Academic literature on the topic 'Kinetics of electroreduction'

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Journal articles on the topic "Kinetics of electroreduction"

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Majidzade, Vusala Asim, Akif Shikhan Aliyev, Mahmoud Elrouby, Dunya Mahammad Babanly, and Dilgam Babir Tagiyev. "Electrodeposition and Growth of Iron from an Ethylene Glycol Solution." Acta Chimica Slovenica 68, no. 1 (2021): 185–92. http://dx.doi.org/10.17344/acsi.2020.6308.

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The electrochemical reduction of iron (III) ions into zero-valent iron from a solution of ethylene glycol was accomplished. The kinetics and mechanism of the electroreduction process were investigated by cyclic and linear polarization techniques. The influence of temperature, potential sweep rate, and concentration of iron (III) ions on the electroreduction process was also studied. The observed values of effective activation energy revealed that the investigated electroreduction process is accompanied by mixed kinetics control. Moreover, the results of SEM and X-ray diffraction analysis confi
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Manzini, Mariléa, and Andrzej Lasia. "Kinetics of electroreduction of Zn2+ at mercury in nonaqueous solutions." Canadian Journal of Chemistry 72, no. 7 (1994): 1691–98. http://dx.doi.org/10.1139/v94-213.

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The electroreduction of Zn2+ was studied in propylene carbonate (PC), acetonitrile (ACN), and hexamethylphosphoramide (HMPA) on mercury at various concentrations of tetraethylammonium perchlorate as a supporting electrolyte using dc polarography, cyclic voltammetry, chronoamperometry, and ac polarography. It was found that in PC and ACN the electroreduction process proceeds in one step. In HMPA, however, the electroreduction proceeds through a CEE mechanism in which a chemical reaction is followed by a charge transfer in two steps. The heterogeneous rate constants, corrected for the double lay
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Maheshwari, Sharad, and Michael J. Janik. "Kinetics of Li-Mediated N2 Electroreduction." Joule 3, no. 4 (2019): 915–16. http://dx.doi.org/10.1016/j.joule.2019.03.024.

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Gao, Yun-ming, Kuo-chih Chou, Xing-min Guo, and Wei Wang. "Electroreduction Kinetics for Molten Oxide Slags." Journal of Iron and Steel Research International 14, no. 1 (2007): 16–20. http://dx.doi.org/10.1016/s1006-706x(07)60004-1.

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Javadova, S. P. "ELECTROCHEMICAL REDUCTION OF SELENIUM IONS FROM ORGANIC SOLUTION." Azerbaijan Chemical Journal, no. 4 (December 12, 2020): 43–48. http://dx.doi.org/10.32737/0005-2531-2020-4-43-48.

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Due to the unique properties of metal dichalcogenides, they are wide used in various fields of nano- and optoelectronics. Bi2Se3 is one of the promising n-type semiconductor materials belonging to the Av – Bvı group, with a band gap of 0.3 eV. To obtain these compounds by co-electrodeposition, we study the electroreduction of the initial components separately. Therefore, the study is devoted to the electrochemical reduction of selenite ions from the ethylene glycol solution. By drawing cyclic and linear polarization curves on Pt electrodes, the kinetics, the mechanism of the process, and the i
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Cafarova, Samira Fikret, Akif Shikhan Aliyev, Mahmoud Elrouby, Nsh Soltanova, and Dilgam Babir Tagiyev. "Studying the electrochemical deposition process of molybdenum from aqueous solution of molybdate ions." Journal of Electrochemical Science and Engineering 5, no. 4 (2016): 231. http://dx.doi.org/10.5599/jese.219.

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<span lang="EN-US">In this study, the tracing of the electroreduction process of molybdate ions in aqueous media at different conditions is achieved for obtaining molybdenum metal in a simple and easy way. The kinetics and the mechanism of the electroreduction of molybdate ions are studied using cathodic polarization technique. It is observed that, the speed of the electroreduction process depends on the speed of the change of the cathodic potential sweep as well as on the temperature of the electrodeposition bath. Moreover, it is observed that, at the potential range from the stationary
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Zhu, Ying, Kuilin Lv, Xingpu Wang, Hequn Yang, Guozheng Xiao, and Ying Zhu. "1D/2D nitrogen-doped carbon nanorod arrays/ultrathin carbon nanosheets: outstanding catalysts for the highly efficient electroreduction of CO2 to CO." Journal of Materials Chemistry A 7, no. 24 (2019): 14895–903. http://dx.doi.org/10.1039/c9ta02353d.

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Baltrūnas, Gintaras, Aušra Valiūnienė, Žana Margarian, Gintarė Viselgienė, and George Popkirov. "The electroreduction kinetics of silver sulfite complexes." Electrochimica Acta 53, no. 22 (2008): 6513–20. http://dx.doi.org/10.1016/j.electacta.2008.04.038.

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Wang, Yuting, Changhong Wang, Mengyang Li, Yifu Yu, and Bin Zhang. "Nitrate electroreduction: mechanism insight, in situ characterization, performance evaluation, and challenges." Chemical Society Reviews 50, no. 12 (2021): 6720–33. http://dx.doi.org/10.1039/d1cs00116g.

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In this review, we summarize the reaction mechanism, in situ characterization, theoretical simulation, and kinetics analysis. The performance evaluation parameters, standard test methods, and an outlook for nitrate electroreduction are discussed.
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Javadova, S. P., V. A. Majidzade, S. F. Jafarova, T. A. Aliyev, A. Sh Aliyev, and D. B. Tagiyev. "ELECTROCHEMICAL BEHAVIOR OF BISMUTH IONS IN CITRATE SOLUTIONS." Azerbaijan Chemical Journal, no. 4 (November 14, 2023): 5–12. http://dx.doi.org/10.32737/0005-2531-2023-4-5-12.

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The scientific paper is devoted to the electrochemical reduction of bismuth ions from citrate electrolytes. The kinetics and mechanism of the process and the influence of various factors on the electroreduction process of bismuth ions were studied by recording cyclic and linear polarization curves on Pt, Ni and Ni/Bi electrodes. The effective activation energy and diffusion coefficient were calculated according to the obtained data. The results of the calculation show that the electroreduction process of the bismuth ions from citrate solutions is accompanied by diffusion polarization
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Dissertations / Theses on the topic "Kinetics of electroreduction"

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Sidhu, Jeswant K., University of Western Sydney, and of Informatics Science and Technology Faculty. "Kinetics and mechanisms of methoxide substitution and electroreduction of hexachlorobenzene." THESIS_FIST_XXX_Sidhu_J.xml, 2000. http://handle.uws.edu.au:8081/1959.7/256.

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Hexachlorobenzene (HCB) is a pollutant, and there is an urgent need to degrade it. Two methods of degrading HCB to ethers are nucleophilic substitution and electroreduction, chosen for their viability and safety. The kinetics of substitution of HCB by potassium hydroxide and methanol were examined. The substitution of HCB by methoxide produced 1,2,3,5-tetrachloro-4.6-dimethoxybenzene (1,2,3,5-TCDMB) as the major substitution product, and side reactions produced extra chloride due to other substitution products. Thus, the proposed reaction mechanism is complicated due to the formation of ethers
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Sidhu, Jeswant K. "Kinetics and mechanisms of methoxide substitution and electroreduction of hexachlorobenzene." Thesis, [Campbelltown, N.S.W. : The Author], 2000. http://handle.uws.edu.au:8081/1959.7/256.

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Hexachlorobenzene (HCB) is a pollutant, and there is an urgent need to degrade it. Two methods of degrading HCB to ethers are nucleophilic substitution and electroreduction, chosen for their viability and safety. The kinetics of substitution of HCB by potassium hydroxide and methanol were examined. The substitution of HCB by methoxide produced 1,2,3,5-tetrachloro-4.6-dimethoxybenzene (1,2,3,5-TCDMB) as the major substitution product, and side reactions produced extra chloride due to other substitution products. Thus, the proposed reaction mechanism is complicated due to the formation of ethers
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Sidhu, Jeswant K. "Kinetics and mechanisms of methoxide substitution and electroreduction of hexachlorobenzene /." [Campbelltown, N.S.W. : The Author], 2000. http://library.uws.edu.au/adt-NUWS/public/adt-NUWS20030627.105240/index.html.

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Thomberg, Thomas. "The kinetics of electroreduction of perozodisulfate anion on cadmium (0001) single crystal electrode /." Online version, 2005. http://dspace.utlib.ee/dspace/bitstream/10062/882/5/thomberg.pdf.

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Шумакова, Наталія Іванівна, Наталия Ивановна Шумакова, Nataliia Ivanivna Shumakova, and Z. M. Protsenko. "Electrochemical Deposition of Film Materials Based on Co and Ag." Thesis, Sumy State University, 2012. http://essuir.sumdu.edu.ua/handle/123456789/35008.

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The technology deposition of film materials with spin-dependent scattering of electrons based on Co and Ag by electrochemical method from sulfate and iodide electrolytes described. The kinetics of electroreduction of Co and Ag from this electrolytes. Determined phase composition of multilayer coatings based on Co and Ag before and after thermal annealing to temperatures T = 523-743 K. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/35008
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Ferreira, de Araújo Jorge Vicente [Verfasser], Peter [Akademischer Betreuer] Strasser, Helmut [Gutachter] Baltruschat, and Matthias [Gutachter] Bickermann. "Differential electrochemical mass spectrometry – design, set up and application for kinetic isotope labeling studies of the electrocatalytic CO2 electroreduction / Jorge Vicente Ferreira de Araújo ; Gutachter: Helmut Baltruschat, Matthias Bickermann ; Betreuer: Peter Strasser." Berlin : Technische Universität Berlin, 2020. http://d-nb.info/1211392236/34.

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Chavis, Grace. "A study of electroreduction kinetics of pentaaminecobalt(III) complexes in aqueous solutions." Diss., 2009. http://proquest.umi.com/pqdweb?did=1917155251&sid=2&Fmt=2&clientId=48051&RQT=309&VName=PQD.

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Hlophe, Mbhuti. "Determination of nitosoamines by DP polarography and investigation of kinetics of electroreduction of N-Nitrosodimethylamine by voltammetric techniques / Mbhuti Hlophe." Thesis, 2005. http://hdl.handle.net/10394/11319.

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This study has two aspects. One concerns the development of a sensitive differential pulse polarographic (DPP) method and its use to conduct a preliminary study of natural waters to detect the presence of nitrosoamines, and the second, where the study was carried out in greater detail, is the investigation of the kinetics of reduction of N-nitrosodimethylamine (NDMA) in aqueous solution. An optimization study was first conducted to identify the conditions that give the greatest sensitivity. Conditions investigated were different supporting electrolytes and solvent mixtures. Supporting electrol
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Book chapters on the topic "Kinetics of electroreduction"

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Pruttskov, Dmitriy, Aleksander Andriiko, and Aleksei Kirichenko. "Kinetics and Mechanism of Si(IV) Electroreduction in Na3AlF6–Al2O3–SiO2 Melts on Al Cathode." In Monographs in Electrochemistry. Springer Nature Switzerland, 2023. http://dx.doi.org/10.1007/978-3-031-29249-1_2.

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Nosal-Wiercińska, Agnieszka, Mariusz Grochowski, and Małgorzata Wiśniewska. "Effects of Amino Acids Protonation on Double-Layer Parameters of the Electrode/Chlorates(VII) Interface, as well as Kinetics and Mechanism of Bi(III) Ion Electroreduction in the Aspect of the “Cap–Pair” Effect." In Nanooptics, Nanophotonics, Nanostructures, and Their Applications. Springer International Publishing, 2018. http://dx.doi.org/10.1007/978-3-319-91083-3_20.

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"Electrode Kinetics of CO2 Electroreduction." In Electrochemical Reduction of Carbon Dioxide. CRC Press, 2016. http://dx.doi.org/10.1201/b20177-11.

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Sun, Dongmei, and Yu Chen. "Electrode Kinetics of CO2 Electroreduction." In Electrochemical Reduction of Carbon Dioxide. CRC Press, 2016. http://dx.doi.org/10.1201/b20177-4.

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Conference papers on the topic "Kinetics of electroreduction"

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Pawlak, Alicja, and Agnieszka Nosal-Wiercińska. "Reinterpretation of the ‘cap-pair’ rule in mixed aqueous-organic electrochemical systems containing ethanol and acetonitrile: mechanism and kinetics of the electroreduction process of Bi(III) ions." In 4th International PhD Student’s Conference at the University of Life Sciences in Lublin, Poland: ENVIRONMENT – PLANT – ANIMAL – PRODUCT 9 April 2025. Wydawnictwo Uniwersytetu Przyrodniczego w Lublinie, 2025. https://doi.org/10.24326/icdsupl4.h016.

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Liu, Zilong, Hayati Onay, Fengzhi Guo, and Pegah Hedayati. "Electrochemically Assisted Deposition of Calcium Carbonate Surfaces for Anionic Surfactant Adsorption: Implications for Enhanced Oil Recovery." In SPE International Conference on Oilfield Chemistry. SPE, 2021. http://dx.doi.org/10.2118/204283-ms.

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Abstract Surface roughness of rocks had a significant influence on surfactant adsorption in enhanced oil recovery (EOR), both in terms of the total amount adsorbed as well as of the kinetics of adsorption. Combining electrochemical techniques and quartz crystal microbalance with dissipation monitoring (QCM) into one analysis setup opens up new avenues for depositing model rock surfaces and investigating the adsorption behavior. Using electrochemically assisted deposition, uniform and well-covered metal-CaCO3 sensors were obtained to simulate rough carbonate rocks and characterized by scanning
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