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Journal articles on the topic 'Ketoether'

Author: Grafiati
Published: 4 June 2021
Last updated: 25 April 2022

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1

Groß, Tobias, and Peter Metz. "An Efficient Gold-Catalyzed Domino Process for the Construction of Tetracyclic Ketoethers." Chemistry - A European Journal 19, no. 44 (October 2, 2013): 14787–90. http://dx.doi.org/10.1002/chem.201302985.

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2

Gross, Tobias, and Peter Metz. "ChemInform Abstract: An Efficient Gold-Catalyzed Domino Process for the Construction of Tetracyclic Ketoethers." ChemInform 45, no. 13 (March 14, 2014): no. http://dx.doi.org/10.1002/chin.201413031.

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3

Gibilisco, Rodrigo Gastón, Ian Barnes, Iustinian Gabriel Bejan, and Peter Wiesen. "Atmospheric fate of two relevant unsaturated ketoethers: kinetics, products and mechanisms for the reaction of hydroxyl radicals with (<i>E</i>)-4-methoxy-3-buten-2-one and (1<i>E</i>)-1-methoxy-2-methyl-1-penten-3-one." Atmospheric Chemistry and Physics 20, no. 14 (July 29, 2020): 8939–51. http://dx.doi.org/10.5194/acp-20-8939-2020.

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Abstract. The kinetics of the gas phase reactions of hydroxyl radicals with two unsaturated ketoethers (UKEs) at (298±3) K and 1 atm of synthetic air have been studied for the first time using the relative-rate technique in an environmental reaction chamber by in situ Fourier-transform infrared spectroscopy (FTIR). The rate coefficients obtained using propene and isobutene as reference compounds were (in units of 10−10 cm3 molecule−1 s−1) as follows: kTMBO (OH + (E)-4-methoxy-3-buten-2-one) = (1.41±0.11) and kMMPO (OH + (1E)-1-methoxy-2-methyl-1-penten-3-one) = (3.34±0.43). In addition, quantification of the main oxidation products in the presence of NOx has been performed, and degradation mechanisms for these reactions were developed. Methyl formate, methyl glyoxal, peroxyacetyl nitrate (PAN) and peroxypropionyl nitrate (PPN) were identified as main reaction products and quantified for both reactions. The results of the present study provide new insights regarding the contribution of these multifunctional volatile organic compounds (VOCs) in the generation of secondary organic aerosols (SOAs) and long-lived nitrogen containing compounds in the atmosphere. Atmospheric lifetimes and implications are discussed in light of the obtained results.
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4

Oku, Akira, Shigeji Ohki, Tomohiro Yoshida, and Kenji Kimura. "Three-carbon ring-enlargement of ethereal oxonium ylides—a viable synthesis of medium-sized cyclic ketoethers." Chem. Commun., no. 9 (1996): 1077–78. http://dx.doi.org/10.1039/cc9960001077.

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5

Pflieger, P., C. Mioskowski, J. P. Salaun, D. Weissbart, and F. Durst. "A new synthesis of α-ketoethers via anchimerically assisted substitution of an α-sulfinyl function with alcohols." Tetrahedron Letters 30, no. 21 (January 1989): 2791–94. http://dx.doi.org/10.1016/s0040-4039(00)99126-3.

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6

Erol, Ibrahim, Cengiz Soykan, Zülfiye Ilter, and Misir Ahmedzade. "Thermal degradation of poly 2-[3-(6-tetralino)-3-methylcyclobutyl]-2-ketoethyl methacrylate." Polymer Degradation and Stability 81, no. 2 (January 2003): 287–95. http://dx.doi.org/10.1016/s0141-3910(03)00099-5.

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7

OKU, A., S. OHKI, T. YOSHIDA, and K. KIMURA. "ChemInform Abstract: Three-Carbon Ring-Enlargement of Ethereal Oxonium Ylides. A Viable Synthesis of Medium-Sized Cyclic Ketoethers." ChemInform 27, no. 37 (August 5, 2010): no. http://dx.doi.org/10.1002/chin.199637225.

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8

Kevill, Dennis N., and Chang-Bae Kim. "Correlation of the Rates of Solvolysis of 2-Phenyl-2-ketoethyl Bromide and Tosylate." Journal of Organic Chemistry 70, no. 4 (February 2005): 1490–93. http://dx.doi.org/10.1021/jo048103d.

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9

Erol, Ibrahim, Zulfiye Ilter, Mehmet Coskun, and Misir Ahmedzade. "Synthesis and characterization of two new aryl cyclobutyl ketoethyl methacrylate monomers and their polymers." Journal of Polymer Science Part A: Polymer Chemistry 39, no. 23 (2001): 4167–73. http://dx.doi.org/10.1002/pola.10068.

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10

Ding, Lei, Qinxiong He, and Jianping Deng. "Using hydroxypropyl-β-cyclodextrin for the preparation of hydrophobic poly(ketoethyl methacrylate) in aqueous medium." Journal of Applied Polymer Science 115, no. 5 (October 26, 2009): 2933–39. http://dx.doi.org/10.1002/app.31390.

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11

Bai, Dachang, Junyan Chen, Bingbing Zheng, Xueyan Li, and Junbiao Chang. "Catalytic [3+3] Annulation of β‐Ketoethers and Cyclopropenones via C(sp 3 )—O/C—C Bond Cleavage under Transition‐Metal Free Conditions." Chinese Journal of Chemistry 39, no. 10 (August 6, 2021): 2769–73. http://dx.doi.org/10.1002/cjoc.202100276.

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12

Erol, Ibrahim, and Mısır Ahmedzade. "Copolymers of 2-(3-mesityl-3-methylcyclobutyl)-2-ketoethyl Methacrylate with Acrylonitrile and Styrene: Synthesis, Characterization, and Monomer Reactivity Ratios." Journal of Polymer Research 12, no. 4 (August 2005): 247–55. http://dx.doi.org/10.1007/s10965-004-4674-5.

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13

Schottenberger, Herwig, Michael Buchmeiser, Johann Polin, and Karl-Eberhard Schwarzhans. "Ferrocen-Derivate der Quadrat- und Propiolsäure. Synthesen und Reaktionen / Ferrocene Derivatives of Squaric Acid and Propiolic Acid. Syntheses and Reactions." Zeitschrift für Naturforschung B 48, no. 11 (November 1, 1993): 1524–32. http://dx.doi.org/10.1515/znb-1993-1110.

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Concepts for linking ferrocene derivatives with conjugated squarate and propiolate based spacer systems have been investigated. Coupling of 3,4-dichlorocyclobut-3-ene-1,2-dione (squaric acid dichloride) with cuproferrocene • dimethylsulfide resulted in 3-chloro-4-ferrocenylcyclobut-3-ene-1,2-dione (ferrocenylsemisquaric acid chloride) and 3,4-diferrocenylcyclobut-3-ene-1,2-dione. Ferrocenylsemisquaric acid chloride was further treated with ethynylferrocene and 4-ethynyl-4-(ferrocenylethynyl)tolan, respectively, to form the corresponding mixed squaric diketones, which required Zn/Pd mediated coupling conditions for sufficient conversion. The symmetrically substituted derivative of ferrocenylacetylene was prepared by the same method.Cupration and subsequent coupling of dilithioferrocene with one equivalent of iodopropiolic acid methyl ester yielded 1′-iodo- 1 -ferrocenylpropiolic acid methyl ester, and with two equivalents 1,16-bis(methoxycarbonylethynyl)biferrocene. Nucleophilic addition of secondary amines to ferrocenylpropiolic acid ethyl ester gave aminoacrylates as intermediates, which rapidly converted to ketoesters during workup. Only in the case of morpholine the corresponding adduct (ferrocenylmorpholino acrylate) could be isolated. 1,3-Diferrocenylprop-2-ene-1-one has been obtained in a Bénary reaction of lithioferrocene with 3-diethylaminoethyl acrylate in quantitative yield.In order to provide alternative syntheses of already known compounds the substitution behavior of different metallated ferrocene intermediates has also been evaluated by reaction with other acid halides (oxalyl chloride, thiophosgene, ethyl chloroformate).All new compounds, 3-chloro-4-ferrocenylcyclobut-3-ene-1,2-dione (1); 3,4-diferrocenylcyclobut-3-ene-1,2-dione (2); 3,4-diferrocenylethynylcyclobut-3-ene-1,2-dione (3); 3-ferrocenyl-4-ferrocenylethynylcyclobut-3-ene-1,2-dione (4); 3-ferrocenyl-4-ferrocenylethynylphenylethynylphenylethynylcyclobut-3-ene-1,2-dione (5); 3-(N-morpholino)-3-ferrocenylethyl acrylate (6); 3-ferrocenyl-3-ketoethyl propanoate (7); iodoferrocenylpropargylic acid methyl ester (8); 1,16-bis(methoxycarbonylethynyl)biferrocene (9) and trans-1,3-diferrocenylprop-2-ene-1-one [105 404-21-5], have been characterized by IR, MS and NMR and in several cases by UV/VIS and DSC.
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14

Erol, Ibrahim, and Mısır Ahmedzade. "Free-radical copolymerization of 2-[3-(6-tetralino)-3-methylcyclobutyl]-2-ketoethyl methacrylate with acrylonitrile and styrene: Synthesis, characterization, and monomer reactivity ratios." Journal of Applied Polymer Science 104, no. 3 (2007): 1979–86. http://dx.doi.org/10.1002/app.25911.

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15

Demirelli, K., M. Coşkun, and M. Değirmenci. "2-(3-Tolyl-3-methylcyclobutyl)-2-hydroxyethyl and 2-(3-tolyl-3-methylcyclobutyl)-2-ketoethyl methacrylates: synthesis, polymerization, and characterization by spectroscopic and thermal analysis." Designed Monomers and Polymers 2, no. 1 (January 1999): 79–91. http://dx.doi.org/10.1163/156855599x00313.

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