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Dissertations / Theses on the topic 'Iron compounds - Synthesis'

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Published: 4 June 2021

Last updated: 11 February 2022

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1

Fraser-Bell, G. "Asymmetric synthesis via iron acyl compounds." Thesis, University of Oxford, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.329923.

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2

Lian, Yiqian. "Chromium and iron organometallics in organic synthesis synthetic studies toward total synthesis of taxol and chromium to iron transfer processes /." Diss., Connect to online resource - MSU authorized users, 2006.

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3

Chi, Xiang-yong. "A Sythetic Study of a Cyclic Siloxydiyne and its Iron Carbonyl Complex." Thesis, University of North Texas, 1989. https://digital.library.unt.edu/ark:/67531/metadc500871/.

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The synthetic studies include the synthesis of the cyclic siloxydiyne, 3,3,5,5,8,8,10,10-octamethyl-4,9-dioxa-3,5,8,10-tetrasilacyclodeca-1,6- diyne [VI] and its novel iron carbonyl complex. In the preparation of [VI] by HBr promoted condensation of bis (methoxydimethylsilyl) acetylene, a minor product, a cyclic trimer was always formed along with the major product [VI]. No evidence of an equilibrium between the trimerization product and the dimerization product was found. Compound [VI] can react with iron carbonyl reagents to produce a novel binuclear iron complex of trimethylenemethane [VII]

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4

Li, Yan, and 李艷. "Synthesis and reactivity of carbene complexes of iron, ruthenium and osmium porphyrins." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2004. http://hub.hku.hk/bib/B31245730.

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5

Mock, Michael T. "Synthesis and reactivity of thioether-supported organoiron and low-valent iron complexes and cyanide-bridged binuclear complexes." Access to citation, abstract and download form provided by ProQuest Information and Learning Company; downloadable PDF file, 282 p, 2008. http://proquest.umi.com/pqdweb?did=1481668291&sid=19&Fmt=2&clientId=8331&RQT=309&VName=PQD.

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6

Walker, Jonathan Charles. "Asymmetric synthesis via iron acyl complexes." Thesis, University of Oxford, 1986. http://ora.ox.ac.uk/objects/uuid:55cfc478-5868-474f-9d2b-532218ec6fd6.

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7

Steiger, George Edward. "Synthesis and thermal decomposition of alkyl-olefin chelate complexes of iron and ruthenium." Diss., Georgia Institute of Technology, 1992. http://hdl.handle.net/1853/28052.

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8

Weber, Ronald J. "Synthesis of pyridine-bis(imine) iron compounds for future polymerization studies." Click here for download, 2006. http://wwwlib.umi.com/cr/villanova/fullcit?p1432834.

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9

Hong, Pengda, and 洪鹏达. "Synthesis and characterization of LiNi0.6Mn0.35Co0.05O2 and Li2FeSiO4/C as electrodes for rechargeable lithium ion battery." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2011. http://hub.hku.hk/bib/B47150294.

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The rechargeable lithium ion batteries (LIB) are playing increasingly important roles in powering portal commercial electronic devices. They are also the potential power sources of electric mobile vehicles. The first kind of the cathode materials, LiXCoO2, was commercialized by Sony Company in 1980s, and it is still widely used today in LIB. However, the high cost of cobalt source, its environmental unfriendliness and the safety issue of LiXCoO2 have hindered its widespread usage today. Searching for alternative cathode materials with low cost of the precursors, being environmentally b

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10

Lambert, Ronald J. W. "The bonding, synthesis and electrochemistry of some iron-sulphur-nitrosyl compounds." Thesis, University of St Andrews, 1990. http://hdl.handle.net/10023/14972.

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Salts of the bls(μ-thiosulphato-S)-bis(dinitrosylferrate)(2-) anion, [Fe2(S2o3)2(NO)4]2- can be prepared by the reaction of iron(ll)/thiosulphate mixtures with nitrite ion. The crystal structure of {(Ph3P)2N}2[ Fe2(S203)2(NO)4] reveals it to adopt a trans structure. 15N n.m.r. studies of this salt also show it to adopt the trans structure in solution. The anion reacts with thiolate ion, RS-, to provide good yields of Fe2(SR)2(NO)4; e.p.r. studies show the mononitrosyl [Fe(N0)(SR)3]3− to be a major intermediate in this reaction. Salts of the Black Roussin ion, [Fe4S3(NO)7]- react with aryldiazo

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11

Kwong, Wai-lun, and 鄺偉倫. "Anti-cancer ytterbium porphyrin and iron polypyridyl complexes: synthesis, cytotoxicity and bioinformaticsstudies." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2012. http://hub.hku.hk/bib/B48521711.

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Discovery of anti-cancer cisplatin was a great success in anti-cancer chemotherapy. Numerous analogues of cisplatin such as carboplatin and oxaliplatin, were developed to improve the clinical effectiveness. Nevertheless, the clinical uses of these platinum-based drugs are limited by the occurrence of drug-resistance, narrow range of susceptible cancer types and severe toxicity. These drawbacks have stimulated the development of other metal-based compounds with distinct mechanisms of anti-cancer action. In this study, a series of ytterbium(III) porphyrin and iron(II) polypyridyl complexes were

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12

Yousif-Ross, Sue A. "Studies toward the synthesis of phosphido-bridged iron carbonyl and nitrosyl compounds /." The Ohio State University, 1988. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487596307356516.

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13

Chan, Sau-han, and 陳秀嫻. "Non-heme iron(III) and gold(III) complexes with dicarboxamide ligands: synthesis, structures and anti-cancerproperties." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2007. http://hub.hku.hk/bib/B39557984.

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14

Chan, Sau-han. "Non-heme iron(III) and gold(III) complexes with dicarboxamide ligands synthesis, structures and anti-cancer properties /." Click to view the E-thesis via HKUTO, 2007. http://sunzi.lib.hku.hk/HKUTO/record/B39557984.

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15

Krüger, Christoph [Verfasser]. "Molecular magnetic switches : synthesis and characterisation of novel iron spin crossover compounds / Christoph Krüger." Hannover : Technische Informationsbibliothek (TIB), 2016. http://d-nb.info/1107038138/34.

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16

Goho, Danielle Sympathie. "Selective production of nitrogen-containing compounds via a modified Fischer-Tropsch process." Master's thesis, Faculty of Engineering and the Built Environment, 2021. http://hdl.handle.net/11427/33736.

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Research on the co-feeding of ammonia into the Fischer-Tropsch (FTS) process over ironbased catalysts revealed that the presence of ammonia during the FTS leads to the formation of nitrogen-containing compounds (NCCs). Recent studies on the addition of ammonia to the FTS process, now known as the Nitrogen Fischer-Tropsch (NFTS) process, reported that the production of NCCs during the NFTS process is enhanced by the presence of oxygenates. The studies, therefore, suggested that oxygenates are the primary precursors of NCCs. However, due to the gap in knowledge related to the NFTS reactions mech

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17

Shyu, Shin-guang. "Synthesis and mechanistic study of dinuclear phosphido-bridged complexes of iron, molybdenum, and tungsten /." The Ohio State University, 1986. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487266362338179.

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18

Pachmayr, Ursula [Verfasser], and Dirk [Akademischer Betreuer] Johrendt. "Hydrothermal synthesis of layered iron-chalcogenide superconductors and related compounds / Ursula Pachmayr ; Betreuer: Dirk Johrendt." München : Universitätsbibliothek der Ludwig-Maximilians-Universität, 2017. http://d-nb.info/1130587428/34.

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19

Holloway, Lauren Renee. "Synthesis and investigation of novel dinitrosyl-Iron complexes of chelated Bis-phosphine ligands| Potential nitric oxide delivery compounds." Thesis, California State University, Long Beach, 2014. http://pqdtopen.proquest.com/#viewpdf?dispub=1527325.

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20

Wilson, Duane C. "Synthesis, Structure, And Characterization Of Rare Earth(Iii) Transition Metal Cyanides; Lanthanide(Ii) And Metallocene Amidotrihydroborates." Columbus, Ohio : Ohio State University, 2009. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1230880974.

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21

Cedervall, Johan. "Synthesis and characterizationof rare earth free magnetic materialsfor permanent magnet applications." Thesis, Uppsala universitet, Institutionen för kemi - Ångström, 2013. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-200882.

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In this thesis the compounds Fe5SiB2 and Fe5PB2 have beensynthesized via high temperature synthesis, including arc melting anddrop synthesis. The structure for both compounds are of Cr5B3 typewith the space group I4/mcm. The cell parameters were refined toa = 5.5533 Å and c = 10.3405 Å for Fe5SiB2 and a = 5.4903 Å andc = 10.3527 Å for Fe5PB2. The saturation magnetization at roomtemperature for Fe5SiB2 has been measured to 138.8 Am2/kg and theanisotropy constant has been estimated to 79 kJ/m3. Theferromagnetic properties and the high anisotropy constant makesthese materials promising as permane

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22

Armstrong, Kenneth Mark. "Catalytic synthesis of organophosphate plastics additives from white phosphorus." Thesis, University of St Andrews, 2011. http://hdl.handle.net/10023/2587.

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Triaryl phosphates were synthesized from white phosphorus and phenols in aerobic conditions and in the presence of iron catalysts and iodine. Full conversion to phosphates was achieved without the use of chlorine or chlorinated solvents, and the reactions do not produce acid waste. Triphenyl phosphate, tritolyl phosphate and tris(2,4-di-tert-butyl)phenyl phosphate were synthesized by this method with 100% conversion from P₄. Various iron(III) diketonates were used to catalyse the conversion. Mechanistic studies showed the reaction to proceed via the formation of phosphorus triiodide (PI₃), the

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23

Mbatha, Lancelot Lungelo Mpatho. "The synthesis, characterization and metathesis reactivity of compounds (with at least one pendant alkene group) of iron, ruthenium and iridium." Master's thesis, University of Cape Town, 2008. http://hdl.handle.net/11427/6331.

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Includes abstract.<br>Includes bibliographical references.<br>This thesis reports on the synthesis, characterisation and metathesis reactivity studies of (i) ruthenium and iron mono(alkenyl) complexes of the type LM(COh{(CH2)nCH=CH2} (M = iron or ruthenium, L = l1s-C sHs or l1 s-CS(CH3)s and n = 2 - 6), 41 - 51; (ii) iridium complexes of the type Cp*Ir(CI)2{PPh2(CH2)mCH=CH2} (m = 2 - 4 and 6), 69 - 72; and (iii) bis(alkenyl) acyl complexes of the type CpFe(CO){C(O)(CH2)nCH=CH2}{PPh2(CH2)mCH=CH2} (n = 3 - 4, m = 3, 4 and 6), 62 - 65.

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24

Wójcik, Katarzyna. "The synthesis, structure and reactivity of iron-bismuth complexes : Potential Molecular Precursors for Multiferroic BiFeO3." Doctoral thesis, Universitätsbibliothek Chemnitz, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-201000715.

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The thesis presented here is focused on the synthesis of iron-bismuth alkoxides and siloxides as precursors for multiferroic BiFeO<sub>3</sub> systems. Spectrum of novel cyclopentadienyl substituted iron-bismuth complexes of the general type [{Cp<sup>y</sup>(CO)<sub>2</sub>Fe}BiX<sub>2</sub>], as potential precursors for cyclopentadienyl iron-bismuth alkoxides or siloxides [{Cp<sup>y</sup>(CO)<sub>2</sub>Fe}Bi(OR)<sub>2</sub>] (R-O<sup>t</sup>Bu, OSiMe<sub>2</sub><sup>t</sup>Bu), were obtained and characterised. The use of wide range of cyclopentadienyl rings in the iron carbonyl compounds all

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25

Anderson, Michael D. 1980. "Novel Misfit Layer Systems: Synthesis and Characterization." Thesis, University of Oregon, 2011. http://hdl.handle.net/1794/12092.

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xxiv, 265 p. : ill. (some col.)<br>Stabilizing mechanisms and design considerations for generating misfit layer compounds with a variety of different structural motifs were explored using designed precursors consisting of elemental layers. Layer order in the precursor film and the behavior of binary reaction couples was used to avoid undesirable reaction intermediates. Electron diffraction patterns of CuCr2 Se4 were inconsistent with prior reports that this compound has the spinel structure and were more consistent with a hexagonal R 3 ̄ structure. STEM imaging also suggests CuCr2 Se4 prepa

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26

RIBEIRO, THATIANA G. D. "Sintese e caracterizacao de nanoparticulas magneticas de oxidos mistos de MnFesub(2)Osub(4) recobertas comm quitosona. Estudos da influencia na dopagem com Gdsup(3+) nas propriedades estruturais e magneticas." reponame:Repositório Institucional do IPEN, 2008. http://repositorio.ipen.br:8080/xmlui/handle/123456789/11515.

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Made available in DSpace on 2014-10-09T12:52:45Z (GMT). No. of bitstreams: 0<br>Made available in DSpace on 2014-10-09T14:02:48Z (GMT). No. of bitstreams: 0<br>Dissertacao (Mestrado)<br>IPEN/D<br>Instituto de Pesquisas Energeticas e Nucleares - IPEN-CNEN/SP

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27

CARMO, JOÃO R. do. "Síntese, caracterização microestrutural e elétrica de compostos cerâmicos à base de soluções sólidas de titanato de estrôncio, titanato de cálcio e óxido de ferro." reponame:Repositório Institucional do IPEN, 2011. http://repositorio.ipen.br:8080/xmlui/handle/123456789/10035.

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Made available in DSpace on 2014-10-09T12:34:02Z (GMT). No. of bitstreams: 0<br>Made available in DSpace on 2014-10-09T13:59:37Z (GMT). No. of bitstreams: 0<br>Tese (Doutoramento)<br>IPEN/T<br>Instituto de Pesquisas Energeticas e Nucleares - IPEN-CNEN/SP

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28

Pryor, Donald Edward. "Synthesis and Bioactivity Studies of Nanoparticles Based on Simple Inorganic and Coordination Gallium Compounds as Cellular Delivering Vehicles of Ga(III) Ions for Potential Therapeutic Applications." Kent State University / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=kent1543554532063877.

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29

Binding, Samantha Carys. "Synthesis and characterisation of permethylpentalene complexes and permethylpentalene derivatives." Thesis, University of Oxford, 2015. http://ora.ox.ac.uk/objects/uuid:7855e90d-7ce9-42eb-b962-b68606ade746.

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This thesis expands the scope for using the permethylpentalene ligand and its precursors in the synthesis of organometallic complexes. <strong>Chapter one</strong> begins with a brief review of linked metallocenes, with which multimetallic compounds bridged by pentalene ligands have often been compared, followed by a comprehensive review of the routes used to make pentalenes and substituted pentalenes. Organometallic compounds of pentalenes are introduced, with a focus on bimetallic systems. <strong>Chapter two</strong> explores the diversification of substituents added to the permethylpentale

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30

Jackson, Henry Lee. "Synthetic models of Fe-type nitrile hydratase /." Thesis, Connect to this title online; UW restricted, 2002. http://hdl.handle.net/1773/8532.

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31

Hoffmann, Andrea Viola [Verfasser], Thomas F. [Akademischer Betreuer] Fässler, and Tom [Akademischer Betreuer] Nilges. "Synthesis and Characterization of New Compounds Structurally Related to Superconducting Iron-Pnictides : In the system Ae–T–E (Ae = Ca, Sr, Ba; T = Fe Co, Ni, Rh; E = Si, Ge, P, As) / Andrea Viola Hoffmann. Betreuer: Thomas F. Fässler. Gutachter: Thomas F. Fässler ; Tom Nilges." München : Universitätsbibliothek der TU München, 2015. http://d-nb.info/1095099884/34.

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32

Rouida, Bouchaïb. "Syntheses diastereoselectivites de complexes chiraux du molybdene et du fer carbonyle par action de derives asymetriques du phosphore." Paris 6, 1988. http://www.theses.fr/1988PA066515.

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La reaction photochimique de plusieurs phosphines asymetriques avec des complexes carbonyles du fer et du molybdene cyclopentadienyls fournit des complexes chiraux. Ceux-ci se forment par couples de diastereoisomeres en proportions variables. L'effet sterique de ces phosphines sur le mecanisme de reaction est etudie. D'autre part, lorsque le complexe cyclopentadienyl carbonyle du fer comporte une liaison fer-silicium, fer-germanium ou fer-etain il se produit des interactions conduisant a des inductions diastereotopiques importantes

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33

Siriwardane, Upali. "Systematic syntheses of iron-triad (Fe,Ru,Os) tetranuclear clusters by redox condensation reactions of [Ru(3);CO(11)) and [Os(3);CO(11)] trinuclear carbonylates; co-crystallization of ruthenium-osmium clusters /." The Ohio State University, 1985. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487264603216477.

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34

MacLeod, Michael M. "Control of Fusarium crown and root rot on tomato seedlings using synthetic iron chelators and phenolic compounds found in lettuce roots." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/mq21095.pdf.

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35

Boudouvas, Denis. "Effet du potassium sur un catalyseur composite Fe-Co-C en synthèse d'hydrocarbures." Grenoble INPG, 1989. http://www.theses.fr/1989INPG0092.

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Etude de la promotion par le potassium du catalyseur composite fe-co-c, c'est-a-dire de l'amelioration de son activite catalytique et de sa selectivite en alcenes. L'addition de potassium est realisee soit par impregnation par une solution aqueuse de k#2co#3, soit par la formation intermediaire d'un compose d'insertion avec le carbone de formule kc#3#2. L'evolution de la selectivite des catalyseurs promus et non promus par le potassium est etudiee a des conversions en monoxyde de carbone analogues a celles d'un procede industriel. Des tests catalytiques a faible conversion et des mesures de ch

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36

Simler, Roland. "Complexation-decomplexation en serie fer-tricarbonyle : nouvelles possibilites en synthese organique." Université Louis Pasteur (Strasbourg) (1971-2008), 1988. http://www.theses.fr/1988STR13174.

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Etude de deux nouvelles possibilites des complexes dieniques de fer-tricarbonyle en synthese organique: le transfert de chiralite lors de leur phodecomplexation reductrice en milieu acide, et l'acces a des cyclopentenones par decomplexation cyclocarbonylante

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37

Chemla, Philippe. "Reactions diastereospecifiques de dienones fer-tricarbonyle : applications a la synthese d'alcools fonctionnalises optiquement purs." Université Louis Pasteur (Strasbourg) (1971-2008), 1988. http://www.theses.fr/1988STR13049.

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La methode de synthese utilisee permet d'acceder avec de bons rendements, a des composes de haute purete optique et de configuration donnee: alpha et gamma aldols et une delta -lactone fonctionnalisee en position 5. Des hydrocarbures optiquement actifs dont le centre asymetrique est eloigne de toute fonction, ont egalement ete synthetises par cette voie

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38

Heider, Silvio. "Synthese neuer tri- und hexadentater Stickstoffbasen für Eisen(II) Spin Crossover Komplexe." Doctoral thesis, Universitätsbibliothek Chemnitz, 2013. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-120783.

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Die vorliegende Arbeit thematisiert Eisen(II)-Komplexe mit Spinübergangseigenschaften. Dafür wurden neue hexadentate Liganden auf Basis von N,N'-Bis(2,2'-bipyridin-6-ylmethyl)-2,2'-biphenylendiamin entwickelt. Die in Kapitel 3.1 vorgestellten Systeme variieren dabei in den jeweiligen Substituenten der 6,6‘-Positionen der Biphenyleinheit. Es wird der Einfluss dieser Gruppen auf die magnetischen Eigenschaften der resultierenden Komplexe gezeigt. Im darauffolgenden Kapitel 3.2 wird ein variiertes Ligandensystem vorgestellt, in welchem anstelle einfacher Substituenten Donorfunktionen eingeführt wu

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39

Alvarez, Gonzalez Eleuterio. "Substitution d'ethers et d'alcools allyliques par differents nucleophiles en presence de complexes de nickel(0) : synthese stereoselective des dienes-1,4 a partir des sulfones dieniques avec le chlorure d'isopropylmagnesium en presence de sels de." Paris 6, 1987. http://www.theses.fr/1987PA066064.

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40

Ben, Salem Azzedine. "Synthese et caracterisation physique et structurale des conducteurs unidimensionnels de type fe : :(1+x)nb::(3-x)se::(10)." Nantes, 1987. http://www.theses.fr/1987NANT2018.

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Ce compose est le prototype d'une serie de formulation (mm')nb::(2)s::(10)(mm' = fe,v,cr,nb,ta) presentant une chaine trigonale prismatique |nbse::(3)| et une double chaine oelaedrique |(mm')se::(6)|. Ces composes ont une transition metal isolant vers 140 k. L'observation d'une onde de densite de charge aux caracteristiques identiques a celles de nbse::(3) indique que la chaine conductrice est la chaine trigonale prismatique |nbse::(3)|. La variation de la conductivite au voisinage de la transition indique un mecanisme de localisation d'anderson. Les proprietes physiques du compose ou se a ete

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41

Tahiri, Mohamed. "Phtalocyanines de fer(i) et de fer(0) : synthese, structure et reactivite." Université Louis Pasteur (Strasbourg) (1971-2008), 1987. http://www.theses.fr/1987STR13043.

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Synthese et caracterisation d'une serie de complexes monoreduits de phtalocyanine de fer de type (fe pc r::(8))**(-) ou r=och::(3), ch::(3), h, cl et cn. On donne les structures par rx de composes monoanioniques et dianionique fe pc**(-) et fe pc**(2-). Proprietes chimiques de fe pc**(2-). De tels especes peuvent etre des modeles d'intermediaires formes dans la reaction de la phenylhydrazine sur la metmyoglobine ou dans le metabolisme de substrats suicides par cytochrome p450

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42

Lenormand-Foucaut, Alix. "Modélisation chimique de protéines fer-soufre à haut potentiel : synthèses et caractérisations physico-chimiques de nouveaux agrégats à ligands thiolates encombrés dans les états (4Fe-4S)2+ et (4Fe-4S)3+." Université Joseph Fourier (Grenoble), 1996. http://www.theses.fr/1996GRE10056.

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Cette these se situe dans le cadre des modelisations chimiques de proteines fer-soufre, plus particulierement les proteines fer-soufre a haut potentiel (hipip). L'objectif est de synthetiser des centres 4fe-4s dans les deux etats d'oxydation physiologiques 4fe-4s#2+ et 4fe-4s#3+ et de les caracteriser d'un point de vue physico-chimique. L'hypothese a partir de laquelle le sujet a ete aborde consiste a supposer qu'il est necessaire d'etablir une zone steriquement encombree et hydrophobe autour de l'agregat afin de proteger le centre 4fe-4s#3+ d'une degradation oxydante. Pratiquement, un tel env

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43

Benaissa, Tahar. "Synthèse de ligands contenant un atome de fluor et pouvant donner des complexes à applications médicales : étude de la complexation de la 5-fluoro-8-hydroxyquinoline avec des cations métalliques, par RMN du fluor." Université Joseph Fourier (Grenoble), 1996. http://www.theses.fr/1996GRE10100.

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Ce travail se place a la convergence de deux grands themes etudies au laboratoire: le marquage de molecules par un atome de fluor et l'etude de la complexation de cations metalliques par des ligands. La premiere partie concerne la preparation de deux series de ligands contenant du fluor: des biphenols et des composes contenant des groupements 2-fluoropyridines. Les biphenols substitues par deux ou quatre atomes de fluor (en position 4,4' ; 5,5' ; 4,4 ;,5,5') ont ete obtenus a partir de bromophenols par une reaction de type ullman. Leurs derives sulfones ont egalement ete prepares pour augmente

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44

Beaujolais, Virginie. "Cavités moléculaires chirales à groupements hydroxyles convergents : synthèses et étude de complexation." Université Joseph Fourier (Grenoble), 1996. http://www.theses.fr/1996GRE10148.

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La complexation du fer est un probleme biologique fondamental, resolu chez les microorganismes par les siderophores, ligands de bas poids moleculaire aptes a solubiliser selectivement les ions ferriques, puis a livrer le metal a la cellule via des processus de reconnaissance complexes. Les siderophores synthetiques presentent a la fois un interet pour l'etude du metabolisme du fer et peuvent avoir des applications therapeutiques dans le cas des surcharges en fer. Un nouveau siderophore synthetique tripodal, base sur trois sous-unites chelatantes de type o,o'-dihydroxybiphenyle, a ete prepare e

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45

Nasri, Habib. "Synthese et caracterisation de porphyrines de fe(ii) et fe(iii) : modelisation du site actif du centre p460 present dans l'hydroxylamine oxydoreductase de la bacterie nitrosomonas europaea." Université Louis Pasteur (Strasbourg) (1971-2008), 1987. http://www.theses.fr/1987STR13149.

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Synthese de modeles du site actif du cytochrome p460 a l'etat reduit. Donc synthese et caracterisation d'une serie de complexes (fe(ii) (or)t piv pp)**(-) ou or=ome, oph, ophf::(4), oac; et des complexes fe(iii)cltpivpp, fe(iii)(oac)tpivpp, fe(iii)(so::(3)cf::(3))(h::(2)o)tpivpp

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M'thiruaine, Cyprian Muturia. "Synthesis and characterization of iron amine complexes." Thesis, 2011. http://hdl.handle.net/10413/9666.

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The organometallic Lewis acid [(η5-C5H5)(CO)2Fe]BF4 reacts with excess dry diethyl ether at low temperatures to form the novel labile complex [(η5-C5H5)(CO)2Fe(OEt2)]BF4 which in turn serves as a precursor in the syntheses of various cationic dicarbonylcyclopentadienyliron complexes. The reactions of [(η5-C5H5)(CO)2Fe(OEt2)]BF4 with various 1-alkylamines, α,ω-diaminoalkanes, N-heterocyclics and heterofunctional amine ligands, as well as olefins, have been investigated. Reactions with 1-alkylamines and α,ω-diaminoalkane ligands lead to a series of novel monuclear and dinuclear complexes of the

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Zobi, Fabio. "Synthesis and characterization of hetero [greek character 'mu']-oxo complexes of ruthenium porphyrin and iron phthalocyanine." 2001. http://wwwlib.umi.com/cr/yorku/fullcit?pMQ66415.

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Thesis (M. Sc.)--York University, 2001. Graduate Programme in Chemistry.<br>Typescript. Includes bibliographical references (leaves 77-83). Also available on the Internet. MODE OF ACCESS via web browser by entering the following URL: http://wwwlib.umi.com/cr/yorku/fullcit?pMQ66415.

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Makunya, Ntaoleng Maureen. "Tertiary phosphine induced migratory carbonyl insertion in cyclopentadienyl complexes of iron." Thesis, 2008. http://hdl.handle.net/10210/393.

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The aim of this study was to investigate the mechanism of phosphine induced migratory carbonyl insertion in the monocyclopentadienyliron(II) carbonyl complex, [η5- (C5H5)Fe(CO)2Me], upon variation of different parameters such as the type and the concentration of the phosphine ligand and the solvent. The mechanism that agrees with the results obtained is presented below.<br>Prof. A. Roodt

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Cassidy, Juanita Morgan. "The synthesis, characterization and intramolecular dynamics of heavy main-group iron carbonyl compounds." Thesis, 1991. http://hdl.handle.net/1911/16427.

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The reaction of TlCl$\sb3\cdot$4H$\sb2$O with a methanolic KOH solution of Fe(CO)$\sb5$ is known to produce $\lbrack\rm Et\sb4N\rbrack\sb2\lbrack Tl\sb2Fe\sb4(CO)\sb{16}\rbrack$ which serves as a precursor for several Tl-Fe carbonyl compounds. When a solution of $\lbrack\rm Et\sb4N\rbrack\sb2\lbrack Tl\sb2Fe\sb4(CO)\sb{16}\rbrack$ is allowed to stand in the sunlight for long periods of time, three new thallium-iron carbonyls are also known to result: $\lbrack\rm Et\sb4N\rbrack\sb2\lbrack Tl\sb2Fe\sb6(CO)\sb{24}\rbrack$, $\lbrack\rm Et\sb4N\rbrack\sb4\lbrack Tl\sb4Fe\sb8(CO)\sb{30}\rbrack$ and

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"Synthesis and characterization of the iron-based superconductor: fluorine and yttrium co-doped SmFeAsO." 2011. http://library.cuhk.edu.hk/record=b5894795.

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Lai, Kwing To = 鐵基超導體的合成與分析 : 氟及釔合摻SmFeAsO / 黎烱韜.<br>Thesis (M.Phil.)--Chinese University of Hong Kong, 2011.<br>Includes bibliographical references.<br>Abstracts in English and Chinese.<br>Lai, Kwing To = Tie ji chao dao ti de he cheng yu fen xi : fu ji yi he shan SmFeAsO / Li Jiongtao.<br>Abstract --- p.i<br>摘要 --- p.iii<br>Acknowledgements --- p.v<br>Table of contents --- p.vii<br>List of table captions --- p.x<br>List of figure captions --- p.xi<br>Chapter Chapter 1 --- Introduction --- p.1<br>Chapter 1.1 --- Superconductivity --- p.1<br>Chapter 1.1.1 --- Physical properties ---

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