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Relevant bibliographies by topics / Isocyanides - Synthesis

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Journal articles

Academic literature on the topic 'Isocyanides - Synthesis'

Author: Grafiati

Published: 4 June 2021

Last updated: 3 February 2022

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Journal articles on the topic "Isocyanides - Synthesis"

1

Ahmadi, Fereshteh, and Ayoob Bazgir. "Synthesis of benzoimidazoquinazolines by cobalt-catalyzed isocyanide insertion–cyclization." RSC Advances 6, no. 66 (2016): 61955–58. http://dx.doi.org/10.1039/c6ra06828f.

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The synthesis of benzoimidazoquinazoline amines by the reaction of isocyanides and benzo[d]imidazol-anilines via a cobalt-catalyzed isocyanide insertion reaction into the two N–H active bonds is reported.

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2

Xiong, Jun, Qi-Xun Feng, Zhi-Ying Mu, et al. "Efficient Synthesis of 4H-3,1-Benzoxazine Derivatives via One-Pot Sequential Passerini-Azide/Palladium-Catalyzed Azide–Isocyanide Coupling/Cyclization Reaction." Synlett 31, no. 10 (2020): 1003–6. http://dx.doi.org/10.1055/s-0039-1690831.

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A new, one-pot method for the synthesis of 4H-3,1-benzoxazine derivatives has been developed. The Passerini-azide reactions of 2-azidobenzaldehydes, trimethylsilyl azide, and isocyanides produced azide intermediate without separation, which then reacted with isocyanides to give 4H-3,1-benzoxazine derivatives via a tandem one-pot palladium-catalyzed azide–isocyanide coupling/cyclization reaction in moderate to good yields.

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3

Vavsari, Vaezeh Fathi, Pegah Shakeri, and Saeed Balalaie. "Application of Chiral Isocyanides in Multicomponent Reactions." Current Organic Chemistry 24, no. 2 (2020): 162–83. http://dx.doi.org/10.2174/1385272824666200110095120.

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As one of the most important building blocks in organic synthesis, isocyanides come in for a wide range of transformations owing mostly to their unusual terminal carbon center adsorbed electrophiles, reacted with nucleophiles, get involved in radical reactions and coordinated with metal centers. The distinctive feature of isocyanide is its ready willingness to participate in multicomponent reactions (MCRs). MCRs represent a great tool in organic synthesis for the construction of new lead structures in a single procedure introducing both structural diversity and molecular complexity in only one

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4

Kim, Jungwon, and Soon Hyeok Hong. "Organocatalytic activation of isocyanides: N-heterocyclic carbene-catalyzed enaminone synthesis from ketones." Chemical Science 8, no. 3 (2017): 2401–6. http://dx.doi.org/10.1039/c6sc05266e.

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5

Kodama, Shintaro, Yuki Yamamoto, Yohsuke Kobiki, et al. "Transition-Metal-Catalyzed Diarylation of Isocyanides with Triarylbismuthines for the Selective Synthesis of Imine Derivatives." Materials 14, no. 15 (2021): 4271. http://dx.doi.org/10.3390/ma14154271.

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The transition-metal-catalyzed diarylation of isocyanides with triarylbismuthines was investigated in detail, and rhodium catalysts such as [RhCl(nbd)]2 were found to selectively afford N-alkyl diaryl ketimines. On the other hand, palladium-catalyzed diarylation proceeded with the incorporation of two molecules of isocyanide, preferentially yielding N,N’-dialkyl or N,N’-diaryl α-diimines. In addition, a cascade synthesis of 2,3-diarylquinoxalines starting from the palladium-catalyzed diarylation of isocyanides with triarylbismuthines was successfully achieved.

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6

Shaabani, Ahmad, Hassan Farhid, Mohammad Mahdi Rostami, and Behrouz Notash. "Synthesis of Depsipeptides via Isocyanide-Based Consecutive Bargellini–Passerini Multicomponent Reactions." SynOpen 05, no. 03 (2021): 167–72. http://dx.doi.org/10.1055/a-1533-3823.

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AbstractAn efficient and straightforward approach has been established for the preparation of a new class of depsipeptide structures via isocyanide-based consecutive Bargellini–Passerini multicomponent reactions. 3-Carboxamido-isobutyric acids bearing an amide bond were obtained via Bargellini multicomponent reaction from isocyanides, acetone, and chloroform in the presence of sodium hydroxide. Next, via a Passerini multicomponent-reaction strategy, a new class of depsipeptides was synthesized using the Bargellini reaction products, isocyanides, and aldehydes. The depsipeptides thus prepared h

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7

Liu, Jian-Quan, Xuanyu Shen, Zhenhua Liu, and Xiang-Shan Wang. "Copper-catalyzed synthesis of arylcarboxamides from aldehydes and isocyanides: the isocyano group as an N1 synthon." Organic & Biomolecular Chemistry 15, no. 30 (2017): 6314–17. http://dx.doi.org/10.1039/c7ob01449j.

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For the first time, transition-metal-catalyzed isocyanide group acting as an N1 synthon rather than exhibiting the carbene-like reactivity was discovered, exploiting a new reactivity profile of isocyanides.

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8

Patil, Pravin, Maryam Ahmadian-Moghaddam, and Alexander Dömling. "Isocyanide 2.0." Green Chemistry 22, no. 20 (2020): 6902–11. http://dx.doi.org/10.1039/d0gc02722g.

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Isocyanides are important chemicals, with limited availability, thus reducing their general use. Our highly improved isocyanide synthesis performed on mole to μ-mole scale, individually or in a 96-well parallel fashion enables unprecedented exploration of novel chemistries.

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9

Anary-Abbasinejad, Mohammad, Maryam Rasekh, and Hossein Anaraki-Ardakani. "Four-Component Reaction of Isocyanides, Acetylenic Esters, and Carboxylic Acids for the Synthesis of Functionalised 2,5-diaminofurans." Journal of Chemical Research 2009, no. 5 (2009): 271–73. http://dx.doi.org/10.3184/030823409x439735.

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An improved four-component reaction of isocyanides is described. The reaction between two equivalents of an isocyanide, dialkyl acetylenedicarboxylates and aliphatic carboxylic acids at room temperature leads to 2,5-diaminofuran derivatives in good yields.

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10

Tailor, Yogesh Kumar, Sarita Khandelwal, Yogita Kumari, Kamlendra Awasthi, and Mahendra Kumar. "An efficient one pot three-component nanocatalyzed synthesis of spiroheterocycles using TiO2 nanoparticles as a heterogeneous catalyst." RSC Advances 5, no. 57 (2015): 46415–22. http://dx.doi.org/10.1039/c5ra04863j.

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An efficient, environmentally benign isocyanide-based domino protocol is presented for synthesizing spiroheterocycles with 2-amino benzothiazole/1,3,4-thiadiazole, cyclohexyl/tert-butyl isocyanides and isatines/cyclic carbonyls, catalyzed by recyclable nanocrystalline TiO<sub>2</sub>.

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