Relevant bibliographies by topics / Isomerization reactions

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  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters
  5. Conference papers
  6. Reports

Academic literature on the topic 'Isomerization reactions'

Author: Grafiati
Published: 4 June 2021
Last updated: 12 February 2022

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Journal articles on the topic "Isomerization reactions"

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Liu, Qiang, Xufang Liu, and Bin Li. "Base-Metal-Catalyzed Olefin Isomerization Reactions." Synthesis 51, no. 06 (2019): 1293–310. http://dx.doi.org/10.1055/s-0037-1612014.

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The catalytic olefin isomerization reaction is a highly efficient and atom-economic transformation in organic synthesis that has attracted tremendous attention both in academia and industry. Recently, the development of Earth-abundant metal catalysts has received growing interest owing to their wide availability, sustainability, and ­environmentally benign nature, as well as the unique properties of non-precious metals. This review provides an overview of a broad range of base-metal-catalyzed olefin isomerization reactions categorized ­according to their different reaction mechanisms.1 Introdu
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Wilger, Dale J., Sydney E. Bottcher, and Lauren E. Hutchinson. "Nickel-Catalyzed anti-Selective Alkyne Functionalization Reactions." Synthesis 52, no. 19 (2020): 2807–20. http://dx.doi.org/10.1055/s-0040-1707885.

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Nickel-catalyzed anti-selective alkyne functionalization reactions are reviewed with an emphasis on the mechanisms that lead to their observed stereoselectivity. Since the isomerization of alkenylnickel species plays a key role in a large number of these reactions, the potential mechanisms for these processes are also described in detail.1 Introduction2 anti-Selective Hydroarylation3 anti-Selective Carboborylation4 anti-Selective Dicarbofunctionalization4.1 Carbocyanative Cyclization4.2 Cyclization with Aryl Donors4.3 Cyclization with CO2 4.4 Intermolecular Dicarbofunctionalization5 anti-Selec
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Vilches-Herrera, Marcelo, Lutz Domke, and Armin Börner. "Isomerization–Hydroformylation Tandem Reactions." ACS Catalysis 4, no. 6 (2014): 1706–24. http://dx.doi.org/10.1021/cs500273d.

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Inanaga, Kazato, Yu Ogawa, Yuuki Nagamoto, et al. "Facile isomerization of silyl enol ethers catalyzed by triflic imide and its application to one-pot isomerization–(2 + 2) cycloaddition." Beilstein Journal of Organic Chemistry 8 (April 27, 2012): 658–61. http://dx.doi.org/10.3762/bjoc.8.73.

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A triflic imide (Tf2NH) catalyzed isomerization of kinetically favourable silyl enol ethers into thermodynamically stable ones was developed. We also demonstrated a one-pot catalytic reaction consisting of (2 + 2) cycloaddition and isomerization. In the reaction sequence, Tf2NH catalyzes both of the reactions.
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DING, WAN-JIAN, LING-YAN NI, WEI-HAI FANG, and JIAN-GUO YU. "THEORETICAL STUDY ON THE UNIMOLECULAR REACTIONS OF GLYOXYLIC ACID." Journal of Theoretical and Computational Chemistry 04, spec01 (2005): 725–36. http://dx.doi.org/10.1142/s021963360500174x.

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The potential energy surfaces of isomerization, decarboxylation, and decarbonylation reactions of glyoxylic acid have been characterized by the B3LYP/cc-pVTZ, B3LYP/aug-cc-pVTZ, and MP2/cc-pVTZ calculations. There is a relatively high barrier on the isomerization pathway from Tc to Tt , due to existence of the intramolecular H-bond in the Tc to Tt structures. The decarboxylation reaction proceeds mainly through a stepwise mechanism. The singlet hydroxyl carbene and carbon dioxide are formed in the first step, which is followed by isomerization of the carbene to formaldehyde in the second step.
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Martínez Cuesta, Sergio, Syed Asad Rahman, and Janet M. Thornton. "Exploring the chemistry and evolution of the isomerases." Proceedings of the National Academy of Sciences 113, no. 7 (2016): 1796–801. http://dx.doi.org/10.1073/pnas.1509494113.

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Isomerization reactions are fundamental in biology, and isomers usually differ in their biological role and pharmacological effects. In this study, we have cataloged the isomerization reactions known to occur in biology using a combination of manual and computational approaches. This method provides a robust basis for comparison and clustering of the reactions into classes. Comparing our results with the Enzyme Commission (EC) classification, the standard approach to represent enzyme function on the basis of the overall chemistry of the catalyzed reaction, expands our understanding of the bioc
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Beattie, JK, MB Celap, MT Kelso, and SM Nesic. "Eigenanalysis of the Coupled First-Order Isomerization Reactions of the Bis[(S)-alaninato]dinitrocobaltate(III) Ion." Australian Journal of Chemistry 42, no. 10 (1989): 1647. http://dx.doi.org/10.1071/ch9891647.

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Three of the five possible geometric isomers of the bis[(S)-alaninato] dinitrocobaltate (III) ion isomerize to the stable fourth isomer by a series of first-order reactions. The fifth isomer is not observed. The kinetics of the isomerizations in neutral, aqueous solutions between 65 and 95 C have been studied by chromatographic separation of the isomers. The data were fitted by eigenanalysis of the coupled first-order differential equations. The results are consistent with a reaction scheme requiring five rate constants, kxy, where xy represents isomerization from isomer x to isomer y. lsomer
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Mallagaray, Álvaro, Gema Domínguez, Ana Gradillas, and Javier Pérez-Castells. "Tandem RCM−Isomerization− Cyclopropanation Reactions." Organic Letters 10, no. 4 (2008): 597–600. http://dx.doi.org/10.1021/ol702766h.

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Tewari, Y. B., and R. N. Goldberg. "Thermodynamics of carbohydrate isomerization reactions." Biophysical Chemistry 24, no. 3 (1986): 291–94. http://dx.doi.org/10.1016/0301-4622(86)85034-7.

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Mantilli, Luca, David Gérard, Sonya Torche, Céline Besnard, and Clément Mazet. "Highly enantioselective isomerization of primary allylic alcohols catalyzed by (P,N)-iridium complexes." Pure and Applied Chemistry 82, no. 7 (2010): 1461–69. http://dx.doi.org/10.1351/pac-con-09-09-10.

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The catalytic asymmetric isomerization of allylic amines to enamines stands out as one of the most accomplished and well-studied reactions in asymmetric catalysis as illustrated by its industrial application. In contrast, the related asymmetric isomerization of primary allylic alcohols to the corresponding aldehydes still constitutes a significant challenge in organic synthesis. Herein, we show that under appropriate reaction conditions, iridium-hydride catalysts promote the isomerization of primary allylic alcohols under very mild reaction conditions. The best catalysts deliver the desired ch
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Dissertations / Theses on the topic "Isomerization reactions"

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Kwak, Young-Woo. "Isomerization Reactions in Organosilicon Chemistry." Thesis, North Texas State University, 1985. https://digital.library.unt.edu/ark:/67531/metadc332336/.

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Dimethylsilene, generated from the thermal gas phase reaction of 1,1-dimethyl-1-silacyclobutane, reacts with alkynes to produce silacyclobutenes or acyclic silanes. The temperature dependence of the product ratios have been determined and the relative reactivities of three different alkynes toward the 1,1-dimethylsilene has been determined. 1-Hydrido-1-methylsilene has been generated by gas phase thermal decomposition from three different precursors. Trapping studies with butadiene and trimethylsilane lead to products expected from dimethylsilylene. The most plausible explanation for these obs
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Bird, Robert. "Reactions of hydrocarbons on oxide catalysts." Thesis, University of Edinburgh, 1987. http://hdl.handle.net/1842/11979.

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Katkova, Olga A. "Photochemical Isomerization and Stereoselective Thermal Reactions of Conjugated Nitrones." Bowling Green State University / OhioLINK, 2005. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1123003688.

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Katkova, Olga. "Photochemical isomerization and stereoselective thermal cycloaddition reactions of conjugated nitrones." Connect to this title online, 2005. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=bgsu1123003688.

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Fu, Yunyi Michael. "Development of a polymer-supported reagent for Trost-Lu isomerization reactions and reagents for Mitsunobu reactions." Click to view the E-thesis via HKUTO, 2008. http://sunzi.lib.hku.hk/hkuto/record/B39793989.

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Fu, Yunyi Michael, and 付運毅. "Development of a polymer-supported reagent for Trost-Lu isomerization reactions and reagents for Mitsunobu reactions." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2008. http://hub.hku.hk/bib/B39793989.

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Finnegan, David Francis. "Tandem Reactions Involving Ruthenium Alkylidenes." Thesis, Boston College, 2009. http://hdl.handle.net/2345/728.

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Thesis advisor: Marc L. Snapper<br>Tandem Reactions have proven themselves to be useful reactions for the synthesis of highly complex materials. Ruthenium alkylidenes are shown to be useful precursors for the development of new tandem processes. First, a new tandem metathesis/hetero-Pauson-Khand process is developed using Grubbs' second generation catalyst. Next, various metatheis/olefin isomerization processes are explored<br>Thesis (PhD) — Boston College, 2009<br>Submitted to: Boston College. Graduate School of Arts and Sciences<br>Discipline: Chemistry
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Yonehara, Takehiro. "Theoretical study on the multi channel dissociation and isomerization reactions of formaldehyde." 京都大学 (Kyoto University), 2006. http://hdl.handle.net/2433/136718.

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Dolliver, Debra D. "Mechanisms of Methoxide Ion Substitution and Acid- Catalyzed Z/E Isomerization of N-Methoxyimines." Thesis, University of North Texas, 2001. https://digital.library.unt.edu/ark:/67531/metadc3017/.

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The second order rate constants for nucleophilic substitution by methoxide of (Z)- and (E)-O-methylbenzohydroximoyl fluorides [C6H4C(F)=NOCH3] with various substituents on the phenyl ring [p-OCH3 (1h, 2h), p-CH3 (1g, 2g), p-Cl (1f, 2f), p-H (1e, 2e), (3,5)-bis-CF3 (1i, 2i)] in 90:10 DMSO:MeOH have been measured. A Hammett plot of these rate constants vs σ values gave positive ρ values of 2.95 (Z isomer) and 3.29 (E isomer). Comparison of these rates with methoxide substitution rates for Omethylbenzohydroximoyl bromide [C6H4C(Br)=NOCH3] and Omethylbenzohydroximoyl chloride [C6H4C(Cl)=NOCH3] r
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Nagendiran, Anuja. "Catalytic reactions with palladium supported on mesocellular foam : Applications in hydrogenation, isomerization, and C-C bond forming reactions." Doctoral thesis, Stockholms universitet, Institutionen för organisk kemi, 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-122061.

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The major part of this thesis concerns the development of catalytic methodologies based on palladium nanoparticles immobilized on aminopropyl-functionalized siliceous mesocellular foam (Pd0-AmP-MCF). The catalytic activity of the precursor to the nanocatalyst, PdII-AmP-MCF is also covered by this work. In the first part the application of Pd0-AmP-MCF in Suzuki-Miyaura cross-coupling reactions and transfer hydrogenation of alkenes under microwave irradiation is described. Excellent reactivity was observed and a broad range of substrates were tolerated for both transformations. The Pd0-AmP-MCF e
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Books on the topic "Isomerization reactions"

1

Thermodynamic properties of isomerization reactions. Hemisphere Pub. Corp., 1993.

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Kangas, Matias. Chemical reaction engineering in skeletal isomerization. Åbo Akademi University, 2008.

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Frenkel, M. L. Thermodynamic Properties of Isomerization Reactions. Taylor & Francis Group, 2020.

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Frenkel, M. L. Thermodynamic Properties of Isomerization Reactions. Taylor & Francis Group, 2020.

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Frenkel, M. L. Thermodynamic Properties of Isomerization Reactions. Taylor & Francis Group, 2020.

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Frenkel, M. L. Thermodynamic Properties of Isomerization Reactions. Taylor & Francis Group, 2020.

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Book chapters on the topic "Isomerization reactions"

1

Simakova, Olga A., Robert J. Davis, and Dmitry Yu Murzin. "Isomerization Reactions." In SpringerBriefs in Molecular Science. Springer International Publishing, 2013. http://dx.doi.org/10.1007/978-3-319-00906-3_7.

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Orchin, M. "Isomerization." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145319.ch90.

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Wegman, R. W. "Isomerization of Formates." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145319.ch153.

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Negishi, E. I. "By Isomerization and Displacement." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145241.ch27.

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Pohorille, A., and M. A. Wilson. "Isomerization Reactions at Aqueous Interfaces." In Reaction Dynamics in Clusters and Condensed Phases. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-011-0786-0_16.

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Theng, Benny K. G. "Clay Mineral Catalysis of Isomerization, Dimerization, Oligomerization, and Polymerization Reactions." In Clay Mineral Catalysis of Organic Reactions. CRC Press, 2018. http://dx.doi.org/10.1201/9780429465789-6.

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Fu, Gregory C. "Recent Advances in Rhodium(I)-Catalyzed Asymmetric Olefin Isomerization and Hydroacylation Reactions." In Modern Rhodium-Catalyzed Organic Reactions. Wiley-VCH Verlag GmbH & Co. KGaA, 2005. http://dx.doi.org/10.1002/3527604693.ch4.

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Rao, B. S., R. A. Shaikh, and A. V. Ramaswamy. "EnhancedparaSelectivity in Alkylation and Isomerization Reactions over Silynated ZSM-5 Zeolite." In ACS Symposium Series. American Chemical Society, 1999. http://dx.doi.org/10.1021/bk-2000-0738.ch015.

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Bott, R. H., L. T. Taylor, and T. C. Ward. "Cross-Linking and Isomerization Reactions of an Acetylene-Terminated Polyisoimide Prepolymer." In ACS Symposium Series. American Chemical Society, 1988. http://dx.doi.org/10.1021/bk-1988-0364.ch033.

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Grubbs, R. H. "Transition Metal Catalyzed Reactions of Olefins in Water: Olefin Metathesis and Isomerization." In Aqueous Organometallic Chemistry and Catalysis. Springer Netherlands, 1995. http://dx.doi.org/10.1007/978-94-011-0355-8_2.

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Conference papers on the topic "Isomerization reactions"

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Shizgal, Bernie D. "A pseudospectral solution of a Fokker-Planck equation to model isomerization reactions." In 30TH INTERNATIONAL SYMPOSIUM ON RAREFIED GAS DYNAMICS: RGD 30. Author(s), 2016. http://dx.doi.org/10.1063/1.4967547.

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Fuss, Werner, Karl L. Kompa, T. Schikarski, W. E. Schmid, and Sergei A. Trushin. "Probing of ultrafast photoinduced isomerization and dissociation reactions by intense-field dissociative ionization." In Optoelectronics and High-Power Lasers & Applications, edited by John W. Hepburn, Robert E. Continetti, and Mark A. Johnson. SPIE, 1998. http://dx.doi.org/10.1117/12.308401.

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Abu-Reesh, Ibrahim M. "Application of third-order polynomial approximate solution to enzymatic glucose isomerization and lactose hydrolysis reactions." In 2011 Fourth International Conference on Modeling, Simulation and Applied Optimization (ICMSAO). IEEE, 2011. http://dx.doi.org/10.1109/icmsao.2011.5775507.

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Ora, Mikko, Johanna Järvi, Mikko Oivanen, and Harri Lönnberg. "Hydrolytic reactions of the phosphorodithioate analog of uridylyl(3',5')uridine: Cleavage, desulfurization and isomerization." In XIth Symposium on Chemistry of Nucleic Acid Components. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 1999. http://dx.doi.org/10.1135/css199902230.

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Balk, M. W., S. H. Courtney, and G. R. Fleming. "Unimolecular reactions of isolated, collisional gas phase and solvated molecules: Connections between stilbene isomerization rates under supersonic jet and thermal gas phase conditions." In AIP Conference Proceedings Volume 146. AIP, 1986. http://dx.doi.org/10.1063/1.35907.

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Lavendy, H., J. M. Robbe, D. Duflot, and J. P. Flament. "MCSCF-CI study of the isomerization reaction HCSi → HSiC." In The 50th international meeting of physical chemistry: Molecules and grains in space. AIP, 1994. http://dx.doi.org/10.1063/1.46617.

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Bolotov, Vasiliy Alexandrovich, Serguei Fedorovich Tikhov, Konstantin Radikovich Valeev, Vladimir Timurovich Shamirzaev, and Valentin Nikolaevich Parmon. "SELECTIVE FORMATION OF LINEAR ALPHA-OLEFINS VIA MICROWAVE CATALYTIC CRACKING OF LIQUID STRAIGHT-CHAIN ALKANES." In Ampere 2019. Universitat Politècnica de València, 2019. http://dx.doi.org/10.4995/ampere2019.2019.9894.

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Linear even-carbon-number alpha-olefins (LAO) with four or more carbon atoms are important compounds of high demand in chemical industry as precursors of a wide range of value-added chemicals [1]. LAO are used as co-monomers for polyethylene production, for the production of alcohols (mainly in detergents and plasticizers) and for synthesis of polyalphaolefins (used in synthetic lubricants). Alpha-olefins (C4, C6, C8 and C10) are mainly used to produce poly(vinyl chloride) plasticizers, high-density and linear low-density polyethylene to impart the stress-crack resistance. C10–C14 alpha-olefin
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Zhang, Jie, Guanghua Shen, Wanzhuang Mai, et al. "Study on the Isomerization Reaction of Turpentine Oil Catalyzed by the Acid-treated HangJin 2# Clay." In 2015 Asia-Pacific Energy Equipment Engineering Research Conference. Atlantis Press, 2015. http://dx.doi.org/10.2991/ap3er-15.2015.62.

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Dzhikiya, O. V., M. D. Smolikov, K. V. Kazantsev, S. S. Yablokova, O. E. Podmareva, and A. S. Belyi. "The effect of palladium addition to sulfated zirconia catalysts on physicochemical and catalytic properties in the n-hexane isomerization reaction." In NANOSCIENCE AND NANOTECHNOLOGY: NANO-SciTech. AIP Publishing, 2019. http://dx.doi.org/10.1063/1.5122022.

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Reports on the topic "Isomerization reactions"

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Smotkin, Eugene. Electrochemically Promoted Organic Isomerization Reactions at Polymer Electrolyte Fuel Cell Cathodes. Defense Technical Information Center, 2011. http://dx.doi.org/10.21236/ada546448.

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Schwartz, Benjamin Joel. Femtosecond dynamics of fundamental reaction processes in liquids: Proton transfer, geminate recombination, isomerization and vibrational relaxation. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/10131752.

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Schwartz, B. J. Femtosecond dynamics of fundamental reaction processes in liquids: Proton transfer, geminate recombination, isomerization and vibrational relaxation. [Spiropyrans]. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/6666275.

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