Academic literature on the topic 'Lanthanoid complexes'

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Journal articles on the topic "Lanthanoid complexes"

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Xiao, Hong-Ping, Jian Zhou, Rong-Qing Zhao, Wei-bing Zhang, and Yong Huang. "A series of lanthanoid selenidoantimonates(v): rare examples of lanthanoid selenidoantimonates based on dinuclear lanthanide complexes." Dalton Transactions 44, no. 13 (2015): 6032–39. http://dx.doi.org/10.1039/c5dt00146c.

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Mahmud, S.D., Birnin-Yauri, U.A., Liman, M.G., and Manga, S.B. "Antimicrobial activity of Bis-salicylaldehyde Ethylenediamine Schiff Base and Its Lanthanoids (III) Complexes." UMYU Journal of Microbiology Research (UJMR) 7, no. 2 (2022): 87–91. http://dx.doi.org/10.47430/ujmr.2272.013.

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Schiff base readily form complex with metal ions and the resultant complexes especially from transition metals were extensively used in many fields of human endeavor including antimicrobial therapy. However, the potentials of Lanthanide-Schiff base complexes as an antimicrobial agent have not been adequately studied. This study aims to synthesize and determine the antimicrobial activity of Bis-salicylaldehyde ethylenediamine Schiff Base and its Lanthanoids (III) Complexes. The Dysprosium (III), Gadolinium (III), Neodymium (III) and Samarium (III) complexes of Schiff base derived from Salicylal
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Benmansour, Samia, and Carlos J. Gómez-García. "Lanthanoid-Anilato Complexes and Lattices." Magnetochemistry 6, no. 4 (2020): 71. http://dx.doi.org/10.3390/magnetochemistry6040071.

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In this review, we describe all the structurally characterized complexes containing lanthanoids (Ln, including La and group 3 metals: Y and Lu) and any anilato-type ligand (3,6-disubstituted-2,5-dihydroxy-1,4-benzoquinone dianion = C6O4X22−). We present all the anilato-Ln compounds including those where, besides the anilato-type ligand, there is one or more coligands or solvent molecules coordinated to the lanthanoid ions. We show the different structural types observed in these compounds: from discrete monomers, dimers and tetramers to extended 1D, 2D and 3D lattices with different topologies
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Bousrez, Guillaume, Philip C. Andrews, Peter C. Junk, Dominique T. Thielemann, and Jun Wang. "Synthesis of Lanthanoid Complexes from Ln2O3 and Diatrizoic Acid." Australian Journal of Chemistry 71, no. 12 (2018): 939. http://dx.doi.org/10.1071/ch18419.

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We present a pathway to synthesize diatrizoate lanthanoid complexes directly from Ln2O3 and diatrizoic acid (DTAH=3,5-diacetamido-2,4,6-triiodobenzoic acid) at room temperature yielding [Ln(H2O)8][DTA]3 in moderate (for the heavier lanthanoids) to good (for the lighter lanthanoids) yields. Compounds were recrystallized from DMSO or water and their X-ray crystal structures were obtained. The complexes have metal centres solely coordinated by solvent molecules with no direct interaction between the metal centre and the DTA anion. The compounds crystallized from DMSO have the formulation [Ln(DMSO
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Vonci, Michele, and Colette Boskovic. "Polyoxometalate-Supported Lanthanoid Single-Molecule Magnets." Australian Journal of Chemistry 67, no. 11 (2014): 1542. http://dx.doi.org/10.1071/ch14166.

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Polyoxometalates are robust and versatile multidentate oxygen-donor ligands, eminently suitable for coordination to trivalent lanthanoid ions. To date, 10 very different structural families of such complexes have been found to exhibit slow magnetic relaxation due to single-molecule magnet (SMM) behaviour associated with the lanthanoid ions. These families encompass complexes with between one and four of the later lanthanoid ions: Tb, Dy, Ho, Er, and Yb. The lanthanoid coordination numbers vary between six and eleven and a range of coordination geometries are evident. The highest energy barrier
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Herrmann, Wolfgang A., Reiner Anwander, Florian C. Munck, et al. "Lanthanoiden-Komplexe, IX [1]. Reaktivitätsbestimmender Einfluß der Ligandenkonstitution bei Seltenerdamiden: Herstellung und Struktur sterisch überladener Alkoxid-Komplexe / Lanthanoid Complexes, IX [1]. Reactivity Control of Lanthanoid Amides through Ligand Effects: Synthesis and Structures of Sterically Congested Alkoxy Complexes." Zeitschrift für Naturforschung B 49, no. 12 (1994): 1789–97. http://dx.doi.org/10.1515/znb-1994-1225.

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It is shown that the introduction of sterically demanding ligands in lanthanoid metal complexes can depend more on the precise composition of the lanthanoid precursor than on the size of the new ligand. Thus, tris(r-butyl)methanol (“rmojt-H”) does not react with the amides Ln[N(SiMe3)2]3 of the “late” (small) lanthanoid metals. However, fast and clean reactions occur with the sterically less demanding derivatives Ln[N(SiHMe2)2]3, with new homoleptic complexes Ln(tritox)3 (Ln = Y, Nd) being formed with practically all metals of this group of elements. The molecular and crystal structures of som
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Massi, Massimiliano, Stefano Stagni, and Mark I. Ogden. "Lanthanoid tetrazole coordination complexes." Coordination Chemistry Reviews 375 (November 2018): 164–72. http://dx.doi.org/10.1016/j.ccr.2017.11.017.

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Deacon, Glen B., Peter C. Junk, Winnie W. Lee, Maria Forsyth, and Jun Wang. "Rare earth 3-(4′-hydroxyphenyl)propionate complexes." New Journal of Chemistry 39, no. 10 (2015): 7688–95. http://dx.doi.org/10.1039/c5nj00787a.

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Structural variation of lanthanoid 3-(4′-hydroxyphenyl)propionates and investigation of the anti-corrosion properties of lanthanum 3-(4′-hydroxyphenyl)propionate are presented, highlighting lanthanoid contraction and the importance of the –CHCH− structural unit of 4-hydroxycinnamates in corrosion mitigation.
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Talon, Romain, Richard Kahn, M. Asunción Durá, et al. "Using lanthanoid complexes to phase large macromolecular assemblies." Journal of Synchrotron Radiation 18 Part 1 (November 5, 2010): 74–78. https://doi.org/10.1107/S0909049510036824.

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Lanthanoid ions exhibit extremely large anomalous X-ray scattering at their <em>L</em><sub>III</sub> absorption edge. They are thus well suited for anomalous diffraction experiments. A novel class of lanthanoid complexes has been developed that combines the physical properties of lanthanoid atoms with functional chemical groups that allow non-covalent binding to proteins. Two structures of large multimeric proteins have already been determined by using such complexes. Here the use of the luminescent europium tris-dipicolinate complex [Eu(DPA)<sub>3</sub>]<sup>3−</sup> to solve the low-resoluti
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MAHMUD, SARATU, U. A. Birnin-Yauri, and M. G. Liman. "CHARACTERIZATION OF BIS-SALICYLALDEHYDE O-PHENYLENEDIAMINE SCHIFF BASE AND ITS DY(III), GD(III), ND(III) AND SM(III) LANTHANOIDS COMPLEXES." FUDMA JOURNAL OF SCIENCES 7, no. 1 (2023): 19–23. http://dx.doi.org/10.33003/fjs-2023-0701-1226.

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Schiff bases have versatile chemical properties and numerous utilities in various industries consequent of their excellent coordination ability with numerous metal ions especially transition metals. To further exploit the chemical versatility of this promising compound, we thoroughly characterize the aged long synthesized Schiff base; Bis-salicylaldehyde o-phenylenediamine (Salphen) and its Lanthanoid (III) complexes of Neodymium, Samarium, Gadolinium and Dysprosium using solubility test, melting and decomposition analysis, FTIR, Uv-visible spectroscopy, conductivity measurement, elemental ana
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Dissertations / Theses on the topic "Lanthanoid complexes"

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Milne, Paul Edward Young. "Polynuclear copper-lanthanoid complexes of pyridone ligands." Thesis, University of Edinburgh, 1993. http://hdl.handle.net/1842/15394.

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The crystal structures of several copper and mixed copper-lanthanoid complexes are reported, using the 6-chloro and 6-methyl derivatives of 2-pyridone as a ligand. With 6-chloro-2-pyridone, a novel dimeric copper complex results, which has been structually and physically studied. This species, under certain conditions, exhibits a dissociation reaction which has been examined using U.V.-vis. and E.P.R. spectroscopy and by cyclic voltammetry. Reaction of this dimeric copper compound with methanol and ethylene glycol results in the formation of tetranuclear and polymeric copper complexes respecti
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D'Alessio, Daniel Mark. "Lanthanoid complexes of tetrazolyl-functionalised Calix[4]arenes." Thesis, Curtin University, 2015. http://hdl.handle.net/20.500.11937/853.

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Syntheses of the bis-, tris- and tetra-tetrazolato calix[4]arene ligands were performed from their corresponding nitrile derivatives. Mono-nuclear lanthanoid complexes were characterised in the presence of triethylamine, while addition of aqueous ammonium acetate resulted in the formation of an unprecedented discrete linear nineteen lanthanoid hydroxo cluster (Ln19). It was found the length of the cluster could be altered to an Ln12 structure, while retaining an identical cluster motif, by simply replacing ammonium acetate with ammonium benzoate.
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Abad, Galán Laura. "Exploring the Chemistry of Lanthanoid β–Triketonate Complexes". Thesis, Curtin University, 2018. http://hdl.handle.net/20.500.11937/70485.

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This thesis reports the design, synthesis and characterisation of new β-triketonate based lanthanoid complexes. The use of systematically modified β-triketone molecules as ligands for these f-metal ions and their effect on the structural and photophysical properties of the complexes were investigated in detail. This study allowed a better understanding of the relationship between structure and photophysical activity of the lanthanoid complexes and the isolation of unusually efficient near-infrared emitters.
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Haddad, Timothy Samir. "Phosphine complexes of zirconium, hafnium and the lanthanoid metals." Thesis, University of British Columbia, 1990. http://hdl.handle.net/2429/31012.

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The synthesis of a variety of new lanthanoid phosphine complexes has been achieved by complexing either one or two amido-diphosphine ligands to yttrium, lutetium or lanthanum. At room temperature, the seven-coordinate bis(amido- diphosphine) complexes, MCl[N(SiMe₂CH₂PR₂)₂]₂- are fluxional and display NMR spectra indicative of complexes where the phosphorus donors are rapidly exchanging, probably via a dissociation-reassociation pathway. It is possible to generate thermally unstable hydrocarbyl complexes of the type, M(R)[N(SiMe₂CH₂PMe₂)₂]₂, which undergo a clean first order elimination of
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Fisher, Christopher Martin. "Macrocyclic Lanthanoid complexes: luminescence studies and potential for bioconjugation." Thesis, University of Hull, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.507815.

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Scott, Natalie M(Natalie Maree) 1976. "Diverse lanthanoid and lithium complexes with pendant donor amide ligands." Monash University, Dept. of Chemistry, 2001. http://arrow.monash.edu.au/hdl/1959.1/8984.

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Shen, Chao. "Structural and Photophysical Investigation of Lanthanoid Complexes of Calixarene-Based Antenna Ligands." Thesis, Curtin University, 2021. http://hdl.handle.net/20.500.11937/89264.

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This thesis presents investigations into structural and photophysical properties of naphthalenetetracarboxylic diimide (NDI) functionalised calixarenes and their corresponding lanthanoid complexes. Six new calixarene ligands were synthesied and fully characterised. Upon complexation, europium (III), ytterbium(III) and neodynium(III) luminescence can be induced by energy transfer from the NDI of ligand and/or calixarene aromatic backbone. The reduction of neutral NDI to NDI radical anion was successful, and the NDI radical anion also sensitised ytterbium(III) luminescence.
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Cameron, Lee John. "Shedding Light on the Structural and Luminescent Properties of Lanthanoid β-Triketonate Complexes". Thesis, Curtin University, 2019. http://hdl.handle.net/20.500.11937/78465.

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This thesis presents research centred around the structural and photophysical characterisation of ß-diketonate and ß-triketonate lanthanoid complexes. The overarching goal was to identify the effect of different co-ligands in lanthanoid complexes. 25 new complexes featuring six different ß-diketonate and ß-triketonate ligands, and four different co-ligands were isolated and characterised. The synthesis of a novel ß-triketonate molecule, bis-tribenzoylmethane, is presented, along with the first reported crystallographically characterised lanthanoid complex with bis-dibenzoylmethane coordinated.
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Hossain, Md Elius. "Lanthanoid formamidinates and halogenoaluminate complexes of the rare earths and alkaline earths: synthesis and reactivity." Thesis, Springer, 2017. https://researchonline.jcu.edu.au/57687/1/JCU_57687-hossain-2017-thesis.pdf.

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This thesis focuses on the synthesis and characterisation of halogenoaluminate π-arene complexes of rare earths and alkaline earths and compares the similarities between the two groups of metals. This thesis also discusses the reactivity of divalent rare earth N,N′- bis(aryl)formamidinate (ArForm) complexes. Study of the synthesis of halogenoaluminate π-arene complexes of rare earths has yielded several new complexes containing η⁶-arene, [Ln(arene)(AlX₄)ₙ] (Ln = La, Ce, Pr, Nd, Gd, Sm, Eu, Yb; arene = toluene, mesitylene; X = Br, I; n = 2, 3). Divalent compounds of Sm, Eu and Yb have lattic
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Chan, Eric J. "Structural systematics of complexes of lanthanoid picrates with unidentate O-donor ligands and other related arrays." University of Western Australia. School of Biomedical, Biomolecular and Chemical Sciences, 2006. http://theses.library.uwa.edu.au/adt-WU2006.0075.

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Structures as determined by single crystal X-ray methods for lanthanoid(III) compounds for series of simple homoleptic species with diverse ligands frequently display variations entailing a diminution in coordination number (‘C.N.’), a consequence of the variation in the size of the atoms/ions due to the ‘lanthanoid contraction’. A change from C.N. nine to eight is common, clearly separating compounds of the light/‘early’ or heavy/‘later’ metal atoms. Earlier work on the complexes of the lanthanoid(III) picrates arose out of the exploration of simple reagents which might usefully exploit lanth
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Books on the topic "Lanthanoid complexes"

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Amoli, Hossein Salar. Chromatographic investigation of some lanthanide complexes. University of Salford, 1990.

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Hirai, Yuichi. Assembled Lanthanide Complexes with Advanced Photophysical Properties. Springer Singapore, 2018. http://dx.doi.org/10.1007/978-981-10-8932-9.

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Omagari, Shun. Energy Transfer Processes in Polynuclear Lanthanide Complexes. Springer Singapore, 2019. http://dx.doi.org/10.1007/978-981-13-6049-7.

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Moss, Michael Alan John. Heteroleptic polyprazolylborate complexes of the lanthanide elements. University of Birmingham, 1988.

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Miyata, Kohei. Highly Luminescent Lanthanide Complexes with Specific Coordination Structures. Springer Japan, 2014. http://dx.doi.org/10.1007/978-4-431-54944-4.

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Lawrence, Royston Graham. Heteroleptic lanthanide complexes as potential photocentres for molecular devices. University of Birmingham, 1995.

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Geraldes, Carlos F. G. C. Lanthanide and Other Transition Metal Ion Complexes and Nanoparticles in Magnetic Resonance Imaging. CRC Press, 2024. http://dx.doi.org/10.1201/9781003374688.

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Spry, Marcus P. Synthesis and structural studies of macrocyclic complexes of the p-block (Sb, Ge, Te, O) and lanthanide (La, Ho, Er, Tm, Pr) elements. typescript, 1999.

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Zargar, Rayees Ahmad, Shabir Ahmad Bhatand, and Sneha Ramdas Wankar. Lanthanide Complexes: Synthesis to Applications. Wiley & Sons, Incorporated, John, 2024.

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Zargar, Rayees Ahmad, Shabir Ahmad Bhatand, and Sneha Ramdas Wankar. Lanthanide Complexes: Synthesis to Applications. Wiley & Sons, Incorporated, John, 2024.

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Book chapters on the topic "Lanthanoid complexes"

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Wessner, D., J. C. G. Bünzli, F. Dunbar, and G. R. Choppin. "Lanthanoid Crown Ether Complexes." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132548.ch29.

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Shibasaki, Masakatsu, and Hiroaki Sasai. "Asymmetric Catalysis with Chiral Lanthanoid Complexes." In Topics in Stereochemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470147313.ch4.

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Fischer, R. Dieter. "NMR-Spectroscopy of Organo-f-Element and Pre-Lanthanoid Complexes: Some Current Trends." In Fundamental and Technological Aspects of Organo-f-Element Chemistry. Springer Netherlands, 1985. http://dx.doi.org/10.1007/978-94-009-5406-9_8.

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Katada, M., T. Nawa, H. Kumagai, S. Kawata, and S. Kitagawa. "Synthesis and 57Fe and 151Eu Mössbauer Spectroscopic Studies of New Lanthanoid-iron Complexes." In Hyperfine Interactions (C). Springer Netherlands, 2002. http://dx.doi.org/10.1007/978-94-010-0281-3_74.

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Hasegawa, Miki, and Yasuchika Hasegawa. "Triboluminescence of Lanthanide Complexes." In The Materials Research Society Series. Springer Nature Singapore, 2023. http://dx.doi.org/10.1007/978-981-99-0260-6_7.

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AbstractThe photoluminescence of lanthanide complexes originating from f–f transitions is generally sensitized through energy transfer from the ligand to the lanthanide ion in the excited state under UV irradiation. This phenomenon is known as the photo-antenna effect. Luminescence driven by mechanical stimuli, such as tapping or rubbing, is called mechanoluminescence or triboluminescence (TL). In recent years, reports on TL in rare-earth complexes, which have attracted attention as novel luminescent materials that do not require an electrical excitation source, have steadily increased. In thi
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Faulkner, Stephen, and Daniel Sykes. "Lanthanide Assemblies and Polymetallic Complexes." In Lanthanide Luminescence. Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/4243_2010_4.

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Shibasaki, Masakatsu, and Harald Gröger. "Chiral Heterobimetallic Lanthanoid Complexes: Highly Efficient Multifunctional Catalysts for the Asymmetric Formation of C-C, C-O, and C-P Bonds." In Lanthanides: Chemistry and Use in Organic Synthesis. Springer Berlin Heidelberg, 1999. http://dx.doi.org/10.1007/3-540-69801-9_5.

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Wang, Kezhi. "β-Diketonate Lanthanide Complexes." In Rare Earth Coordination Chemistry. John Wiley & Sons, Ltd, 2010. http://dx.doi.org/10.1002/9780470824870.ch2.

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Spangler, Corinna, and Michael Schäferling. "Luminescent Chemical and Physical Sensors Based on Lanthanide Complexes." In Lanthanide Luminescence. Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/4243_2010_1.

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Bünzli, Jean-Claude G. "Luminescence Bioimaging with Lanthanide Complexes." In Luminescence of Lanthanide Ions in Coordination Compounds and Nanomaterials. John Wiley & Sons Ltd, 2014. http://dx.doi.org/10.1002/9781118682760.ch04.

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Conference papers on the topic "Lanthanoid complexes"

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Sudoh, Susumu, Takafumi Miyanaga, and Ryo Miyamoto. "XAFS Study of the Local Structure of Some Lanthanoid(III) Complexes." In X-RAY ABSORPTION FINE STRUCTURE - XAFS13: 13th International Conference. AIP, 2007. http://dx.doi.org/10.1063/1.2644552.

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Kanetomo, Takuya, and Takayuki Ishida. "Luminescent single-ion magnets from Lanthanoid(III) complexes with monodentate ketone ligands." In PROGRESS IN APPLIED MATHEMATICS IN SCIENCE AND ENGINEERING PROCEEDINGS. AIP Publishing LLC, 2016. http://dx.doi.org/10.1063/1.4941214.

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Puntus, Lada N., Elena V. Sergeeva, Dmitrii Y. Antonov, Konstantin A. Lyssenko, and Francois Kajzar. "Luminescent lanthanide complexes for advanced photonic applications." In Security + Defence, edited by Colin Lewis, Douglas Burgess, Roberto Zamboni, François Kajzar, and Emily M. Heckman. SPIE, 2010. http://dx.doi.org/10.1117/12.865136.

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Leif, Robert C., Dayong Jin, James Piper, et al. "Calibration beads containing luminescent lanthanide ion complexes." In Biomedical Optics (BiOS) 2008, edited by Daniel L. Farkas, Dan V. Nicolau, and Robert C. Leif. SPIE, 2008. http://dx.doi.org/10.1117/12.762110.

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Knyazev, Andrey, Maxim Karyakin, Dmitry Lapaev, Vladimir Lobkov, and Yury Galyametdinov. "Luminescent materials based on anisometric lanthanide complexes." In IV International Conference on Applications of Optics and Photonics, edited by Manuel Filipe P. Martins Costa. SPIE, 2019. http://dx.doi.org/10.1117/12.2530946.

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Karout, H. El, A. Andrushchak, Z. Sofiani, Y. El Kouari, and B. Sahraoui. "Selected Lanthanide Complexes for Nonlinear Optical Applications." In 2023 23rd International Conference on Transparent Optical Networks (ICTON). IEEE, 2023. http://dx.doi.org/10.1109/icton59386.2023.10207554.

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Miroshnichenko, Anna S., Ivan S. Mukhin, and Regina M. Islamova. "Bioinspired Self-Healing Luminescent Lanthanide Bipyridinedicarboxiamide Complexes." In IOCB 2024. MDPI, 2024. http://dx.doi.org/10.3390/proceedings2024107006.

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Kawahara, Kosuke, Yuta Okumura, Yuji Takiguchi, Daisuke Nakane, and Takashiro Akitsu. "Lightening calculations for Schiff base lanthanide complexes." In INTERNATIONAL CONFERENCE OF COMPUTATIONAL METHODS IN SCIENCES AND ENGINEERING ICCMSE 2022. AIP Publishing, 2024. http://dx.doi.org/10.1063/5.0192856.

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Chengelis, Demetra A., Adrienne M. Yingling, Grzegorz Filipczyk, and Stéphane Petoud. "Lanthanide complexes with more intense luminescence: a strategy for the formation of polymetallic lanthanide dendrimer complexes and semiconductor nanocrystal compounds." In Optics East 2006, edited by Nibir K. Dhar, Achyut K. Dutta, and M. Saif Islam. SPIE, 2006. http://dx.doi.org/10.1117/12.691288.

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Vallarino, Lidia M., Patrick M. Harlow, and Robert C. Leif. "Lanthanide macrocyclic complexes, 'quantum dyes': optical properties and significance." In OE/LASE'93: Optics, Electro-Optics, & Laser Applications in Science& Engineering, edited by Joseph R. Lakowicz and Richard B. Thompson. SPIE, 1993. http://dx.doi.org/10.1117/12.144724.

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Reports on the topic "Lanthanoid complexes"

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Evans, W. J. Synthesis and chemistry of yttrium and lanthanide metal complexes. Office of Scientific and Technical Information (OSTI), 1991. http://dx.doi.org/10.2172/6267724.

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Brichart, Thomas, Mahmoud Ould Metidji, Mario Silva, Sissel Opsahl Viig, and Tor Bjørnstad. Lanthanide-Complexed Esters for Single-Well SOR Measurements. University of Stavanger, 2021. http://dx.doi.org/10.31265/usps.208.

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The main objective has been to improve the prevailing single-well chemical tracer push-and-pull technique, SWCTT, for measurement of residual oil saturation (SOR) in defined pay zones in a single well test [1,2,3] after water injection on the following subjects: • Improvement in tracer detection limits by a factor &gt; 1000 • On-site or even on-line detection of tracer signal in true time • Reduction in the needed amount of tracer by a factor of &gt; 1000 • Reduced footprint on production platforms during tracer operation The intended audience and technology users are oil and service companies
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Bromm, A. J. Jr, L. M. Vallarino, R. C. Leif, and J. R. Quagliano. The addition of a second lanthanide ion to increase the luminescence of europium(III) macrocyclic complexes. Office of Scientific and Technical Information (OSTI), 1998. http://dx.doi.org/10.2172/314151.

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Evans, W. J. Synthesis and chemistry of yttrium and lanthanide metal complexes. Progress report, March 15, 1991--March 14, 1992. Office of Scientific and Technical Information (OSTI), 1991. http://dx.doi.org/10.2172/10104789.

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