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Journal articles on the topic 'Lanthanide series'

Author: Grafiati

Published: 4 June 2021

Last updated: 8 February 2022

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1

Evans, William J., and David S. Lee. "Early developments in lanthanide-based dinitrogen reduction chemistry." Canadian Journal of Chemistry 83, no. 4 (April 1, 2005): 375–84. http://dx.doi.org/10.1139/v05-014.

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Although the first crystallographically characterized lanthanide dinitrogen complex was reported in 1988 with samarium, it is only in recent years that this field has expanded to include fully characterized examples for the entire series of lanthanides. The development of lanthanide dinitrogen chemistry has been aided by a series of unexpected results that present some good lessons in the development of science. This review presents a chronological account of the lanthanide dinitrogen chemistry discovered in our laboratory through the summer of 2004.Key words: lanthanides, dinitrogen, reduction, alkali metal, nitrogen fixation, diazenido.

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2

Xiao, Hong-Ping, Jian Zhou, Rong-Qing Zhao, Wei-bing Zhang, and Yong Huang. "A series of lanthanoid selenidoantimonates(v): rare examples of lanthanoid selenidoantimonates based on dinuclear lanthanide complexes." Dalton Transactions 44, no. 13 (2015): 6032–39. http://dx.doi.org/10.1039/c5dt00146c.

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3

Zhou, Jian, Rong-Qing Zhao, Tao Yang, Xing Liu, Hong-Ping Xiao, Hua-Hong Zou, and Xiao-Feng Tan. "A series of new lanthanoid thioarsenates: insights into the influence of lanthanide contraction on the formation of new lanthanoid thioarsenates." Dalton Transactions 44, no. 16 (2015): 7203–12. http://dx.doi.org/10.1039/c4dt03912b.

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A series of new lanthanoid thioarsenates were prepared and they would be helpful for gaining insights into the influence of lanthanide contraction on the formation of other new lanthanoid thioarsenates.

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4

Pallares, Roger M., David Faulkner, Dahlia D. An, Solène Hébert, Alex Loguinov, Michael Proctor, Jonathan A. Villalobos, et al. "Genome-wide toxicogenomic study of the lanthanides sheds light on the selective toxicity mechanisms associated with critical materials." Proceedings of the National Academy of Sciences 118, no. 18 (April 26, 2021): e2025952118. http://dx.doi.org/10.1073/pnas.2025952118.

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Lanthanides are a series of critical elements widely used in multiple industries, such as optoelectronics and healthcare. Although initially considered to be of low toxicity, concerns have emerged during the last few decades over their impact on human health. The toxicological profile of these metals, however, has been incompletely characterized, with most studies to date solely focusing on one or two elements within the group. In the current study, we assessed potential toxicity mechanisms in the lanthanide series using a functional toxicogenomics approach in baker’s yeast, which shares many cellular pathways and functions with humans. We screened the homozygous deletion pool of 4,291 Saccharomyces cerevisiae strains with the lanthanides and identified both common and unique functional effects of these metals. Three very different trends were observed within the lanthanide series, where deletions of certain proteins on membranes and organelles had no effect on the cellular response to early lanthanides while inducing yeast sensitivity and resistance to middle and late lanthanides, respectively. Vesicle-mediated transport (primarily endocytosis) was highlighted by both gene ontology and pathway enrichment analyses as one of the main functions disturbed by the majority of the metals. Protein–protein network analysis indicated that yeast response to lanthanides relied on proteins that participate in regulatory paths used for calcium (and other biologically relevant cations), and lanthanide toxicity included disruption of biosynthetic pathways by enzyme inhibition. Last, multiple genes and proteins identified in the network analysis have human orthologs, suggesting that those may also be targeted by lanthanides in humans.

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5

Раджабов, Е. А., and В. А. Козловский. "Перенос электрона между разнородными лантаноидами в кристаллах BaF-=SUB=-2-=/SUB=- --- II механизмы переноса." Физика твердого тела 61, no. 5 (2019): 888. http://dx.doi.org/10.21883/ftt.2019.05.47587.19f.

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The processes of electron transfer from a divalent lanthanide acceptor (Eu, Sm, Yb) to a trivalent lanthanide donor (Nd, Sm, Dy, Tm, Yb) and reverse thermal transfer are studied in barium fluoride crystals. Electron phototransfer at room temperatures is accompanied by a counter-movement of the charge-compensating interstitial fluorine. In the process of photobleaching at low temperatures, the divalent lanthanide donor turns out to be near the interstitial fluorine, which causes its 4f-5d absorption bands to shift to the red. The magnitude of the shift increases with decreasing size of the lanthanide in the series (Nd, Sm, Dy, Tm, Yb). Detailed mechanisms of photo and thermal electron transfer between heterogeneous lanthanides in BaF2 crystals are analyzed.

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6

Hlava, P. F. "Problems in electron microprobe analysis of the lanthanides: The x-ray lines." Proceedings, annual meeting, Electron Microscopy Society of America 48, no. 2 (August 12, 1990): 200–201. http://dx.doi.org/10.1017/s0424820100134594.

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Electron microprobe analysis of materials that contain the lanthanide series of rare earth elements (REE) in natural abundance ratios presents a difficult and truly unique set of problems due to the their chemical and crystallographic similarity and the complexity of the L-spectra used for analysis. REEs differ from one another by the number of protons in their nuclei and the number of electrons in their second inner shell. There are two series of REEs - the lanthanides, from atomic number 58 through 71 and the actinides from 90 through 103. By convention, when most workers speak of the REEs they refer to the lanthanides plus lanthanum, often yttrium and rarely scandium (because these elements are geochemically associated with the lanthanides proper). The terms REE and lanthanide, when used in this paper, will refer to elements of atomic number 57 through 71. In all of these elements the two outer shells, where the valence electrons reside, are essentially identical resulting in chemical behavior that is also essentially identical.

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7

Dunaev, Anatoliy M., Vladimir B. Motalov, and Lev S. Kudin. "ELECTRON WORK FUNCTION OF LANTHANIDE TRIIODIDES." IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA KHIMICHESKAYA TEKHNOLOGIYA 63, no. 11 (October 27, 2020): 13–20. http://dx.doi.org/10.6060/ivkkt.20206311.6292.

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Desorption enthalpies of LnI4– and Ln2I7– associative ions (Ln = La, Ce, Pr, Nd, Gd, Tb, Dy, Ho, Er, Tm, and Lu) and the enthalpy of sublimation of LnI3 molecules were determined by Knudsen effusion mass spectrometric technique. These data were used to calculate the effective values of electron work function φe of polycrystalline samples of lanthanide triiodides LnI3 for the first time. The calculation methodology is based on the study of thermochemical cycles, which include atoms, molecules, ions, and electrons being in thermodynamic equilibrium with the LnI3 crystal inside the effusion cell. The values obtained for different lanthanides turned out to be close. They lie in the range of about 2.4 – 4.4 eV with an average value in the series: φe = 3.2 ± 0.3 eV. The latter value is close to those for previously studied lanthanide tribromides. No secondary periodicity of φe was found within the calculated errors along the lanthanide series. The results obtained are in quantitative agreement with the theoretical calculation of the values of the band gap of lanthanide triiodides. Comparison of φe with other classes of lanthanide compounds such as oxides, hexaborides, and lanthanide metals shows relatively high electron emission ability yielding only to alkali and alkali-earth metals.

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8

Shahbazi, Shayan, C. J. Oldham, Austin D. Mullen, John D. Auxier II, and Howard L. Hall. "Synthesis, thermogravimetric analysis and enthalpy determination of lanthanide β-diketonates." Radiochimica Acta 107, no. 12 (November 26, 2019): 1173–84. http://dx.doi.org/10.1515/ract-2018-3085.

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Abstract This work reports thermodynamic characterizations of lanthanide β-diketonates for use in nuclear fission product separation. Adsorption and sublimation enthalpies have been shown to be linearly correlated, therefore there is motivation to determine sublimation thermodynamics. An isothermal thermogravimetric analysis method is employed on fourteen lanthanide chelates for the ligands 2,2,6,6-tetramethyl-3,5-heptanedione and 6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedione to determine sublimation enthalpies. No linear trend is seen across the series; values show a cyclical nature, possibly indicating a greater influence of chemisorption for some complexes and less of a role of physisorption in dictating adsorption differences between lanthanides in the same series. This is in line with previous reports in terms of the chromatographic separation order of the lanthanides. The results reported here can be used to manipulate separations parameters and column characteristics to better separate these lanthanide chelates. Fourteen chelates of the ligand 1,1,1-trifluoro-2,4-pentanedione are also thermally characterized but found to not sublime and be undesirable for this method. Additionally, all chelates are characterized by constant heating thermogravimetric analysis coupled with mass spectrometry, melting point analysis, elemental analysis and FTIR.

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9

Liu, Juewen. "Lanthanide-dependent RNA-cleaving DNAzymes as metal biosensors." Canadian Journal of Chemistry 93, no. 3 (March 2015): 273–78. http://dx.doi.org/10.1139/cjc-2014-0465.

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Lanthanides represent a group of very important but challenging analytes for biosensor development. These 15 elements are very similar in their chemical properties. So far, limited success has been realized using the rational ligand design approach. My laboratory has successfully accomplished the task of carrying out combinatorial selection to isolate lanthanide-dependent RNA-cleaving DNAzymes. We report two new DNAzymes, each discovered in a different selection condition and both are highly specific to lanthanides. When both DNAzymes are used together, it is possible to identify the last few heavy lanthanides. Upon introducing a phosphorothioate modification, one of the abovementioned DNAzymes becomes highly active with many toxic heavy metals. With the selection of more DNAzymes with different activity patterns cross the lanthanide series, a sensor array might be produced for identifying each ion. This article is a minireview of the current developments on this topic and some of the historical aspects. It reflects the main content of the Fred Beamish Award presentation delivered at the 2014 Canadian Society for Chemistry Conference in Vancouver. Future directions in this area are also discussed.

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10

Gallardo, Piedraescrita, Elisa Abas, Alicia Buceta, Francisco Merchán, Asunción Luquin, Saif A. Haque, and Mariano Laguna. "A Series of [Ln(NO₃)₃(4’-(4-Bromophenyl)-2,2’:6’,2’’-Terpyridine)] Lanthanide Derivatives." Solid State Phenomena 257 (October 2016): 160–64. http://dx.doi.org/10.4028/www.scientific.net/ssp.257.160.

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Lanthanide complexes [Ln (NO3)3(4’-(4-bromophenyl)-2,2’:6’,2’’-terpyridine)]; being Ln all the non radiative lanthanide elements (1 – 14), have been synthesized and characterized by IR, 1H NMR, MALDI-MS and the X-ray structures of the La, Nd, Sm, Eu and Dy complexes, showing a linear comparison of the average M-O and M-N distances with the ionic radius or the number of f electrons of the lanthanides. The luminescence properties of complexes 4 (Nd), 5 (Sm), 6 (Eu), 8 (Tb), 9 (Dy) in the solid state and in the acetonitrile solutions of 5 (Sm) and 6 (Eu) are reported.

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11

de Melo, Fernando, Sabrina Almeida, and Henrique Toma. "Magnetic Nanohydrometallurgy Applied to Lanthanide Separation." Minerals 10, no. 6 (June 11, 2020): 530. http://dx.doi.org/10.3390/min10060530.

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Lanthanides play an important role in modern technology because of their outstanding optical, electronic, and magnetic properties. Their current hydrometallurgical processing involves lixiviation, leading to concentrates of elements whose separation requires exhaustive procedures because of their similar chemical properties. In this sense, a new nanotechnological approach is here discussed, involving the use of iron oxide nanoparticles functionalized with complexing agents, such as diethylenetriaminepentaacetic acid (DTPA), for carrying out the magnetic extraction and separation of the lanthanide ions in aqueous solution. This strategy, also known as magnetic nanohydrometallurgy (MNHM), was first introduced in 2011 for dealing with transition metal recovery in the laboratory, and has been recently extended to the lanthanide series. This technology is based on lanthanide complexation and depends on the chemical equilibrium involved. It has been better described in terms of Langmuir isotherms, considering a uniform distribution of the metal ions over the nanoparticles surface, as evidenced by high angle annular dark field microscopy. The observed affinity parameters correlate with the lanthanide ion contraction series, and the process dynamics have been studied by monitoring the nanoparticles migration under an applied magnetic field (magnetophoresis). The elements can be reversibly captured and released from the magnetically confined nanoparticles, allowing their separation by a simple acid-base treatment. It can operate in a circular scheme, facilitated by the easy magnetic recovery of the extracting agents, without using organic solvents and ionic exchange columns. MNHM has been successfully tested for the separation of the lanthanide elements from monazite mineral, and seems a promising green nanotechnology, particularly suitable for urban mining.

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12

Majdan, Marek. "Correlation in the lanthanide series." Monatshefte f�r Chemie Chemical Monthly 121, no. 10 (October 1990): 731–37. http://dx.doi.org/10.1007/bf00808365.

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13

Tan, Xiao-Feng, Jian Zhou, Hua-Hong Zou, Lianshe Fu, Qiuling Tang, and Peng Wang. "A series of lanthanide glutarates: lanthanide contraction effect on crystal frameworks of lanthanide glutarates." RSC Advances 7, no. 29 (2017): 17934–40. http://dx.doi.org/10.1039/c7ra01552f.

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Although some 3-D lanthanide glutarates have been reported, they exhibit a very robust structural type, whose structure is not changed by different Ln³⁺ ions, but compound 3 shows a new structural type.

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14

Cotton, Simon A., Jack M. Harrowfield, Lioubov I. Semenova, Brian W. Skelton, Alexandre N. Sobolev, and Allan H. White. "Allan White and Polypyridines: Extending the Lanthanide(III) Complex Series." Australian Journal of Chemistry 73, no. 6 (2020): 434. http://dx.doi.org/10.1071/ch19129.

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X-Ray structure determinations on 41 complexes of lanthanide(iii) halides, principally bromides, with 2,2′-bipyridine, 1,10-phenanthroline, and 2,2′:6′,2″-terpyridine provide a considerable extension to the earlier work of Allan White on such materials and a substantial extension of general work on polypyridine complexes of lanthanide halides. Complexes of 1:1, 1:2, and 2:4 metal-to-ligand composition have been characterised across a broad selection of the lanthanide elements, many of these species showing a higher overall ratio of ligand to lanthanide due to the incorporation of uncoordinated ligand within the crystal lattice. Although stacking of the aromatic entities is apparent in these adducts, in most instances H-bonding of unbound N to coordinated water appears to be the principal interaction involved in their formation.

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15

Tan, Xiao-Feng, Jian Zhou, Lianshe Fu, Hong-Ping Xiao, Hua-Hong Zou, and Qiuling Tang. "A series of new lanthanide fumarates displaying three types of 3-D frameworks." Dalton Transactions 45, no. 12 (2016): 5253–61. http://dx.doi.org/10.1039/c6dt00205f.

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16

He, Xihong, Guoxin Tian, Jing Chen, and Linfeng Rao. "Characterization of the extracted complexes of trivalent lanthanides with purified cyanex 301 in comparison with trivalent actinide complexes." Dalton Trans. 43, no. 46 (2014): 17352–57. http://dx.doi.org/10.1039/c4dt02553a.

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17

Li, Lei-Lei, Rui Pan, Jun-Wei Zhao, Bai-Feng Yang, and Guo-Yu Yang. "A series of lanthanide germanate cluster organic frameworks." Dalton Transactions 45, no. 30 (2016): 11958–67. http://dx.doi.org/10.1039/c6dt01629d.

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18

Wang, Xia, Yaxing Wang, Yanlong Wang, Hanzhou Liu, Yugang Zhang, Wei Liu, Xiangxiang Wang, and Shuao Wang. "Color-tunable X-ray scintillation based on a series of isotypic lanthanide–organic frameworks." Chemical Communications 56, no. 2 (2020): 233–36. http://dx.doi.org/10.1039/c9cc08114c.

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X-ray excited luminescence from lanthanide–organic frameworks are reported for the first time, enabling color-tunable visualization of X-ray radiation by changing the lanthanide moiety in the crystals.

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19

Krsmanović, R., Stefano Polizzi, and P. Canton. "Characterization of Nanoporous Lanthanide-Doped Gadolinium Gallium Garnet Powders Obtained by Propellant Synthesis." Materials Science Forum 494 (September 2005): 143–48. http://dx.doi.org/10.4028/www.scientific.net/msf.494.143.

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In the present work we study the nanocrystalline powders of lanthanide-doped Gd3Ga5O12 (GGG, gadolinium gallium garnet) prepared using propellant synthesis. A series of GGG samples containing a number of different trivalent lanthanide ions (Tm, Er, Ho, Eu, Sm, Nd, and Pr) in different quantities (1%, 5%, 10%) were produced. Samples were characterized by X-ray diffraction (pre- and post calcination) for phase identification and line-broadening analysis, and by electron microscopy (SEM and TEM) for morphological and nanostructural investigation. Thermal behavior of the powder was investigated by thermal gravimetric analysis (TGA) and differential thermal analysis (DTA). The samples have a polycrystalline porous structure. Elemental microanalysis made by energy dispersive X-ray spectroscopy (EDX) detector attached to TEM and XRD unit-cell determinations confirmed that the lanthanides ions entered the structure of GGG. Crystallites have a high degree of disorder.

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20

Wong-Ng, Winnie, Boris Paretzkin, and Edwin R. Fuller. "Crystal Chemistry and Phase Equilibria of the BaO-R2O3-CuO Systems." Advances in X-ray Analysis 33 (1989): 453–65. http://dx.doi.org/10.1154/s0376030800019881.

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AbstractTwo important factors, the progressively decreasing size of the lanthanides, which is known as the lanthanide contraction, as well as the stability of different oxidation states of these elements influence the prediction of compound formation in the Ba-R-Cu-O systems. A systematic investigation of these lanthanide systems and comparison with the Y system has revealed a correlation of the effect of the above factors, in particular the size factor, on the trend of phase formation, solid solution formation and phase compatibility diagrams of the Ba-R-Cu-O systems. For example, it has been found that the smaller the size of R3+ or the greater the mismatch betwaen Ba2+ and R3+ in the solid solution series Ba2-ZR1+lCu3O6+x, the smaller the extent of solid solution formation. This differing extent of solid solution formation influences the ternary phase relationships.

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21

Chan, Eric J., Jack M. Harrowfield, Brian W. Skelton, and Allan H. White. "X-Ray Structural Studies of Small-Bite Ligands on Large Cations – Lanthanide(III) Ions and Dimethylphosphate." Australian Journal of Chemistry 73, no. 6 (2020): 539. http://dx.doi.org/10.1071/ch19506.

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Reactions of lanthanide chlorides or trifluoracetates (tfa) or picrates with trimethylphosphate alone in the first two cases or trimethylphosphate plus 1,10-phenanthroline or 2,2′;6′,2′′-terpyridine in the third, result in the formation of crystalline products containing dimethylphosphate (dmp–). Single crystal X-ray structural characterisation of these materials has shown that the stoichiometrically simple Ln(dmp)3 species obtained with chloride reactants and the lighter lanthanides are polymeric and commonly dimorphic, while the stoichiometrically more variable mixed dmp/tfa complexes have structures closely related to one phase of the Ln(dmp)3 family, and the presence of picrate and aza-aromatic ligands enables the isolation of Y and Lu derivatives containing binuclear species. In all, the dmp– ligands adopt exclusively the κ1O;κ1O′ bridging mode, the overall results indicating that this should apply to the complete lanthanide series.

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22

Zhang, Qingrui, Xiuyun Yang, Ruiping Deng, Liang Zhou, Yang Yu, and Yunhui Li. "Synthesis and Near Infrared Luminescence Properties of a Series of Lanthanide Complexes with POSS Modified Ligands." Molecules 24, no. 7 (March 30, 2019): 1253. http://dx.doi.org/10.3390/molecules24071253.

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A polyhedral oligomeric silsesquioxanes (POSS) modified 8-hydroxyquinoline derivative (denoted as Q-POSS) was synthesized and used as a ligand to coordinate with lanthanide ions to obtain a series of lanthanide complexes Ln(Q-POSS)3 (Ln = Er3+, Yb3+, Nd3+). The as-prepared lanthanide complexes have been characterized by FT-IR, UV–Vis, and elemental analysis. All these complexes showed the characteristic near-infrared (NIR) luminescence originated from the corresponding lanthanide ions under excitation. Compared with the unmodified counterparts LnQ3 (HQ = 8-hydroxyquinoline), the Ln(Q-POSS)3 complexes showed obviously increased emission intensity, which was ascribed mainly to the steric-hindrance effects of the POSS moiety in the ligands. It is believed that the POSS group could suppress undesired excimer formation and intermolecular aggregation, thus decreasing the concentration quenching effect of the corresponding lanthanide complexes.

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23

Jiang, Shang-Da, Shan-Shan Liu, Li-Nan Zhou, Bing-Wu Wang, Zhe-Ming Wang, and Song Gao. "Series of Lanthanide Organometallic Single-Ion Magnets." Inorganic Chemistry 51, no. 5 (February 22, 2012): 3079–87. http://dx.doi.org/10.1021/ic202511n.

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24

Regueiro-Figueroa, Martín, David Esteban-Gómez, Andrés de Blas, Teresa Rodríguez-Blas, and Carlos Platas-Iglesias. "Understanding Stability Trends along the Lanthanide Series." Chemistry - A European Journal 20, no. 14 (February 27, 2014): 3974–81. http://dx.doi.org/10.1002/chem.201304469.

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25

Lansman, J. B. "Blockade of current through single calcium channels by trivalent lanthanide cations. Effect of ionic radius on the rates of ion entry and exit." Journal of General Physiology 95, no. 4 (April 1, 1990): 679–96. http://dx.doi.org/10.1085/jgp.95.4.679.

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Currents flowing through single dihydropyridine-sensitive Ca2+ channels were recorded from cell-attached patches on C2 myotubes. In the presence of dihydropyridine agonist to prolong the duration of single-channel openings, adding micromolar concentrations of lanthanum (La), cerium (Ce), neodymium (Nd), gadolinium (Gd), dysprosium (Dy), or ytterbium (Yb) to patch electrodes containing 110 mM BaCl2 caused the unitary Ba2+ currents to fluctuate between fully open and shut states. The kinetics of channel blockade followed the predictions of a simple open channel block model in which the fluctuations of the single-channel current arose from the entry and exit of blocking ions from the pore. Entry rates for all the lanthanides tested were relatively insensitive to membrane potential, however, exit rates depended strongly on membrane potential increasing approximately e-fold per 23 mV with hyperpolarization. Individual lanthanide ions differed in both the absolute rates of ion entry and exit: entry rates decreased as cationic radius decreased; exit rates also decreased with cationic radius during the first part of the lanthanide series but then showed little change during the latter part of the series. Overall, the results support the idea that smaller ions enter the channel more slowly, presumably because they dehydrate more slowly; smaller ions also bind more tightly to a site within the channel pore, but lanthanide residence time within the channel approaches a maximum for the smaller cations with radii less than or equal to that of Ca2+.

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26

Hua, Carol, Hui Min Tay, Qilin He, and T. David Harris. "A Series of Early Lanthanide Chloranilate Frameworks with a Square Grid Topology." Australian Journal of Chemistry 72, no. 10 (2019): 778. http://dx.doi.org/10.1071/ch19193.

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A series of lanthanide chloranilate frameworks containing a (4,4)-net with LaIII, CeIII, NdIII, SmIII, and EuIII have been synthesised and structurally characterised. Two structure types of square grids were obtained for these frameworks. Type 1 consists of the formula (Et4N)[Ln(can)2(H2O)] (Ln=LaIII, CeIII, NdIII; H2can=chloranilic acid) and crystallised in the tetragonal space group I4/m, featuring a nine-coordinate lanthanide ion with a coordinated water molecule and four chloranilate ligands. Type 2, (Et4N)[Ln(can)2] (SmIII and EuIII) crystallised in the I4/mcm space group, and contains an eight-coordinate lanthanide ion without a coordinated water molecule. A single-crystal-to-single-crystal transformation was carried out for (Et4N)[Nd(can)2(H2O)] on removal of the coordinated aqua ligand.

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27

Lin, Xiao-Ming, Ji-Liang Niu, Pei-Xian Wen, Yan-Na Lu, Lei Hu, Da-Liang Zhang, and Yue-Peng Cai. "From 1D to 3D lanthanide coordination polymers constructed with pyridine-3,5-dicarboxylic acid: synthesis, crystal structures, and catalytic properties." RSC Advances 6, no. 68 (2016): 63425–32. http://dx.doi.org/10.1039/c6ra13242a.

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Three series of lanthanide coordination polymers have been synthesized. The structural difference may be derived from the lanthanide contraction. Moreover, we also discussed the size-selective catalytic activity towards cyanosilylation of aldehydes.

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28

Batrice, Rami J., J. August Ridenour, R. Lee Ayscue III, Jeffery A. Bertke, and Karah E. Knope. "Synthesis, structure, and photoluminescent behaviour of molecular lanthanide–2-thiophenecarboxylate–2,2′:6′,2′′-terpyridine materials." CrystEngComm 19, no. 35 (2017): 5300–5312. http://dx.doi.org/10.1039/c7ce01192j.

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A lanthanide series incorporating 2-thiophenecarboxylate and terpyridine is presented. Four structure types are observed with differences in the coordination number and nuclearity of the complexes attributed to the effects of the lanthanide contraction.

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29

Jing, Huiru, Wenyan Dan, Jiaxing Zhu, Yun Ling, Yu Jia, Yongtai Yang, Xiaofeng Liu, Zhenxia Chen, and Yaming Zhou. "Multimetal lanthanide phosphonocarboxylate frameworks: structures, colour tuning and near-infrared emission." Dalton Transactions 50, no. 21 (2021): 7380–87. http://dx.doi.org/10.1039/d1dt01052b.

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A series of isostructural (3,18)-connected lanthanide phosphonocarboxylate frameworks were designed by using Ln₇-clusters as SBUs, which served as a platform to accommodate various lanthanide ions for integrating multi-luminescence properties.

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30

El-Enein, S. A. Abou, A. M. Ali, Y. K. Abdel-Monem, M. H. Senna, and Metwally Madkour. "Novel lanthanide(III) 4-methylbenzoylhydrazide complexes as precursors for lanthanide oxide nanophotocatalysts." RSC Advances 9, no. 72 (2019): 42010–19. http://dx.doi.org/10.1039/c9ra08080e.

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31

Lin, Shuang-Yan, Chao Wang, Lang Zhao, Jianfeng Wu, and Jinkui Tang. "Chiral mononuclear lanthanide complexes and the field-induced single-ion magnet behaviour of a Dy analogue." Dalton Transactions 44, no. 1 (2015): 223–29. http://dx.doi.org/10.1039/c4dt02889a.

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A rare series of enantiopure mononuclear lanthanide complex pairs were obtained by using a chiral macrocyclic ligand and thiocyanate. The Dy complex was revealed to be a rare seven-coordinated lanthanide-based SIM encapsulated in a macrocyclic ligand.

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32

Pei, Yun-Peng, Jian-Gen Huang, Rong-Hua Hu, Yun-Xia Yang, Jie Zhou, and Wen-Tong Chen. "Metal-induced property variation for a series of lanthanide-vanadium porphyrins." Journal of Porphyrins and Phthalocyanines 19, no. 06 (June 2015): 811–18. http://dx.doi.org/10.1142/s1088424615500674.

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Three lanthanide-vanadium porphyrins, [ LnV ( TPPS ) H 2 O ]n ( Ln = Tb (1), Dy (2), Er (3); H 6 TPPS = tetra(4-sulfonatophenyl)porphyrin), have been prepared from hydrothermal reactions and their structures were characterized by single crystal X-ray diffraction technique. The macrocyclic ring of H 6 TPPS is coplanar and the center is occupied by the vanadium(III) ion. The lanthanide(III) ions are bound by eight oxygen atoms to yield a distorted square anti-prism geometry. They are characteristic of a three-dimensional (3-D) open framework with a void space of around 210 Å3. Fluorescence studies reveal that compounds 1–3 exhibit an emission band in the red region with the quantum yields being of 2.0%, 1.4% and 5.0%, respectively. CV/DPV results discover one quasi-reversible wave (1), one reductive peak (2) and two reductive peaks (3). Compounds 1–3 show largely different photophysical and electrochemical properties, although their structures only show tiny difference in lanthanide metal ions. This is due to metal-induced properties variation.

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33

Li, Weijia, Ruji Wang, Shufeng Si, and Yadong Li. "Synthesis, structures and properties of series lanthanide nitrilotriacetates." Journal of Molecular Structure 694, no. 1-3 (June 2004): 27–31. http://dx.doi.org/10.1016/j.molstruc.2004.01.018.

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34

Wei, Jingjing, Lu Yang, Pengtao Ma, Jingping Wang, and Jingyang Niu. "A Series of Multi-Dimensional Lanthanide-Containing Peroxoisopolymolybdates." Crystal Growth & Design 13, no. 8 (July 19, 2013): 3554–60. http://dx.doi.org/10.1021/cg400536e.

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35

Pourret, Olivier, and Raul E. Martinez. "Modeling lanthanide series binding sites on humic acid." Journal of Colloid and Interface Science 330, no. 1 (February 2009): 45–50. http://dx.doi.org/10.1016/j.jcis.2008.10.048.

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36

Akdeniz, Z., Z. Çiçek, and M. P. Tosia. "Ionic Interactions in Lanthanide Halides." Zeitschrift für Naturforschung A 55, no. 11-12 (December 1, 2000): 861–66. http://dx.doi.org/10.1515/zna-2000-11-1204.

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Abstract We determine a model of the ionic interactions in RX3 compounds (where R is a metal in the rare-earth series from La to Lu and X = CI, Br or I) by an analysis of data on the static and dynamic structure of their molecular monomers. The potential energy function that we adopt is patterned after earlier work on Aluminium trichloride [Z. Akdeniz and M. P. Tosi, Z. Naturforsch. 54a, 180 (1999)], but includes as an essential element the electric polarizability of the trivalent metal ion to account for a pyramidal shape of RX3 molecules. From data referring mostly to trihalides of elements at the ends and in the middle of the rare-earth series (/. e. LaX3, GdX3 and LuX3), we propose systematic variations for the effective valence, ionic radius and electric polarizability of the metal ions across the series. As a first application of our results we predict the structure of the Dy2Cl6 and Dy2Br6 molecular dimers and demonstrate by comparison with electron diffraction data that lanthanide-ion polarizability plays a quantitative role also in this state of tetrahedral-like coordination.

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37

Zhang, Lina, Chao Zhang, Bin Zhang, Chenxia Du, and Hongwei Hou. "Two series of pH-dependent lanthanide complexes showing solvent-induced single crystal to single crystal transformation, sorption and luminescence properties." CrystEngComm 17, no. 14 (2015): 2837–46. http://dx.doi.org/10.1039/c5ce00263j.

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38

Jiang, Y., R. J. Holmberg, F. Habib, L. Ungur, I. Korobkov, L. F. Chibotaru, and M. Murugesu. "Probing the structural and magnetic properties of a new family of centrosymmetric dinuclear lanthanide complexes." RSC Advances 6, no. 61 (2016): 56668–73. http://dx.doi.org/10.1039/c6ra12070a.

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A series of centrosymmetric dinuclear lanthanide complexes, including Gd^III (1), Dy^III (2), Ho^III (3), Er^III (4) and Yb^III (5), have been synthesized and studied for the effects of lanthanide contraction on their magnetic properties.

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39

An, Haiyan, Hua Zhang, Zhaofei Chen, Yangguang Li, Xuan Liu, and Hao Chen. "A series of three-dimensional architectures constructed from lanthanide-substituted polyoxometalosilicates and lanthanide cations or lanthanide–organic complexes as linkers." Dalton Transactions 41, no. 27 (2012): 8390. http://dx.doi.org/10.1039/c2dt30251a.

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40

Wegner, W., T. Jaroń, and W. Grochala. "Preparation of a series of lanthanide borohydrides and their thermal decomposition to refractory lanthanide borides." Journal of Alloys and Compounds 744 (May 2018): 57–63. http://dx.doi.org/10.1016/j.jallcom.2018.02.020.

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41

Canaj, Angelos B., Milosz Siczek, Marta Otręba, Tadeusz Lis, Giulia Lorusso, Marco Evangelisti, and Constantinos J. Milios. "Building 1D lanthanide chains and non-symmetrical [Ln2] “triple-decker” clusters using salen-type ligands: magnetic cooling and relaxation phenomena." Dalton Transactions 45, no. 46 (2016): 18591–602. http://dx.doi.org/10.1039/c6dt02932a.

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42

Zheng, Yuhua, Kai Liu, Xun Sun, Rengui Guan, Huijuan Su, Hongpeng You, and Caixia Qi. "A series of nano/micro-sized metal–organic frameworks with tunable photoluminescence properties." CrystEngComm 17, no. 11 (2015): 2321–26. http://dx.doi.org/10.1039/c4ce02456g.

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43

Jia, Jia, Jianing Xu, Shengyan Wang, Pengcheng Wang, Lijuan Gao, Miao Yu, Yong Fan, and Li Wang. "Lanthanide coordination polymers constructed from 5-(1H-tetrazol-5-yl)isophthalic acid ligand: white light emission and color tuning." CrystEngComm 17, no. 31 (2015): 6030–36. http://dx.doi.org/10.1039/c5ce00823a.

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A series of lanthanide coordination polymers (LnCPs), namely [Ln(TZI) (H₂O)₅]_n(1–5) [Ln = Nd (1), Eu (2), Gd (3), Tb (4) and Sm (5)], were synthesized through the self-assembly of 5-(1H-tetrazol-5-yl)isophthalic acid (H₃TZI) ligand and lanthanide ions.

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44

Bag, Prasenjit, Chandresh Kumar Rastogi, Sourav Biswas, Sri Sivakumar, Valeriu Mereacre, and Vadapalli Chandrasekhar. "Homodinuclear lanthanide {Ln2} (Ln = Gd, Tb, Dy, Eu) complexes prepared from an o-vanillin based ligand: luminescence and single-molecule magnetism behavior." Dalton Transactions 44, no. 9 (2015): 4328–40. http://dx.doi.org/10.1039/c4dt03429e.

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Zhang, Pei-Zhi, Rui Liu, Ling-Dong Sun, Hao Dong, Lin-Dong Li, Xiao-Yu Zheng, Ke Wu, and Chun-Hua Yan. "Phase segregation enabled scandium fluoride–lanthanide fluoride Janus nanoparticles." Inorganic Chemistry Frontiers 5, no. 8 (2018): 1800–1804. http://dx.doi.org/10.1039/c8qi00328a.

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Feng, Xun, Rongfang Li, Liya Wang, Seik Weng Ng, Guozhan Qin, and Lufang Ma. "A series of homonuclear lanthanide coordination polymers based on a fluorescent conjugated ligand: syntheses, luminescence and sensor for pollutant chromate anion." CrystEngComm 17, no. 41 (2015): 7878–87. http://dx.doi.org/10.1039/c5ce01454a.

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Lv, Xue-Hui, Shuai-Liang Yang, Yuan-Xia Li, Chen-Xi Zhang, and Qing-Lun Wang. "A family of lanthanide compounds based on nitronyl nitroxide radicals: synthesis, structure, magnetic and fluorescence properties." RSC Advances 7, no. 61 (2017): 38179–86. http://dx.doi.org/10.1039/c7ra05764d.

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48

Smith, Paul H., Zelideth E. Reyes, Chi Woo Lee, and Kenneth N. Raymond. "Characterization of a series of lanthanide amine cage complexes." Inorganic Chemistry 27, no. 23 (November 1988): 4154–65. http://dx.doi.org/10.1021/ic00296a015.

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49

Comba, Peter, Michael Großhauser, Rüdiger Klingeler, Changhyun Koo, Yanhua Lan, Dennis Müller, Jaena Park, Annie Powell, Mark J. Riley, and Hubert Wadepohl. "Magnetic Interactions in a Series of Homodinuclear Lanthanide Complexes." Inorganic Chemistry 54, no. 23 (November 20, 2015): 11247–58. http://dx.doi.org/10.1021/acs.inorgchem.5b01673.

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Meng, Xiangyu, Xiansong Liu, Chaocheng Liu, Cong Zhang, Haohao Li, and Khalid Mehmood Ur Rehman. "Microstructure and properties of lanthanide series M-type hexaferrites." Journal of Materials Science: Materials in Electronics 28, no. 8 (January 6, 2017): 6352–57. http://dx.doi.org/10.1007/s10854-016-6319-y.

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