Relevant bibliographies by topics / L12 ordered precipitates

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Academic literature on the topic 'L12 ordered precipitates'

Author: Grafiati
Published: 6 September 2023

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Journal articles on the topic "L12 ordered precipitates"

1

Sun, Yuanyang, Yuhong Zhao, Huijun Guo, Xiaolin Tian та Hua Hou. "Early Stages of Precipitation in γ' Phase of a Ni–Al–Ti Model Alloy: Phase-Field and First-Principles Study". Science of Advanced Materials 12, № 5 (2020): 746–54. http://dx.doi.org/10.1166/sam.2020.3716.

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The early stages of precipitation process of the γ' phase of a Ni–Al–Ti alloy are investigated by microscopic phase-field and first-principles calculations. The simulated results indicate that a pre-precipitate with L10 structure appears before the L12 ordered phase, and then this metastable phase gradually transforms to L12 ordered phase; finally, the precipitated phase is composed of γ' ordered phase and γ matrix phase. The occupation probabilities of Al, Ni, and Ti atoms also illustrate the formation of the L10 phase and its situ conversion to L12 ordered phase constituted by a complicated compound Ni3(AlTi). Through the analyses of order parameter and occupation probability, the precipitation mechanism of γ' phase is drawn as a combination of congruent ordering and destabilization decomposition. Meanwhile, we also find that the growth and coarsening of the γ' phase occur via mixed mechanisms of Ostwald ripening and coalescence coarsening of neighboring precipitates. Moreover, the first-principles method is applied to calculate the thermodynamic parameters and validate further the appearance of the metastable phase and the site preference of Ti atom, which offers an explanation for atomic occupancy characteristics in the precipitate.
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2

Doi, Minoru. "Two-Phase Microstructures Formed by Phase-Separation of Coherent Precipitates in Elastically Constrained Alloy Systems." Materials Science Forum 638-642 (January 2010): 2215–20. http://dx.doi.org/10.4028/www.scientific.net/msf.638-642.2215.

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Coherent two-phase microstructures consisting of ordered precipitate and disordered matrix phases sometimes exhibit a phase-separation, which brings the split and/or the decelerated coarsening of precipitates. When the coherent two-phase microstructure of A1+L12 (+’) in Ni-base alloys are aged inside the two-phase region of A1+L12 , the L12 precipitate sometimes exhibit a phase-separation and A1 phase newly appears and grows in each L12 precipitate. Phase-separations of the same type to the above also take place due to ageing of coherent two-phase microstructures of A2+D03 and A2+B2 in Fe-base alloys: D03 and B2 precipitates sometimes exhibit phase-separations and A2 phase newly appears and grows in both precipitates. These types of phase-separation take place under the influence of chemical free energy. In the course of further ageing, the new disordered phases of A1 and A2 change their morphology in various ways depending on the elastic constraint: i.e. the morphology of new A1 or A2 phase is influenced by the elastic energies and the surface energy.
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3

Zhao, Bing Bing, Xian Ping Dong, Feng Sun, and Lan Ting Zhang. "Impact of L12-Ordered Precipitation on the Strength of Alumina-Forming Austenitic Heat-Resistant Steels." Materials Science Forum 941 (December 2018): 692–97. http://dx.doi.org/10.4028/www.scientific.net/msf.941.692.

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Alumina-forming austenitic (AFA) heat-resistance steels firstly developed by Yamamoto et al. at Oak Ridge National Laboratory have been reported as a new promising class of steels with potential for use in high temperature applications in recent years. The creep resistance of AFA steels is improved mainly by precipitation strengthening. Besides modifying the typical existing precipitates, i.e. MC and M23C6 type carbides, B2-NiAl and Fe2Nb-type Laves phase, introduction of coherent L12-ordered precipitate is highly desired. L12-ordered phase gamma prime (γ’) is the most important precipitate for high-temperature strengthening in Ni-based superalloys. In the present work, we demonstrate that addition of 2.8 wt. % Cu to an AFA steel promotes the formation of an L12-ordered phase with the dominating elements Ni, Cu and Al. TEM characterization after slow rate tensile tests indicated there were the different precipitation behaviours at 700°C and 750°C. It was revealed that the occurrence of L12-ordered Ni-Cu-Al phase depends on temperature and Ni content. This opens up new opportunities to promote the formation of L12-ordered phase in Fe-based austenitic heat-resistance steels and benefit high-temperature mechanical properties.
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4

De Hosson, J. T. M. "Superlattice dislocations in L12 ordered alloys and in alloys containing L12 ordered precipitates." Materials Science and Engineering 81 (August 1986): 515–23. http://dx.doi.org/10.1016/0025-5416(86)90288-0.

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5

Gayle, Frank W., and John B. VanderSande. "Characterization of Rapidly Solidified Aluminum-Lithium Alloys." Proceedings, annual meeting, Electron Microscopy Society of America 43 (August 1985): 26–29. http://dx.doi.org/10.1017/s0424820100117224.

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Aluminum-lithium alloys are presently the subject of much research due to the effectiveness of lithium in reducing density, raising elastic modulus and providing for high strength. The strengthening precipitate is the metastable, L12-ordered Al3Li (Cu3Au prototype), or δ'. In binary alloys, δ’ precipitates homogeneously with a spherical shape, coherent with the aluminum matrix. These lithium-containing alloys suffer from poor ductility and fracture toughness, however, which has been attributed to 1) the shear-able nature of the δ’ precipitate, resulting in work softening and slip localization on the relevant slip planes, and 2) precipitate free zone formation along high angle grain boundaries.In a previous paper we proposed that Zr could partially substitute for Li in δ', resulting in a ternary Al3(Li,Zr) phase, which we call δ”. It was anticipated that such a phase would be more resistant to dislocation shear than δ’ from observation of deformation behavior of Al-Zr alloys containing the coherent L12-ordered Al3Zr precipitate.
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6

Moritani, Tomokazu, Masahiro Ota, Takao Kozakai, and Minoru Doi. "TEM Observations of Two-Phase Microstructure Formed by Phase Separation of Gamma-Prime Precipitates in Ni-Al-Si Alloys." Materials Science Forum 561-565 (October 2007): 2361–64. http://dx.doi.org/10.4028/www.scientific.net/msf.561-565.2361.

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The phase-separation behaviour of γ’ precipitates in Ni-7.1Al-6.7Si alloy was investigated by means of transmission electron microscopy (TEM). When the alloy is aged at 1173K, coherent spherical γ’ particles having ordered L12 structure appear in γ matrix having disordered A1 structure. When the two-phase microstructure of γ + γ’ is aged at 973K, spherical γ particles precipitate in the individual γ’ precipitates. In the course of ageing at 973K, the new γ particles grow keeping the spherical shape, their number gradually decreases and finally γ particles aging at 1173K gradually change their shape from sphere to cuboid, but do not practically change their size, i.e. such phase-separation behaviour brings the decelerated growth of γ’ precipitates.
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7

Wang, Rui, Yilei Fu, Guoliang Xie, Zifan Hao, Shuai Zhang, and Xinhua Liu. "The Microstructure and Mechanical Properties of Cu-20Ni-20Mn Alloy Fabricated by a Compact Preparation Process." Metals 10, no. 11 (2020): 1528. http://dx.doi.org/10.3390/met10111528.

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A novel compact preparation process has been developed to produce a Cu-20Ni-20Mn alloy. This process involves heating-cooling combined mould (HCCM) continuous casting, a solution treatment at 800 °C, rolling at room temperature and a final ageing step at 450 °C. This process eliminates two hot deformation processes, namely, hot forging and hot rolling, greatly improving production efficiency and reducing production costs compared with the traditional preparation process. The alloy fabricated by this process was found to have excellent mechanical properties. Additionally, the formation of precipitated phases during the ageing step is accelerated by this new process. The hardness of the samples reaches 476 HV after ageing for 10 h. Stable, ordered precipitates of Ni3Mn(L12 phase) are observed in the rolled specimen, and the orientation relationship between the copper matrix and ordered Ni3Mn phase (L12 phase) is [200]Cu//[010]Ni3Mn and [011]Cu//[011]Ni3Mn. Precipitation strengthening is the main reason for the increase of strength of the sample during the ageing process. The mechanical properties and ageing precipitation process of the alloy are affected by the rolling process. The precipitation rate of the rolled sample is greatly increased during the ageing process, leading to a larger amount of precipitates.
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8

Jang, Ok Jun, Cheol-Woong Yang, and Dong Bok Lee. "Transmission Electron Microscopy Characterization of Thermomechanically Treated Al3Ti–(8, 10, 15)% Cr Intermetallics." Microscopy and Microanalysis 19, S5 (2013): 89–94. http://dx.doi.org/10.1017/s1431927613012403.

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AbstractThe ordered L12-type Al3Ti–(8, 10, 15)% Cr intermetallic compounds, namely, Al67Ti25Cr8, Al66Ti24Cr10, and Al59Ti26Cr15, were prepared by induction melting followed by thermomechanical treatment. Their microstructure, compositional variation, and crystal structure were characterized using X-ray diffraction, optical microscopy, and scanning and transmission electron microscopy equipped with energy-dispersive spectroscopy. The Al67Ti25Cr8 alloy consisted of the L12-Al3Ti matrix and precipitates of α2-Ti3Al, D022-Al3Ti, and γ-TiAl. The Al66Ti24Cr10 and Al59Ti26Cr15 alloys consisted of the L12-Al3Ti matrix and grains of α-TiAl and β-Cr.
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9

Eggeler, Y. M., K. V. Vamsi, and T. M. Pollock. "Precipitate Shearing, Fault Energies, and Solute Segregation to Planar Faults in Ni-, CoNi-, and Co-Base Superalloys." Annual Review of Materials Research 51, no. 1 (2021): 209–40. http://dx.doi.org/10.1146/annurev-matsci-102419-011433.

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The mechanical properties of superalloys are strongly governed by the resistance to shearing of ordered precipitates by dislocations. In the operating environments of superalloys, the stresses and temperatures present during thermomechanical loading influence the dislocation shearing dynamics, which involve diffusion and segregation processes that result in a diverse array of planar defects in the ordered L12 γ′ precipitate phase. This review discusses the current understanding of high-temperature deformation mechanisms of γ′ precipitates in two-phase Ni-, Co-, and CoNi-base superalloys. The sensitivity of planar fault energies to chemical composition results in a variety of unique deformation mechanisms, and methods to determine fault energies are therefore reviewed. The degree of chemical segregation in the vicinity of planar defects reveals an apparent phase transformation within the parent γ′ phase. The kinetics of segregation to linear and planar defects play a significant role in high-temperature properties. Understanding and controlling fault energies and the associated dislocation dynamics provide a new pathway for the design of superalloys with exceptional properties.
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10

Vorontsov, V. A., R. E. Voskoboinikov, and Catherine M. F. Rae. "Prediction of Mechanical Behaviour in Ni-Base Superalloys Using the Phase Field Model of Dislocations." Advanced Materials Research 278 (July 2011): 150–55. http://dx.doi.org/10.4028/www.scientific.net/amr.278.150.

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The “Phase-Field Model of Dislocations” (PFMD) was used to simulate shearing of gamma-prime precipitate arrays in single crystal turbine blade superalloys. The focus of the work has been on the cutting of the L12 ordered precipitates by a<112>{111} dislocation ribbons during Primary Creep. The Phase Field Model presented incorporates specially developed Generalised Stacking Fault Energy (–surface) data obtained from atomistic simulations. The topography of this surface determines the shearing mechanisms observed in the model. The merit of the new –surface, is that it accounts for the formation of extrinsic stacking faults, making the model more relevant to creep deformation of superalloys at elevated temperatures.
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