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Journal articles on the topic 'Lanthanide(III) Bromide'

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Published: 5 June 2025
Last updated: 1 August 2025

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1

R., K. AGARWAL, and KUMAR PRAVESH. "Synthesis and Characterisation of Dibenzyl Sulphoxide Adducts with Lanthanide(III) Bromide and Nitrate." Journal of Indian Chemical Society Vol. 65, Jun 1988 (1988): 450–51. https://doi.org/10.5281/zenodo.6303527.

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Department of Chemistry, Lajpat Rai (Post-Graduate) College, Sahibabad-201 005 <em>Manuscript received </em><em>21 December 1987, </em><em>revised </em><em>24 </em><em>March </em><em>1988, </em><em>accepted 6 April </em><em>1988</em> Synthesis and Characterisation of Dibenzyl Sulphoxide Adducts with Lanthanide(III) Bromide and Nitrate.
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2

Dhepe, A. S., and A. B. Zade. "Spectrophotometric Study of Ternary Complex Forming Systems of Some Lanthanide Metal Ions with Eriochrome Cyanine R in Presence of Cetylpyridinium Bromide for Microdetermination." E-Journal of Chemistry 8, no. 3 (2011): 1264–74. http://dx.doi.org/10.1155/2011/871685.

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Study of coordination compounds of lanthanide elements has received a great attention due to growing applications in science and technology. Number of chromogenic reagents form water soluble colored complexes with lanthanides. Eriochrome cyanine R (ECR) a member of triphenylmethane type of dye has been reported to form green colored complexes with lanthanides and has been used for microdetermination of these metal ions. Addition of cationic surfactant, Cetylpyridinium bromide (CPB), a cationic surfactant sensitizes the color reactions of Gd(III), Tb(III), Dy(III), Ho(III) and Lu(III) with ECR.
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3

Zade, Anil B., Pawan P. Kalbende, Mayuri S. Umekar, and Gajanan W. Belsare. "Sensitization of Eriochromeazurol-B in Presence of Cetyldimethylethylammonium Bromide for the Microdetermination of Some Lanthanides." E-Journal of Chemistry 9, no. 4 (2012): 2394–406. http://dx.doi.org/10.1155/2012/587240.

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Cetyldimethylethylammonium bromide, a cationic surfactant has been used to decolorize eriochromeazurol B, an anionic triphenylmethane type of dye. Addition of specific lanthanide metal ion to this decolorized solution resulted into intense colored stable ternary complex with large bathochromic shift from 540 nm (binary complex) to 650 nm (ternary complex) with increase in absorbance values at shifted wavelength. CDMEAB thus decreases the color intensity of ECAB and increases the absorbance value of ternary complexes. This two fold advantage resulted into enhancement in molar absorptivities and
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4

Chiriac, Florentina L., Monica Iliş, Augustin Madalan, Doina Manaila-Maximean, Mihail Secu, and Viorel Cîrcu. "Thermal and Emission Properties of a Series of Lanthanides Complexes with N-Biphenyl-Alkylated-4-Pyridone Ligands: Crystal Structure of a Terbium Complex with N-Benzyl-4-Pyridone." Molecules 26, no. 7 (2021): 2017. http://dx.doi.org/10.3390/molecules26072017.

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This work focuses on the investigation of the liquid crystalline behavior and luminescence properties of the lanthanide complexes of Eu(III), Sm(III) and Tb(III) with N-biphenyl-alkylated-4-pyridone ligands. The organic ligands having a biphenyl group attached via a long flexible spacer with either 9 or 10 carbon atoms were synthesized by the reaction between 4-hydroxypyridine and the corresponding bromide compounds. The chemical structures of the organic and lanthanide complexes were assigned based on elemental analysis, single-crystal X-ray diffraction, 1H, 13C NMR and IR spectroscopies, and
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5

Deacon, Glen B., Tiecheng Feng, Peter C. Junk, et al. "Structural Variety in Solvated Lanthanoid(III ) Halide Complexes." Australian Journal of Chemistry 53, no. 10 (2000): 853. http://dx.doi.org/10.1071/ch00117.

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Treatment of lanthanum metal with CH2Br2 or CH2I2 in tetrahydrofuran (thf) under ultrasound conditions yields the corresponding [LaX3(thf)4] (X = Br, I) complexes in good yield. Recrystallization of [LaBr3(thf)4] from 1,2-dimethoxyethane (dme) or bis(2-methoxyethyl) ether (diglyme) generates [LaBr2(µ-Br)(dme)2]2 and [LaBr2(dig-lyme)2][LaBr4(diglyme)]. Treatment of lanthanoid metals with hexachloroethane in dme yields [LnCl3(dme)2] (Ln = La, Nd, Er or Yb) and in acetonitrile [YbCl2(MeCN)5]2[YbCl3(MeCN)(-Cl)2YbCl3(MeCN)]. The reaction of Yb metal pieces with 1,2-dibromoethane in thf and dme gave
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6

Cotton, Simon A., Jack M. Harrowfield, Lioubov I. Semenova, Brian W. Skelton, Alexandre N. Sobolev, and Allan H. White. "Allan White and Polypyridines: Extending the Lanthanide(III) Complex Series." Australian Journal of Chemistry 73, no. 6 (2020): 434. http://dx.doi.org/10.1071/ch19129.

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X-Ray structure determinations on 41 complexes of lanthanide(iii) halides, principally bromides, with 2,2′-bipyridine, 1,10-phenanthroline, and 2,2′:6′,2″-terpyridine provide a considerable extension to the earlier work of Allan White on such materials and a substantial extension of general work on polypyridine complexes of lanthanide halides. Complexes of 1:1, 1:2, and 2:4 metal-to-ligand composition have been characterised across a broad selection of the lanthanide elements, many of these species showing a higher overall ratio of ligand to lanthanide due to the incorporation of uncoordinated
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7

Schustereit, Tanja, Harald Henning, Thomas Schleid, and Ingo Hartenbach. "Syntheses and Crystal Structures of the Bromide-derivatized Lanthanoid(III) Ortho-Oxomolybdates(VI) LnBr[MoO4] (Ln = Pr, Nd, Sm, Gd– Lu)." Zeitschrift für Naturforschung B 68, no. 5-6 (2013): 616–24. http://dx.doi.org/10.5560/znb.2013-3083.

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The lanthanoid(III) bromide ortho-oxomolybdates(VI) LnBr[MoO4] (Ln = Pr, Nd, Sm, Gd - Lu) crystallize triclinically in the space group P1 (a=686 - 689, b=713 - 741, c=1066 - 1121 pm, a =103 - 106, b =107 - 108, g = 92 - 95°) with Z =4. The crystal structure contains two crystallographically distinguishable Ln3+ cations, each one with a coordination number of seven plus one. (Ln1)3+ is surrounded by three bromide and four plus one oxide anions, while for (Ln2)3+ just one bromide and six plus one oxide anions belong to the coordination sphere. Considering the smallest lanthanoids, however, the d
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8

Goerigk, Felix C., Veronica Paterlini, Katharina V. Dorn, Anja-Verena Mudring, and Thomas Schleid. "Synthesis and Crystal Structure of the Short LnSb2O4Br Series (Ln = Eu–Tb) and Luminescence Properties of Eu3+-Doped Samples." Crystals 10, no. 12 (2020): 1089. http://dx.doi.org/10.3390/cryst10121089.

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Pale yellow crystals of LnSb2O4Br (Ln = Eu–Tb) were synthesized via high temperature solid-state reactions from antimony sesquioxide, the respective lanthanoid sesquioxides and tribromides. Single-crystal X-ray diffraction studies revealed a layered structure in the monoclinic space group P21/c. In contrast to hitherto reported quaternary lanthanoid(III) halide oxoantimonates(III), in LnSb2O4Br the lanthanoid(III) cations are exclusively coordinated by oxygen atoms in the form of square hemiprisms. These [LnO8]13− polyhedra form layers parallel to (100) by sharing common edges. All antimony(II
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9

MEYER, G. "ChemInform Abstract: Complex Lanthanoid(III) Chlorides, Bromides and Iodides." ChemInform 23, no. 6 (2010): no. http://dx.doi.org/10.1002/chin.199206300.

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10

A., B. Zade, and S. Dhepe A. "Spectrophotometric microdetermination of gadolinium(III) and terbium(III) with xylenol orange in presence of cationic cetylpyridinium bromide as a surfactant." Journal of Indian Chemical Society Vol. 90, Sep 2013 (2013): 1367–78. https://doi.org/10.5281/zenodo.5789068.

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Department of Chemistry, Laxminarayan Institute of Technology, R. T. M. Nagpur University, Nagpur-440 010, Maharashtra, India <em>E-mail</em>: ab_zade18@yahoo.com Fax: 91-712-2561107 Department of Applied Chemistry, Smt. Radhikatai Pandav College of Engineering, Nagpur-411 204, Maharashtra, India <em>E-mail:</em> as_dhepe@yahoo.com <em>Manuscript received online 04 December 2012, revised 28 December 2012, accepted 30 December 2012</em> Xylenol orange (XO) has been reported earlier to form violet colored binary complexes with several lanthanides and used for the determination of several metal i
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11

Schustereit, Tanja, Harald Henning, Thomas Schleid, and Ingo Hartenbach. "ChemInform Abstract: Syntheses and Crystal Structures of the Bromide-Derivatized Lanthanoid(III) ortho-Oxomolybdates(VI) LnBr[MoO4] (Ln: Pr, Nd, Sm, Gd-Lu)." ChemInform 44, no. 37 (2013): no. http://dx.doi.org/10.1002/chin.201337004.

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12

Semenova, Lioubov I., and Allan H. White. "Structural Systematics of Rare Earth Complexes. XVII Hydrated 1 : 1 Adducts of 2,2′:6′,2″-Terpyridine with the Lanthanoid(III) Bromides and Some Binuclear Hydroxy-Bridged Dimers." Australian Journal of Chemistry 52, no. 6 (1999): 539. http://dx.doi.org/10.1071/ch98048.

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Room-temperature single-crystal X-ray structural characterizations are recorded for hydrated lan- thanoid(III) bromide/2,2′:6′,2″-terpyridine (tpy) (1 : 1) complexes, showing all to be ionic and of the form [(tpy)Ln(OH2)x]Br3.yH2O, where x and y are 6 and 1 for the isomorphous series Ln = La(-)Er (and intermediate members, by presumption), and 5 and various values for Ln = Tm, Yb, Lu. Crystals of [(tpy)Ln(OH2)6]Br3.H2O are monoclinic, P 21/c, a ≈ 8·5, b ≈ 18, c ≈ 16·3 Å, β ≈ 108°, Z = 4; for Ln = La, Er, conventional R values on |F| were 0·048, 0·080 for No 4027, 1347 ‘observed’ (I &gt; 3σ(I))
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13

Liu, Lanjun, Mengyao Zhang, Qingzhong Guo, Zhanhui Zhang, and Junfang Guo. "A terbium(III) lanthanide-organic framework as selective and sensitive iodide/bromide sensor in aqueous medium." Dalton Transactions, 2021. http://dx.doi.org/10.1039/d0dt03879b.

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A potent luminescent sensor for the detection of iodide ion was developed based on a terbium(III)-based lanthanide–organic framework [Tb(cpia)(H2O)2]n‧nH2O (1), which was prepared under hydrothermal condition using 5-(4-carboxyphenoxy)-isophthalic acid (H3cpia)...
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14

Groth, Ulrich, Christian Kesenheimer, and Juergen Neidhoefer. "Lanthanoids in Organic Synthesis. Part 6. Diastereoselective Addition of Organocerium(III) Reagents Derived from 3-Substituted Propargyl Bromides to Aldehydes." ChemInform 37, no. 49 (2006). http://dx.doi.org/10.1002/chin.200649174.

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15

Locke, Ralf J. C., Maria Weis, and Thomas Schleid. "LnSb2O4Br (Ln=Nd and Er) and Sb4O5Br2: Lanthanoid‐Bearing and ‐Free Antimony(III) Oxide Bromides." Zeitschrift für anorganische und allgemeine Chemie, June 3, 2024. http://dx.doi.org/10.1002/zaac.202300243.

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AbstractSb4O5Br2 crystallizes plate‐shaped in the monoclinic space group P21/c with the lattice parameters a=660.82(5) pm, b=513.71(4) pm, c=1346.35(9) pm and β=97.876(3)° for Z=2. Its crystal structure contains {[Sb4O5]2+} layers with connected [(Sb1)O3+1]5− ψ1‐units and undisturbed pyramidal [(Sb2)O3]3− ψ1‐units, where the free electron pair is counted as a pseudo‐ligand (ψ). The bromide anions required for charge compensation of these cationic {[Sb4O5]2+} layers form single sheets and are only bonded via van‐der‐Waals interactions in this crystal structure, as the nearest distance to antimo
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