Academic literature on the topic 'Kinetic rates'

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Journal articles on the topic "Kinetic rates"

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Sihn, Sangwook, Gregory J. Ehlert, Ajit K. Roy, and Jonathan P. Vernon. "Identifying unified kinetic model parameters for thermal decomposition of polymer matrix composites." Journal of Composite Materials 53, no. 20 (2018): 2875–90. http://dx.doi.org/10.1177/0021998318805821.

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Predicting thermal responses of composite materials requires accurate input parameters derived from reliable thermal property characterization and kinetic models. Composite material properties and decomposition kinetics vary with temperature and heating rate. Typically, conventional kinetic models derived from thermogravimetric analysis data result in multiple sets of kinetic model parameters, which are difficult to implement into numerical simulations under widely varying temperature and heating rate conditions. Here, a methodology was developed to reliably predict decomposition processes of
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French, Andrew S., and Lisa L. Stockbridge. "Fractal and Markov behavior in ion channel kinetics." Canadian Journal of Physiology and Pharmacology 66, no. 7 (1988): 967–70. http://dx.doi.org/10.1139/y88-159.

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Kinetic analysis of ion channel recordings attempts to distinguish the number and lifetimes of channel molecular states. Most kinetic analysis assumes that the lifetime of each state is independent of previous channel history, so that open and closed durations are Markov processes whose probability densities are sums of exponential decays. An alternative approach assumes that channel molecules have many configurtions with widely varying lifetimes. Rates of opening and closing then vary with the time scale of observation, leading to fractal kinetics. We have examined kinetic behavior in two typ
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Du, Hong Shuang, Xiang Yu Li, Xue Yong Ren, and Yan Xue Han. "Pyrolysis Kinetics Equation of Larch Bark." Advanced Materials Research 772 (September 2013): 313–18. http://dx.doi.org/10.4028/www.scientific.net/amr.772.313.

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The larch bark was examined by non-isothermal means to determine the mass loss kinetics of the thermal decomposition with linear temperature programming in nitrogen atmosphere. In this work, mechanism equation of = was used forCoats-Redfern integral methodat the different heating rates. The apparent activation energy, pre-exponential factor and the pyrolysis kinetic equations at the different heating rates were obtained. The pyrolysis temperature area was divided into two separate temperature regions for the pyrolysis kinetic equation and the two components were decomposed respectively at the
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Acuna-Askar, K., M. V. Gracia-Lozano, J. F. Villarreal-Chiu, J. G. Marmolejo, M. T. Garza-Gonzalez, and B. Chavez-Gomez. "Effect of soil and a nonionic surfactant on BTE-oX and MTBE biodegradation kinetics." Water Science and Technology 52, no. 8 (2005): 107–15. http://dx.doi.org/10.2166/wst.2005.0237.

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The biodegradation kinetics of BTE-oX and MTBE, mixed all together, in the presence of 905mg/L VSS of BTEX-acclimated biomass was evaluated. Effects of soil and Tergitol NP-10 in aqueous samples on substrate biodegradation rates were also evaluated. Biodegradation kinetics was evaluated for 36 hours, every 6 hours. MTBE biodegradation followed a first-order one-phase kinetic model in all samples, whereas benzene, toluene and ethylbenzene biodegradation followed a first-order two-phase kinetic model in all samples. O-xylene biodegradation followed a first-order two-phase kinetic model in the pr
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Vyazovkin, Sergey. "Activation Energies and Temperature Dependencies of the Rates of Crystallization and Melting of Polymers." Polymers 12, no. 5 (2020): 1070. http://dx.doi.org/10.3390/polym12051070.

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The objective of this review paper is to survey the phase transition kinetics with a focus on the temperature dependence of the rates of crystallization and melting, as well as on the activation energies of these processes obtained via the Arrhenius kinetic treatment, including the treatment by isoconversional methods. The literature is analyzed to track the development of the basic models and their underlying concepts. The review presents both theoretical and practical considerations regarding the kinetic analysis of crystallization and melting. Both processes are demonstrated to be kinetical
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Vincze, István, László Endrényi, and László Tóthfalusi. "Bioequivalence metrics for absorption rates: linearity, specificity, sensitivity." Acta Pharmaceutica Hungarica 89, no. 1 (2019): 17–21. http://dx.doi.org/10.33892/aph.2019.89.17-21.

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Aims:In order to ensure the therapeutic equivalence of generic products, it would be important to contrast measures additional to Cmax in order to assess differences in absorption rates. Our aim was to compare partial AUC (PAUC), Swing, and PTF to Cmax in terms of sensitivity, specificity and linearity under identical kinetic conditions.
 Methods:Single-dose and multiple-dose concentration curves were generated assuming one-compartment models. Kinetic sensitivity curves were obtained by gradually changing the absorption rate constant and keeping all other parameters fixed.
 Results:A
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S, Jargalmaa, Tsatsral G, Battsetseg M, et al. "Kinetic study of Mongolian coals by thermal analysis." Mongolian Journal of Chemistry 18, no. 44 (2018): 20–23. http://dx.doi.org/10.5564/mjc.v18i44.933.

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Thermal analysis was used for the thermal characterization of the coal samples. The experiments were performed to study the pyrolysis and gasification kinetics of typical Mongolian brown coals. Low rank coals from Shivee ovoo, Ulaan ovoo, Aduun chuluun and Baganuur deposits have been investigated. Coal samples were heated in the thermogravimetric apparatus under argon at a temperature ranges of 25-1020ºC with heating rates of 10, 20, 30 and 40ºC/min. Thermogravimetry (TG) and derivative thermogravimetry (DTG) were performed to measure weight changes and rates of weight losses used for calculat
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Tsai, Lung Chang, Jian Ming Wei, Yung Chuan Chu, et al. "RDX Kinetic Model Evaluation by Nth Order Kinetic Algorithms and Model Simulations." Advanced Materials Research 189-193 (February 2011): 1413–16. http://dx.doi.org/10.4028/www.scientific.net/amr.189-193.1413.

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A kinetic model based on the thermal decomposition of 1,3,5-trinitro-1,3,5-triazmane (RDX) was constructed via differential scanning calorimetry (DSC), well-known kinetic equations, curve-fitting analysis, and simulations of thermal analysis. Our objective was to analyze thermokinetic parameters derived from heating rates used in DSC and compare simulations of thermal decomposition under various kinetic models. Experimental results were strongly dependent on the validity of the kinetic model, which was based on an appropriate mathematical model and a proper method for the evaluation of kinetic
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Palfey, Bruce A., and Rebecca L. Fagan. "Analysis of the Kinetic Isotope Effects on Initial Rates in Transient Kinetics†." Biochemistry 45, no. 45 (2006): 13631–40. http://dx.doi.org/10.1021/bi061214h.

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Johnson, C. A., and J. L. Keltner. "Optimal Rates of Movement for Kinetic Perimetry." Archives of Ophthalmology 105, no. 1 (1987): 73–75. http://dx.doi.org/10.1001/archopht.1987.01060010079035.

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Dissertations / Theses on the topic "Kinetic rates"

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Sepúlveda, Márquez Alfonso. "Nanocalorimetric studies of several kinetic phenomena over a wide range of heating rates." Doctoral thesis, Universitat Autònoma de Barcelona, 2010. http://hdl.handle.net/10803/32132.

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Para comprender propiedades esenciales de materiales es necesario disponer de una configuración experimental de alta precisión. Nanocalorimetría basada en membranas es una herramienta importante para el análisis termo‐físico ya que esta técnica puede lograr resoluciones en el orden de pJ/K facilitando la detección de posibles nano‐fases en materiales modernos. Algunos materiales de nueva generación pueden ser complicados de producir en alta escala y sólo pueden estar disponibles en cantidades pequeñas o en capas delgadas. Algunos ejemplos de aplicaciones atractivas incluyen la síntesis de
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Song, Feng. "Formation and dissociation reaction rates and relevant kinetic behavior of propane gas hydrate (PGH)." Morgantown, W. Va. : [West Virginia University Libraries], 2001. http://etd.wvu.edu/templates/showETD.cfm?recnum=2263.

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Thesis (M.S.)--West Virginia University, 2001.<br>Title from document title page. Document formatted into pages; contains xi, 59 p. : ill. Includes abstract. Includes bibliographical references (p. 57-59).
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Sriramulu, Suresh. "Rates of the surface reactions in methanol and carbon monoxide electrooxidation : experimental measurements and kinetic modeling /." Thesis, Connect to this title online; UW restricted, 1999. http://hdl.handle.net/1773/9904.

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Kneeshaw, Tara Ann. "Evaluation of kinetic controls on sulfate reduction in a contaminated wetland-aquifer system." [College Station, Tex. : Texas A&M University, 2008. http://hdl.handle.net/1969.1/ETD-TAMU-2972.

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Scally, Shaun. "Insights into kinetic controls and metal speciation in natural waters from an understanding of mobility and dissociation rates." Thesis, Lancaster University, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.431737.

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Khan, Firoz R. "Investigation of turbulent flows and instabilities in a stirred vessel using particle image velocimetry." Thesis, Loughborough University, 2005. https://dspace.lboro.ac.uk/2134/14171.

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Extensive use of stirred vessels in the process industries for various operations has attracted researchers to study the mixing mechanisms and its effects on the processes. Among the various flow-measuring methods, Particle Image Velocimetry (PlV) technique has become more popular in comparison to LDA and HW A methods because of its ability to provide instantaneous velocity fields. The present study uses this technique to investigate the flowfields and turbulent properties in a 290mm vessel stirred by Rushton Disc turbine (RDT) and Pitched blade turbine (PBT) impellers. Angle-resolved instanta
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Venham, Lanny Dean. "Kinetic studies of alpha-silyl radicals : 1) relative rates of bromination of substituted benzyltrimethylsilanes : 2) laser flash photolysis study of the absolute rates of formation of alpha-silyl radicals /." The Ohio State University, 1986. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487268021746361.

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Ganguly, Jibamitra, Massimiliano Tirone, and Kenneth Domanik. "Cooling rates of LL, L and H chondrites and constraints on the duration of peak thermal conditions: Diffusion kinetic modeling and implications for fragmentation of asteroids and impact resetting of petrologic types." PERGAMON-ELSEVIER SCIENCE LTD, 2016. http://hdl.handle.net/10150/621538.

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We have carried out detailed thermometric and cooling history studies of several LL-, L- and H-chondrites of petrologic types 5 and 6. Among the selected samples, the low-temperature cooling of St. Severin (LL6) has been constrained in an earlier study by thermochronological data to an average rate of similar to 2.6 degrees C/My below 500 degrees C. However, numerical simulations of the development of Fe-Mg profiles in Opx-Cpx pairs using this cooling rate grossly misfit the measured compositional profiles. Satisfactory simulation of the latter and low temperature thermochronological constrain
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Danielson, Thomas Lee. "Investigation of Static and Dynamic Reaction Mechanisms at Interfaces and Surfaces Using Density Functional Theory and Kinetic Monte Carlo Simulations." Diss., Virginia Tech, 2016. http://hdl.handle.net/10919/71296.

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The following dissertation is divided into two parts. Part I deals with the modeling of helium trapping at oxide-iron interfaces in nanostructured ferritic alloys (NFAs) using density functional theory (DFT). The modelling that has been performed serves to increase the knowledge and understanding of the theory underlying the prevention of helium embrittlement in materials. Although the focus is for nuclear reactor materials, the theory can be applied to any material that may be in an environment where helium embrittlement is of concern. In addition to an improved theoretical understanding
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Dogan, Berna [Verfasser], Karsten [Akademischer Betreuer] [Gutachter] Reuter, and Carlo [Gutachter] Camilloni. "In Silico Prediction of Dissolution Rates of Pharmaceutical Ingredients: Micro-Kinetic Model Based on Spiral Dissolution / Berna Dogan. Betreuer: Karsten Reuter. Gutachter: Karsten Reuter ; Carlo Camilloni." München : Universitätsbibliothek der TU München, 2016. http://d-nb.info/1106382234/34.

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Books on the topic "Kinetic rates"

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Melander, Lars C. S. Reaction rates of isotopic molecules. R.E. Krieger Pub. Co., 1987.

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W, Wharton Christopher, ed. Enzyme kinetics. IRL Press, 1988.

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Chemical kinetics: The study of reaction rates in solution. Wiley-VCH, 1990.

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Connors, Kenneth A. Chemical kinetics: The study of reaction rates in solution. VCH, 1990.

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Gray, Peter. Chemical oscillations and instabilities: Non-linear chemical kinetics. Clarendon, 1994.

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1923-, Grunwald Ernest, ed. Rates and equilibria of organic reactions as treated by statistical, thermodynamic, and extrathermodynamic methods. Dover Publications, 1989.

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Purich, Daniel L. Handbook of biochemical kinetics. Academic, 1999.

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Joos, Nathaniel Ian. Surface oxygen exchange kinetics and oxygen diffusion rates in YSZ single crystals and mixed conducting oxides. National Library of Canada, 1999.

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Rhatigan, Jennifer L. Effects of gas-phase radiation and detailed kinetics on the burning and extension of a solid fuel. National Aeronautics and Space Administration, Johnson Space Center, 2001.

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Branch, M. C. Ignition and combustion of bulk metals at normal, elevated, and reduced gravity: Annual technical report, NASA grant no. NAG-3-1685. Center for Combustion Research, University of Colorado at Boulder, 1995.

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Book chapters on the topic "Kinetic rates"

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Amacher, Michael C. "Methods of Obtaining and Analyzing Kinetic Data." In Rates of Soil Chemical Processes. Soil Science Society of America, 2015. http://dx.doi.org/10.2136/sssaspecpub27.c2.

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Dove, P. M. "Chapter 6. KINETIC AND THERMODYNAMIC CONTROLS ON SILICA REACTIVITY IN WEATHERING ENVIRONMENTS." In Chemical Weathering Rates of Silicate Minerals, edited by Arthur F. White and Susan L. Brantley. De Gruyter, 1995. http://dx.doi.org/10.1515/9781501509650-008.

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Holzhütter, Hermann-Georg, and Anke Schwendel. "Estimation of Enzymatic Flux Rates from Kinetic Isotope Experiments." In Modern Trends in Biothermokinetics. Springer US, 1993. http://dx.doi.org/10.1007/978-1-4615-2962-0_18.

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Barbuti, Roberto, Francesca Levi, Paolo Milazzo, and Guido Scatena. "Probabilistic Model Checking of Biological Systems with Uncertain Kinetic Rates." In Lecture Notes in Computer Science. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-04420-5_8.

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Schlanges, M., and Th Bornath. "Kinetic Theory of Ionization and Recombination Rates for Dense Quantum Plasmas." In Strongly Coupled Coulomb Systems. Springer US, 2002. http://dx.doi.org/10.1007/0-306-47086-1_11.

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Moon, In-Hyung, and Dong-Mook Won. "Sintering Kinetic Analysis by Dilatometric Data Obtained at Different Heating Rates." In Advanced Science and Technology of Sintering. Springer US, 1999. http://dx.doi.org/10.1007/978-1-4419-8666-5_4.

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de Bakker, Paul I. W., Sylvia Tara, and James M. Briggs. "Thermodynamic Correlation with Kinetic Association Rates for Several Mutants of Mouse Acetylcholinesterase." In Structure and Function of Cholinesterases and Related Proteins. Springer US, 1998. http://dx.doi.org/10.1007/978-1-4899-1540-5_96.

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Akinlabi, Emmanuel O., Marta Wacławczyk, Juan Pedro Mellado, and Szymon P. Malinowski. "Estimating Turbulence Kinetic Energy Dissipation Rates in Atmospheric Flows: A Priori Study." In Springer Proceedings in Physics. Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-030-22196-6_41.

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Kalyuzhnyi, S., V. Sklyar, and J. Rodríguez. "Investigation of Kinetic and Microbiological Features of UASB-Reactor Performance Under Various Organic Loading Rates." In Advances in Bioprocess Engineering. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-017-0641-4_51.

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Wilson, W. David, and Farial A. Tanious. "Kinetic Analysis of Drug-Nucleic Acid Binding Modes: Absolute Rates and Effects of Salt Concentration." In Molecular Aspects of Anticancer Drug-DNA Interactions. Macmillan Education UK, 1994. http://dx.doi.org/10.1007/978-1-349-13330-7_6.

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Conference papers on the topic "Kinetic rates"

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Gorbachev, Yuriy. "Non-equilibrium reaction rates in chemical kinetic equations." In THE EIGHTH POLYAKHOV’S READING: Proceedings of the International Scientific Conference on Mechanics. Author(s), 2018. http://dx.doi.org/10.1063/1.5034666.

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Ozgur, Beytullah, Attila Gursoy, and Ozlem Keskin. "Relation between kinetic conversion rates and ANM mode frequencies." In 2010 5th International Symposium on Health Informatics and Bioinformatics (HIBIT). IEEE, 2010. http://dx.doi.org/10.1109/hibit.2010.5478902.

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SCHLANGES, M., T. BORNATH, and R. PRENZEL. "QUANTUM KINETIC APPROACH TO REACTION RATES OF DENSE PLASMAS." In Proceedings of the Conference “Kadanoff-Baym Equations: Progress and Perspectives for Many-Body Physics”. WORLD SCIENTIFIC, 2000. http://dx.doi.org/10.1142/9789812793812_0037.

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Tian, Tianhai. "Estimation of Kinetic Rates of MAP Kinase Activation from Experimental Data." In 2009 International Joint Conference on Bioinformatics, Systems Biology and Intelligent Computing. IEEE, 2009. http://dx.doi.org/10.1109/ijcbs.2009.78.

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Hsu, Sheng-Yen, and James S. T’ien. "Effects of Chemical Kinetics on Concurrent-Flow Flame Spread Rates Over Solids: A Comparison Between Buoyant Flow and Forced Flow Cases." In ASME 2007 International Mechanical Engineering Congress and Exposition. ASMEDC, 2007. http://dx.doi.org/10.1115/imece2007-42293.

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In the present study, detailed numerical models with a one-step finite-rate chemical reaction are employed to investigate the kinetic rate effect (through the variation of the pre-exponential factor) on concurrent flame spread rates. It is found that flames in forced-flow are less sensitive to the change of kinetics than flames in buoyant-flow; and narrow samples are more sensitive to the change of kinetics compared with wide samples. The rate of chemical kinetics affects the flame spread rates through its influence on the flame and the flow structures. For buoyant flames, gravity-induced velo
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Kim, E., and S. Thynell. "Condensed-phase kinetic rates of RDX from confined rapid thermolysis/FTIR spectroscopy." In 34th AIAA/ASME/SAE/ASEE Joint Propulsion Conference and Exhibit. American Institute of Aeronautics and Astronautics, 1998. http://dx.doi.org/10.2514/6.1998-3828.

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Yeh, Gour-Tsyh (George), and Yilin Fang. "Reaction Rates in a Transport System with Both Kinetic and Equilibrium Reactions." In World Environmental and Water Resources Congress 2009. American Society of Civil Engineers, 2009. http://dx.doi.org/10.1061/41036(342)187.

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Davidson, D. F., D. C. Snell, and R. K. Hanson. "Shock-tube excimer photolysis and the measurement of N atom kinetic rates." In Current topics in shock waves 17th international symposium on shock waves and shock tubes Bethlehem, Pennsylvania (USA). AIP, 1990. http://dx.doi.org/10.1063/1.39385.

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Horv, Andr, and Daniele Manini. "Parameter Estimation of Kinetic Rates in Stochastic Reaction Networks by the EM Method." In 2008 International Conference on Biomedical Engineering And Informatics (BMEI). IEEE, 2008. http://dx.doi.org/10.1109/bmei.2008.237.

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Mozammel, Hoque Md, and Masahiro Ota. "Kinetic Study of Waste Wood and Its Carbonization." In 2002 International Joint Power Generation Conference. ASMEDC, 2002. http://dx.doi.org/10.1115/ijpgc2002-26030.

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This study deals with the conversion of waste wood into solid fuel charcoal. Thermogravimetric and differential thermal analyses techniques are used to investigate the kinetics of thermochemical conversion of waste wood. The thermal degradation characteristics and the kinetic parameters (order of reaction, activation energy and pre-exponential factor) are determined at different heating rates using TG/DTA curves. The decomposition of the components could be modeled by an Arrhenius kinetic expression. The kinetic parameters are determined from the thermogravimetric data by a least square techni
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Reports on the topic "Kinetic rates"

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Altshuler, Dmitry A., and Denis M. Reidy. Computational Prediction of Kinetic Rate Constants. Defense Technical Information Center, 2006. http://dx.doi.org/10.21236/ada459261.

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Asenath-Smith, Emily, Emma Ambrogi, Lee Moores, Stephen Newman, and Jonathon Brame. Leveraging chemical actinometry and optical radiometry to reduce uncertainty in photochemical research. Engineer Research and Development Center (U.S.), 2021. http://dx.doi.org/10.21079/11681/42080.

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Subtle aspects of illumination sources and their characterization methods can introduce significant uncertainty into the data gathered from light-activated experiments, limiting their reproducibility and technology transition. Degradation kinetics of methyl orange (MO) and carbamazepine (CM) under illumination with TiO₂ were used as a case study for investigating the role of incident photon flux on photocatalytic degradation rates. Valerophenone and ferrioxalate actinometry were paired with optical radiometry in three different illumination systems: xenon arc (XE), tungsten halogen (W-H), and
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Moores, Lee, Stacy Jones, Garrett George, David Henderson, and Timothy Schutt. Photo degradation kinetics of insensitive munitions constituents nitroguanidine, nitrotriazolone, and dinitroanisole in natural waters. Engineer Research and Development Center (U.S.), 2021. http://dx.doi.org/10.21079/11681/41900.

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Herein the matrix effects on the kinetics of aqueous photolysis for the individual munitions constituents of IMX-101: nitroguanidine (NQ), dinitroanisole (DNAN), and nitrotriazolone (NTO) are reported along with the environmentally relevant kinetics and quantum yields. Photolysis potentially represents a major degradation pathway for these munitions in the environment and further understanding the complex matrices effects on photolytic kinetics was needed. Aqueous systems are of particular interest due to the high solubility of NQ (3,800 ppm) and NTO (16,642 ppm) compared to the traditional mu
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Kim, J. Y., Y. Kishimoto, W. Horton, and T. Tajima. Kinetic resonance damping rate of the toroidal ion temperature gradient mode. Office of Scientific and Technical Information (OSTI), 1993. http://dx.doi.org/10.2172/10105875.

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Kim, J. Y., Y. Kishimoto, W. Horton, and T. Tajima. Kinetic resonance damping rate of the toroidal ion temperature gradient mode. Office of Scientific and Technical Information (OSTI), 1993. http://dx.doi.org/10.2172/10188391.

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Chongxuan Liu, Zheming Wang, John M. Zachara, and James K. Fredrickson. Influence of Mass Transfer on Bioavailability and Kinetic Rate of Uranium(VI) Biotransformation. Office of Scientific and Technical Information (OSTI), 2006. http://dx.doi.org/10.2172/895929.

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Grant, M. W. Kinetic and Thermodynamic Implications of some Commonly Used Rate Laws for Glass Dissolution. Office of Scientific and Technical Information (OSTI), 2001. http://dx.doi.org/10.2172/781037.

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Ploenjes, E., P. Palm, I. Adamovich, W. Lempert, and V. Subramaniam. Experimental and Analytical Development of Kinetic Rate Data for Radiating Rocket Plume Species. Defense Technical Information Center, 2002. http://dx.doi.org/10.21236/ada406003.

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Rodriguez, Patrick James. Characterization and refinement of carbide coating formation rates and dissolution kinetics in the Ta-C system. Office of Scientific and Technical Information (OSTI), 1996. http://dx.doi.org/10.2172/385606.

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Fugate, G., J. F. Feil-Jenkins, J. C. Sullivan, and K. L. Nash. Actinide complexation kinetics: rate and mechanism of dioxoneptunium (V) reaction with chlorophosphonazo III. Office of Scientific and Technical Information (OSTI), 1996. http://dx.doi.org/10.2172/436450.

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