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Journal articles on the topic 'Isohexide'

Author: Grafiati

Published: 6 September 2023

Last updated: 31 July 2025

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1

Wroblewska, Aleksandra, Arkadiusz Zych, Shanmugam Thiyagarajan, et al. "Towards sugar-derived polyamides as environmentally friendly materials." Polymer Chemistry 6, no. 22 (2015): 4133–43. http://dx.doi.org/10.1039/c5py00521c.

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As part of our ongoing study investigating isohexide-based polyamides, we have synthesized isosorbide(bis(propan-1-amine)) (DAPIS) and studied its reactivity in the polymerization towards fully biobased polyamides.

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2

Marubayashi, Hironori, Takaaki Ushio, and Shuichi Nojima. "Crystallization of polyesters composed of isohexides and aliphatic dicarboxylic acids: Effects of isohexide stereoisomerism and dicarboxylic acid chain length." Polymer Degradation and Stability 146 (December 2017): 174–83. http://dx.doi.org/10.1016/j.polymdegradstab.2017.10.005.

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3

Ji, Xiaodong, Zikun Wang, Jingling Yan, and Zhen Wang. "Partially bio-based polyimides from isohexide-derived diamines." Polymer 74 (September 2015): 38–45. http://dx.doi.org/10.1016/j.polymer.2015.07.051.

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4

Wu, Jing, Pieter Eduard, Shanmugam Thiyagarajan, et al. "Isohexide Derivatives from Renewable Resources as Chiral Building Blocks." ChemSusChem 4, no. 5 (2011): 599–603. http://dx.doi.org/10.1002/cssc.201100076.

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5

Wu, Jing, Shanmugam Thiyagarajan, Célia Fonseca Guerra, et al. "Isohexide Dinitriles: A Versatile Family of Renewable Platform Chemicals." ChemSusChem 10, no. 16 (2017): 3202–11. http://dx.doi.org/10.1002/cssc.201700617.

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6

Rajput, Bhausaheb S., Kalpakasseril Girija Lekshmy, Shamal K. Menon, and Samir H. Chikkali. "Synthesis of isohexide-di(ether-ene)s and ADMET polymerization." Green Materials 5, no. 2 (2017): 63–73. http://dx.doi.org/10.1680/jgrma.16.00017.

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7

Wu, Jing, Jiefei Qi, Yiming Lin, et al. "Lipase-Catalyzed Fully Aliphatic Copolyesters Based on Renewable Isohexide Isomers." ACS Sustainable Chemistry & Engineering 9, no. 4 (2021): 1599–612. http://dx.doi.org/10.1021/acssuschemeng.0c06733.

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8

Wu, Jing, Pieter Eduard, Lidia Jasinska-Walc, et al. "Fully Isohexide-Based Polyesters: Synthesis, Characterization, and Structure–Properties Relations." Macromolecules 46, no. 2 (2012): 384–94. http://dx.doi.org/10.1021/ma302209f.

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9

Gormong, Ethan A., Theresa M. Reineke, and Thomas R. Hoye. "Synthesis of Isohexide Diyne Polymers and Hydrogenation to Their Saturated Polyethers." ACS Macro Letters 10, no. 8 (2021): 1068–72. http://dx.doi.org/10.1021/acsmacrolett.1c00422.

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10

Ji, Xiaodong, Zikun Wang, Zhen Wang, and Jingling Yan. "Bio-Based Poly(Ether Imide)s from Isohexide-Derived Isomeric Dianhydrides." Polymers 9, no. 11 (2017): 569. http://dx.doi.org/10.3390/polym9110569.

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11

Senkina, Julia, and Spencer Knapp. "Incorporation of an Isohexide Subunit into the Endochin-like Quinolone Scaffold." Molecules 29, no. 15 (2024): 3615. http://dx.doi.org/10.3390/molecules29153615.

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In order to improve the drug-likeness qualities, the antimalarial endochin-like quinolone (ELQ) scaffold has been modified by replacing the 4-(trifluoromethoxy)phenyl portion with an isoidide unit that is further adjustable by varying the distal O-substituents. As expected, the water solubilities of the new analogs are greatly improved, and the melting points are lower. However, the antimalarial potency of the new analogs is reduced to EC50 > 1 millimolar, a result ascribable to the hydrophilic nature of the new substitution.

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12

Gustini, Liliana, Cristina Lavilla, Antxon Martínez de Ilarduya, Sebastián Muñoz-Guerra, and Cor E. Koning. "Isohexide and Sorbitol-Derived, Enzymatically Synthesized Renewable Polyesters with Enhanced Tg." Biomacromolecules 17, no. 10 (2016): 3404–16. http://dx.doi.org/10.1021/acs.biomac.6b01224.

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13

Jasinska-Walc, Lidia, Dmytro Dudenko, Artur Rozanski, et al. "Structure and Molecular Dynamics in Renewable Polyamides from Dideoxy–Diamino Isohexide." Macromolecules 45, no. 14 (2012): 5653–66. http://dx.doi.org/10.1021/ma301091a.

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14

Thiyagarajan, Shanmugam, Linda Gootjes, Willem Vogelzang, Jacco van Haveren, Martin Lutz, and Daan S. van Es. "Renewable Rigid Diamines: Efficient, Stereospecific Synthesis of High Purity Isohexide Diamines." ChemSusChem 4, no. 12 (2011): 1823–29. http://dx.doi.org/10.1002/cssc.201100398.

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15

Shin, Seunghan, Jae Won Seo, Jin Ku Cho, Sangyong Kim, Jaeryung Cha, and Myoung Seon Gong. "Bio-based chiral dopants having an isohexide skeleton for cholesteric liquid crystal materials." Green Chemistry 14, no. 4 (2012): 1163. http://dx.doi.org/10.1039/c2gc16261j.

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16

Vijjamarri, Srikanth, Marianne Hull, Edward Kolodka, and Guodong Du. "Renewable Isohexide-Based, Hydrolytically Degradable Poly(silyl ether)s with High Thermal Stability." ChemSusChem 11, no. 17 (2018): 2881–88. http://dx.doi.org/10.1002/cssc.201801123.

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17

Wu, Jing, Shanmugam Thiyagarajan, Célia Fonseca Guerra, et al. "Back Cover: Isohexide Dinitriles: A Versatile Family of Renewable Platform Chemicals (ChemSusChem 16/2017)." ChemSusChem 10, no. 16 (2017): 3278. http://dx.doi.org/10.1002/cssc.201701482.

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18

Thiyagarajan, Shanmugam, Jing Wu, Rutger J. I. Knoop, Jacco van Haveren, Martin Lutz, and Daan S. van Es. "Isohexide hydroxy esters: synthesis and application of a new class of biobased AB-type building blocks." RSC Adv. 4, no. 89 (2014): 47937–50. http://dx.doi.org/10.1039/c4ra07896a.

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Here we present the synthesis of a new family of sugar derived 1,4:3,6-dianhydrohexitol based AB-type monomers, containing one methyl ester group and a secondary hydroxyl group in all four possible stereo isomers (RR, RS, SR, SS).

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19

Engel, Rebecca V., Johannes Niemeier, Anja Fink, and Marcus Rose. "Unravelling the Mechanism of the Ru/C-Catalysed Isohexide and Ether Isomerization by Hydrogen Isotope Exchange." Advanced Synthesis & Catalysis 360, no. 12 (2018): 2358–63. http://dx.doi.org/10.1002/adsc.201800058.

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20

Bratash, G. S. "1,4:3,6-Dianhydrohexites." BIO Web of Conferences 82 (2024): 01003. http://dx.doi.org/10.1051/bioconf/20248201003.

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It is known that derivatives of isosorbide and isomannide can impart a sweet taste, for example, dimethyl ether of isosorbide is used as an ingredient in the production of chewing gums, hard sweets [1], isosorbide dipropanoate is widely used in the production of bakery products [1]. Mixed isohexite esters and esters (especially isosorbide) are used as flavor enhancers. Currently, isosorbide is proposed to be used as a component of the mixture used for the water-base ink pigment. This component has excellent dispersion stability, which is necessary for printing [1]. All production methods leadi

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21

Craythorne, Steven J., Ciara L. Pollock, Alexander J. Blake, Mark Nieuwenhuyzen, Andrew C. Marr, and Patricia C. Marr. "A low molecular weight hydro and organogelator derived from an isohexide and sol–gel transcription of the alcogel." New Journal of Chemistry 33, no. 3 (2009): 479. http://dx.doi.org/10.1039/b814274b.

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22

Vijjamarri, Srikanth, Marianne Hull, Edward Kolodka, and Guodong Du. "Cover Feature: Renewable Isohexide-Based, Hydrolytically Degradable Poly(silyl ether)s with High Thermal Stability (ChemSusChem 17/2018)." ChemSusChem 11, no. 17 (2018): 2839. http://dx.doi.org/10.1002/cssc.201801922.

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23

Cefalì, Federica, Anna Iuliano, Federica Balzano, Gloria Uccello Barretta, Valerio Zullo, and Carlo Baldassari. "Isohexide-Based Tunable Chiral Platforms as Amide- and Thiourea-Chiral Solvating Agents for the NMR Enantiodiscrimination of Derivatized Amino Acids." Molecules 29, no. 6 (2024): 1307. http://dx.doi.org/10.3390/molecules29061307.

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New arylamide- and arylthiourea-based chiral solvating agents (CSAs) were synthesized starting from commercially available isomannide and isosorbide. The two natural isohexides were transformed into the three amino derivatives, having isomannide, isosorbide, and isoidide stereochemistry, then the amino groups were derivatized with 3,5-dimethoxybenzoyl chloride or 3,5-bis(trifluoromethyl)phenyl isothiocyanate to obtain the CSAs. Bis-thiourea derivative containing the 3,5-bis(trifluoromethyl)phenyl moiety with exo–exo stereochemistry was remarkably efficient in the differentiation of NMR signals

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24

Ji, Xiaodong, Jingling Yan, Xiuju Liu, Zikun Wang, and Zhen Wang. "Synthesis and properties of polyimides derived from bis(4-aminophenyl)isohexides." High Performance Polymers 29, no. 2 (2016): 197–204. http://dx.doi.org/10.1177/0954008316634443.

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Several partially bio-based polyimides have been successfully synthesized by polycondensation between bis(4-aminophenyl)isohexides with various commercial dianhydrides. Flexible and free-standing films were readily obtained from their poly(amic acid) or polyimide solutions. A systematic investigation of the structure–property relationship of polyimides highlights the significant impact of the isohexides moieties on their physical and mechanical properties (glass transition temperature, inherent viscosity, thermal stability, solubility, and mechanical properties). The results revealed that thes

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25

Rajput, B. S., S. R. Gaikwad, S. K. Menon, and S. H. Chikkali. "Sustainable polyacetals from isohexides." Green Chemistry 16, no. 8 (2014): 3810. http://dx.doi.org/10.1039/c4gc00543k.

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26

Kieber, Robert J., Samantha A. Silver, and Justin G. Kennemur. "Stereochemical effects on the mechanical and viscoelastic properties of renewable polyurethanes derived from isohexides and hydroxymethylfurfural." Polymer Chemistry 8, no. 33 (2017): 4822–29. http://dx.doi.org/10.1039/c7py00949f.

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Biomass-derived polyurethanes were synthesized using 2,5-bishydroxymethylfuran (BHMF) and diisocyanate functionalized isohexides, isosorbide bis(3-isocyanatopropanoate) (ISBIP) and isomannide bis(3-isocyanatopropanoate) (IMBIP), at varying feed ratios.

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27

Muñoz-Guerra, Sebastián, Cristina Lavilla, Cristina Japu, and Antxon Martínez de Ilarduya. "Renewable terephthalate polyesters from carbohydrate-based bicyclic monomers." Green Chem. 16, no. 4 (2014): 1716–39. http://dx.doi.org/10.1039/c3gc42394h.

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Carbohydrate-based bicyclic compounds, isohexides and diacetalized alditols and aldarates, are suitable polycondensation monomers to prepare partially renewable aromatic copolyesters displaying a satisfactory pattern of basic properties and enhancedT<sub>g</sub>and hydrodegradability.

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28

Jennifer B. Galvin, Gary Bond. "2-METHYLPENTANE (ISOHEXANE)." Journal of Toxicology and Environmental Health, Part A 58, no. 1-2 (1999): 81–92. http://dx.doi.org/10.1080/009841099157449.

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29

Janvier, Marine, Sylvie Moebs-Sanchez, and Florence Popowycz. "Nitrogen-functionalized Isohexides in Asymmetric Induction." CHIMIA International Journal for Chemistry 70, no. 1 (2016): 77–83. http://dx.doi.org/10.2533/chimia.2016.77.

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30

Kadraoui, Mohammed, Thibault Maunoury, Zoubir Derriche, Stéphane Guillarme, and Christine Saluzzo. "Isohexides as Versatile Scaffolds for Asymmetric Catalysis." European Journal of Organic Chemistry 2015, no. 3 (2014): 441–57. http://dx.doi.org/10.1002/ejoc.201402851.

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31

Alghamdi, Mohammed, Ibrahim Al-Kharsan, Sana Shahab, et al. "Investigation of Energy and Exergy of Geothermal Organic Rankine Cycle." Energies 16, no. 5 (2023): 2222. http://dx.doi.org/10.3390/en16052222.

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In this study, modeling and thermodynamic analysis of the combined double flash geothermal cycle generation was conducted using zeotropic fluid as the working fluid in the Organic Rankine Cycle (ORC). The analysis was performed based on the first and second laws of thermodynamics. Hexane, cyclohexane, isohexane, R245fa, and R236ea exhibit good performance at higher temperatures. In this study, three fluids—hexane, cyclohexane, and isohexane—were used. First, the model results for the pure fluids were compared with those of previous studies. Then, the important parameters of the cycle, includin

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32

Kadraoui, Mohammed, Thibault Maunoury, Zoubir Derriche, Stephane Guillarme, and Christine Saluzzo. "ChemInform Abstract: Isohexides as Versatile Scaffolds for Asymmetric Catalysis." ChemInform 46, no. 13 (2015): no. http://dx.doi.org/10.1002/chin.201513310.

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33

Jacolot, Maïwenn, Sylvie Moebs-Sanchez, and Florence Popowycz. "Diastereoselective Iridium-Catalyzed Amination of Biosourced Isohexides Through Borrowing Hydrogen Methodology." Journal of Organic Chemistry 83, no. 16 (2018): 9456–63. http://dx.doi.org/10.1021/acs.joc.8b01162.

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34

Bahé, Florian, Lucie Grand, Elise Cartier, et al. "Direct Amination of Isohexides via Borrowing Hydrogen Methodology: Regio- and Stereoselective Issues." European Journal of Organic Chemistry 2020, no. 5 (2020): 599–608. http://dx.doi.org/10.1002/ejoc.201901661.

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35

Pfützenreuter, Rebecca, and Marcus Rose. "Aqueous-Phase Amination of Biogenic Isohexides by using Ru/C as a Solid Catalyst." ChemCatChem 8, no. 1 (2015): 251–55. http://dx.doi.org/10.1002/cctc.201501077.

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36

Ershov, Mikhail A., Tamer M. M. Abdellatief, Dmitriy A. Potanin, Nikita A. Klimov, Elena A. Chernysheva, and Vladimir M. Kapustin. "Characteristics of Isohexene as a Novel Promising High-Octane Gasoline Booster." Energy & Fuels 34, no. 7 (2020): 8139–49. http://dx.doi.org/10.1021/acs.energyfuels.0c00945.

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37

Kuk, M. S., and R. J. Hron. "Cottonseed extraction with a new solvent system: Isohexane and alcohol mixtures." Journal of the American Oil Chemists' Society 75, no. 8 (1998): 927–30. http://dx.doi.org/10.1007/s11746-998-0268-4.

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38

Basevich, V. Ya, A. A. Belyaev, S. N. Medvedev, V. S. Posvyanskii, and S. M. Frolov. "Detailed kinetic mechanism of the multistep oxidation and combustion of isopentane and isohexane." Russian Journal of Physical Chemistry B 9, no. 6 (2015): 933–39. http://dx.doi.org/10.1134/s1990793115060159.

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39

Liao, Chen-hao, and Jui-Ching Hsieh. "Feasibility and performance analysis of utilizing spent mushroom substrate as biomass fuel." E3S Web of Conferences 479 (2024): 05003. http://dx.doi.org/10.1051/e3sconf/202447905003.

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A novel biomass system has been developed that utilizes spent mushroom substrates (SMS) and combines a pre-drying and drying system. The novel biomass system consists of a boiler and an Organic Rankine Cycle (ORC), which employs Isohexane as the working fluid to enable operation at high temperatures. The high moisture content of the SMS is dried by pre-drying from condensation waste heat of ORC and drying from the flue gas of the boiler to improve the calorific value of SMS. In the present study, the moisture content of the SMS and evaporation temperature of the ORC ranged from 50% to 65% and

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40

Nagy, Istvan, Ryan A. Krenz, Robert A. Heidemann, and Theo W. de Loos. "High-pressure phase equilibria in the system linear low density polyethylene+isohexane: Experimental results and modelling." Journal of Supercritical Fluids 40, no. 1 (2007): 125–33. http://dx.doi.org/10.1016/j.supflu.2006.04.005.

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41

Vera, David, Francisco Jurado, Bárbara de Mena, and Jesús C. Hernández. "A Distributed Generation Hybrid System for Electric Energy Boosting Fueled with Olive Industry Wastes." Energies 12, no. 3 (2019): 500. http://dx.doi.org/10.3390/en12030500.

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This paper presents the theoretical model and the simulation of a cutting edge hybrid power system composed of an externally-fired gas turbine (EFGT) coupled with an organic Rankine cycle (ORC) as a bottoming unit for the maximization of electrical power. The power plant is fed with different biomass sources from olive industry wastes (pruning, dry pomace, stones, leaves and twigs), providing more than 550 kW of electric power and a net electrical efficiency of 26.0%. These wastes were burnt directly at atmospheric pressure in an EFGT, producing 400 kW of electric power and exhaust gases at 30

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42

Zheng, Jingjing, Tao Yu, and Donald G. Truhlar. "Multi-structural thermodynamics of C–H bond dissociation in hexane and isohexane yielding seven isomeric hexyl radicals." Physical Chemistry Chemical Physics 13, no. 43 (2011): 19318. http://dx.doi.org/10.1039/c1cp21829h.

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43

Chicinaş, Horea Florin, Darius Ovidiu Jucan, Glad Contiu, and Cătălin Popa. "Effect of Aqueous Milling on the Total Carbon Content of Hard Metal Powders." Advanced Engineering Forum 42 (September 7, 2021): 3–8. http://dx.doi.org/10.4028/www.scientific.net/aef.42.3.

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Materials consisting of a hard phase, usually WC, and a tough binder, traditionally Co, form the most successful class of composite materials, also known as Hard Metals (HM) or Cemented Carbides. Powder metallurgy routes are employed generally for the production of such [1]. The typical processing route of such materials involves mixing the components, kneading and consolidation. Alcohols, alkanes and alkenes are commonly used to limit any excessive heating and oxidation of powders during mixing the components. In this study, we report the results of milling in a more environmentally friendly

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44

Carré, Patrick, Thomas Piofczyk, Sarah Bothe, Chandra dev Borah, and Sara Hadjiali. "Solvent solutions: Comparing extraction methods for edible oils and proteins in a changing regulatory landscape. Part 4: Impacts on energy consumption." OCL 31 (2024): 32. https://doi.org/10.1051/ocl/2024031.

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This study compares various solvents for edible oil extraction, focusing on their energy consumption impacts. The research examines traditional hexane and alternative solvents, using both theoretical calculations and experimental data. The article presents a thermodynamic analysis of solvent-water separation using ChemSep software for rectification simulations. Results show significant differences in energy requirements, with acetone being potentially the most efficient and alcohols (ethanol and isopropanol) requiring substantially more energy at desolventization step. Solvent hold-up in the m

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45

Jin, Jun, Liyou Zheng, Warda Mwinyi Pembe, et al. "Production of sn -1,3-distearoyl-2-oleoyl-glycerol-rich fats from mango kernel fat by selective fractionation using 2-methylpentane based isohexane." Food Chemistry 234 (November 2017): 46–54. http://dx.doi.org/10.1016/j.foodchem.2017.04.165.

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46

Guzović, Zvonimir, Zlatko Bačelić Medić, and Marina Budanko. "Effect of Working Fluid on Characteristics of Organic Rankine Cycle with Medium Temperature Geothermal Water." Energies 18, no. 7 (2025): 1699. https://doi.org/10.3390/en18071699.

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The total installed geothermal power plant capacity at year-end 2023 was 16,335 MW, while the forecast for the installed capacity in 2025 is 19,331 MW. In Croatia, several medium-temperature geothermal resources (geothermal water) with temperatures from 90 to 200 °C exist, by means of which it is possible to produce electricity in binary plants, with the Organic Rankine Cycle (ORC) or with the Kalina cycle. In earlier studies, the authors presented the results of an energy-exergy analysis of geothermal sources at Velika Ciglena (170 °C), Lunjkovec-Kutnjak (140 °C), Babina Greda (125 °C), and R

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47

Windels, Simon, Jef Vanhoof, Sander Spittaels, Robin Coeck, Dirk De Vos, and Thomas Cuypers. "Tandem electrooxidation ‐ reductive amination of biobased isohexides towards bicyclic diamines." ChemSusChem, March 29, 2024. http://dx.doi.org/10.1002/cssc.202301627.

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Isohexide‐derived diamines are considered preferred precursors for the production of biobased polyurethanes and polyamides. However, current synthesis methods from isohexides suffer from serious issues concerning selectivity and the recyclability of the process auxiliaries (e.g. homogeneous catalysts), which renders a translation to the industry highly unlikely. Here, we report on the production of such diamine building blocks, via a tandem electrooxidation – reductive amination process in which the process auxiliaries can be easily recycled. The application of (immobilized) TEMPO in combinati

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48

Lin, Yiming, Mengting Ye, Xu Zhang, et al. "Biodegradable copolyesters based on a “soft” isohexide building block with tunable viscoelasticity and self-adhesiveness." Polymer Chemistry, 2022. http://dx.doi.org/10.1039/d2py00586g.

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With the aim of developing novel biodegradable functional polymers, a series of copolyesters (PBIA) with low Tg values and tunable self-adhesiveness were synthesized by utilizing a unique “soft” isohexide building...

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49

Zullo, Valerio, Anna Iuliano, Gennaro Pescitelli, and Francesco Zinna. "Tunable Excimer Circularly Polarized Luminescence in Isohexide Derivatives from Renewable Resources." Chemistry – A European Journal 28, no. 15 (2022). http://dx.doi.org/10.1002/chem.202104226.

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50

Zullo, Valerio, Marcin Górecki, Lorenzo Guazzelli, Andrea Mezzetta, Gennaro Pescitelli, and Anna Iuliano. "Exploiting isohexide scaffolds for the preparation of chiral ionic liquids tweezers." Journal of Molecular Liquids, October 2020, 114528. http://dx.doi.org/10.1016/j.molliq.2020.114528.

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