) of the migrating group. The chapter analyses crossover experiments wh
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Harwood, Laurence M. "Acid catalysed aromatic rearrangements." In Polar Rearrangements. Oxford University Press, 1992. http://dx.doi.org/10.1093/hesc/9780198556701.003.0006.

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This chapter reviews arbitrary distinction to create the classification of aromatic rearrangements. It considers reactions that are initiated by the generation of an arenium ion and involve migration around the aromatic ring or from a side chain onto the aromatic nucleus. It also points out that the migration terminus positioned on an aromantic ring is initiated by protonation or by a Lewis acid, which is commonly a consequence of equilibration to form thermodynamically stable products. The chapter highlights intramolecular migration, which occurs via a π-complex that leads to equilibration be
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Taber, Douglass F. "The Nakada Synthesis of (-)-FR182877." In Organic Synthesis. Oxford University Press, 2013. http://dx.doi.org/10.1093/oso/9780199965724.003.0084.

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The Streptomyces metabolite (-)-FR182877 3 binds to and stabilizes microtubules, showing the same potency of anticancer activity as Taxol (paclitaxel). Masahisa Nakada of Waseda University assembled (Angew. Chem. Int. Ed. 2009, 48, 2580) the hexacyclic ring system of 3 by the tandem intramolecular Diels-Alder–intramolecular hetero Diels-Alder cyclization of 1, generating seven new stereogenic centers in a single step. The construction of the pentaene substrate 1 started with the known aldehyde 4, prepared by homologation of commercial ethyl 3-methyl-4-oxocrotonate. Addition of the propionyl ox
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Henderson, Richard A. "The insertion reaction." In The Mechanisms of Reactions at Transition Metal Sites. Oxford University Press, 1993. http://dx.doi.org/10.1093/hesc/9780198557463.003.0012.

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This chapter focuses on insertion reactions, wherein the overall effect of the reaction bears no relationship to the mechanism and is accomplished by a variety of small molecules. These reactions are most commonly achieved by sulfur dioxide, alkynes, alkenes, carbon monoxide, and nitric oxide, which can be inserted into metal-carbon bonds and metal-hydrogen bonds. The mechanistic description of the reaction is typically that of an intramolecular migration process. The chapter outlines the general principles of the mechanism in relationship to alkenes, carbon monoxide, and nitric oxide.
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Taber, Douglass F. "Intramolecular Diels-Alder Cycloaddition: 7-Isocyanoamphilecta- 11(20),15-diene (Miyaoka), (–)-Scabronine G (Kanoh), Basiliolide B (Stoltz), Hirsutellone B (Uchiro), Echinopine A (Chen)." In Organic Synthesis. Oxford University Press, 2015. http://dx.doi.org/10.1093/oso/9780190200794.003.0078.

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The amphilectane diterpenes, exemplified by 7-isocyanoamphilecta-11(20),15-diene 3, have been little investigated. In the course of a synthesis of 3, Hiroaki Miyaoka of the Tokyo University of Pharmacy and Life Sciences took advantage (Synlett 2011, 547) of the kinetic enolization and silylation of 1 to convert it into a trienone that spontaneously cyclized to 2. Scabronine G 6, isolated from the mushroom Sarcodon scabrosus, was found to enhance the secretion of neurotrophic factors from 1321N1 astrocytoma cells. To set the absolute configuration of the two quaternary centers that are 1, 4 on
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Taber, Douglass. "The Carter Synthesis of (-)-Lycopodine." In Organic Synthesis. Oxford University Press, 2011. http://dx.doi.org/10.1093/oso/9780199764549.003.0099.

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Rich G. Carter of Oregon State University described (J. Am. Chem. Soc. 2008, 130, 9238) the first enantioselective synthesis of the Lycopodium alkaloid (-)-lyopodine 3. A key step in the assembly of 3 was the diastereoselective intramolecular Michael addition of the keto sulfone of 1 to the enone, leading to the cyclohexanone 2. The key cyclization substrate 1 bore a single secondary methyl group. While that could have been derived from a natural product, it was operationally easier to effect chiral auxiliary controlled conjugate addition to the crotonyl amide 4, leading, after methoxide excha
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Patil, Nitin T., Rahul D. Kavthe, and Yoshinori Yamamoto. "Metal-Catalyzed Intramolecular Heteroatom (X)→Carbon (C) Functional Group Migration Reactions Involving Additions of X–Y Bonds Across Alkynes." In Advances in Heterocyclic Chemistry. Elsevier, 2010. http://dx.doi.org/10.1016/s0065-2725(10)01002-0.

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Conference papers on the topic "Intramolecular migration"

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Hatada, Keisuke, Shigeru Abe, Soki Goto, et al. "Imaging femtosecond intramolecular hydrogen migration via polarization-Averaged molecular-frame photoelectron angular distributions." In International Conference on Ultrafast Phenomena. Optica Publishing Group, 2022. http://dx.doi.org/10.1364/up.2022.th4a.18.

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We investigated the signature of ultrafast hydrogen dynamics in Polarization-Averaged Molecular-Frame Photoelectron Angular Distributions and studied intramolecular hydrogen migrations by the spectra for CH3OH2+, C2H5OH2+ and C3H7OH2+.
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Elkhadragy, Lobna, Hadel Alsaran, and Weiwen Long. "Abstract 2391: Intramolecular regulation of ERK3's kinase activity and migration/invasion-promoting ability by the C-terminus." In Proceedings: AACR Annual Meeting 2018; April 14-18, 2018; Chicago, IL. American Association for Cancer Research, 2018. http://dx.doi.org/10.1158/1538-7445.am2018-2391.

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3

Chen, Peng-Yu, Wei-Hui Chen, and Che-Wun Hong. "Nanofludic Analysis on Methanol Crossover of Direct Methanol Fuel Cells." In ASME 2008 First International Conference on Micro/Nanoscale Heat Transfer. ASMEDC, 2008. http://dx.doi.org/10.1115/mnht2008-52095.

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Direct methanol fuel cells (DMFCs) are considered as a competitive power source candidate for portable electronic devices. Nafion® has been widely used for the electrolyte of DMFCs because of its good proton conductivity and high chemical and mechanical stability. However, the major problem that must be solved before commercialization is the high methanol crossover through the membrane. There are a number of studies on experiments about the methanol crossover rate through the membrane but only few theoretical investigations have been presented [1–3]. In this paper, an atomistic model [4] is pr
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