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Journal articles on the topic 'Lanthanide(lll) Iodide Complexes'

Author: Grafiati

Published: 5 June 2025

Last updated: 15 July 2025

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1

R., K. AGARWAL, and K. GUPTA S. "Lanthanide(lll) Iodide Complexes of 5,6-Benzoquinoline and 2-Ethoxycarbonylaminopyridine." Journal of Indian Chemical Society Vol. 63, Nov 1986 (1986): 995–98. https://doi.org/10.5281/zenodo.6297724.

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Department of Chemistry, Lajpat Rai Post-Graduate College, Sahibabad-201 005 <em>Manuscript received 5 November 1985, revised 21 July 1986, accepted 5 September 1986</em> Lanthanide(lll) Iodide Complexes of 5,6-Benzoquinoline and 2-Ethoxycarbonylaminopyridine.

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2

Sulekh, Chandra, Raizada Smriti, and Rani Soni. "Lanthanide complexes of tetradentate macrocyclic ligand Synthesis and spectroscopic investigation." Journal of Indian Chemical Society Vol. 85, Aug 2008 (2008): 783–91. https://doi.org/10.5281/zenodo.5819416.

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Department of Chemistry, Zakir Husain College (University of Delhi), JLN Marg, New Delhi-11 0 002, India Department of Chemistry, M. M. H. College, Ghaziabad-20 1 001, Uttar Pradesh, India <em>E-mail :</em> schandra _ OO@yahoo. com; soni _ teotia81 @yahoo. co. in       Fax : 91-11-23215906 <em>Manuscript received 15 October 2007, revised 13 May 2008, accepted 16 May 2008</em> In the present paper, the lanthanide complexes derived from (1,5,8,12-tetraaza-2,4,9,11-tetramethyl cyclotetraaza-1,4,8,11-tetraene) were synthesized. The general composition of the complexes is [Ln(L)

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3

RENU, AHUJA, and DWIVEDI K. "Potentiometric Studies on Lanthanide(III) Mixed-ligand Complexes in Aqueous Solution." Journal of Indian Chemical Society Vol. 68, Dec 1991 (1991): 643–45. https://doi.org/10.5281/zenodo.5968374.

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School of Studies in Chemistry,Jiwaji University, Gwalior-474 011 <em>Manuscript received 22 April 1991, accepted 6 December 1991</em> Several mixed ligand complexing systems of the type 1 : 1 : 1<strong> </strong>MAB (where M =La<sup>III</sup>, Pr<sup>Ill</sup>, Nd<sup>lll</sup> and Sm<sup>llI</sup>; A=disodium salt of ethyleneglycol bis(2-amino- ethylether)tetraacetic acid (EGTA) , B= alanine or phenylalanine) have been studied potentiometrically Thermodynamic equilibrium constants have been evaluated along with the parameters Δ<em>G</em>º, Δ<em>H</em>º and Δ<em>S

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4

Gould, Colin A., K. Randall McClain, Daniel Reta, et al. "Ultrahard magnetism from mixed-valence dilanthanide complexes with metal-metal bonding." Science 375, no. 6577 (2022): 198–202. http://dx.doi.org/10.1126/science.abl5470.

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Magnetic effects of lanthanide bonding Lanthanide coordination compounds have attracted attention for their persistent magnetic properties near liquid nitrogen temperature, well above alternative molecular magnets. Gould et al . report that introducing metal-metal bonding can enhance coercivity. Reduction of iodide-bridged terbium or dysprosium dimers resulted in a single electron bond between the metals, which enforced alignment of the other valence electrons. The resultant coercive fields exceeded 14 tesla below 50 and 60 kelvin for the terbium and dysprosium compounds, respectively. —JSY

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5

Giesbrecht, Garth R., John C. Gordon, David L. Clark, and Brian L. Scott. "Auto-ionization in Lutetium Iodide Complexes: Effect of the Ionic Radius on Lanthanide−Iodide Binding." Inorganic Chemistry 43, no. 3 (2004): 1065–70. http://dx.doi.org/10.1021/ic035090y.

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6

R., K. AGARWAL, and GUPTA S.K. "Synthesis and Characterisation of Lanthanide Iodide and Thiocyanate Complexes with 5,6-Benzoquinoline-N-oxide." Journal of Indian Chemical Society Vol. 64, Apr 1987 (1987): 247–49. https://doi.org/10.5281/zenodo.7066284.

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Department of Chemistry, Lajpat Ral (Post-Graduate) College, Sahibabad-201 005 <em>Manuscript received 19 August 1985, revised 17 December 1986, accepted 22 April 1987</em> Synthesis and Characterisation of Lanthanide Iodide and Thiocyanate Complexes with 5,6-Benzoquinoline-<em>N</em>-oxide.

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7

Kornilov, A. D., M. S. Grigoriev, and E. V. Savinkina. "Comparison of the rare earth complexes iodides and polyiodides with biuret." Fine Chemical Technologies 17, no. 2 (2022): 172–81. http://dx.doi.org/10.32362/2410-6593-2022-17-2-172-181.

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Objectives. Currently, several hundred polyiodide compounds have been synthesized and structurally characterized, but so far, no formation patterns for certain polyiodide ions have been revealed. The purpose of this work is to continue the search for formation regularities of polyiodides, including polyiodides of lanthanide complexes.Methods. Iodide and polyiodide of samarium complexes with biuret (BU), [Sm(BU)4]I3·BU·2H2O and [Sm(BU)4][I5][I]2, were first synthesized and characterized by X-ray diffraction analysis and infrared spectroscopy, respectively.Results. The obtained compounds complem

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8

Joseph, Siby, and P. K. Radhakrishnan. "Yttrium and lanthanide iodide complexes of N,N′-bis(4-antipyrylmethylidene)ethylenediamine." Polyhedron 18, no. 13 (1999): 1881–84. http://dx.doi.org/10.1016/s0277-5387(98)00432-x.

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9

Hanna, George M., and Cesar A. Lau-Cam. "1H NMR Spectroscopic Method with Chiral Eu(III) Shift Reagent for the Determination of the Enantiomeric Composition of Naproxen." Journal of AOAC INTERNATIONAL 75, no. 3 (1992): 417–22. http://dx.doi.org/10.1093/jaoac/75.3.417.

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Abstract A simple method based on the use of 1H NMR spectroscopy with chiral Eu(lll) shift reagent is described for the determination of (S)-(+)- and (R)-(-)-naproxen In the presence of each other. To enhance the coordinating affinity of the substrate for the lanthanide Ion, the sample was first derivatized to a mixture of methyl esters, which in the presence of Eu(hfc)3 formed short-lived diastereomeric complexes with sufficient nonequivalency In the 1H NMR spectrum. Optimum complexing conditions corresponded to concentrations of substrate and Eu(hfc)3 of 0.1 M each in CDCI3. In this matter,

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10

R., S. Talegaonkar, and S. Burghate A. "pH-metric studies on formation constants of the complexes of substituted thiazolyl Schiff's bases with some lanthanide metal ions." Journal of Indian Chemical Society Vol. 89, Nov 2012 (2012): 1585–89. https://doi.org/10.5281/zenodo.5771932.

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Post Graduate Department of Chemistry, Shri Shivaji Science College, Amravati-444 603, Maharashtra, India <em>E-mail</em> : rupaliyeotikar@gmail.com Manuscript received 22 September 2011, revised 08 February 2012, accepted 09 February 2012 The stability constants of the complexes of La<sup>llI</sup>, Pr<sup>lll</sup> and Sm<sup>III</sup> with 2-[3-(4-methoxy-phenyl)-1-(4-phenyl-thiazol-2-yllmino )-allyl]-4-methyl phenol, 2-[3-pheny 1-1-( 4-pheny 1-thiazol-2-ylim ino )-allyl]-4-methy 1-phenol and 2-[3-( 4- chlorophenyl)-1-(4-phenyl-thiazol-2-ylimino)-allyl]-4-methyl-phenol have been determined

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11

Rukk, Nataliya S., Dmitry V. Albov, Ravshan S. Shamsiev, et al. "Synthesis, X-ray crystal structure and cytotoxicity studies of lanthanide(III) iodide complexes with antipyrine." Polyhedron 44, no. 1 (2012): 124–32. http://dx.doi.org/10.1016/j.poly.2012.06.075.

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12

Raj, Kumar Dubey, Kumar Mishra Sharad, Mariya Ayesha, and Kumar Mishra Anil. "Preparation, properties, spectral (IR, electronic, FAB-MS and PXRD) and magnetic characterization of some lanthanide complexes containing tridentate thiosemicarbazone ligand." Journal of Indian Chemical Society Vol. 90, Jan 2013 (2013): 41–48. https://doi.org/10.5281/zenodo.5764019.

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Synthetic Inorganic & Metallo-Organic Research Laboratory, Department of Chemistry, University of Allahabad, Allahabad-211 002, Uttar Pradesh, India <em>E-mail</em> : rajalkoxy@yahoo.com <em>Manuscript received online 24 January 2012, revised 22 February 2012, accepted 11 April 2012</em> Schiff bases, containing 'S' donor atom, such as benzophenonethiosemicarbazone (btscH), salicylidenethiosemicarbazone (stscH) and bis-salicylidenethiosemicarbazone (bstscH) have been reacted with methanolic solution of LnCJ<sub>3</sub>.7H<sub>2</sub>O (Ln = La<sup>III </sup>and Ce<sup>III</sup

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13

Emandi, Anca, Mariana Balasoiu, and Tudor Rosu. "New Complexes of Pr(III), Sm(III), Gd(lll), Gd(III), La(III) 1-(2-Benzthyazolyl)-3-methyl-4-azo-(4-nitrophenyl)-Pyrazolyn-5-one." SOUTHERN BRAZILIAN JOURNAL OF CHEMISTRY 6, no. 6 (1998): 53–62. http://dx.doi.org/10.48141/sbjchem.v6.n6.1998.55_1998.pdf.

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1-(2-Benzthyazolyl)-3-methyl-4-azo-(4-nitrophenyl)-Pyrazolyn-5-one (HL) possesses a chelating behavior. Its chelates with a number of trivalent lanthanide ions Pr(III), Sm(III),Gd(III), Ho(III), La(III) of the type Na3[Ln(L)2(OH)4] have been isolated and characterized on the basis of their elemental analyses, IR and visible spectra, magnetic and molar conductance studies, thermal and X-ray analysis and molecular weight determinations. All chelates have a monomeric octa-coordinated stn1cture and square antiprismatic (C2) symmetry.

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14

Windorff, Cory J., Megan T. Dumas, Joseph W. Ziller, Andrew J. Gaunt, Stosh A. Kozimor, and William J. Evans. "Small-Scale Metal-Based Syntheses of Lanthanide Iodide, Amide, and Cyclopentadienyl Complexes as Analogues for Transuranic Reactions." Inorganic Chemistry 56, no. 19 (2017): 11981–89. http://dx.doi.org/10.1021/acs.inorgchem.7b01968.

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15

Gubina, Katerina E., Vladimir A. Ovchynnikov, Vladimir M. Amirkhanov, Helmut Fischer, Rüdiger Stumpf, and Viktor V. Skopenko. "Lanthanide Complexes with Carbacylamidophosphates: The First Registration of Chelate Coordination of the Neutral Ligand Form in the Structure of Di-(N,Nf-tetramethyl-NM -benzoylphosphoryl- triamide)cerium(III) Nitrate." Zeitschrift für Naturforschung B 55, no. 7 (2000): 576–82. http://dx.doi.org/10.1515/znb-2000-0704.

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Abstract The coordination compounds of the general formula Ln(HL)2(NO3)3, (where Ln = La - Eu (without Pm), HL = C6H5C(O)NHP(O)[N(CH3)2]2, N,Nʹ-tetramethyl-Nʺ-benzovlphosphoryl-triamide) have been synthesized and characterized by means of IR, UV-VIS, 1H, 31P NMR spectroscopy, and X-ray analysis. The complexes are isostructural according to X-ray powder diffraction studies. The crystal structure of the cerium(lll) complex has been determined. Crystal data: monoclinic, P21/c, with a = 10.503(9), b = 15.62(2), c = 21.91(2) Å, β = 99.56(8)°, Z = 4, V = 3546(6) Å3, R1= 0.0550, wR2 = 0.1383 for 6970

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16

Xie, Zuowei, Zhixian Liu, Feng Xue, Zeying Zhang та Thomas C. W. Mak. "Synthesis and X-ray crystal structure of bis[η5-1,3-bis(trimethylsilyl)cyclopentadienyl] lanthanide and yttrium iodide complexes". Journal of Organometallic Chemistry 542, № 2 (1997): 285–89. http://dx.doi.org/10.1016/s0022-328x(97)00148-4.

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17

Karmazin, Lydia, Marinella Mazzanti, Jean-Philippe Bezombes, Christelle Gateau, and Jacques Pécaut. "Comparative Structural Studies of Iodide Complexes of Uranium(III) and Lanthanide(III) with Hexadentate Tetrapodal Neutral N-Donor Ligands." Inorganic Chemistry 43, no. 16 (2004): 5147–58. http://dx.doi.org/10.1021/ic049538m.

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18

Grechin, Oleg V., and Pavel R. Smirnov. "ON ORIGIN OF SMALL-ANGLE MAXIMA ON X-RAY SCATTERING INTENSITY CURVES OF AQUEOUS ELECTROLYTE SOLUTIONS." IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENIY KHIMIYA KHIMICHESKAYA TEKHNOLOGIYA 59, no. 6 (2018): 72. http://dx.doi.org/10.6060/tcct.20165906.5374k.

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At the X-ray diffraction analysis of high concentrated aqueous electrolyte solutions with multiply charged cations small angle maxima or pre-peaks are arising on scattering intensity curves (IC) (at about 1 Å). Their existence is connected with structural appearance so called “intermediate-range order”. Previously for explanation of this phenomenon some not completely correct hypotheses were suggested. On the example of raw X-ray diffraction data of some aqueous electrolyte solutions in wide concentration range collected by using MoKα-radiation the dynamic of small angle maxima shape change ha

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19

Evans, William J., Gerd W. Rabe, and Joseph W. Ziller. "Utility of N-Methylimidazole in Isolating Crystalline Lanthanide Iodide and Hydroxide Complexes: Crystallographic Characterization of Octasolvated [Sm(N-MeIm)8]I3 and Polymetallic [SmI(.mu.-I)(N-MeIm)3]2, [(N-MeIm)5Sm(.mu.-OH)]2I4, and {[(N-MeIm)4Sm(.mu.-OH)]3(.mu.3-OH)2}I4." Inorganic Chemistry 33, no. 14 (1994): 3072–78. http://dx.doi.org/10.1021/ic00092a010.

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