Academic literature on the topic 'Iron-aluminium alloys'

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Journal articles on the topic "Iron-aluminium alloys"

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Hilfrich, K., K. Nembach, W. Petry, O. Schärpf, and E. Nembach. "Superlattices in iron-rich iron-aluminium alloys." Physica B: Condensed Matter 180-181 (June 1992): 588–90. http://dx.doi.org/10.1016/0921-4526(92)90403-f.

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Ji, Shou Xun, Feng Gao, and Zhong Yun Fan. "Thermodynamics Calculation of Extra Mn Addition in the Recycling of Al-Si-Cu Aluminium Alloys." Materials Science Forum 877 (November 2016): 33–38. http://dx.doi.org/10.4028/www.scientific.net/msf.877.33.

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Iron contamination from scrapped materials is always a problem in producing high quality secondary aluminium alloys. Consequently, the iron removal during recycling of aluminium alloys is essential and important in industrial practice. This work aims to study the effect of extra Mn addition on the effectiveness and efficiency of iron removal during recycling. The thermodynamics assessment was carried out for Al-Si-Cu alloys to find out the variation of balanced iron and manganese in the liquid melt and in the sediment solid Fe-rich intermetallics with different levels of extra Mn addition. The effect of alloy composition and processing temperatures was investigated. The findings help to understand the capability and fundamentals of iron removal in aluminium alloys.
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Turmezey, T., Vilmos Stefániay, and A. Griger. "Microstructure of Iron Containing Aluminium Alloys." Key Engineering Materials 38-39 (January 1991): 43–64. http://dx.doi.org/10.4028/www.scientific.net/kem.38-39.43.

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Devan, J. H., and P. F. Tortorelli. "Oxidation/sulfidation of iron-aluminium alloys." Materials at High Temperatures 11, no. 1-4 (January 1993): 30–35. http://dx.doi.org/10.1080/09603409.1993.11689436.

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Meyer, M., L. Mendoza-Zélis, and Francisco H. Sánchez. "Mechano-Synthesis of Iron Containing Aluminium Alloys." Materials Science Forum 179-181 (February 1995): 177–82. http://dx.doi.org/10.4028/www.scientific.net/msf.179-181.177.

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Ashtari, P., K. Tetley-Gerard, and K. Sadayappan. "Removal of iron from recycled aluminium alloys." Canadian Metallurgical Quarterly 51, no. 1 (January 2012): 75–80. http://dx.doi.org/10.1179/1879139511y.0000000026.

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Gogia, A. K., P. V. Rao, and J. A. Sekhar. "Rapidly solidified aluminium-iron-misch metal alloys." Journal of Materials Science 20, no. 9 (September 1985): 3091–100. http://dx.doi.org/10.1007/bf00545173.

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Carrera, E. A., J. H. Ramírez-Ramírez, F. A. Pérez-González, J. A. González, I. Crespo, I. Braceras, I. Martínez-de-la-Pera, et al. "Molten aluminium attack on iron based alloys." International Journal of Cast Metals Research 30, no. 3 (February 7, 2017): 171–79. http://dx.doi.org/10.1080/13640461.2017.1283878.

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Kalinina, Natalia Yevgrafovna, Tatyana Valerevna Nosova, Alexander Vasilievich Kalinin, Stella Igorevna Mamchur, Anton Albertovich Shakhov, and Igor Alexandrovich Mamchur. "WELDING ALUMINIUM ALLOYS REFRACTORY MODIFIERS TREATMENT – THE EFFECTIVE METHOD FOR CHARACTERISTICS INCREASING." Journal of Rocket-Space Technology 27, no. 4 (December 30, 2019): 74–78. http://dx.doi.org/10.15421/451912.

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The effect of modification by refractory dispersed compositions on the grain structure and properties of welded aluminium alloys is determined. Aluminium alloys of the Al-Mg-Mn system of chemical composition were studied: 4.8-6.0% magnesium, 0.3-0.5% manganese; 0.45 – 0.90% iron; aluminium - base. The iron content corresponded to the pre-eutectic and post-eutectic compositions of the aluminium-iron system. Titanium carbide (TiC) modifier powders with a dispersion of 1-5 microns obtained by the method of plasmachemical synthesis. The microstructure of the alloys was studied using MIM-8 and Neophot-2 optical microscopes. The strength properties of the alloys were determined using the MUP-20 machine. Production of samples was carried out according to GOST 1497-84 and GOST 9454-80. Fluidity was determined by the spiral sample method. The properties of alloys before and after modification were investigated. Improved technological properties of aluminium alloys after modification. Increased fluidity in AMg5 and 1420 alloys by 1.5% and 6%, respectively. The obtained homogeneous dispersed structure of aluminium alloys after modification. The strength properties of modified alloys are increased by20 %. Experiments were conducted on the effect of the charge type on the structure and properties of technically pure aluminium and aluminium alloys AMg5 and 1420. The advantage of solid charge in the smelting of aluminium ingots in reducing porosity and grinding grain in comparison with the use of liquid charge is established. The effective effect of the refractory modifier of titanium carbide on the properties of aluminium alloys is proved.
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Hurtalová, Lenka, Eva Tillová, and Mária Chalupová. "The Study of Iron Intermetallic Phases Morphology with Applying Deep Etching in Secondary Al-Si Alloys." Materials Science Forum 782 (April 2014): 359–64. http://dx.doi.org/10.4028/www.scientific.net/msf.782.359.

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The morphology control of intermetallic phases is very important in secondary aluminium cast alloy, because these alloys contain more of additional elements, which forms various intermetallic phases in the structure. Improvement of the mechanical properties is strongly depending upon the morphology, type and distribution of the second phases, which are in turn a function of the alloy composition and cooling rate. The iron intermetallic phase has the greatest influence on mechanical properties. It is necessary to study microstructure of Al-Si alloys, because the metallographic evaluation of aluminium alloys is not simple and these alloys are used for production many mechanical components, especially for cars, aerospace and rail vehicles. The study of iron intermetallic phases was performed using light microscope Neophot 32 and SEM observation with EDX analysis. For study the morphology of these phases were samples deep-etched for 30 s in HCl solution, in order to reveal the three-dimensional morphology of the iron phases.
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Dissertations / Theses on the topic "Iron-aluminium alloys"

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Coleman, Andrew John. "Filiform corrosion of aluminium alloys and iron." Thesis, Swansea University, 2007. https://cronfa.swan.ac.uk/Record/cronfa42908.

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Shollock, B. A. "Precipitation in rapidly solidified aluminium-chromium-iron alloys." Thesis, University of Oxford, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.238185.

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Hull, S. "Precipitation in aluminium based and iron based alloys." Thesis, University of Reading, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.370120.

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Hale, Geoffrey Eric. "The structure and properties of iron-manganese-aluminium alloys." Thesis, University of Leeds, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.434965.

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Humphreys, Elen Siobhain. "Production and characterisation of rapidly solidified Al-V-Fe alloys." Thesis, University of Oxford, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.302070.

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Deards, Nicola. "Recrystallisation nucleation and microtexture development in aluminium-iron rolled alloys." Thesis, University of Cambridge, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.259602.

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Syahril. "Effect of ternary additions and thermomechanical treatments on the properties of Fe-11wt% Al alloys." Thesis, Imperial College London, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.325578.

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COUTO, ANTONIO A. "Influencia do teor de cromo e de tratamentos termicos na microestrutura e no comportamento mecanico de ligas intermetalicas ordenadas a base de Fesub3 Al." reponame:Repositório Institucional do IPEN, 1998. http://repositorio.ipen.br:8080/xmlui/handle/123456789/10701.

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Tese (Doutoramento)
IPEN/T
Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP
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Tash, Mahmoud. "Effect [sic] des paramètres métallurgiques sur le comportement d'usinage des alliages 356 et 319 (étude de forage et de taraudage) /." Thèse, Chicoutimi : Université du Québec à Chicoutimi, 2005. http://theses.uqac.ca.

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PAOLA, JEAN C. C. de. "Efeito de tratamentos termicos e da adicao de cromo nas propriedades mecanicas de ligas Fe-24 atAl." reponame:Repositório Institucional do IPEN, 1998. http://repositorio.ipen.br:8080/xmlui/handle/123456789/10664.

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IPEN/D
Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP
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Books on the topic "Iron-aluminium alloys"

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Schanssema, Marko. Iron-aluminium alloys for fossil fuel combustion systems. Birmingham: University of Birmingham, 1996.

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Nyichomba, Blasius Bavo. The dimensional accuracy of sand castings (commercial aluminium alloys and grey cast iron). Birmingham: University of Birmingham, 1990.

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Jones, S. J. The influence of homogenisation treatment and manganese content on the aluminium-iron-silicon intermetallics in 6063 aluminium alloys. Manchester: UMIST, 1994.

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Elfadhli, Abd Elhafid Ibrahim. The effect of yttrium on the spallation of oxide scales formed on iron-chromium aluminium alloys at elevated temperatures. Manchester: UMIST, 1998.

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Hiramatsu, N. The effects of alloying elements on the oxidation of thin foils of iron-chromium-aluminium alloys at high temperatures. Manchester: UMIST, 1996.

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International Workshop on Effect of Iron and Silicon in Aluminium and its Alloys (1989 Balatonfured, Hungary). Effect of iron and silicon in aluminium and its alloys: Proceedings of the International Workshop, held in Balatonfured, Hungary, May 1989. Zurich, Switzerland: Trans Tech Publications, 1990.

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Deniszczyk, Józef. Struktura elektronowa, właściwości magnetyczne i parametry struktury nadsubtelnej wybranych międzymetalicznych związków żelaza o strukturze typu B2, DO3 i L21. Katowice: Wydawnictwo Uniwersytetu Śląskiego, 2005.

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International Seminar on Refining and Alloying of Liquid Aluminium on Ferro-Alloys (1985 Trondheim, Norway). Refining and alloying of liquid aluminium and ferro-alloys: Proceedings of the International Seminar of Refining and Alloying of Liquid Aluminium and Ferro-Alloys, the Norwegian Institute of Technology, Trondheim, August 1985. Düsseldorf: Aluminium-Verlag, 1985.

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International Seminar on Refining and Alloying of Liquid Aluminium and Ferro-Alloys (1985 Norwegian Institute of Technology). Refining and alloying of liquid aluminium and ferro-alloys: Proceedings of the International Seminar on Refining and Alloying of Liquid Aluminium and Ferro-Alloys, the Norwegian Institute of Technology, Trondheim, August 1985. Düsseldorf: Aluminium-Verlag, 1985.

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Belov, N. A., D. G. Eskin, and A. A. Aksenov. Iron in Aluminium Alloys: Impurity and Alloying Element (Advances in Metallic Alloys). CRC, 2002.

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Book chapters on the topic "Iron-aluminium alloys"

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Risanti, D. D., and G. Sauthoff. "Iron–Aluminium-Base Alloys with Strengthening Laves Phase for Structural Applications at High Temperatures." In Materials Science Forum, 865–68. Stafa: Trans Tech Publications Ltd., 2005. http://dx.doi.org/10.4028/0-87849-960-1.865.

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Tokuda, Kenji, Shinji Kumai, Akiko Ishihara, and Kenta Suzuki. "Influences of Iron Content and Solidification Rate on Mechanical Properties of 6022 Base Aluminium Alloys." In Materials Science Forum, 1889–94. Stafa: Trans Tech Publications Ltd., 2006. http://dx.doi.org/10.4028/0-87849-408-1.1889.

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Røyset, Jostein, J. R. Leinum, H. G. Øverlie, and Oddvin Reiso. "An Investigation of the Solubility of Scandium in Iron-Bearing Constituent Particles in Aluminium Alloys." In Materials Science Forum, 531–36. Stafa: Trans Tech Publications Ltd., 2006. http://dx.doi.org/10.4028/0-87849-408-1.531.

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"Iron as an Impurity in Aluminum Alloys." In Iron in Aluminium Alloys, 201–60. CRC Press, 2002. http://dx.doi.org/10.1201/9781482265019-10.

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"Iron as an Additive in Aluminum Alloys." In Iron in Aluminium Alloys, 261–322. CRC Press, 2002. http://dx.doi.org/10.1201/9781482265019-11.

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"Chapter 1Phase Diagrams of Iron-ContainingAluminum Alloys." In Iron in Aluminium Alloys, 17–106. CRC Press, 2002. http://dx.doi.org/10.1201/9781482265019-8.

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"Structure and Properties of Iron-Containing Aluminum Alloys: General Features." In Iron in Aluminium Alloys, 107–200. CRC Press, 2002. http://dx.doi.org/10.1201/9781482265019-9.

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"Nickel–iron, cobalt–iron and aluminium–iron alloys." In Electrical Steels - Volume 1: Fundamentals and basic concepts, 447–75. Institution of Engineering and Technology, 2019. http://dx.doi.org/10.1049/pbpo157f_ch16.

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Kumar Singh, Shailesh, and Vivek K. Singh. "Design and Development of High Entropy Alloys Using Artificial Intelligence." In Advances in High-Entropy Alloys - Materials Research, Exotic Properties and Applications [Working Title]. IntechOpen, 2021. http://dx.doi.org/10.5772/intechopen.96761.

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The conventional design approach of alloys initiates with one principal element and continues by adding several alloying elements to obtain desired properties. In this method, the intrinsic properties of the designed alloy are governed by the principal element. For example, in steel alloy, iron is the principal element, Aluminium in aluminium alloy, and so on. Compared to the conventional alloy, high entropy alloys do not have any dominating elements; all the elements present in these alloys either have an equal or near-equal ratio of elements. As reported in the literature, these alloys exhibit interesting material properties such as high strength, high hardness, improved elevated temperature strength, and magnetic properties. These characteristics make HEAs a suitable option for high-performance applications in the aero engine, aerospace structures, and machine tools. High entropy alloy has multiple principal elements as shown in schematic diagram 1; it leads to much higher possible compositions than conventional alloys. The huge compositional space provides an opportunity to improve desired mechanical properties. If it is explored through “trial and error,” it will be challenging and cumbersome. Therefore, search schemes that can competently and promptly recognize particular alloys with desired properties are essential. Artificial Intelligence is a useful tool to model, discover, and optimize new alloys that enable predicting individual material properties as a function of composition. While the application of Artificial Intelligence is quite popular in many aspects of society, its usage in material informatics is still in the nascent stage. The algorithm used in artificial intelligence is trained to pick up predictive rules from data and create a material model quicker than a computational model and can even generate the model for which no physical model exists. Artificial Intelligence (AI) allows predicting a set of experiments to be conducted to detect new alloy having desired properties. Thus, AI can be used as a valuable tool to optimize the development of new alloys.
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Jolly, M. R., K. Salonitis, E. Pagone, and M. Papanikolaou. "Substitution of cast iron engine components with aluminium alloys: A life cycle perspective." In Gießtechnik im Motorenbau 2019, 153–68. VDI Verlag, 2019. http://dx.doi.org/10.51202/9783181023396-153.

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Conference papers on the topic "Iron-aluminium alloys"

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Johansson, P., J. Liu, and S. Savage. "Nickel-Iron-Aluminium Shape Memory Alloys with Improved Properties by Rapid Solidification." In ESOMAT 1989 - Ist European Symposium on Martensitic Transformations in Science and Technology. Les Ulis, France: EDP Sciences, 1989. http://dx.doi.org/10.1051/esomat/198904008.

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Chakravarty, H., J. Ballor, and C. J. Boehlert. "Effect of Alloying Additions of Aluminium and Iron on the Creep Resistance of Ti-12Cr (wt.%)." In HT2019. ASM International, 2019. http://dx.doi.org/10.31399/asm.cp.ht2019p0355.

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Abstract Titanium (Ti) and its alloys are among the desired materials for biomaterial, marine, and aerospace applications due to their excellent properties. Metastable beta titanium (β-Ti) alloys exhibit enhanced strengths and hardness values after thermomechanical processing (TMP) due to the presence of omega (ω) and alpha (α) phase precipitates in the beta (β) matrix. In this study, the creep properties of three different β-Ti alloys, Ti-12Cr-1Fe-3Al (wt. %), Ti-12Cr-3Al (wt. %), and T- 12Cr (wt. %), were experimentally obtained at different applied stresses and at 683 K. The relationship between microstructure and creep properties was investigated. X-ray diffractometer (XRD), optical microscope (OM), and scanning electron microscope (SEM) were used to help characterize the microstructure before and after creep deformation. The hardness of alloys increased after heat treatment for 48 hrs at 410 ºC due to the precipitation of the α and ω phases. The creep tests showed that Ti-12Cr-1Fe-3Al (wt. %) was the most creep resistant and Ti-12Cr (wt. %) was the least creep resistant.
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Karimi, A., P. H. Giauque, M. Sagradi, G. Barbezat, and A. Salito. "High Damping Capacity Iron-Chromium-Aluminium Based Coatings for Surface Vibration Control." In ITSC 1998, edited by Christian Coddet. ASM International, 1998. http://dx.doi.org/10.31399/asm.cp.itsc1998p0581.

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Abstract The ability of high damping iron-chromium-aluminium alloys and coatings to absorb noise and vibrations has been investigated over a wide range of frequencies and amplitudes. The damping capacity was determined using a cantilever method based on the modal analysis technique of the flat beams and was found to be very sensitive to internal stress of specimens. Heat treatment usually enhanced the loss capability, but only an optimised annealing restored the maximum damping capacity. The influence of vibration amplitude evidenced by appearance of a maximum around ε = 10-4”, while the vibration frequency did not influence 'damping behaviour significantly. The position of the maximum damping was shifted towards lower strains with annealing time and temperature. The structure of magnetic domains was observed using the magneto-optical Kerr effect and their modification following to an applied stress or magnetic field was associated with different values of the damping capacity. Accordingly, the beneficial effect of annealing on damping capacity arises on the one hand from improved mobility of unpinned domain walls and on the other hand from growth of 90° domains considered as the principal responsible of damping. Addition of aluminium between 1-8 wt%. improved the damping values notably around 4 wt%.
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Polishetty, Ashwin, Sarat Singamneni, and Guy Littlefair. "A Comparative Assessment of Austempered Ductile Iron as a Substitute in Weight Reduction Applications." In ASME 2008 International Manufacturing Science and Engineering Conference collocated with the 3rd JSME/ASME International Conference on Materials and Processing. ASMEDC, 2008. http://dx.doi.org/10.1115/msec_icmp2008-72091.

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Manufacturing engineering has had to undergo drastic changes in the approach to material selection in order to meet new design challenges. In the automotive industry, researchers in their effort to reduce emissions and satisfy environmental regulations, have shifted their focus to new emerging materials such as high-strength aluminium alloys, metal matrix composites, plastics, polymers and of late, Austempered Ductile Iron (ADI). ADI is a good choice for design where the criterion is high performance at reduced weight and cost. The unique, ausferrite microstructure gives the material desirable material properties and an edge over other materials. A comparative study of ADI in terms of materials properties and machining characteristics with other materials is desirable to highlight the potential of the material. This paper focuses on a comparative assessment of material and machining characteristics of ADI for different applications. The properties under consideration are machinability, weight and cost savings and versatility. ADI has a higher strength-to-weight ratio than aluminium making it a ready alternative for material selection. In terms of machinability, there are some problems associated with machining of ADI due to its work hardening nature. This paper attempts to identify the possible potential applications of ADI, by critically reviewing specific applications such as machinability, overall economics and service.
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Mazars, P., D. Manesse, and C. Lopvet. "Degradation of MCrA1Y Coatings by Interdiffusion." In ASME 1987 International Gas Turbine Conference and Exhibition. American Society of Mechanical Engineers, 1987. http://dx.doi.org/10.1115/87-gt-58.

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Coatings such as NiCrA1Y, CoCrA1Y and FeCrA1Y are deposited by plasma spraying under partial pressure on commercial f.c.c. alloys of nickel, cobalt, and iron. The interdiffusion between coating and substrate is limited in the cases of NiCrA1Y/Ni base and CoCrA1Y/Co base. On the other hand, rapid diffusion of the aluminium into the substrate occurs in the system FeCrA1Y/Fe base. When mixed systems MCrA1Y/M’ base are studied, an interdiffusion is usually observed between the elements M and M’ except in the case of the systems NiCrA1Y/Co base and FeCrA1Y/Co base where carbide diffusion barriers are formed.
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Horowitz, Emmanuel. "The Importance of Establishing an Operational Approach for the Selection of Materials in the Reactors of the Future." In 16th International Conference on Nuclear Engineering. ASMEDC, 2008. http://dx.doi.org/10.1115/icone16-48651.

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Nuclear scientists and engineers should consider adopting a more operational approach for the purpose of selecting their future materials. For each type of nuclear power generating reactor, for each coolant (water, helium or liquid metal), the next generation of specialists and decision-makers will need to choose and optimise the iron or nickel alloys, steels, ODS (oxide dispersed strengthened steels) and ceramics that are going to be used. It may well be considered that either each reactor type has its own, specific materials, or, in a complementary manner, that the efforts for improvements should be shared. At high temperatures, as found on fuel-cladding liners, heat exchangers or even tubes or tube liners, different types of steels and alloys may be envisaged. It is considered that austenitic steels provide a better creep resistance at high temperature but they must be stabilized by nickel, thereby becoming more expensive. Ferrite steels could be better as far as swelling, mechanical strength and thermal behaviour are concerned. To withstand corrosion, chromium or aluminium, ODS steels could turn out to be good solutions, if they can comply with stringent criteria. Concerning heat exchangers, choices must be made between iron and nickel alloys, according to proposed operating conditions. In the case of sodium-cooled rapid neutron reactors (RNRs), ferritic-martensitic alloys with 9%–12% chromium or chromium ODS steels could prove suitable, especially if we judge by their specific mechanical behaviour, up to at least 700°C. Nevertheless, behaviour of these steels — with respect to ageing, anisotropy, radiation induced segregation, radiation induced precipitation, reduction of activation products and welding — needs be better understood and qualified. Sodium heat exchanger materials should be carefully chosen since they have to withstand corrosion arising from the primary flow and also from the secondary or tertiary flow (either sodium or molten salts, gas or water); therefore, experimental loops are necessary to gain improved understanding and assessment of the designs envisioned. One way to improve alloys is through thermal, mechanical treatments or by surface treatments. A better way could, however, be to improve the nanostructure and mesostructure of the materials chosen at the drawing-board stage, for instance by nano-size cluster dispersion and grain size controls; experimental tests, microscope and spectroscope observations, multi-scale modelling and thermodynamics computing could also help calibrate and implement these improvements. Large, experimental databases and codes will be the keystone to defining more operational knowledge bases that will then allow us to determine terms of reference for the new materials. Failing this, time will be running out — within the next twenty years — to design and develop nuclear prototypes consistent with the criteria laid down for “Generation IV” reactors.
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Foong, Chee-Hoe, Marian Wiercigroch, and William F. Deans. "Nonlinear Dynamics of Orthogonal Metal Cutting: Experimental Studies." In ASME 1999 Design Engineering Technical Conferences. American Society of Mechanical Engineers, 1999. http://dx.doi.org/10.1115/detc99/vib-8028.

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Abstract The elimination of chatter is one of the major aims in machining to improve geometrical accuracy and surface finish. In this study, occurrence of chatter was investigated experimentally using a specially designed rig by examining time histories of the cutting and thrust force components. A broad experimental study was conducted using brass, cast iron and aluminium samples. It was found that by changing the horizontal stiffness of the rig, the thrust force variations (in the vertical direction) were completely eliminated for the cast iron samples. A systematic analysis of the chip formation for the aluminium alloy is presented.
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Mishigdorzhiyn, Undrakh, Nikolay Ulakhanov, and Alexander Semenov. "Electron-Beam Surface Modification of Boron-Based Diffusion Layers Obtained of the Surface of Steel H21." In HT2021. ASM International, 2021. http://dx.doi.org/10.31399/asm.cp.ht2021exabp0038.

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Abstract In recent years the interest in the development of new protective coatings with improved functional properties for machine parts’ surface have been of great fundamental and applied importance. The current study is devoted to the creation of coatings based on boron and aluminium on the surface of alloy steel using a cutting-edge method, combining thermal-chemical treatment (TCT) and subsequent electron beam processing (EBP). TCT was carried out in treatment pastes based on boron carbide and aluminum at 950°C and 1050°C for 2 hours. As a result of processing, diffusion layers with a thickness of up to 120 μm and 580 μm were formed on the steel surface after TCT at 950°C and 1050°C respectively. The subsequent EBP led to a complete transformation of the primary diffusion layer and an increase in its thickness to 1.6 mm. XRD analysis showed significant differences in composition before and after EBP: new compound, such as tungsten borides (WB, W2B9) and iron boride (Fe2B) were detected. In addition, it was determined that the distribution of microhardness and elemental composition (B, Al, W) over the layer thickness after EBP had a more favorable profile without significant fluctuations compared to the sample after TCT. The concentration of Al decreased significantly after EBP. It dropped from 18% after TCT to a low of 1%.
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9

Nickson, Ian D., Colin Boxall, Angela Jackson, and Guy O. H. Whillock. "The Development of a Method for the Simultaneous Measurement of Cerium (IV) and Chromium (VI) Species in Nitric Acid Media." In ASME 2009 12th International Conference on Environmental Remediation and Radioactive Waste Management. ASMEDC, 2009. http://dx.doi.org/10.1115/icem2009-16124.

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The corrosion of stainless steel in nitric acid media is a major concern for the nuclear industry. Several reprocessing schemes such as PUREX (Plutonium Uranium Reduction Extraction) and UREX (Uranium Reduction Extraction) utilise nitric acid media, and an understanding of the behaviour of key chemical species in these process streams is vital if their effect on associated corrosion reactions and their rates is to be accurately assessed and quantified. This will allow for more accurate prediction of the working lifetime of any stainless steel surface in contact with the process stream in question. Two such key species that are found in nuclear process streams are cerium as Ce(IV) and chromium as Cr(VI), both of which may act as corrosion accelerants. The redox chemistry of cerium and chromium in highly active liquor (HAL) will depend on nitrous acid concentration, temperature, acidity, total nitrate and possibly the influence of other dissolved species and hence an analytical technique for the on-line measurement of these quantities would be useful for lifetime prediction and corrosion prevention. As a result of this, a strategy for the simultaneous measurement of both Ce(IV) and Cr(VI) species in the presence of other ions typically found in process streams (such as Iron, Magnesium Neodymium and Aluminium) has been developed. The work presented will discuss the design and implementation of the electrochemical techniques that we have used in the development of this strategy and in the measurement of the species in question.
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