Academic literature on the topic 'Laboratory technique of chemistry'

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Journal articles on the topic "Laboratory technique of chemistry"

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Nesměrák, Karel, and Radek Chalupa. "Eponyms in Laboratory Equipment." Chemické listy 116, no. 12 (December 15, 2022): 719–29. http://dx.doi.org/10.54779/chl20220719.

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In the chemistry laboratory, we can find plenty of tools that bear the name of their creator. Such names are called eponyms. The article presents 72 of the most commonly used representatives of eponymic names in the laboratory technique. Their primary sources (where possible) and actual creators were identified by excerpting historical chemical literature including rare and not easily accessible items. The article shows that some eponymic names are not based on the name of the discoverer, but rather on the names of the manufacturers (e.g., Griffin beaker), the names of those who popularized the device (e.g., Liebig condenser), or who were associated with it because of their fame (e.g., Willstätter needle). Eponymic names in the laboratory technique are not only a legacy of the past and an important means of communication in contemporary chemistry, but they can also be used to communicate chemistry to students and lay people, using interesting stories hidden behind them. Full text English translation is available in the on-line version.
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Bond, Alan M. "Laboratory techniques in electroanalytical chemistry." Journal of Chromatography A 755, no. 2 (December 1996): 313. http://dx.doi.org/10.1016/s0021-9673(96)00641-3.

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Achterberg, Eric P. "Laboratory techniques in electroanalytical chemistry." TrAC Trends in Analytical Chemistry 15, no. 10 (November 1996): 550. http://dx.doi.org/10.1016/s0165-9936(96)80740-0.

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Pungor, E. "Laboratory techniques in electroanalytical chemistry." TrAC Trends in Analytical Chemistry 4, no. 10 (November 1985): XXII. http://dx.doi.org/10.1016/0165-9936(85)87050-3.

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Türk, Fatma, Alipaşa Ayas, and Fethiye Karslı. "Effectiveness of analogy technique on students’ achievement in general chemistry laboratory." Procedia - Social and Behavioral Sciences 2, no. 2 (2010): 2717–21. http://dx.doi.org/10.1016/j.sbspro.2010.03.402.

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Bradley, David. "Laboratory Profile: Teenage technique coming of age." Analytical Chemistry 70, no. 1 (January 1998): 22A. http://dx.doi.org/10.1021/ac981707v.

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Marshall, William J., and Peter E. G. Mitchell. "Total Parenteral Nutrition and the Clinical Chemistry Laboratory." Annals of Clinical Biochemistry: International Journal of Laboratory Medicine 24, no. 4 (July 1987): 327–36. http://dx.doi.org/10.1177/000456328702400401.

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Parenteral nutrition is a well-established technique for feeding patients with intestinal failure and other conditions which render enteral feeding impossible. Biochemical tests are required in the initial assessment of these patients, for monitoring their response to treatment and for the detection and management of complications. The use of these tests is discussed critically and guidelines are provided for the frequency with which they should be performed. Chemical pathologists and clinical biochemists have an important role in the provision of parenteral nutrition as members of multi-disciplinary nutrition teams.
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Cerdà, Víctor, Jessica Avivar, and Amalia Cerdà. "Laboratory automation based on flow techniques." Pure and Applied Chemistry 84, no. 10 (June 27, 2012): 1983–98. http://dx.doi.org/10.1351/pac-con-11-11-14.

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Flow techniques have undoubtedly aroused special interest in relation to many other automatic methodologies of analysis. Ever since segmented flow analysis (SFA) was developed by Skeggs in 1957, flow techniques have been in continuous evolution toward new develop-ments. There is no solid argument in favor of using any particular flow technique separately; rather, substantial advantages can be derived from their combination. Since flow-based methods are nonseparative tools, the advantages of combining flow techniques with separation techniques are noteworthy. High selectivity can be achieved by coupling them with liquid chromatography (LC), gas chromatography (GC), solid-phase extraction (SPE), or capillary electrophoresis (CE). Thus, a detailed description of flow techniques, their evolution, their hyphenation advantages, and a critical comparison between current developed methods exploiting flow techniques aimed at solving present analytical needs are reviewed in this article.
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Seery, Michael K., Hendra Y. Agustian, Euan D. Doidge, Maciej M. Kucharski, Helen M. O’Connor, and Amy Price. "Developing laboratory skills by incorporating peer-review and digital badges." Chemistry Education Research and Practice 18, no. 3 (2017): 403–19. http://dx.doi.org/10.1039/c7rp00003k.

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Laboratory work is at the core of any chemistry curriculum but literature on the assessment of laboratory skills is scant. In this study we report the use of a peer-observation protocol underpinned by exemplar videos. Students are required to watch exemplar videos for three techniques (titrations, distillations, preparation of standard solutions) in advance of their practical session, and demonstrate the technique to their peer, while being reviewed. For two of the techniques (titrations and distillations), the demonstration was videoed on a mobile phone, which provide evidence that the student has successfully completed the technique. In order to develop digital literacy skills, students are required to upload their videos to a video sharing site for instructor review. The activity facilitated the issuing of digital badges to students who had successfully demonstrated competency. Students’ rating of their knowledge, experience, and confidence of a range of aspects associated with each technique significantly increased as a result of the activity. This work, along with student responses to questions, video access, and observations from implementation are reported in order to demonstrate a novel and useful way to incorporate peer-assessment of laboratory skills into a laboratory programme, as well as the use of digital badges as a means of incorporating and documenting transferable skills on the basis of student generated evidence.
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Obaya V, Adolfo E., Carlos Osorio G, and Yolanda Marina Vargas. "Writing as a teaching learning technique: an example in chemistry (molar solution)." Budapest International Research and Critics in Linguistics and Education (BirLE) Journal 3, no. 2 (May 10, 2020): 1056–64. http://dx.doi.org/10.33258/birle.v3i2.1034.

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Techniques are needed to train students in "writing to learn"., whose main goal is to "learn to write". This work aims to exemplify how writing can be a teaching learning technique in an example in Chemistry to develop a correct understanding of the preparation of molar solutions in the laboratory. It is essential that this is carried out in the classroom in a way that develops the reflective, analytical and cognitive skills of students. All this within an environment with safety measures at work.
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Dissertations / Theses on the topic "Laboratory technique of chemistry"

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Powell, Mary Cynthia Barton. "Podcast Effectiveness as Scaffolding Support for Students Enrolled in First-Semester General Chemistry Laboratories." Thesis, University of North Texas, 2010. https://digital.library.unt.edu/ark:/67531/metadc30502/.

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Podcasts covering essential first-semester general chemistry laboratory techniques and central concepts that aid in experimental design or data processing were prepared and made available for students to access on an as-needed basis on iPhones- or iPod touches-. Research focused in three areas: the extent of podcast usage, the numbers and types of interactions between instructors and research teams, and student performance on graded assignments. Data analysis indicates that the podcast treatment research teams accessed a podcast 2.86 times on average during each week that podcasts were available. Comparison of interaction data for the lecture treatment research teams and podcast treatment research teams reveals that interactions with instructors were statistically significantly fewer for teams that had podcast access rather than a pre‐laboratory lecture. The implication of the results is that student research teams were able to gather laboratory information more effectively when it was presented in an on-demand podcast format. Finally, statistical analysis of data on student performance on graded assignments indicates no significant differences between outcome measures for the treatment groups when compared as cohorts. The only statistically significant difference is between students judged to be highly motivated; for this sub‐group the students in the podcast treatment group earned a course average that was statistically significantly higher than those in the lecture treatment group. This research study provides some of the first data collected on the effectiveness of podcasts delivered as needed in a first-semester general chemistry laboratory setting.
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Donohue, Tammy Schumacher. "A Comparison of Common Laboratory Techniques for the Analysis of Thiocarbamate Pesticides." University of Akron / OhioLINK, 2012. http://rave.ohiolink.edu/etdc/view?acc_num=akron1342049057.

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Smith, Catherine Joyce. "New tools for organic chemistry : proof-of-concept studies using new reactors, reagents and techniques for the laboratory scale synthesis of small molecule building blocks in flow." Thesis, University of Cambridge, 2011. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.609683.

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McBride, Phil Blake. "REVITALIZING CHEMISTRY LABORATORY INSTRUCTION." Miami University / OhioLINK, 2003. http://rave.ohiolink.edu/etdc/view?acc_num=miami1070500644.

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Larsson, Malin. "Laboratory Chemistry in Natural Science." Thesis, Kristianstad University College, Department of Teacher Education, 2006. http://urn.kb.se/resolve?urn=urn:nbn:se:hkr:diva-3988.

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University level laboratory work is reformulated to fit into the chemistry and

natural science education in the upper secondary school of Sweden. This thesis

describes how this reformulation is performed both from the chemical and the

didactic point of view. The resulting laboratory manual has been tested by students

in the target group with positive response. Interest lay in how to present

laboratory experiments far different from what they usually did and how it actually

connected to their studies in natural science. How much did attitudes and

self-efficacy influence the implementation of the laboratory work and how did

the students collaborate? The author designed the laboratory work, observed an

implementation of parts of the laboratory work through laboratory lessons in a

school class and made a follow-up interview with the teacher.

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Benites, Galbiati Martín. "A silicon laboratory: chemistry without chemicals." Revista de Química, 2014. http://repositorio.pucp.edu.pe/index/handle/123456789/99186.

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El Premio Nobel de Química de 2013 ha sido otorgado a A. Warshel, M. Levitt y M. Karplus debido al desarrollo de métodos híbridos de cálculo para química computacional. En este artículo se presentará una breve introducción del uso de los métodos de química computacional. Se describirá cómo se desarrollaron, y por qué, los métodos híbridos de cálculo, conocidos como QM/MM (Quantum Mechanics/Molecular Mechanics) para el estudio de sistemas macromoleculares, sobre todo para el caso de su aplicación en enzimas y bioquímica. Finalmente, se comentarán los alcances y expectativas futuras para estos métodos, desarrollados en los años 70.
The 2013 Nobel Prize in chemistry was awarded to A.Warshel, M.Levitt and M.Karplus for their contribution to the development of hybrid methods for computational chemistry. In this article a brief introduction about computational chemistry methods is presented. This paper will show the order in which the QM/MM (Quantum Mechanics/Molecular Mechanics) methods were developed for the study of macromolecular systems and specially their application in enzymes and biochemistry. Finally, the reach and future prospects of these methods originally developed by A. Warshel, M.Levitt and M. Karplus in the seventies will be discussed.
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Tuncdemir, Fatih. "A Laboratory Study Of Fracture Grouting Technique In Sand." Phd thesis, METU, 2008. http://etd.lib.metu.edu.tr/upload/12609768/index.pdf.

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In this study, fracture grouting technique of saturated, granular soils of different fine content were investigated. Model tests were carried out by using fluid particulate grouts namely micro fine cement and ordinary portland cement grouts. Basically, relationships were obtained between soil conditions (grain size distribution, relative density, overburden stress) and grouting parameters (type of grout, grouting pressure, amount of injected grout, rheological properties of the grout or water/solids ratio). At the end of the tests the soil specimens were exposed and the final grout shapes were observed and correlated with the grouting parameters. Response of soil specimens to grouting process under different grouting pressures and grout compositions was analyzed. Amount of heave occurred at the top of the specimen during injections was recorded at each test. Micro fine cement grout and ordinary portland cement grout showed significant differences rheologically. Micro fine cement grout, with much higher Blaine fineness, lower specific gravity, lower viscosity and cohesion, lower bleed and filtration coefficients, made it possible to fracture the fine sandy soils of different fine content. Results of tests performed with micro fine cement grouts show that fracturing pressure generally decreases with an increase in the water content of the grout but generally increases as the fine content of the soil increases. A higher relative density of the soil increases the fracturing pressure significantly. The volumes of grout injected into soil specimens until fracturing show an increasing tendency as the water/solids ratio decrease. Ordinary portland cement grout, on the other hand, exposed to high pressure filtration during grouting in relatively clean sand and addition of some amount of kaolinite or fines is required to reduce the filtration percentages during grouting in order to fracture grout the sandy soil. Filtration due to high permeabilities results in accumulation of cement particles around the injection point and grouting tends to take a form similar to compaction grouting.
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Lorson, Mark Vernon. "A comparison of microcomputer-based laboratories and traditional laboratory methods in the high school chemistry laboratory /." The Ohio State University, 1991. http://rave.ohiolink.edu/etdc/view?acc_num=osu148768748580838.

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Fay, Michael E. "Exploring the Undergraduate Chemistry Laboratory Curriculum: Faculty Perspectives." Oxford, Ohio : Miami University, 2008. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=miami1208894481.

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Schroeder, Jacob Daniel. "Implementing the Science Writing Heuristic laboratory report format in the undergraduate organic chemistry laboratory." [Ames, Iowa : Iowa State University], 2008.

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Books on the topic "Laboratory technique of chemistry"

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Synthesis and technique in inorganic chemistry. 2nd ed. Mill Valley, Calif: University Science Books, 1986.

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S, Fessenden Joan, and Landgrebe John A, eds. Organic laboratory techniques. 2nd ed. Pacific Grove, Calif: Brooks/Cole, 1993.

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S, Fessenden Joan, and Feist Patty 1949-, eds. Organic laboratory techniques. 3rd ed. Pacific Grove, CA: Brooks/Cole Thomson Learning, 2000.

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T, Crosby N., Prichard F. Elizabeth, and Newman Ernest J, eds. Quality in the analytical chemistry laboratory. Chichester: Published on behalf of ACOL (University of Greenwich) by J. Wiley, 1995.

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1949-, Rauchfuss Thomas B., Angelici Robert J, and Angelici Robert J, eds. Synthesis and technique in inorganic chemistry: A laboratory manual. 3rd ed. Sausalito, Calif: University Science Books, 1999.

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Quality assurance for the analytical chemistry laboratory. Oxford: Oxford University Press, 2007.

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Pavia, Donald L. Introduction to organic laboratory techniques. 3rd ed. Philadelphia: Saunders College Publishing, 1988.

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Nilsen, Clifford L. Managing the analytical laboratory: Plain and simple. Buffalo Grove, IL: Interpharm Press, 1996.

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M, Pike Ronald, and Trumpeter Peter, eds. Microscale organic laboratory: Techniques & experiments. New York: Wiley Custom Services, 2001.

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Garner, Charles M. Techniques and experiments for advanced organic laboratory. New York: Wiley, 1997.

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Book chapters on the topic "Laboratory technique of chemistry"

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Barger, Anne M. "Clinical Chemistry." In Clinical Pathology and Laboratory Techniques for Veterinary Technicians, 95–140. Chichester, UK: John Wiley & Sons, Ltd, 2017. http://dx.doi.org/10.1002/9781119421351.ch4.

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Debreczeni, Loránd A., Anna Kovácsay, and Sandor Nagy. "Basics in Laboratory Medicine: Past, Present, and Future." In Analytical Techniques for Clinical Chemistry, 775–85. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2012. http://dx.doi.org/10.1002/9781118271858.ch25.

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Ceglarek, Uta, Georg Martin Fiedler, and Joachim Thiery. "Applications of LC-MS/MS in Clinical Laboratory Diagnostics." In Analytical Techniques for Clinical Chemistry, 507–34. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2012. http://dx.doi.org/10.1002/9781118271858.ch18.

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Dux, James P. "Statistical Quality Control Techniques." In Handbook of Quality Assurance for the Analytical Chemistry Laboratory, 31–46. Boston, MA: Springer US, 1990. http://dx.doi.org/10.1007/978-1-4684-1458-5_3.

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Dux, James P. "Statistical Quality Control Techniques." In Handbook of Quality Assurance for the Analytical Chemistry Laboratory, 31–46. Boston, MA: Springer US, 1990. http://dx.doi.org/10.1007/978-1-4757-5377-6_3.

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Schlemmer, Stephan, Wolf Geppert, Andreas Wolf, Juraj Glosik, David Parker, Laurent Wiesenfeld, Holger Kreckel, Daniel Wolf Savin, and Oskar Asvany. "Gas Phase Chemistry." In Laboratory Astrochemistry, 109–228. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2014. http://dx.doi.org/10.1002/9783527653133.ch3.

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Goltra, Peter S. "Laboratory-Based Chemistry." In Medcin, 182–95. New York, NY: Springer New York, 1997. http://dx.doi.org/10.1007/978-1-4612-2286-6_50.

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Carrasco, Nathalie. "Plasma Chemistry, Laboratory." In Encyclopedia of Astrobiology, 1. Berlin, Heidelberg: Springer Berlin Heidelberg, 2021. http://dx.doi.org/10.1007/978-3-642-27833-4_5141-1.

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Christian, Donnell. "Forensic Chemistry." In The Forensic Laboratory Handbook, 35–61. Totowa, NJ: Humana Press, 2006. http://dx.doi.org/10.1385/1-59259-946-x:35.

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Schubbert, Rainer. "Molecular Biology Laboratory Layout." In Molecular Biological and Immunological Techniques and Applications for Food Chemists, 1–39. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2010. http://dx.doi.org/10.1002/9780470637685.ch1.

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Conference papers on the topic "Laboratory technique of chemistry"

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Romero, E., R. Senger, and P. Marschall. "Air Injection Laboratory Experiments on Opalinus Clay. Experimental techniques, Results and Analyses." In 3rd EAGE Shale Workshop - Shale Physics and Shale Chemistry. Netherlands: EAGE Publications BV, 2012. http://dx.doi.org/10.3997/2214-4609.20143925.

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Wylde, Jonathan J., Alexander R. Thornton, Mark Gough, Rifky Akbar, and William A. Bruckmann. "Calcite Scale Mitigation in a Very Low Watercut, Low Salinity, HPHT Environment: Lessons Learned in Surveillance, Mitigation and Scale Inhibitor Performance Monitoring for an Onshore Field." In SPE International Conference on Oilfield Chemistry. SPE, 2021. http://dx.doi.org/10.2118/204288-ms.

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Abstract A prolific Southeast Asia onshore oilfield has enjoyed scale free production for many years before recently experiencing a series of unexpected and harsh calcite scaling events. Well watercuts were barely measurable, yet mineral scale deposits accumulated quickly across topside wellhead chokes and within downstream flowlines. This paper describes the scale management experience, and the specific challenges presented by this extraordinarily low well water cut, low pH, calcium carbonate scaling environment. To the knowledge of the authors, no previous literature works have been published regarding such an unusual and aggressive mineral scale control scenario. A detailed analysis of the scaling experience is provided, including plant layout, scaling locations, scale surveillance and monitoring programs, laboratory testing, product selection and implementation, and scale inhibitor efficacy surveillance and monitoring programs. The surveillance and application techniques themselves are notable, and feature important lessons learned for addressing similar very low water cut and moderate pH calcium carbonate scaling scenarios. For example, under ultra-low watercut high temperature well production conditions, it was found that a heavily diluted scale inhibitor was necessary to achieve optimum scale control, and a detailed laboratory and field implementation process is described that led to this key learning lesson. The sudden and immediate nature of the occurrence demanded a fast-track laboratory testing approach to rapidly identify a suitable scale inhibitor for the high temperature topside calcium carbonate scaling scenario. The streamlined selection program is detailed, however what could not be readily tested for via conventional laboratory testing was the effect of <1% water cut, and how the product would perform in that environment. A risk-managed field surveillance program was initiated to determine field efficiency of the identified polymeric scale inhibitor and involved field-trialing on a single well using a temporary restriction orifice plate (ROP) to modify the residence time of the injected chemical. The technique proved very successful and identifed that product dispersibility was important, and that dilution of the active scale inhibitor had a positive effect on dispersibility for optimum inhibitor action. The lessons learned were rolled out to all at-risk field producers with positive results. The ongoing success of this program continues and will be detailed in the manuscript and presentation. This paper demonstrates a unique situation of calcium carbonate scale formation and control that utilized a previously unreported and analytical surveillance approach. The cumulative performance derived by improving not only chemical selection, but the way the wells were managed via surveillance and chemical management decision making processes is compelling and of value to other production chemists working in the scaling arena.
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Mazurkiewicz, Paul. "Advanced Analytical Chemistry Techniques Enable Rapid, Cheap and Concise Electronic Failure Analysis." In ISTFA 2004. ASM International, 2004. http://dx.doi.org/10.31399/asm.cp.istfa2004p0457.

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Abstract This article introduces several analytical chemistry techniques that are extremely useful in the electronics failure analysis (FA) laboratory, but are not normally found in FA laboratories. It presents the techniques in simple language and makes a case for the inclusion of chemists in the rapidly evolving and ever-shrinking world of microelectronic failure analysis. The article discusses the following techniques in terms of their applications, advantages, and operating principles: gel permeation chromatography, gas chromatography-mass spectrometry, Fourier transform-infrared spectroscopy, and electron spectroscopy for chemical analysis (ESCA). As we move into the world of nanotechnology, these techniques will become key in analyzing failures that cannot be visualized using traditional FA methods.
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Liu, Zhengwei, Sankaran Murugesan, Sunder Ramachandran, and Peng Jin. "Next Generation Oilfield on-Site Trace Chemicals Analysis by SERS." In SPE International Conference on Oilfield Chemistry. SPE, 2021. http://dx.doi.org/10.2118/204369-ms.

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Abstract Accurate and precise monitoring of chemical additives in oilfield brine is an important aspect of oil and gas operations towards corrosion control and flow assurance. Many operators are required to monitor the residual concentrations of chemical additives in production systems at specific locations to monitor and troubleshoot factors affecting chemical deliverability and performance. However, residual measurements are extremely problematic due to many factors, including the surface active nature of the chemicals and high ionic strength of the brine. The error on residual measurements can often be over 100%. Residual measurement typically requires the collection of a water sample, which often needs to be transported to a centralized analytical laboratory. Analytical techniques used to measure residuals are based on several combinations of separation (e.g. chromatography, liquid-liquid extraction, etc.) and detection (e.g. various forms of spectroscopy). However, most of these methods lack portability and require tedious laboratory procedures located off-site. The current paper describes a nanotechnology-enabled Raman spectroscopy method developed and tested for monitoring chemical inhibitor residuals. Development of this technology with handheld instrumentation provides better detection and quantification of chemical additives in the field and reduces time and cost compared to sending samples to off-site laboratories for data collection.
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Cheney, J., and G. Kusinski. "Utilizing Computational Metallurgy to Design Amorphous and Nanocrystalline Coatings for Wear and Corrosion Resistance." In ITSC 2012, edited by R. S. Lima, A. Agarwal, M. M. Hyland, Y. C. Lau, C. J. Li, A. McDonald, and F. L. Toma. ASM International, 2012. http://dx.doi.org/10.31399/asm.cp.itsc2012p0556.

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Abstract Computational metallurgy is a technique being used and developed in the field of bulk alloys to design and develop novel amorphous and nanocrystalline materials. This technology can be transitioned to develop chemistries for both wear and corrosion resistant thermal spray coatings. Using computational metallurgy and small scale laboratory experiments, nanostructured and amorphous chemistries can be designed to specifically accommodate one of the many environmental conditions challenging the oil and gas industry. This study reviews the design procedures behind developing three unique chemistries intended to function in different environments: 1) an Fe-based chemistry designed for metal to metal sliding wear resistance, 2) an Fe-based chemistry containing elevated refractory content intended specifically for spray and fuse applications to resist sulfurous corrosion, and 3) a Ni-based chemistry similar to Alloy C276 for high temperature corrosion resistance. All three alloys were designed using computational techniques and eventually manufactured into cored wires for use within the twin wire arc spray (TWAS) process. The fine grained structure provides unique benefits to each application including 1) high hardness, 2) ability to rapidly form protective scale, 3) low melting temperature and creep resistance.
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Houchin, Lanne R., Dorian Granizo, and Joseph Conine. "New Single-Step Acidizing Technique Treats Severe Fines Damage Over a Wide Range of Temperatures and Mineralogies." In SPE International Conference and Exhibition on Formation Damage Control. SPE, 2022. http://dx.doi.org/10.2118/208806-ms.

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Abstract Most sandstone reservoirs in shallow water continental shelf fields are fully mature and require economical low-risk stimulation treatments to achieve maximum recovery. The once characterized "New Fronter" developments in Deepwater and Ultra Deepwater are also entering the mature, end of life status. 2019 had the largest increase in acid stimulation treatments ever in the Deepwater Gulf of Mexico. This study focused on identifying a HF acid derivative treatment that could be used as a single-step sandstone acid treatment, with all the associated benefits, but would not require acid flowback services. Five commercially available buffered, retarded, and HF derivative acid chemistries were tested to determine the risks of facility upsets. Laboratory tests showed that these HF derivative acid chemistries had varying levels of potential facility upset risk in either viscous emulsion formation or overboard water quality noncompliance. A new Fluoroboric Acid (HBF4) chemistry was developed building on 80 years of well-known performance history. This chemistry has all the benefits of HBF4, is compatible with most sensitive minerals and does not cause facility upsets. Ninety-three treatments were done in the eastern and central US GOM without the expense of flowback equipment. These treatments resulted in an 88% economic success rate and only 2 short term oil and grease noncompliance instances in the facilitie overboard water discharge.
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Lang, Fred D., and Tom Canning. "An Oxy-Hydrocarbon Model of Fossil Fuels." In ASME 2007 Power Conference. ASMEDC, 2007. http://dx.doi.org/10.1115/power2007-22007.

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This paper asserts a new method of analyzing fossil fuels, useful for sorting coals into well defined categories and for the identification of outlying ultimate analysis data. It describes a series of techniques starting with a new multi-variant approach for describing the lower Ranks of coal, progressing to a classical, but modified, single-variant approach for the volatile and high energy Ranks. In addition, for a few special cases, multiple low and high Ranks are also well described by the multi-variant approach. As useful as these techniques are for analyzing fuel chemistry in the laboratory arena, this work was initiated in support of Exergetic Systems’ Input/Loss Method. At commercial coal-fired power plants, Input/Loss allows the determination of fuel chemistry based on combustion effluents. The methods presented allow equations to be developed independent of combustion stoichiometrics, which improve Input/Loss accuracy in determining fuel chemistry on-line and in real time.
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Aguiar, Janaina I. S., Hamidreza Samouei, and Amir Mahmoudkhani. "Uncovering Mysteries of Waxphaltenes: Meticulous Experimental Studies of Field and Lab Deposits Unveil Nature of Wax-Asphaltene Intermolecular Interactions." In SPE International Conference on Oilfield Chemistry. SPE, 2021. http://dx.doi.org/10.2118/204315-ms.

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Abstract In recent years, the utilization of modern sampling tools provided access to the field deposits from several offshore and onshore wells producing asphaltenic crudes. Compositional analysis of field deposits revealed the presence of asphaltenes and wax as major fractions, while system conditions traditionally implied precipitation and deposition of asphaltenes only. Most of the previous studies on organic deposition have been conducted with the key assumption that aggregation and precipitation of wax and asphaltene occur independently. A few researchers investigated the solubility parameter's alteration, but they did not incorporate waxes found in the oilfield deposits. This study aims to investigate the nature of "waxphaltenes"; from intermolecular interactions between asphaltenes and wax in samples collected from fields and made in the laboratory. Asphaltenes samples were extracted and fully characterized by proton nuclear magnetic resonance (NMR) and Fourier-transform infrared spectroscopy (FTIR). Paraffin waxes were identified using gas chromatography (GC), differential scanning calorimetry (DSC), NMR, and FTIR. Precipitation tests of asphaltenes with n-heptane at high temperature were performed both in the presence and absence of wax; GC, NMR and FTIR techniques evaluated the precipitates and the material dispersed in solution. It was found that asphaltenes co-precipitated with waxes even at higher temperatures than the normal wax appearance temperature (WAT) of the crude oil or the model solutions and that long and medium size paraffin waxes had higher tendencies to coprecipitate with asphaltenes than either short chain or very long chain paraffin hydrocarbons. The results also indicated that the amount of wax that co-precipitates with asphaltenes was more related to asphaltene structure but is independent of the asphaltenes or wax content. Heteroatoms played an important role in the interactions between wax and asphaltenes during precipitation and separation.
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Tsuruta, Tadahiko, Masahiro Uchida, Katsuhiro Hama, Hiroya Matsui, Shinji Takeuchi, Kenji Amano, Ryuji Takeuchi, Hiromitsu Saegusa, Toshiyuki Matsuoka, and Takashi Mizuno. "Current Status of Phase II Investigations: Mizunami Underground Research Laboratory (MIU) Project." In ASME 2009 12th International Conference on Environmental Remediation and Radioactive Waste Management. ASMEDC, 2009. http://dx.doi.org/10.1115/icem2009-16262.

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The Mizunami Underground Research Laboratory (MIU) Project, a comprehensive research project investigating the deep underground environment in crystalline rock, is being conducted by the Japan Atomic Energy Agency at Mizunami City, Central Japan. The MIU Project is being carried out in three overlapping phases: Surface-based Investigation (Phase I), Construction (Phase II), and Operation (Phase III), with a total duration of 20 years. The overall project goals of the MIU Project from Phase I through to Phase III are: 1) to establish techniques for investigation, analysis and assessment of the deep geological environment, and 2) to develop a range of engineering techniques for deep underground application. Phase I was completed in March 2004, and Phase II investigations associated with the construction of the underground facilities are currently underway. Phase II investigation goals are to evaluate the geological, hydrogeological, hydrogeochemical and rock mechanical models developed in Phase I and to assess changes in the deep geological environment caused by the construction of underground facilities. Geological mapping, borehole investigations for geological, hydrogeological, hydrochemical and rock mechanical studies are being carried out in shafts and research galleries in order to evaluate the models. Long-term monitoring of changes in groundwater chemistry and pressure associated with the construction of the underground facilities continue in and around the MIU site, using existing boreholes and monitoring systems. This report summarizes the current status of the MIU Project on results of the Phase II investigations to date.
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Esmonde-White, Karen, I. Lewis, Mary Lewis, and Tory Woolf. "Raman spectroscopy as a tool for understanding oil or fat quality in food products." In 2022 AOCS Annual Meeting & Expo. American Oil Chemists' Society (AOCS), 2022. http://dx.doi.org/10.21748/jyvx7273.

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Many natural and produced foods contain oils or fats, and their presence affects the product shelf life and sensory attributes. Analysis of oils or fats in these foods can be carried out using wet chemistry, chromatographic, or spectroscopic techniques. Molecular spectroscopic techniques of near-infrared, infrared, or Raman have the benefit of providing a non-destructive chemical and molecular structure analysis with the ability to measure oil or fat quality directly in a process or in the laboratory. Raman spectroscopy is a molecular spectroscopy technique that is highly specific, can measure in aqueous systems, and provides a multi-attribute measurement in a single probe. We provide an overview of the information provided by a Raman spectrum, including the presence of cis or trans isomers, fatty acid saturation, and polymorphic stability. An application example of Raman spectroscopy in dark and milk chocolate will be presented to showcase Raman's capability to measure qualitative and quantitative quality aspects of fats in a complex and highly fluorescent matrix. Our initial feasibility studies showed initial markers of cocoa butter quality that support additional studies with more samples.
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Reports on the topic "Laboratory technique of chemistry"

1

Sopok, Samuel. Chemistry Laboratory Operations Manual. Fort Belvoir, VA: Defense Technical Information Center, August 1992. http://dx.doi.org/10.21236/ada420000.

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Peter, J. M., and M. G. Gadd. Introduction to the volcanic- and sediment-hosted base-metal ore systems synthesis volume, with a summary of findings. Natural Resources Canada/CMSS/Information Management, 2022. http://dx.doi.org/10.4095/328015.

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This volume presents results of research conducted during phase 5 of the Volcanic- and Sedimentary-hosted Base Metals Ore Systems project of the Geological Survey of Canada's Targeted Geoscience Initiative (TGI) program. The papers in this volume include syntheses and primary scientific reports. We present here a synopsis of the findings during this TGI project. Research activities have addressed several mineral deposit types hosted in sedimentary rocks: polymetallic hyper-enriched black shale, sedimentary exhalative Pb-Zn, carbonate-hosted Pb-Zn (Mississippi Valley-type; MVT), and fracture-controlled replacement Zn-Pb. Other carbonate-hosted deposits studied include a magnesite deposit at Mount Brussilof and a rare-earth element-F-Ba deposit at Rock Canyon Creek, both of which lack base metals but are spatially associated with the MVT deposits in the southern Rocky Mountains. Volcanogenic massive-sulfide deposits hosted in volcanic and mixed volcanic-sedimentary host rock settings were also examined. Through field geology, geochemical (lithogeochemistry, stable and radiogenic isotopes, fluid inclusions, and mineral chemistry), and geophysical (rock properties, magnetotelluric, and seismic) tools, the TGI research contributions have advanced genetic and exploration models for volcanic- and sedimentary-hosted base-metal deposits and developed new laboratory, geophysical, and field techniques to support exploration.
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Green, D. W., R. R. Heinrich, D. G. Graczyk, P. C. Lindahl, and A. S. Boparai. Analytical Chemistry Laboratory progress report for FY 1991. Office of Scientific and Technical Information (OSTI), December 1991. http://dx.doi.org/10.2172/10135386.

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Green, D. W., A. S. Boparai, and D. L. Bowers. Analytical Chemistry Laboratory. Progress report for FY 1996. Office of Scientific and Technical Information (OSTI), December 1996. http://dx.doi.org/10.2172/471429.

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Boparai, A. S., D. L. Bowers, D. G. Graczyk, D. W. Green, and P. C. Lindahl. Analytical Chemistry Laboratory progress report for FY 1998. Office of Scientific and Technical Information (OSTI), March 1999. http://dx.doi.org/10.2172/12021.

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Green, D. W., R. R. Heinrich, D. G. Graczyk, P. C. Lindahl, and M. D. Erickson. Analytical Chemistry Laboratory progress report for FY 1989. Office of Scientific and Technical Information (OSTI), December 1989. http://dx.doi.org/10.2172/5055765.

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Green, D. W., R. R. Heinrich, D. G. Graczyk, P. C. Lindahl, and A. S. Boparai. Analytical Chemistry Laboratory progress report for FY 1991. Office of Scientific and Technical Information (OSTI), December 1991. http://dx.doi.org/10.2172/5499461.

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8

Xu, Ning. Actinide Analytical Chemistry Capabilities -Los Alamos National Laboratory. Office of Scientific and Technical Information (OSTI), September 2016. http://dx.doi.org/10.2172/1329654.

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Green, D. W., R. R. Heinrich, D. G. Graczyk, P. C. Lindahl, A. S. Boparai, and D. A. Bass. Analytical Chemistry Laboratory progress report for FY 1992. Office of Scientific and Technical Information (OSTI), December 1992. http://dx.doi.org/10.2172/10166234.

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Green, D. W., R. R. Heinrich, and K. J. Jensen. Analytical Chemistry Laboratory progress report for FY 1985. Office of Scientific and Technical Information (OSTI), December 1985. http://dx.doi.org/10.2172/5955611.

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