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1

Gupta, Aman, Ditipriya Bose, Sandeep Tiwari, Vikrant Sharma, and Jai Prakash. "Techno–economic and environmental impact analysis of electric two-wheeler batteries in India." Clean Energy 8, no. 3 (May 3, 2024): 147–56. http://dx.doi.org/10.1093/ce/zkad094.

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Abstract This paper presents a comprehensive techno–economic and environmental impact analysis of electric two-wheeler batteries in India. The technical comparison reveals that sodium-ion (Na-ion) and lithium-ion (Li-ion) batteries outperform lead–acid batteries in various parameters, with Na-ion and Li-ion batteries exhibiting higher energy densities, higher power densities, longer cycle lives, faster charge rates, better compactness, lighter weight and lower self-discharge rates. In economic comparison, Na-ion batteries were found to be ~12–14% more expensive than Li-ion batteries. However, the longer lifespans and higher energy densities of Na-ion and Li-ion batteries can offset their higher costs through improved performance and long-term savings. Lead–acid batteries have the highest environmental impact, while Li-ion batteries demonstrate better environmental performance and potential for recycling. Na-ion batteries offer promising environmental advantages with their abundance, lower cost and lower toxic and hazardous material content. Efficient recycling processes can further enhance the environmental benefits of Na-ion batteries. Overall, this research examines the potential of Na-ion batteries as a cheaper alternative to Li-ion batteries, considering India’s abundant sodium resources in regions such as Rajasthan, Chhattisgarh, Jharkhand and others.
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Conder, Joanna, Cyril Marino, Petr Novák, and Claire Villevieille. "Do imaging techniques add real value to the development of better post-Li-ion batteries?" Journal of Materials Chemistry A 6, no. 8 (2018): 3304–27. http://dx.doi.org/10.1039/c7ta10622j.

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Imaging techniques are increasingly used to study Li-ion batteries and, in particular, post-Li-ion batteries such as Li–S batteries, Na-ion batteries, Na–air batteries and all-solid-state batteries. Herein, we review recent advances in the field made through the use of these techniques.
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3

Walter, Marc, Maksym V. Kovalenko, and Kostiantyn V. Kravchyk. "Challenges and benefits of post-lithium-ion batteries." New Journal of Chemistry 44, no. 5 (2020): 1677–83. http://dx.doi.org/10.1039/c9nj05682c.

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4

Peng, Qiong, Javed Rehman, Kamel Eid, Ayman S. Alofi, Amel Laref, Munirah D. Albaqami, Reham Ghazi Alotabi, and Mohamed F. Shibl. "Vanadium Carbide (V4C3) MXene as an Efficient Anode for Li-Ion and Na-Ion Batteries." Nanomaterials 12, no. 16 (August 17, 2022): 2825. http://dx.doi.org/10.3390/nano12162825.

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Li-ion batteries (LIBs) and Na-ion batteries (SIBs) are deemed green and efficient electrochemical energy storage and generation devices; meanwhile, acquiring a competent anode remains a serious challenge. Herein, the density-functional theory (DFT) was employed to investigate the performance of V4C3 MXene as an anode for LIBs and SIBs. The results predict the outstanding electrical conductivity when Li/Na is loaded on V4C3. Both Li2xV4C3 and Na2xV4C3 (x = 0.125, 0.5, 1, 1.5, and 2) showed expected low-average open-circuit voltages of 0.38 V and 0.14 V, respectively, along with a good Li/Na storage capacity of (223 mAhg−1) and a good cycling performance. Furthermore, there was a low diffusion barrier of 0.048 eV for Li0.0625V4C3 and 0.023 eV for Na0.0625V4C3, implying the prompt intercalation/extraction of Li/Na. Based on the findings of the current study, V4C3-based materials may be utilized as an anode for Li/Na-ion batteries in future applications.
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5

Tian, Meng, Chaohui Wei, Jinlei Zhang, and Zhaoxiang Wang. "Electronic properties and storage capability of two-dimensional nitridosilicate MnSi2N4 from first-principles." AIP Advances 12, no. 11 (November 1, 2022): 115127. http://dx.doi.org/10.1063/5.0127013.

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Through first-principles calculations, we successfully identified a two-dimensional layered nitridosilicate-MnSi2N4 in hexagonal structure, as a novel anode for lithium (Li) and sodium (Na) ion batteries. Phonon and molecular dynamics simulations manifest the favorable dynamic stability of MnSi2N4. The predicted material exhibits metallic behavior with high Young’s modulus of 457 GPa and aqueous insolubility. MnSi2N4 possesses low diffusion barrier for Li (0.32 eV) and Na (0.19 eV), as well as high storage capacity as an anode for Li (320 mAh g−1) and Na (160 mAh g−1) ion batteries, respectively. These properties, including excellent electronic conductivity, low diffusion barrier, and high storage capacity, enable MnSi2N4 a promising anode for Li and Na ion batteries.
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6

Kim, Haegyeom, Jihyun Hong, Kyu-Young Park, Hyungsub Kim, Sung-Wook Kim, and Kisuk Kang. "Aqueous Rechargeable Li and Na Ion Batteries." Chemical Reviews 114, no. 23 (September 11, 2014): 11788–827. http://dx.doi.org/10.1021/cr500232y.

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7

Kotobuki, Masashi. "Recent progress of ceramic electrolytes for post Li and Na batteries." Functional Materials Letters 14, no. 03 (February 18, 2021): 2130003. http://dx.doi.org/10.1142/s1793604721300036.

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Recently, post Li batteries have been intensively researched due to high cost and localization of Li sources, especially for large-scale applications. Concurrently, ceramic electrolytes for post Li batteries also gain much attention to develop all-solid-state post Li batteries. The most intensively researched post Li battery is Na battery because of chemical and electrochemical similarities between Li and Na elements. Many good review papers about Na battery have been published including Na-ion conductive ceramic electrolytes. Contrary, ceramic electrolytes for other post Li batteries like K, Mg, Ca, Zn and Al batteries are hardly summarized. In this review, research on ceramic electrolytes for K, Mg, Ca, Zn and Al batteries is analyzed based on latest papers published since 2019 and suggested future research direction of ceramic electrolytes for post-Li batteries.
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8

Puttaswamy, Rangaswamy, Ranjith Krishna Pai, and Debasis Ghosh. "Recent progress in quantum dots based nanocomposite electrodes for rechargeable monovalent metal-ion and lithium metal batteries." Journal of Materials Chemistry A 10, no. 2 (2022): 508–53. http://dx.doi.org/10.1039/d1ta06747h.

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This review summarizes the recent progress in quantum dot based nanocomposites as electrode materials in Li/Na/K-ion batteries, as cathodes in Li–S and Li–O2 batteries and in improving the electrochemical performance of Li metal anode batteries.
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9

Ustyuzhanina, S. V., and A. A. Kistanov. "Pervoprintsipnye issledovaniya adsorbtsii Li i Na na poverkhnosti monosloya MgCl2." Письма в Журнал экспериментальной и теоретической физики 118, no. 9-10 (11) (December 15, 2023): 683–88. http://dx.doi.org/10.31857/s1234567823210097.

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Ab initio calculations have been performed to study the dynamic stability of a new MgCl2 monolayer and the formation of point defects in it. The possibility of using the MgCl2 monolayer in Li- and Na-ion batteries has been analyzed. It has been shown that the MgCl2 monolayer has the dynamic stability but can contain point defects. These point defects can improve the adsorption capability of the MgCl2 monolayer with respect to Li and Na atoms. The results obtained in this work indicate that the MgCl2 monolayer is a promising material for application in Li- and Na-ion batteries.
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10

Sun, Meiling, Gwenaëlle Rousse, Matthieu Saubanère, Marie-Liesse Doublet, Daniel Dalla Corte, and Jean-Marie Tarascon. "A2VO(SO4)2 (A = Li, Na) as Electrodes for Li-Ion and Na-Ion Batteries." Chemistry of Materials 28, no. 18 (September 14, 2016): 6637–43. http://dx.doi.org/10.1021/acs.chemmater.6b02759.

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11

Tada, Kohei, Hiroyuki Ozaki, Tetsu Kiyobayashi, Mitsunori Kitta, and Shingo Tanaka. "How does the Li-distribution in the 16d sites determine the stability of A3(Li,Ti5)O12 (A = Li and Na)?" RSC Advances 10, no. 55 (2020): 33509–16. http://dx.doi.org/10.1039/d0ra06125e.

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Li3(Li,Ti5)O12 (LTO) is a stable and safe negative electrode material for Li-ion batteries, and its Na substitute Na3(Li,Ti5)O12 (NTO) is a counterpart for the Na-ion battery.
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12

Campéon, Benoît D. L., Chen Wang, and Yuta Nishina. "Iron nanoparticle templates for constructing 3D graphene framework with enhanced performance in sodium-ion batteries." Nanoscale 12, no. 42 (2020): 21780–87. http://dx.doi.org/10.1039/d0nr05682k.

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13

Kubota, Kei, Mouad Dahbi, Tomooki Hosaka, Shinichi Kumakura, and Shinichi Komaba. "Towards K-Ion and Na-Ion Batteries as “Beyond Li-Ion”." Chemical Record 18, no. 4 (February 14, 2018): 459–79. http://dx.doi.org/10.1002/tcr.201700057.

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14

Rudola, Ashish, Christopher J. Wright, and Jerry Barker. "Reviewing the Safe Shipping of Lithium-Ion and Sodium-Ion Cells: A Materials Chemistry Perspective." Energy Material Advances 2021 (November 25, 2021): 1–12. http://dx.doi.org/10.34133/2021/9798460.

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High energy density lithium-ion (Li-ion) batteries are commonly used nowadays. Three decades’ worth of intense research has led to a good understanding on several aspects of such batteries. But, the issue of their safe storage and transportation is still not widely understood from a materials chemistry perspective. Current international regulations require Li-ion cells to be shipped at 30% SOC (State of Charge) or lower. In this article, the reasons behind this requirement for shipping Li-ion batteries are firstly reviewed and then compared with those of the analogous and recently commercialized sodium-ion (Na-ion) batteries. For such alkali-ion batteries, the safest state from their active materials viewpoint is at 0 V or zero energy, and this should be their ideal state for storage/shipping. However, a “fully discharged” Li-ion cell used most commonly, composed of graphite-based anode on copper current collector, is not actually at 0 V at its rated 0% SOC, contrary to what one might expect—the detailed mechanism behind the reason for this, namely, copper dissolution, and how it negatively affects cycling performance and cell safety, will be summarized herein. It will be shown that Na-ion cells, capable of using a lighter and cheaper aluminum current collector on the anode, can actually be safely discharged to 0 V (true 0% SOC) and beyond, even to reverse polarity (negative voltages). It is anticipated that this article spurs further research on the 0 V capability of Na-ion systems, with some suggestions for future studies provided.
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15

Liang, Hao-Jie, Bao-Hua Hou, Wen-Hao Li, Qiu-Li Ning, Xu Yang, Zhen-Yi Gu, Xue-Jiao Nie, Guang Wang, and Xing-Long Wu. "Staging Na/K-ion de-/intercalation of graphite retrieved from spent Li-ion batteries: in operando X-ray diffraction studies and an advanced anode material for Na/K-ion batteries." Energy & Environmental Science 12, no. 12 (2019): 3575–84. http://dx.doi.org/10.1039/c9ee02759a.

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16

Tarascon, Jean-Marie. "Na-ion versus Li-ion Batteries: Complementarity Rather than Competitiveness." Joule 4, no. 8 (August 2020): 1616–20. http://dx.doi.org/10.1016/j.joule.2020.06.003.

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17

Kumar, Saurabh, R. Ranjeeth, Neeraj Kumar Mishra, Rajiv Prakash, and Preetam Singh. "NASICON-structured Na3Fe2PO4(SO4)2: a potential cathode material for rechargeable sodium-ion batteries." Dalton Transactions 51, no. 15 (2022): 5834–40. http://dx.doi.org/10.1039/d2dt00780k.

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18

Han, Ying, Ning Lin, Tianjun Xu, Tieqiang Li, Jie Tian, Yongchun Zhu, and Yitai Qian. "An amorphous Si material with a sponge-like structure as an anode for Li-ion and Na-ion batteries." Nanoscale 10, no. 7 (2018): 3153–58. http://dx.doi.org/10.1039/c7nr08886h.

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19

Li, Min, Angelo Mullaliu, Stefano Passerini, and Marco Giorgetti. "Titanium Activation in Prussian Blue Based Electrodes for Na-ion Batteries: A Synthesis and Electrochemical Study." Batteries 7, no. 1 (January 7, 2021): 5. http://dx.doi.org/10.3390/batteries7010005.

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Sodium titanium hexacyanoferrate (TiHCF, Na0.86Ti0.73[Fe(CN)6]·3H2O) is synthesized by a simple co-precipitation method in this study. Its crystal structure, chemical composition, and geometric/electronic structural information are investigated by X-ray powder diffraction (XRPD), microwave plasma-atomic emission spectroscopy (MP-AES), and X-ray absorption spectroscopy (XAS). The electroactivity of TiHCF as a host for Li-ion and Na-ion batteries is studied in organic electrolytes. The results demonstrate that TiHCF is a good positive electrode material for both Li-ion and Na-ion batteries. Surprisingly, however, the material shows better electrochemical performance as a Na-ion host, offering a capacity of 74 mAh g−1 at C/20 and a 94.5% retention after 50 cycles. This is due to the activation of Ti towards the redox reaction, making TiHCF a good candidate electrode material for Na-ion batteries.
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20

Li, Min, Angelo Mullaliu, Stefano Passerini, and Marco Giorgetti. "Titanium Activation in Prussian Blue Based Electrodes for Na-ion Batteries: A Synthesis and Electrochemical Study." Batteries 7, no. 1 (January 7, 2021): 5. http://dx.doi.org/10.3390/batteries7010005.

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Sodium titanium hexacyanoferrate (TiHCF, Na0.86Ti0.73[Fe(CN)6]·3H2O) is synthesized by a simple co-precipitation method in this study. Its crystal structure, chemical composition, and geometric/electronic structural information are investigated by X-ray powder diffraction (XRPD), microwave plasma-atomic emission spectroscopy (MP-AES), and X-ray absorption spectroscopy (XAS). The electroactivity of TiHCF as a host for Li-ion and Na-ion batteries is studied in organic electrolytes. The results demonstrate that TiHCF is a good positive electrode material for both Li-ion and Na-ion batteries. Surprisingly, however, the material shows better electrochemical performance as a Na-ion host, offering a capacity of 74 mAh g−1 at C/20 and a 94.5% retention after 50 cycles. This is due to the activation of Ti towards the redox reaction, making TiHCF a good candidate electrode material for Na-ion batteries.
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21

Mukherjee, Ayan, Rosy, Tali Sharabani, Ilana Perelshtein, and Malachi Noked. "High-rate Na0.7Li2.3V2(PO4)2F3 hollow sphere cathode prepared via a solvothermal and electrochemical ion exchange approach for lithium ion batteries." Journal of Materials Chemistry A 8, no. 40 (2020): 21289–97. http://dx.doi.org/10.1039/d0ta07912j.

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Electrochemical ion exchange of Na+ with Li+ to design high rate Na0.7Li2.3V2(PO4)2F3 hollow spherical cathode for lithium ion batteries.
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22

Chu, Kainian, Mulin Hu, Bo Song, Senlin Chen, Junyu Li, Fangcai Zheng, Zhiqiang Li, Rui Li, and Jingya Zhou. "MOF-derived nitrogen-doped porous carbon nanofibers with interconnected channels for high-stability Li+/Na+ battery anodes." RSC Advances 13, no. 9 (2023): 5634–42. http://dx.doi.org/10.1039/d2ra08135k.

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Heteroatom-doped porous carbon materials have been widely used as anode materials for Li-ion and Na-ion batteries, however, improving the specific capacity and long-term cycling stability of ion batteries remains a major challenge.
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23

Anh Nguyen, Hoang, Pham Phuong Nam Le, Le Thanh Nguyen Huynh, Tran Van Man, and My Loan Phung Le. "Investigation of Na-immigration into olivine LiFePO4." Science and Technology Development Journal - Natural Sciences 3, no. 1 (April 26, 2019): 46–54. http://dx.doi.org/10.32508/stdjns.v3i1.724.

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In 21th century, rechargeable batteries are main key of modern technology in many applications from portable devices (smartphone, laptop) to large-scale (hydride electric vehicle-HEV, smart grid system). Among the rechargeable batteries, Li-ion battery (LIB) is outstanding member due to the highest gravimetric as well as volumetric capacity; and Sodium-ion batteries (SIBs) can have contribution to alternating LIBs in large-scale application. Li-ion and Na-ion batteries have the same configuration with an insertion/extraction reversible of Li+ ions and Na+ ions into electrode positive and negative during charge-discharge process. This work aimed to investigate Na-immigration into olivine LiFePO4. The olivine phase LiFePO4 was prepared by hydrothermal process. The synthesized LiFePO4 was characterized the structure, morphology and electrochemical properties. The XRD pattern showed the high crystalline and, the Rietveld refinement with X2 = 2.32% confirmed the highly pure olivine phase without impurity. The SEM images exhibited the uniform and good distribution of synthesized olivine in submicrometric scale. The delithiated phase FePO4 was prepared by electrochemical oxidation at low rate C/20. The charge-discharge curves demonstrated the reversible Na-immigration into olivine host with a highest capacity of 80 mAh/g, the cyclability was found out in 73 mAh/g upon 30 cycles. The ex-situ XRD (electrode after electrochemical oxidation, electrode after Na-insertion) revealed the stability of FePO4 framework during Na-immigration.
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24

Xu, Zhijie, Fangxu Hu, De Li, and Yong Chen. "Electrochemical Oscillation during Galvanostatic Charging of LiCrTiO4 in Li-Ion Batteries." Materials 14, no. 13 (June 29, 2021): 3624. http://dx.doi.org/10.3390/ma14133624.

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In the late 1960s, the establishment of Prigogine’s dissipative structure theory laid the foundation for the (electro)chemical oscillation phenomenon, which has been widely investigated in some electrochemical reactions, such as electro-catalysis and electro-deposition, while the electrochemical oscillation of Li-ion batteries has just been discovered in spinel Li4Ti5O12 a few years before. In this work, spinel LiCrTiO4 samples were synthesized by using a high-temperature solid-state method, characterized with SEM (Scanning electron microscope), XRD (X-ray diffraction), Raman and XPS (X-ray photoelectron spectroscopy) measurements, and electrochemically tested in Li-ion batteries to study the electrochemical oscillation. When sintering in a powder form at a temperature between 800 and 900 °C, we achieved the electrochemical oscillation of spinel LiCrTiO4 during charging, and it is suppressed in the non-stoichiometric LiCrTiO4 samples, especially for reducing the Li content or increasing the Cr content. Therefore, this work developed another two-phase material as the powder-sintered LiCrTiO4 exhibiting the electrochemical oscillation in Li-ion batteries, which would inspire us to explore more two-phase electrode materials in Li-ion batteries, Na-ion batteries, etc.
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25

Arroyo-De Dompablo, M. Elena. "Understanding sodium versus lithium intercalation potentials of electrode materials for alkali-ion batteries." Functional Materials Letters 07, no. 06 (December 2014): 1440003. http://dx.doi.org/10.1142/s1793604714400037.

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Differences in average voltages for the alkali ion intercalation ( Li , Na ) in a variety of electrode materials are investigated. The average Li and Na insertion potentials in the cavities of ◻ ReO 3-perovskite, ramsdellite-◻ Ti 2 O 4, layered-◻2 A 2 Ti 3 O 7 ( A = Li , Na ) and NASICON-◻ Na 3 Ti 2( PO 4)3 have been calculated by first principles calculations at the density functional theory level. The results identify the type of site occupied by the inserted ion as the relevant structural parameter. Occupation of large sites (c.n. = 12, 8) might yield Na insertion voltages higher than Li ones. On the other extreme, occupation of tetrahedral sites raises the Li insertion voltage as much as 0.8 V above the Na one. For octahedral sites the higher polarizing character of Li ions vs. Na ions acts as a key-factor to bring the Li intercalation voltage above that of Na intercalation.
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26

Ko, Wonseok, Bonyoung Koo, Hyunyoung Park, Jungmin Kang, and Jongsoon Kim. "Recent Progress of Cathode Materials for Na-ion batteries." Ceramist 25, no. 1 (March 31, 2022): 76–89. http://dx.doi.org/10.31613/ceramist.2022.25.1.04.

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Recently, many researchers focus on Na-ion batteries as an alternative to Li-ion batteries, owing to their low cost and high natural abundance. However, they suffer from low electrochemical performance and large volume expansion, which makes difficult to industrial application. Therefore, various strategies have been proposed to address the current issues, such as particle-size control, surface-coating, and application of electrode material with various crystal structures. Herein, we briefly introduce and discuss the recent research with development trend of cathode material for Na-ion batteries.
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27

Schneider, Simon F., Christian Bauer, Petr Novák, and Erik J. Berg. "A modeling framework to assess specific energy, costs and environmental impacts of Li-ion and Na-ion batteries." Sustainable Energy & Fuels 3, no. 11 (2019): 3061–70. http://dx.doi.org/10.1039/c9se00427k.

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28

Wei, Zengxi, Lei Wang, Ming Zhuo, Wei Ni, Hongxia Wang, and Jianmin Ma. "Layered tin sulfide and selenide anode materials for Li- and Na-ion batteries." Journal of Materials Chemistry A 6, no. 26 (2018): 12185–214. http://dx.doi.org/10.1039/c8ta02695e.

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In this review, we report the recent research progress in the area of design and synthesis of tin sulfide and selenide (SnS, SnS2, SnSe, and SnSe2) based anode materials for Li-ion batteries and Na-ion batteries.
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29

Rahman, Muhammad Mominur, and Feng Lin. "Oxygen Redox Chemistry in Rechargeable Li-Ion and Na-Ion Batteries." Matter 4, no. 2 (February 2021): 490–527. http://dx.doi.org/10.1016/j.matt.2020.12.004.

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30

Chayambuka, Kudakwashe, Grietus Mulder, Dmitri L. Danilov, and Peter H. L. Notten. "From Li‐Ion Batteries toward Na‐Ion Chemistries: Challenges and Opportunities." Advanced Energy Materials 10, no. 38 (August 12, 2020): 2001310. http://dx.doi.org/10.1002/aenm.202001310.

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31

Robert Ilango, P., and Shengjie Peng. "Electrospinning techniques for Li, Na and K-ion batteries." Current Opinion in Electrochemistry 18 (December 2019): 106–12. http://dx.doi.org/10.1016/j.coelec.2019.10.016.

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32

Zhu, Jiajie, Husam N. Alshareef, and Udo Schwingenschlögl. "Functionalized NbS2as cathode for Li- and Na-ion batteries." Applied Physics Letters 111, no. 4 (July 24, 2017): 043903. http://dx.doi.org/10.1063/1.4985694.

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Černý, Radovan, Emilie Didelot, Yolanda Sadikin, Matteo Brighi, and Fabrizio Murgia. "Metal hydro-borates for Li- and Na-ion batteries." Acta Crystallographica Section A Foundations and Advances 74, a2 (August 22, 2018): e282-e282. http://dx.doi.org/10.1107/s2053273318090939.

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Fan, Long, Jingjing Zhang, Jianhua Cui, Yongchun Zhu, Jianwen Liang, Lili Wang, and Yitai Qian. "Electrochemical performance of rod-like Sb–C composite as anodes for Li-ion and Na-ion batteries." Journal of Materials Chemistry A 3, no. 7 (2015): 3276–80. http://dx.doi.org/10.1039/c4ta06771a.

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35

Huang, Chunlai, Junping Hu, and Chuying Ouyang. "Theoretical prediction on net boroxene as a promising Li/Na-ion batteries anode." RSC Advances 13, no. 24 (2023): 16758–64. http://dx.doi.org/10.1039/d3ra03007e.

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36

Zhang, Yujie, Jingwei Shen, Xue Li, Zhongxue Chen, Shun-an Cao, Ting Li, and Fei Xu. "Rechargeable Mg–M (M = Li, Na and K) dual-metal–ion batteries based on a Berlin green cathode and a metallic Mg anode." Physical Chemistry Chemical Physics 21, no. 36 (2019): 20269–75. http://dx.doi.org/10.1039/c9cp03836a.

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37

Søndergaard, M., K. J. Dalgaard, E. D. Bøjesen, K. Wonsyld, S. Dahl, and B. B. Iversen. "In situ monitoring of TiO2(B)/anatase nanoparticle formation and application in Li-ion and Na-ion batteries." Journal of Materials Chemistry A 3, no. 36 (2015): 18667–74. http://dx.doi.org/10.1039/c5ta04110d.

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38

Kuganathan, Navaratnarajah, Raveena Sukumar, and Poobalasuntharam Iyngaran. "Defect Properties of Li2NiGe3O8." Clean Technologies 4, no. 3 (July 1, 2022): 619–28. http://dx.doi.org/10.3390/cleantechnol4030038.

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There is a growing interest in finding a suitable electrolyte material for the construction of rechargeable Li-ion batteries. Li2NiGe3O8 is a material of interest with modest Li-ionic conductivity. The atomistic simulation technique was applied to understand the defect processes and Li-ion diffusion pathways, together with the activation energies and promising dopants on the Li, Ni, and Ge sites. The Li-Ni anti-site defect cluster was found to be the dominant defect in this material, showing the presence of cation mixing, which can influence the properties of this material. Li-ion diffusion pathways were constructed, and it was found that the activation energy for a three-dimensional Li-ion migration pathway is 0.57 eV, which is in good agreement with the values reported in the experiment. The low activation energy indicated that Li-ion conductivity in Li2NiGe3O8 is fast. The isovalent doping of Na, Fe and Si on the Li, Ni and Ge sites is energetically favorable. Both Al and Ga are candidate dopants for the formation of Li-interstitials and oxygen vacancies on the Ge site. While Li-interstitials can improve the capacity of batteries, oxygen vacancies can promote Li-ion diffusion.
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39

Sun, Ya-Nan, Liangtao Yang, Zhu-Yin Sui, Li Zhao, Mustafa Goktas, Hang-Yu Zhou, Pei-Wen Xiao, Philipp Adelhelm, and Bao-Hang Han. "Synthesis and thermodynamic investigation of MnO nanoparticle anchored N-doped porous carbon as the anode for Li-ion and Na-ion batteries." Materials Chemistry Frontiers 3, no. 12 (2019): 2728–37. http://dx.doi.org/10.1039/c9qm00599d.

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Zhao, Yang. "Interface Engineering and Understanding for the Next-Generation Batteries." ECS Meeting Abstracts MA2022-01, no. 1 (July 7, 2022): 75. http://dx.doi.org/10.1149/ma2022-01175mtgabs.

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Lithium-ion batteries (LIBs) have become the most widely used energy storage systems for portable electronic devices and electric vehicles. With the increasing requirements of high energy density, next-generation batteries, including Li-metal batteries, Na-metal batteries and solid-state batteries, have received huge attention in recent years. For most batteries, the interfacial issues between the electrolyte (both liquid and solid) and electrodes are critical factors affecting the performance of the batteries. Atomic and molecular layer deposition (ALD and MLD) are considered as ideal strategies for overcoming the interfacial issues for the batteries. In this talk, I will introduce our research about interface engineering and understanding for next-generation batteries. i) The interface is one of the key factors for the Li and Na deposition behaviors and battery performances. We developed ALD and MLD approaches to fabricate the artificial interface with significantly improved electrochemical performances and reduced dendrite formation for Li/Na metal anodes. ii) We further design different ALD/MLD thin films to stabilize the interfaces for solid-state Li batteries. iii) We have also developed ex-situ and in-situ synchrotron X-ray techniques for next-generation batteries.
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41

Lécuyer, Margaud, Marc Deschamps, Dominique Guyomard, Joël Gaubicher, and Philippe Poizot. "Electrochemical Assessment of Indigo Carmine Dye in Lithium Metal Polymer Technology." Molecules 26, no. 11 (May 21, 2021): 3079. http://dx.doi.org/10.3390/molecules26113079.

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Lithium metal batteries are inspiring renewed interest in the battery community because the most advanced designs of Li-ion batteries could be on the verge of reaching their theoretical specific energy density values. Among the investigated alternative technologies for electrochemical storage, the all-solid-state Li battery concept based on the implementation of dry solid polymer electrolytes appears as a mature technology not only to power full electric vehicles but also to provide solutions for stationary storage applications. With an effective marketing started in 2011, BlueSolutions keeps developing further the so-called lithium metal polymer batteries based on this technology. The present study reports the electrochemical performance of such Li metal batteries involving indigo carmine, a cheap and renewable electroactive non-soluble organic salt, at the positive electrode. Our results demonstrate that this active material was able to reversibly insert two Li at an average potential of ≈2.4 V vs. Li+/Li with however, a relatively poor stability upon cycling. Post-mortem analyses revealed the poisoning of the Li electrode by Na upon ion exchange reaction between the Na countercations of indigo carmine and the conducting salt. The use of thinner positive electrodes led to much better capacity retention while enabling the identification of two successive one-electron plateaus.
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42

Hu, Huating, Liming Wu, Paul Gebhardt, Xiaofei Zhang, Alexey Cherevan, Birgit Gerke, Rainer Pöttgen, Andrea Balducci, Stefano Passerini, and Dominik Eder. "Growth mechanism and electrochemical properties of hierarchical hollow SnO2 microspheres with a “chestnut” morphology." CrystEngComm 19, no. 43 (2017): 6454–63. http://dx.doi.org/10.1039/c7ce01288h.

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43

Vujkovic, Milica. "Comparison of lithium and sodium intercalation materials." Journal of the Serbian Chemical Society 80, no. 6 (2015): 801–4. http://dx.doi.org/10.2298/jsc141119127v.

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Low abundance of lithium in Earth?s crust and its high participation in overall cost of lithium-ion batteries incited intensive investigation of sodium-ion batteries, in hope that they may become similar in basic characteristics: specific energy and specific power. Furthermore, over the last years the research has been focused on the replacement of organic electrolytes of Li- and Na-ion batteries, by aqueous electrolytes, in order to simplify the production and improve safety of use. In this lecture, some recent results on the selected intercalation materials are presented: layered structure vanadium oxides, olivine and nasicon phosphates, potentially usable in both Li and Na aqueous rechargeable batteries. After their characterization by X-ray diffraction and electron microscopy, the electrochemical behavior was studied by both cyclic voltammetry and hronopotenciometry. By comparing intercalation kinetics and coulombic capacity of these materials in LiNO3 and NaNO3 solutions, it was shown that the following ones: Na1.2V3O8, Na2V6O16/C , NaFePO4/C and NaTi2(PO4)3/C may be used as electrode materials in aqueous alkali-ion batteries.
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Yang, Yingchang, Xiaobo Ji, Mingjun Jing, Hongshuai Hou, Yirong Zhu, Laibing Fang, Xuming Yang, Qiyuan Chen, and Craig E. Banks. "Carbon dots supported upon N-doped TiO2 nanorods applied into sodium and lithium ion batteries." Journal of Materials Chemistry A 3, no. 10 (2015): 5648–55. http://dx.doi.org/10.1039/c4ta05611f.

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Liu, Tianyuan, Ki Chul Kim, Byeongyong Lee, Zhongming Chen, Suguru Noda, Seung Soon Jang, and Seung Woo Lee. "Self-polymerized dopamine as an organic cathode for Li- and Na-ion batteries." Energy & Environmental Science 10, no. 1 (2017): 205–15. http://dx.doi.org/10.1039/c6ee02641a.

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He, Yu, Xia Lu, and Duck Young Kim. "A first-principles study on Si24 as an anode material for rechargeable batteries." RSC Advances 8, no. 36 (2018): 20228–33. http://dx.doi.org/10.1039/c8ra01829d.

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47

Kulish, Vadym V., and Sergei Manzhos. "Comparison of Li, Na, Mg and Al-ion insertion in vanadium pentoxides and vanadium dioxides." RSC Advances 7, no. 30 (2017): 18643–49. http://dx.doi.org/10.1039/c7ra02474f.

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48

Liao, Jin-Yun, Brandon De Luna, and Arumugam Manthiram. "TiO2-B nanowire arrays coated with layered MoS2 nanosheets for lithium and sodium storage." Journal of Materials Chemistry A 4, no. 3 (2016): 801–6. http://dx.doi.org/10.1039/c5ta07064c.

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Wang, Jian-Gan, Huanhuan Sun, Huanyan Liu, Dandan Jin, Rui Zhou, and Bingqing Wei. "Edge-oriented SnS2 nanosheet arrays on carbon paper as advanced binder-free anodes for Li-ion and Na-ion batteries." Journal of Materials Chemistry A 5, no. 44 (2017): 23115–22. http://dx.doi.org/10.1039/c7ta07553g.

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Song, Weixin, Xiaobo Ji, Jun Chen, Zhengping Wu, Yirong Zhu, Kefen Ye, Hongshuai Hou, Mingjun Jing, and Craig E. Banks. "Mechanistic investigation of ion migration in Na3V2(PO4)2F3 hybrid-ion batteries." Physical Chemistry Chemical Physics 17, no. 1 (2015): 159–65. http://dx.doi.org/10.1039/c4cp04649h.

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The ion-migration mechanism of Na3V2(PO4)2F3 is investigated in Na3V2(PO4)2F3–Li hybrid-ion batteries through a combined computational and experimental study.
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