Academic literature on the topic 'Iodine atoms'

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Journal articles on the topic "Iodine atoms"

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Čenský, Miroslav, Otomar Špalek, Vít Jirásek, Jarmila Kodymová, and Ivo Jakubec. "Atomic Iodine Generation via Fluorine Atoms for Chemical Oxygen-Iodine Laser." Collection of Czechoslovak Chemical Communications 71, no. 5 (2006): 739–55. http://dx.doi.org/10.1135/cccc20060739.

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Chemical generation of atomic iodine for a chemical oxygen-iodine laser (COIL) was investigated experimentally. In the two-step reaction mechanism, molecular fluorine reacts with nitrogen oxide and formed fluorine atoms react then with hydrogen iodide to iodine atoms. The efficiency of this process was studied in dependence on mixing conditions, flow rate of reacting gases and pressure in reactor. A maximum concentration of atomic iodine was obtained at approximately equimolar ratio of reacting gases (F2, NO and HI), which agrees well with the stoichiometry of production reactions. A shortage
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Zhang, L. Y., X. L. Hou, and S. Xu. "Speciation of <sup>127</sup>I and <sup>129</sup>I in atmospheric aerosols at Risø, Denmark: insight into sources of iodine isotopes and their species transformations." Atmospheric Chemistry and Physics Discussions 15, no. 17 (2015): 25139–73. http://dx.doi.org/10.5194/acpd-15-25139-2015.

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Abstract. Speciation analysis of iodine in aerosols is a very useful approach for understanding geochemical cycling of iodine in the atmosphere. In this study, overall iodine species, including water-soluble iodine species (iodide, iodate and water-soluble organic iodine), NaOH-soluble iodine and insoluble iodine have been determined for 129I and 127I in the aerosols collected at Risø, Denmark, between March and May 2011 (shortly after the Fukushima nuclear accident) and in December 2014. The measured concentrations of total iodine are in the range of 1.04–2.48 ng m−3 for 127I and (11.3–97.0)
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Zhang, Luyuan, Xiaolin Hou, and Sheng Xu. "Speciation of <sup>127</sup>I and <sup>129</sup>I in atmospheric aerosols at Risø, Denmark: insight into sources of iodine isotopes and their species transformations." Atmospheric Chemistry and Physics 16, no. 4 (2016): 1971–85. http://dx.doi.org/10.5194/acp-16-1971-2016.

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Abstract. Speciation analysis of iodine in aerosols is a very useful approach for understanding geochemical cycling of iodine in the atmosphere. In this study, overall iodine species, including water-soluble iodine species (iodide, iodate and water-soluble organic iodine), NaOH-soluble iodine, and insoluble iodine have been determined for 129I and 127I in the aerosols collected at Risø, Denmark, during March and May 2011 (shortly after the Fukushima nuclear accident) and in December 2014. The measured concentrations of total iodine are in the range of 1.04–2.48 ng m−3 for 127I and (11.3–97.0)
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Sundick, R. S., D. Herdegen, T. R. Brown, A. Dhar, and N. Bagchi. "Thyroidal iodine metabolism in obese-strain chickens before immune-mediated damage." Journal of Endocrinology 128, no. 2 (1991): 239—NP. http://dx.doi.org/10.1677/joe.0.1280239.

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ABSTRACT Several studies have shown that iodine plays a role in spontaneous autoimmune thyroiditis in man and other animals. In addition, abnormalities of iodine metabolism have been found in patients with Hashimoto's thyroiditis and in chickens of the obese strain (OS), an animal model of spontaneous autoimmune thyroiditis. We have examined several parameters of iodine metabolism before immune damage in this model and in the related Cornell strain (CS), a strain which develops a late-onset mild thyroiditis, to discover a possible causal relationship between altered iodine metabolism and the i
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Rudiuk, Vitalii V., Anna M. Shaposhnyk, Vyacheslav M. Baumer, Igor A. Levandovskiy, and Svitlana V. Shishkina. "Salts of 4-[(benzylamino)carbonyl]-1-methylpyridinium and iodide anions with different cation:iodine stoichiometric ratios." Acta Crystallographica Section E Crystallographic Communications 77, no. 12 (2021): 1219–23. http://dx.doi.org/10.1107/s2056989021011300.

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The two iodide salts, 4-[(benzylamino)carbonyl]-1-methylpyridinium iodide–iodine (2/1), C14H15N2O+·I−·0.5I2, I, and 4-[(benzylamino)carbonyl]-1-methylpyridinium triiodide, C14H15N2O+·I3 −, II, with different cation:iodine atoms ratios were studied. Salt I contains one cation, one iodide anion and half of the neutral I2 molecule in the asymmetric unit (cation:iodine atoms ratio is 1:2). Salt II contains two cations, one triiodide anion (I 3 −) and two half triiodide anions (cation:iodine atoms ratio is 1:3). The NH group forms N—H...I hydrogen bonds with the I− anion in the crystal of I or N—H.
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Reuter, Hans, and Hilko Wilberts. "On the structural diversity anions coordinate to the butterfly-shaped [(R2Sn)3O(OH)2]2+ cations and vice versa." Canadian Journal of Chemistry 92, no. 6 (2014): 496–507. http://dx.doi.org/10.1139/cjc-2013-0517.

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The syntheses and crystal structures of [(t-Bu2Sn)3O(OH)2]CO3·3MeOH, 1a, [(t-Bu2Sn)3O(OH)2]CO3·3H2O·acetone, 1b, [(t-Bu2Sn)3O(OH)2][I]2·[(t-Bu2Sn(OH)I]2·2DMSO, 1c, and [(Cy2Sn)3O(OH)2][I]2·2DMSO, 2a, all containing the trinuclear [(R2Sn)3O(OH)2]2+ ion have been described. The butterfly shape of this cation is derived from two annulated, four-membered tin–oxygen rings with a central μ3-oxygen atom and trigonal-bipyramidally coordinated tin atom both belonging to both rings and two μ2-hydroxyl groups and two outer, four-fold coordinated tin atoms. In 1a and 1b, the carbonate anions interact with
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Wzgarda-Raj, Kinga, Martyna Nawrot, Agnieszka J. Rybarczyk-Pirek, and Marcin Palusiak. "Ionic cocrystals of dithiobispyridines: the role of I...I halogen bonds in the building of iodine frameworks and the stabilization of crystal structures." Acta Crystallographica Section C Structural Chemistry 77, no. 8 (2021): 458–66. http://dx.doi.org/10.1107/s2053229621006306.

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It has been confirmed that mercaptopyridines undergo spontaneous condensation in redox reaction with iodine-forming dithiopyridines. In the solid state, these compounds are protonated at the N atoms and cocrystallize with iodine forming salt structures, namely, 2-[(pyridin-2-yl)disulfanyl]pyridinium triiodide sesquiiodine, C10H9N2S2 +·I3 −·1.5I2, and 4,4′-(disulfanediyl)dipyridinium pentaiodide triiodide, C10H10N2S2 2+·I5 −·I3 −. Dithiopyridine cations are packed among three-dimensional frameworks built from iodide anions and neutral iodine molecules, and are linked by hydrogen, halogen and ch
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Malakhov, I. A., N. A. Orlova, V. V. Shelkovnikov, E. V. Vasilyev, and A. A. Chernonosov. "Synthesis and Spectral Properties of Iodine-Substituted Dyes Based on Benzothiazolium Salts." Žurnal organičeskoj himii 60, no. 1 (2024): 132–42. https://doi.org/10.31857/s0514749224010126.

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Two series of new thiacarbocyanines with iodine atoms in the donor and/or acceptor block have been synthesized. The absorption spectra of the iodinated dyes in the region of singlet-singlet S0-S1 and singlet-triplet S0-T1 transitions are investigated. The introduction of iodine atoms into the dye structures leads to a red shift of the absorption maximum, regardless of the position of iodine in the molecule. For dyes with two or more iodine atoms, a low-intensity long-wave absorption shoulder in the region from 650 to 1000 nm is detected, which corresponds to singlet-triplet absorption.
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Sorti, Letizia, Fiammetta Vitulano, Elia Cappellini, et al. "Electrochemical Iodination through the In Situ Generation of Iodinating Agents: A Promising Green Approach." Molecules 28, no. 14 (2023): 5555. http://dx.doi.org/10.3390/molecules28145555.

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The synthesis of iodinated compounds using cheap, simple, and green strategies is of fundamental importance. Iodination reactions are mainly used to synthesize useful intermediates, especially in the pharmaceutical field, where they are employed for the production of contrast media or of iodinated active pharmaceutical ingredients. Traditional synthetic methods suffer from the use of erosive, toxic, or hazardous reactants. Approaches which involve the use of molecular iodine as an iodinating agent require the addition of an oxidizing agent, which is often difficult to handle. Electrochemistry
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Albrecht, Ralf, Heinrich Menning, Thomas Doert, and Michael Ruck. "Hydroflux synthesis and crystal structure of Tl3IO." Acta Crystallographica Section E Crystallographic Communications 76, no. 10 (2020): 1638–40. http://dx.doi.org/10.1107/s2056989020012359.

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Single-crystals of thallium(I) iodide oxide Tl3IO were obtained as by-product in a hydroflux synthesis at 473 K for 10 h. A potassium hydroxide hydroflux with a water-base molar ratio of 1.6 and the starting materials TlNO3, RhI3 and Ba(NO3)2 was used, resulting in a few black needle-shaped crystals. X-ray diffraction on a single-crystal revealed the hexagonal space group P63/mmc (No. 194) with lattice parameters a = 7.1512 (3) Å and c = 6.3639 (3) Å. Tl3IO crystallizes as hexagonal anti-perovskite (anti-BaNiO3 type) and is thus structurally related to the alkali-metal halide/auride oxides M 3
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Dissertations / Theses on the topic "Iodine atoms"

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Girard, Bertrand. "Etude de la collision reactive ii + f -> if + i par fluorescence induite par laser." Paris 6, 1987. http://www.theses.fr/1987PA066398.

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Etude de cette collision par la methode des faisceaux croises et grace a la transition (b <- x) intense, dans le visible, apres analyse de la saturation du processus d'excitation laser de cette transition de if forme. Deduction des populations des differents niveaux rovibrationnels de l'etat x. Etablissement d'une cartographie detaillee de la distribution rotationnelle des niveaux vibrationnels v = 8 a 20 de l'etat x de if: aspect bimodal qui implique la coexistence de deux chemins reactionnels differents. Attribution a un artefact de l'important signal observe anterieurement pour v = 0. Mesur
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鄺珠聯 and Chu-luen Kwong. "The reaction of O(3P) atoms with methyl iodide: studies of nascent reaction products with considerationsfrom the observations of the O(3P) reaction with acetylene." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1992. http://hub.hku.hk/bib/B31233107.

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Raybone, D. "Chemiluminescent and photochemical processes in the gas phase." Thesis, University of Manchester, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.383197.

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Van, Der Waals Dominic. "Atom economical and environmentally benign metal catalysed synthesis." Thesis, University of Bath, 2014. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.636541.

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The use of inexpensive metal catalysts for a range of acylation reactions including the activation of anhydrides and the aminolysis of esters. Discussion on the use of a heterogeneous copper catalyst for teh reduction of a range of organic functional groups and its use in amination of nitriles.
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Tallavaara, P. (Pekka). "Characterization of liquid crystals in porous materials by means of NMR of probe atoms and molecules." Doctoral thesis, University of Oulu, 2008. http://urn.fi/urn:isbn:9789514287848.

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Abstract The present thesis describes a method for characterization of liquid crystals in confined spaces by means of NMR of probe atoms and molecules. 129Xe isotope enriched xenon gas and 13C isotope enriched methyl iodide and methane were used as probes. Behavior of solutes and liquid crystals confined to porous materials was investigated using 129Xe and 13C NMR spectroscopy. Uniaxial nematic liquid crystals Phase 4 and ZLI 1115 were used as a medium. Controlled pore glass with well defined and known properties was used as a porous material. The behavior of liquid crystals and solutes in va
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Rafferty, Sean M. "Selective Ketyl Couplings via Atom Transfer Catalysis." The Ohio State University, 2020. http://rave.ohiolink.edu/etdc/view?acc_num=osu1587494763808417.

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Grelier, Gwendal. "Les réactions d'amination C(sp³)–H catalytiques par transfert de nitrènes : diversité moléculaire et éco-compatibilité." Thesis, Université Paris-Saclay (ComUE), 2018. http://www.theses.fr/2018SACLS237.

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Cette thèse est consacrée au développement de réactions d'amination C(sp³)-H catalysées au Rhodium(ᴵᴵ) impliquant la chimie des nitrènes. La première partie décrit la valorisation des sous-produits des réactifs d'iode hypervalent comme des briques moléculaires dans des séquences Amination/Couplage croisé. Le réactif d'iode hypervalent joue alors le rôle d'oxydant pour la génération d'un nitrène, du substrat pour l'amination C(sp³)-H et de partenaire de couplage pour les réactions palladocatalysées. La seconde partie concerne le développement d'une nouvelle source de nitrène : les carbamimidate
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Norberg, Daniel. "Quantum Chemical Studies of Radical Cation Rearrangement, Radical Carbonylation, and Homolytic Substitution Reactions." Doctoral thesis, Uppsala : Acta Universitatis Upsaliensis, 2007. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-8178.

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CHEN, YOU-LI, and 陳佑禮. "Studies of Excited Iodine Atoms from Photodissociations of CH3I." Thesis, 2002. http://ndltd.ncl.edu.tw/handle/78951122349266841592.

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Wu, Yen-tien, and 吳彥典. "Studies of Excited Iodine Atoms from Photodissociations of CH3I." Thesis, 2004. http://ndltd.ncl.edu.tw/handle/35771774760507903004.

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碩士<br>國立中山大學<br>化學系研究所<br>92<br>Methyl iodide photolysis has drawn considerable attention over the past years as an “instantaneous” pseudo-linear dissociation that may be described by a two dimensional potential energy surface. Single photon excitation in methyl iodide results in a direct rupture of the C-I bound, and the dissociation occurs in 〜0.1 ps. The Ã-band photodissocation of methyl iodide yields ground state methyl radicals [CH3 X(2A2˝)] and either ground state iodine atoms [(2P3/2)I≡I] or spin-orbit excited iodine atoms [(2P1/2)I≡I*] . In the present work, we used the IR emission tec
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Books on the topic "Iodine atoms"

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Mohan, Man, Anil Kumar Maini, and Aranya B. Bhattacherjee. Advances in Laser Physics and Technology. Edited by Anil K. Razdan. Foundation Books, 2014. http://dx.doi.org/10.1017/9789385386084.

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Lasers are created to study the timescale of electron motion in atoms and molecules. They also have wide applications in areas like solid state, plasma physics, nanoscience and defence technology. This book helps readers to master the large variety of physical phenomena and technological aspects involved in laser technology. Besides explaining the physical principles and common techniques of laser science and technology, it also elaborates on topics like High-harmonic Generation (HHG) and strong-field Non-sequential Double Ionization (NSDI), effects of a low energy atto-second pulse, laser spe
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Book chapters on the topic "Iodine atoms"

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Hirota, E., K. Kuchitsu, T. Steimle, J. Vogt, and N. Vogt. "185 IN3 Iodine azide." In Molecules Containing No Carbon Atoms and Molecules Containing One or Two Carbon Atoms. Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-540-70614-4_186.

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Hirota, E., K. Kuchitsu, T. Steimle, J. Vogt, and N. Vogt. "186 IO2 Iodine dioxide." In Molecules Containing No Carbon Atoms and Molecules Containing One or Two Carbon Atoms. Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-540-70614-4_187.

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Hirota, E., K. Kuchitsu, T. Steimle, J. Vogt, and N. Vogt. "15 CFIO Carbonic fluoride iodide." In Molecules Containing No Carbon Atoms and Molecules Containing One or Two Carbon Atoms. Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-540-70614-4_216.

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Hirota, E., K. Kuchitsu, T. Steimle, J. Vogt, and N. Vogt. "151 H2I– Dihydrogen – iodide (1/1)." In Molecules Containing No Carbon Atoms and Molecules Containing One or Two Carbon Atoms. Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-540-70614-4_152.

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Hirota, E., K. Kuchitsu, T. Steimle, J. Vogt, and N. Vogt. "13 ArHI Argon – hydrogen iodide (1/1)." In Molecules Containing No Carbon Atoms and Molecules Containing One or Two Carbon Atoms. Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-540-70614-4_14.

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Curran, Dennis P. "Iodine Atom Transfer Reactions in Organic Synthesis." In Free Radicals in Synthesis and Biology. Springer Netherlands, 1989. http://dx.doi.org/10.1007/978-94-009-0897-0_3.

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Hirota, E., K. Kuchitsu, T. Steimle, J. Vogt, and N. Vogt. "26 CHIO2 Carbon dioxide – hydrogen iodide (1/1)." In Molecules Containing No Carbon Atoms and Molecules Containing One or Two Carbon Atoms. Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-540-70614-4_227.

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Ptzel, M., S. Pritz, and J. Liebscher. "Substitution by Iodine Atoms." In Three Carbon-Heteroatom Bonds: Esters and Lactones; Peroxy Acids and R(CO)OX Compounds; R(CO)X, X=S, Se, Te. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-021-00463.

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Compton, Robert N., and Michael A. Duncan. "Fluorescence Lifetime of Iodine Vapor." In Laser Experiments for Chemistry and Physics, Second Edition, 2nd ed. Oxford University PressOxford, 2024. https://doi.org/10.1093/oso/9780198900825.003.0028.

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Abstract Fluorescence is one of the most fundamental relaxation processes exhibited by atoms and molecules following optical excitation. Its rate is characterized in the form of the fluorescence lifetime, which is an exponential decay following pulsed excitation. This chapter describes the measurement of the fluorescence lifetime of iodine vapor following pulsed laser excitation with a Nd:YAG laser at 532 nm. The apparatus described is generally applicable for studies of fluorescence lifetimes for a variety of atomic or molecular species. Different methods of fitting the exponential decay are
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Yusif Hajibala, Shukurlu, and Huseynov Tokay Maharram. "Increased Morbidity and Its Possible Link to Impaired Selenium Status." In Selenium and Human Health [Working Title]. IntechOpen, 2023. http://dx.doi.org/10.5772/intechopen.110848.

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This chapter summarizes the latest information on the main differences in the chemical properties of selenium proteins and their sulfur analogues, Se proteins and their functions, Se-accumulating proteins, the relationship between Se and hemoglobin, Selenium in gerontology, Selenium and iodine deficiency conditions, Se and immunity, Selenium as an antioxidant in nitrite poisoning. Also discussed are some of the results of the first studies on protein enrichment with selenium carried out in the seventies of the last century. This native protein was natural silk fibroin. Fibroin has since become
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Conference papers on the topic "Iodine atoms"

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Mikheyev, P. A., N. I. Ufimtsev, A. V. Demyanov, I. V. Kochetov, and A. P. Napartovich. "Plasma chemistry of iodine atoms production for CW oxygen-iodine laser." In XIX International Symposium on High-Power Laser Systems and Applications, edited by Kerim R. Allakhverdiev. SPIE, 2013. http://dx.doi.org/10.1117/12.2010462.

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Špalek, Otomar, Vít Jirásek, Miroslav Čenský, Jarmila Kodymová, Irena Picková, and Ivo Jakubec. "Chemical oxygen-iodine laser with atomic iodine generated via fluorine atoms." In International Conference on Lasers, Applications, and Technologies '07, edited by Vladislav Panchenko, Vladimir Golubev, Andrey Ionin, and Alexander Chumakov. SPIE, 2007. http://dx.doi.org/10.1117/12.753179.

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De Young, Russell J. "Low threshold solar-pumped lasers using alkyl iodides." In OSA Annual Meeting. Optica Publishing Group, 1986. http://dx.doi.org/10.1364/oam.1986.tuu4.

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The conversion of sunlight into high power laser light in space could have important applications in space manufacturing and propulsion. Thus, research on solar-pumped lasers could lead to large orbiting solar collectors concentrating sunlight on an appropriate lasant producing megawatts of cw power. Presently, most research has focused on the alkyl iodides which absorb solar light near 280 nm and then photodissociate into a radical and an excited iodine atom which lases at 1.315 μm. A number of alkyl iodides have been investigated (i-C3F7I, C2F5I, n-C4F9I, CF3I) with the goal of defining the
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Spalek, Otomar, Vit Jirasek, Miroslav Censky, Jarmila Kodymova, Ivo Jakubec, and Gordon D. Hager. "Chemical oxygen-iodine laser with atomic iodine generated via Cl or F atoms." In Prague -- 2004 DL over. SPIE, 2005. http://dx.doi.org/10.1117/12.611007.

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Spalek, Otomar, Vit Jirasek, Miroslav Censky, Jarmila Kodymova, Ivo Jakubec, and Gordon D. Hager. "Atomic iodine generation via F atoms for COIL." In High-Power Laser Ablation 2004, edited by Claude R. Phipps. SPIE, 2004. http://dx.doi.org/10.1117/12.544272.

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Mikheyev, Pavel A., Andrey V. Demyanov, Nikolay I. Ufimtsev, et al. "Oxygen assisted iodine atoms production in an RF discharge." In SPIE LASE, edited by Steven J. Davis, Michael C. Heaven, and J. Thomas Schriempf. SPIE, 2016. http://dx.doi.org/10.1117/12.2218350.

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Mikheyev, Pavel A., Andrey V. Demyanov, Nikolay I. Ufimtsev, Igor V. Kochetov, Valeriy N. Azyazov, and Anatoly P. Napartovich. "Oxygen assisted iodine atoms production in an RF discharge for a cw oxygen-iodine laser." In XX International Symposium on High Power Laser Systems and Applications, edited by Chun Tang, Shu Chen, and Xiaolin Tang. SPIE, 2015. http://dx.doi.org/10.1117/12.2065315.

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Tanabe, Yuto, Yuma Sakamoto, Takuya Kohno, Daisuke Akamatsu, and Feng-Lei Hong. "Absolute frequency measurement of an iodine-stabilized laser at 556 nm for laser cooling of Yb." In Conference on Lasers and Electro-Optics/Pacific Rim. Optica Publishing Group, 2022. http://dx.doi.org/10.1364/cleopr.2022.cfa6g_04.

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The precision spectroscopy of the iodine transitions at 556 nm will benefit research on Yb cold atoms owing to the frequency coincidence of the iodine hyperfine transitions and the 1S0-3P1 spin-forbidden transition of Yb. We perform Doppler-free spectroscopy of hyperfine structures of molecular iodine using the second harmonic of a 1112-nm diode laser.
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Spalek, Otomar, Vit Jirasek, Miroslav Censky, Jarmila Kodymova, Ivo Jakubec, and Gordon D. Hager. "Experimental results on chemical generation of atomic iodine via Cl atoms for chemical oxygen-iodine laser." In SPIE Proceedings, edited by Krzysztof M. Abramski, Edward F. Plinski, and Wieslaw Wolinski. SPIE, 2003. http://dx.doi.org/10.1117/12.515576.

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Mikheyev, P. A., M. V. Zagidullin, N. I. Ufimtsev, N. A. Khvatov, A. I. Voronov, and V. N. Azyazov. "COIL operation with iodine atoms generated in a glow discharge." In 18th International Symposium on Gas Flow & Chemical Lasers & High Power Lasers, edited by Tanja Dreischuh, Petar A. Atanasov, and Nikola V. Sabotinov. SPIE, 2010. http://dx.doi.org/10.1117/12.880051.

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