Relevant bibliographies by topics / Iridium(III) chloride

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Academic literature on the topic 'Iridium(III) chloride'

Author: Grafiati
Published: 5 June 2025
Last updated: 1 August 2025

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Journal articles on the topic "Iridium(III) chloride"

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Schlapp-Hackl, Inge, Christoph Falschlunger, Kathrin Zauner та ін. "Syntheses and crystal structures of [IrIII{C(CHCO2Et)(dppm)2-κ4 P,C,C′,P′}ClH]Cl·2.75CH2Cl2 and its derivatives, [IrIII{C(CHCO2Et)(dppm)2-κ4 P,C,C′,P′}(CH2CO2Et)Cl]Cl·CH3OH·0.5H2O, [IrIII{C(CHCO2Et)(dppm)2-κ4 P,C,C′,P′}Cl2]Cl·CH3OH·2H2O and [IrIII{C(CHCO2Et)(dppm)2-κ4 P,C,C′,P′}(CH2CO2Et)(CO)]Cl2·2CH2Cl2·1.5H2O". Acta Crystallographica Section E Crystallographic Communications 75, № 1 (2019): 12–20. http://dx.doi.org/10.1107/s2056989018017024.

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The common feature of the four iridium(III) salt complexes, (bis{[(diphenylphosphanyl)methyl]diphenylphosphanylidene}(ethoxyoxoethanylidene)methane-κ4 P,C,C′,P′)chloridohydridoiridium(III) chloride methylene chloride 2.75-solvate (4), (bis{[(diphenylphosphanyl)methyl]diphenylphosphanylidene}(ethoxyoxoethanylidene)methane-κ4 P,C,C′,P′)chlorido(ethoxyoxoethanido)iridium(III) chloride–methanol–water (1/1/0.5) (5), (bis{[(diphenylphosphanyl)methyl]diphenylphosphanylidene}(ethoxyoxoethanylidene)methane-κ4 P,C,C′,P′)dichloridoiridium(III) chloride–methanol–water (1/1/2) (6) and (bis{[(diphenylphosph
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2

Anjali, Goel, R. Verma G., and S. Singh H. "Kinetics and mechanism of iridium(III) chloride catalyzed oxidation of ethylene glycol and methyl glycol by hexacyanoferrate(III) in aqueous alkaline medium." Journal of Indian Chemical Society Vol. 79, Aug 2002 (2002): 665–67. https://doi.org/10.5281/zenodo.5843309.

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Department of Chemistry. Kanya Gurukul Mahavidhyalaya, Gurukul Kangri University, Jwalapur, Hardwar-249 407, India <em>E-mail : </em>dr_anjaligoel@rediffmail.com&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; <em>Fax : </em>91-0133-452290 Chemistry Department, S. D. (P.G.) College, Muzaffernagar-251 001, India Chemical Laboratories, University of Allahabad, Allahabad-21 1 002, India <em>Manuscript received 28 July 2000, revised 27 September 2001. accepted 21 March 2002</em> The iridiurn(III) chloride catalyzed oxidation of ethylene glycol and me
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Partl, Gabriel Julian, Felix Nussbaumer, Inge Schlapp-Hackl, et al. "Crystal structures of four new iridium complexes, each containing a highly flexible carbodiphosphorane PCP pincer ligand." Acta Crystallographica Section E Crystallographic Communications 74, no. 6 (2018): 846–52. http://dx.doi.org/10.1107/s2056989018007569.

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Compound [Ir(C8H12)(C51H45P4)]Cl2or [Ir(cod)(CH(dppm)2-κ3P,C,P)]Cl2(1a), was obtained from [IrCl(cod)]2and the carbodiphosphorane (CDP) salt [CH(dppm)2]Cl [where cod = cycloocta-1,5-diene and dppm = bis(diphenylphosphino)methane]. Treatment of1awith thallium(I) trifluoromethanesulfonate [Tl(OTf)] and subsequent crystallization gave complex [Ir(C8H12)(C51H45P4)](OTf)2·CH3CO2C2H5·CH2Cl2or [Ir(cod)(CH(dppm)2-κ3P,C,P)](OTf)2·CH3CO2C2H5·CH2Cl2(1b) [systematic name: (cycloocta-1,5-diene)(1,1,3,3,5,5,7,7-octaphenyl-1,7-diphospha-3,5-diphosphoniaheptan-4-yl)iridium(I) bis(trifluoromethanesulfonate)–et
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4

Schenk, Wolfdieter A., and Johanna Leißner. "Oxidative Addition von H2 und HCl an Iridium-Schwefelmonoxid- und Schwefeldioxid-Komplexe/ Oxidative Addition von H2 und HCl an Iridium-Schwefelmonoxid- und Schwefeldioxid-Komplexe." Zeitschrift für Naturforschung B 42, no. 8 (1987): 967–71. http://dx.doi.org/10.1515/znb-1987-0807.

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AbstractSquare planar iridium(I) complexes of sulfur monoxide and sulfur dioxide undergo oxidative addition with dihydrogen and hydrogen chloride. The resulting hydrido-iridium(III) complexes have been characterized by 1H , 31P NMR and IR spectroscopy. The limited stability of the sulfur monoxide derivatives is explained as resulting from decreased back-bonding between iridium and sulfur.
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Wu, Chun, Guodong Li, Quan-Bin Han, et al. "Real-time detection of oxalyl chloride based on a long-lived iridium(iii) probe." Dalton Transactions 46, no. 48 (2017): 17074–79. http://dx.doi.org/10.1039/c7dt04054g.

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Pigulski, Bartłomiej, Agata Jarszak, and Sławomir Szafert. "Selective synthesis of iridium(iii) end-capped polyynes by oxidative addition of 1-iodopolyynes to Vaska's complex." Dalton Transactions 47, no. 47 (2018): 17046–54. http://dx.doi.org/10.1039/c8dt04219e.

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The reaction of bis(triphenylphosphine)iridium(i) carbonyl chloride (Vaska's complex) with a series of 1-iodopolyynes (1-C<sub>n</sub>I and2-C<sub>n</sub>I) gave σ-polyynyl iridium(iii) complexes with general formula R(CC)<sub>n</sub>Ir(PPh<sub>3</sub>)<sub>2</sub>(Cl)(I)(CO).
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7

Lagos, Yolanda, Joana Palou-Mir, Antonio Bauzá, et al. "New chloride-dimethylsulfoxide-iridium(III) complex with histaminium." Polyhedron 102 (December 2015): 735–40. http://dx.doi.org/10.1016/j.poly.2015.10.036.

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8

(Miss), MANIBALA, S. SINGH H., KRISHNA B., and K. TANDON P. "lridium(lll) Chloride Catalysed Oxidation of Propan-2-one by Hexacyanoferrate(III) in Aqueous Alkaline Medium." Journal of Indian Chemical Society Vol. 62, Jun 1985 (1985): 434–37. https://doi.org/10.5281/zenodo.6319445.

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Chemical Laboratories, University of Allahabad, Allahabad-211 002 <em>Manuscript received 15 January 1983, revised 7 March 1984, accepted 8 June 1985</em> The kinetic data show direct proportionality with respect to ferrkyanide concentra&shy;tions. The reaction rate is directly proportional to the substrate, OH<sup>-</sup> ions and iridium(III) at lower concentrations, but at higher concentrations the rate becomes independent of the substrate, alkali and the catalyst concentrations. These data suggest the formation of an activated complex between the substrate and iridium(III). Toffs complex w
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M., P. SINGH, K. TANDON P., M. SINGH R., and MEHROTRA ALKA. "lridium(III) Chloride catalysed Oxidation of some Alcohols by Alkaline Hexacyanoferrate(III)." Journal of Indian Chemical Society Vol. 67, June 1990 (1990): 458–62. https://doi.org/10.5281/zenodo.6163515.

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Chemical Laboratories, University of Allahabad, Allahabad-211 002 <em>Manuscript received 24 July 1989, revised 15 December 1989, accepted 6 February 1990</em> The oxidation of methanol, ethanol, propanol-1 and butanol-1 by alkaline hexacyanoferrate(III) using iridium(III) chloride as a homogeneous catalyst reveals first order kinetics at low concentrations. thereafter the rate of the reaction becomes independent with respect to hexacyanoferrate(III) and hydroxide ions each at their higher concentrations. The reaction follows direct proportionality with respect to [IrCl<sub>3</sub>], &nbsp;and
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10

Merola, Joseph S., Carla Slebodnick та Christopher Houser. "Crystal structure of di-μ-chlorido-bis[dichloridobis(methanol-κO)iridium(III)] dihydrate: a surprisingly simple chloridoiridium(III) dinuclear complex with methanol ligands". Acta Crystallographica Section E Crystallographic Communications 71, № 5 (2015): 528–30. http://dx.doi.org/10.1107/s2056989015006672.

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The reaction between IrCl3·xH2O in methanol led to the formation of small amounts of the title compound, [Ir2Cl6(CH3OH)4]·2H2O, which consists of two IrCl4O2octahedra sharing an edgeviachloride bridges. The molecule lies across an inversion center. Each octahedron can be envisioned as being comprised of four chloride ligands in the equatorial plane with methanol ligands in the axial positions. A lattice water molecule is strongly hydrogen-bonded to the coordinating methanol ligands and weak interactions with coordinating chloride ligands lead to the formation of a three-dimensional network. Th
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Book chapters on the topic "Iridium(III) chloride"

1

Lambert, Tristan H. "C–O Ring-Containing Natural Products: Cyanolide A (Krische), Bisabosqual A (Parker), Iso-Eriobrucinol A (Hsung), Trichodermatide A (Hiroya), Batrachotoxin Core (Du Bois)." In Organic Synthesis. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780190646165.003.0048.

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Michael J. Krische at the University of Texas at Austin developed (Angew. Chem. Int. Ed. 2013, 52, 4470) a total synthesis of cyanolide A 7 in only seven steps, a sequence so short it is shown here in its entirety. Diol 1 was subjected to enantioselective cat­alytic bisallylation under iridium catalysis to furnish 2 with very high levels of ste­reocontrol. Cross metathesis using ruthenium catalyst 3 first with ethyl vinyl ketone and then with ethylene resulted in the production of pyran 4. Glycosylation of 4 with phenylthioglycoside 5, stereoselective reduction of the ketone function, and oxid
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