Academic literature on the topic 'Lead zirconate titanate doped with lanthanum or barium'

The physical layering of sol-gel-derived lead zirconate titanate (PZT) 52/48 and lanthanum-doped PZT (PLZT) 2/52/48 on platinized silicon substrates was investigated to determine if the ferroelectric properties and fatigue resistance could be influenced by different layering sequences. Monolithic thin films of PZT and PLZT were characterized to determine their ferroelectric properties. Sandwich structures of Pt/PZT/PLZT/PLZT/PZT/Au and Pt/PLZT/PZT/PZT/PLZT/Au and alternating structures of Pt/PZT/PLZT/PZT/PLZT/Au and Pt/PLZT/PZT/PLZT/PZT/Au were then fabricated and characterized. X-ray photoelectron spectroscopy depth profiles revealed that the layering sequence remained intact up to 700 °C for 45 min. It was found that the end layers in the multilayered films had a significant influence on the resulting hysteresis behavior and fatigue resistance. A direct correlation of ferroelectric properties and fatigue resistance can be made between the data obtained from the sandwiched structures and their end-layer monolithic thin film counterparts. Alternating structures also showed an improvement in the fatigue resistance while the polarization values remained between those for PZT and PLZT thin films.

The lanthanum-doped lead zirconate titanate ceramic is a well-known photostrictive material and has been studied extensively as wireless photo-controlled microactuators for its characteristic of photostrictive effect. However, the hysteresis phenomenon between photovoltage and photo-induced deformation has seriously hindered the application of the high-frequency dynamic field. The primary purpose of this article is to propose a photo response torsion actuator driven by opto-electrostatic hybrid driving method based on lanthanum-doped lead zirconate titanate ceramic to achieve the goal of rapid response regardless of the hysteresis phenomenon. To this end, this study observed the driving voltage, the relationship between the photovoltaic voltage of lanthanum-doped lead zirconate titanate ceramic and the deflection of the actuator, and the influence of different loads on driving characteristics through a series of experiments. From these experiments, the results indicate that when lanthanum-doped lead zirconate titanate ceramic is irradiated by ultraviolet light, the photovoltaic voltage with load is lower than that without load. The trend of deformation curves is in agreement with the trend of the driving voltage curves under different loads conditions. And the deformation of torsion actuator increases with the increase in light intensity. Therefore, the photo response torsion actuator driven by the opto-electrostatic hybrid driving method can control the deformation with rapid response speed effectively; meanwhile, the hysteresis phenomenon can be ignored.

Controllable photoinduced scatterers were investigated in Nd³⁺-doped lead lanthanum zirconate titanate (PLZT) perovskite ceramics, the total number of which will increase dramatically with the induction of light intensity.

The aim of this work was to obtain Pb0.92(La0.08)(Zr0.65Ti0.35)0.98O3 materials co-doped with two different lanthanide ions (Ln3+) and characterization how they influence on the physical properties of prepared 8/65/35 PLZT: Ln3+ ceramics. As a co-dopant, praseodymium (Pr3+) and neodymium (Nd3+) ions were used at the concentration of 0.0 and 0.5 wt.% respectively. The ceramic powders of 8/65/35 PLZT, PLZT:Pr3+ as well PLZT:Nd3+ were synthesized by conventional ceramic route, from high purity raw oxide materials (>99,9%). All compositions of the ceramic samples were sintered via single time process at Ts=1200°C/3h, by the hot uniaxial pressing method. Performed measurements have shown dependence of used dopant on structure, microstructure, and dielectric as well optical properties of the fabricated 8/65/35 PLZT: Ln3+ materials.

Les principaux objectifs de cette thèse de doctorat ont été de réaliser la synthèse et la caractérisation structurale et dieléctrique des échantillons céramiques ferroélectriques appartenants au système Pb1-xRxZr0,40Ti0,60O3 avec R = Ba et La et x entre 0,00 à 0,50. Ce système a été choisi car il est un matériel ferroélectrique qui a des propriétés physiques intéressantes, comme haute constante diélectrique et piézo-électrique, ce qui les rend candidats potentiels pour des applications telles que les condensateurs à haute densité d'énergie et les actionneurs. Afin d'évaluer le comportement relaxor, les études ont été effectuées avec la variation de la composition, du type de dopage (par des atomes de la même ou différente valence – La ou Ba) et de la taille des particules de céramique, dès l'échelle micrométrique à l'échelle nanométrique. Les échantillons céramiques micrométriques ont été préparées par la méthode de réaction de l'état solide et la frittage dans un four électrique conventionnel. Les données fournies par la technique de diffraction des rayons X de cettes échantillons ont montré une transition de une phase tétragonal pour une phase cubique avec l'augmentation de la concentration de cations substituants. Ces changements ont été attribués à une diminution de distorsion dans le maille cristallographique en raison de l'apparition de défauts causés par l'incorporation de dopage. Les mesures électriques ont été obtenues par spectroscopie d'impédance et ont montré un comportement électrique relaxor à partir de compositions avec plus de 12% at. La et de 30% at. Ba pour les systèmes PLZT et PBZT, respectivement. Les mesures électriques de l'échantillon avec 12%, 13% et 14% at. La et 30% at. Ba présentent un comportement qui, selon la littérature, est liée à une transition de phase spontanée d'un comportement relaxor et au comportement d'un matérial ferroélectrique normal. La technique de diffraction des rayons X a également été utilisé pour surveiller le processus de transition de phase en fonction de la température pour échantillons PLZT et PBZT. Il est possible de voir le changement de structure tétragonal de groupe d'espace P4mm en structure cubique de groupe d'espace Pm-3m. En ce qui concerne la structure locale, nous avons effectué des mesures expérimentales avec la technique de spectroscopie d'absorption des rayons X dans le spectre XANES aux seuils d'absorption de différents éléments pour les échantillons PLZT et PBZT. Dans les cas de seuil d'absorption K du titane, l'intégration de La et Ba atomes de la structure du PZT entraîne une diminution dans le désordre local dans le octaèdre TiO6, vérifié par la réduction du déplacement statique de atome Ti au centre de l'octaèdre TiO6. Cette évolution est plus faible pour les échantillons que montrent le comportement relaxor. Les spectres d'absorption EXAFS au seuil LIII du plomb et seuil K du zirconium ont été effectués aussi et ces mesures indiquent que la structure locale autour des atomes de plomb ou de zirconium est également affectée par l'introduction des atomes de La et Ba dans la structure. Le comportement relaxor a été aussi étudié en fonction de la taille de grain dans une échelle nanométrique. Ainsi les échantillons de compostions PZT, PLZT11 et PBZT10 ont eté préparés en utilisant la méthode de synthèse chimique de polymères précurseurs et le processus de frittage par spark plasma. La caractérisation de ces échantillons par diffraction de rayons X montrent que les paramétres de maille réduisent en comparison avec les échantillons de même composition et taille de grain micrométrique. Pour l'échantillon de composition PLZT11, il est possible de constater le comportement relaxor par les mesures de la constante dieléctrique en fonction de la température. Les changements quand la taille de grain est dans une échelle nanométrique sont attribués à la limitation des frontières de grains, qui provoquent un systéme de tension, responsable de la diminuition des paramétres de maille, et provoquent l'apparition de domaines ferroélectriques nanométriques
The main objectives of this doctoral thesis were the synthesis and structural characterization of Pb1-xRxZr0.40Ti0.60O3 ferroelectric ceramic samples, with R = Ba and La and x between 0.00 to 0.50. This system was chosen because its interesting physical properties such as high dielectric and piezoelectric constant. These characteristics make it potential candidate for applications such as capacitors in high energy density and actuators. To evaluate the relaxor behavior, the studies were carried out with the change in the composition, type of doping (by atoms of the same or different valence – La or Ba) and the particle size of ceramics, from the micrometer to nanometer scale. Micrometric ceramic samples are prepared by the method of reaction of solid state and sintering in a conventional furnace. The characterization with X-ray diffraction technique of these samples showed a transition from tetragonal phase to a cubic phase with increase of the dopping cation concentration. These changes have been attributed to the appearance of defects caused by the incorporation of La or Ba cations. Electrical measurements were obtained by impedance spectroscopy and showed a electric relaxor behavior from compositions with more than 12 at. % of La and the 30 at. % of Ba for PLZT and PBZT systems, respectively. These measurements for the samples with 12 at. %, 13 at. % and 14 at. % of La and 30 at. % of Ba exhibit a behavior that, according to the literature, is related to a spontaneous phase transition from a relaxor behavior to a normal ferroelectric behsvior. The technique of X-ray diffraction also been used to monitor the phse transition phase as a function of the temperature for PLZT and PBZT samples. It is possible to note the change in a tetragonal structure with P4mm space group to a cubic structure with Pm-3m space group. Concerning the local structure, XANES spectra in the absorption edge of various elements in PLZT and PBZT samples were performed. In the cases of Ti K-edge absorption, the dopping of La and Ba atoms in the PZT structure leads to a decrease of the local disorder in the TiO6 octahedron and it is verified the reduction of static displacement of Ti atom in the center of the TiO6 octahedron. This displacement is lower for samples that show relaxor behavior. The EXAFS measurements in Pb LIII-edge and Zr K-edge were performed and also indicate that local structure around lead or zirconium atoms is also affected by the introduction of La and Ba atoms in the PZT structure. The relaxor behavior was also studied depending on the size of particle size in a nanometer scale. Thus samples PZT, PLZT11 and PBZT10 compositions were prepared using the synthesis method of precursor polymers and the process of sintering by spark plasma. Characterization of these samples by X-ray diffraction shows that the lattice parameters are reduced in comparison with samples of the same composition and micrometer particle size. For PLZT11 composition, it is possible to observe a relaxor behavior by measurement of the dielectric permittivity as a function of the temperature. These changes when the grain size is in a nanoscale are attributed to the grain boundaries, that are responsible for the decrease in the lattice parameters and the appearance of ferroelectric nanodomains

The literature shows there is confusion regarding the factors that control the electrical properties and observed lattice response of PLZT. This study aims to characterise the electrical properties and study the lattice response of PLZT to help resolve these issues. Powders with varying compositions were produced by the mixed oxide process. A range of specimen grain sizes was produced by varying the temperature and hold time during pressure-less sintering. Lanthanum affects the grain growth and diffusion rate, changing the grain size, density and reducing the axial ratio. Strain and polarisation hysteresis, d33 , and permittivity with temperature were all measured. Lanthanum increases the d33 value and reduces the Curie temperature and coercive field strength. However, the results show that grain size and axial ratio also alter these properties. The lattice response was determined using neutron diffraction. Specific planes' lattice spacings, in different spatial directions, were measured by re-orientating the specimens relative to the neutron beam. The spacing of these planes was found to vary with applied field, as a result of the converse-piezoelectric effect, and clastic misfit strains resulting from domain reorientation in surrounding grains. Lattice strain in the nonpolar direction larger than that in the polar direction was observed, along with a small tensile lattice strain in the polar direction after poling. The large strain in the non-polar direction is attributed to elastic misfit strains, but an additional voltageinduced strain was found in that direction, potentially a result of the elastic misfit strain distorting the lattice and allowing the polarisation to align with the field. The tensile poling strain result is explained by a change in the crystal structure, or by considering elastic misfit strains between neighbouring domains. This study has discussed the factors affecting the macroscopic piezoelectric properties, and contributed to the understanding of the underlying lattice response. Supplied by The British Library - 'The world's knowledge'

Waste heat can be directly converted into electrical energy by performing the Olsen cycle on pyroelectric materials. The Olsen cycle consists of two isothermal and two isoelectric field processes in the electric displacement versus electric field diagram. This paper reports on the energy harvested by lanthanum doped lead zirconate titanate (8/65/35 PLZT) subjected to the Olsen cycle. The material was alternatively dipped into a cold and a hot silicone oil bath under specified electric fields. A maximum energy density of 770 J/L per cycle corresponding to a power density of 9.6 W/L was obtained for temperatures between 25 and 160°C and electric fields cycled between 0.2 and 4.5 MV/m.

Photostrictive materials are lanthanum-modified lead zirconate titanate (Pb, La)(Zr, Ti) O3 ceramics doped with WO3, called PLZT, exhibit large photostriction under uniform illumination of high-energy light. Photostrictive materials are ferrodielectric ceramics that have a photostrictive effect. Photostriction arises from a superposition of the photovoltaic effect, i.e. the generation of large voltage from the irradiation of light, and the converse-piezoelectric effect, i.e. expansion or contraction under the voltage applied. When non-centrosymmetric materials, such as ferroelectric single crystals or polarized ferroelectric ceramics, are uniformly illuminated, a high voltage, considerably exceeding the band gap energy, is generated. Along with this photovoltage, mechanical strain is also induced due to the converse piezoelectric effect. Photostrictive materials offer the potential for actuators with many advantages over traditional transducing electromechanical actuators made of shape memory alloys and electroceramics (piezoelectric and electrostrictive). Drawback of traditional actuators is that they require hard-wired connections to transmit the control signals which introduce electrical noise into the control signals; on the other hand PLZT actuators offer non-contact actuation, remote control, and immune from electric/magnetic disturbances. Some experimental research has been conducted on the use of PLZT materials, such as optical motor as an electromechanical device suitable for miniaturization, micro-waking machine, photo driven relay device using PLZT bimorphs and high speed (less than 10 ns), low-voltage, low power consumption optical switch. Authors have developed a computational method and implemented in an in-house finite element code which will be useful for designing systems incorporating thin film photostrictive actuators. The purpose of this current research work is to design and develop an experimental test set-up for photostriction effect measurement of PLZT thin film of different thickness, size and location on silicon wafer as smart beams, which may be useful for various MEMS device as optical actuator. The experimental results will be verified by comparing with the FEA modeling results.