Academic literature on the topic 'Li4SiO4'

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Journal articles on the topic "Li4SiO4"

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Gong, Yichao, Lin Liu, Jianqi Qi, et al. "A comprehensive study on Li4Si1−xTixO4 ceramics for advanced tritium breeders." Journal of Advanced Ceramics 9, no. 5 (2020): 629–40. http://dx.doi.org/10.1007/s40145-020-0419-0.

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Abstract Hetero-element doped lithium orthosilicates have been considered as advanced tritium breeders due to the superior performances. In this work, Li4Si1−xTixO4 ceramics were prepared by proprietary hydrothermal process and multistage reactive sintering. The reaction mechanism of Li4Si1−xTixO4 was put forward. XRD and SEM analyses indicate that insertion of Ti leads to lattice expansion, which promotes the grain growth and changes the fracture mode. The compressive tests show that the crush load increases almost four times by increasing x from 0 to 0.2. However, the thermal conductivity an
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Shan, Shao Yun, Qing Ming Jia, Li Hong Jiang, and Ya Ming Wang. "Effect of Different Silicon Sources on CO2 Absorption Properties of Li4SiO4 at High Temperature." Advanced Materials Research 213 (February 2011): 515–18. http://dx.doi.org/10.4028/www.scientific.net/amr.213.515.

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Using cheap and porous diatomite or zeolite as silicon sources, we prepared firstly Li4SiO4 matetials for high temperature CO2 capture through solid-state method, and mainly investigated effects of silicon sources on the CO2 absorption properties of Li4SiO4 materials. Phase composition was analyzed by X-ray diffraction, and the CO2 absorption properties were studied by the simultaneous thermal thermogravimetric analyzer (TG-DSC). The results showed that Li4SiO4 materials using zeolite as silicon source showed little CO2 absorption properties, while Li4SiO4 materials using diatomite as silicon
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Yan, Xianyao, Yingjie Li, Xiaotong Ma, Jianli Zhao, and Zeyan Wang. "Performance of Li4SiO4 Material for CO2 Capture: A Review." International Journal of Molecular Sciences 20, no. 4 (2019): 928. http://dx.doi.org/10.3390/ijms20040928.

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Lithium silicate (Li4SiO4) material can be applied for CO2 capture in energy production processes, such as hydrogen plants, based on sorption-enhanced reforming and fossil fuel-fired power plants, which has attracted research interests of many researchers. However, CO2 absorption performance of Li4SiO4 material prepared by the traditional solid-state reaction method is unsatisfactory during the absorption/regeneration cycles. Improving CO2 absorption capacity and cyclic stability of Li4SiO4 material is a research highlight during the energy production processes. The state-of-the-art kinetic an
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Guan, Qiushi, Tao Gao, Yanhong Shen та ін. "First-principles study of electronic, dynamical and thermodynamic properties of γ-Li4SiO4". International Journal of Modern Physics B 29, № 18 (2015): 1550128. http://dx.doi.org/10.1142/s0217979215501283.

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We have studied the structural, electronic and dynamic properties of γ- Li4SiO4(lithium orthosilicate) using density functional theory (DFT) with the generalized gradient approximation (GGA). The crystal structure is fully relaxed. The electronic band structure and Density of States (DOS) calculations indicate that γ- Li4SiO4is an insulator with an indirect band gap of 5.19 eV and it has a conduction band with the width of 5.92 eV and two valance bands with the width of 4.45 eV and 0.57 eV, respectively. In the partial DOS, Li and Si electronic densities increase more sharply than O atoms. Com
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Zhai, You Wen, Jin Hu, Xiao Qin Zhu, Kai Jun Wang, and Wei Jun Zhang. "Preparation and Characterization of Lithium Orthosilicate Ceramic Pebbles by Melt Spraying Method." Key Engineering Materials 697 (July 2016): 818–21. http://dx.doi.org/10.4028/www.scientific.net/kem.697.818.

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This paper studied the experimental procedures,, test equipment and test methodology of the melt spraying method. Meanwhile, according to performance index of lithium orthosilicate (Li4SiO4) ceramic pebbles to optimize the melt spraying method. Test analysis of the diameter of orthosilicate pebbles, degree of spheroid of orthosilicate pebbles, surface topography of orthosilicate pebbles, metallographic structure of orthosilicate pebbles, section morphology, crushing strength and phase composition. Results in this work indicate that the lithium orthosilicate (Li4SiO4) ceramic pebbles with a fla
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Kinjyo, Tomohiro, and Masabumi Nishikawa. "Tritium Release Behavior from Li4SiO4." Fusion Science and Technology 46, no. 4 (2004): 561–70. http://dx.doi.org/10.13182/fst04-a591.

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Xiang, Mao Qiao, Ying Chun Zhang, Yun Zhang, Chao Fu Wang, and Yong Hong Yu. "Preparation of Li4SiO4 Ceramic Pebbles by Agar Method Using Li2SiO3 and Li2CO3 as Raw Materials." Key Engineering Materials 697 (July 2016): 814–17. http://dx.doi.org/10.4028/www.scientific.net/kem.697.814.

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Lithium-containing ceramic pebbles, the likeliest tritium breeders in the future, are needed in the fusion reactor blankets. Currently, lithium orthosilicate (Li4SiO4) has been widely studied for tritium breeding pebble as it has 1250 °C melting temperature, 0.54 g/cm3 lithium concentration, and excellent tritium release performance. For simplifying reaction mechanism and the preparation technology to tailor the properties, the Li4SiO4 breeders were produced with an agar-gel technology using stable and cheap lithium metasilicate and lithium carbonate as starting materials. In addition, the sol
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Zhao, Linjie, Qiushi Guan, Jiamao Li, et al. "First-principles study on the structural and electronic properties of Li4SiO4 and Al-doped Li4SiO4." Fusion Engineering and Design 113 (December 2016): 331–35. http://dx.doi.org/10.1016/j.fusengdes.2016.03.069.

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Reimann, J., and G. Wörner. "Thermal creep of Li4SiO4 pebble beds." Fusion Engineering and Design 58-59 (November 2001): 647–51. http://dx.doi.org/10.1016/s0920-3796(01)00513-0.

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Yang, Mao, Yichao Gong, Guangming Ran, et al. "Tritium release behavior of Li4SiO4 and Li4SiO4 + 5 mol% TiO2 ceramic pebbles with small grain size." Journal of Nuclear Materials 514 (February 2019): 284–89. http://dx.doi.org/10.1016/j.jnucmat.2018.12.013.

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Dissertations / Theses on the topic "Li4SiO4"

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Moretto, Pietro [Verfasser]. "Permeation von Deuterium und anderen Gasen durch Lithiumorthosilikat (Li4SiO4) Scheiben / Pietro Moretto." Karlsruhe : KIT-Bibliothek, 1990. http://d-nb.info/1163320242/34.

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Ho, Jacky. "Application of sorption-enhanced catalysis to ethanol reforming." Thesis, KTH, Skolan för kemivetenskap (CHE), 2016. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-180553.

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Lithium orthosilicate (Li4SiO4) is known to be a high temperature CO2 capture material. This work was focused on comparing Li4SiO4 to the extensively studied CaO as an adsorbent in sorption enhanced catalysis. Thermogravimetric analysis was used to study the effects of sorption temperature and compaction on Li4SiO4 using 15vol% CO2 in N2. After 2 hours of CO2 adsorption at 550°C the powder reached 35wt% uptake of CO2, corresponding to 93.6% of maximum efficiency and complete regeneration was possible at 700°C. Pressing Li4SiO4 to granular forms greatly decreased CO2 adsorption rates. Efforts t
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Amorim, Suélen Maria de. "Captura de CO2 em altas temperaturas por meio da reação de carbonatação do ortossilicato de lítio (Li4SiO4)." reponame:Repositório Institucional da UFSC, 2013. https://repositorio.ufsc.br/handle/123456789/107441.

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Dissertação (mestrado) - Universidade Federal de Santa Catarina, Centro Tecnológico, Programa de Pós-graduação em Engenharia Química, Florianópolis, 2013<br>Made available in DSpace on 2013-12-06T00:08:01Z (GMT). No. of bitstreams: 1 318953.pdf: 3624684 bytes, checksum: 7b1e247f44d1ad6038417ee8aa370956 (MD5) Previous issue date: 2013<br>Uma das mais promissoras técnicas de captura de dióxido de carbono consiste na sua separação através da reação reversível com um sólido inorgânico. Neste trabalho, foi estudada a captura de dióxido de carbono em altas temperaturas por meio da reação de carbon
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Abagnato, Samuele. "Analisi di impatto ambientale con metodologia LCA della cattura di CO2 con sorbenti: confronto tra calcium looping e sorbenti a base di Li4SiO4." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2021.

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Negli ultimi decenni è emersa l'urgenza di limitare gli impatti ambientali dovuti all'emissione di gas serra, ed in particolare della CO2. Una delle tecniche individuate per contribuire a limitare queste emissioni nel settore della produzione elettrica è la Carbon Capture and Storage (CCS). La CO2 può essere rimossa dai fumi della combustione attraverso sorbenti solidi: in un primo reattore (il carbonator) i sorbenti solidi adsorbono la CO2 dalla corrente di fumi mentre in un secondo reattore (il calciner) i sorbenti vengono rigenerati. In questa tesi si confrontano due metodi di cattura con s
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Wu, Chung-Hsuan, and 吳仲軒. "Biodiesel production from soybean oil catalyzed by LiAlO2 and Li4SiO4." Thesis, 2015. http://ndltd.ncl.edu.tw/handle/27884702204138835201.

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碩士<br>國立臺中教育大學<br>科學教育與應用學系科學教育碩士班<br>104<br>In this study, lithium carbonate (Li¬2CO3) is separately synthesized with aluminum oxide (Al2O3) or silicon dioxide (SiO2) for lithium aluminate (LiAlO2) or lithium silicate (Li4SiO4), where the source of silicon dioxide is the calcination of kaolinite. The products are regarded as the heterogeneous alkali catalyst for producing biodiesel with the transesterification. The synthesized catalyst is analyzed the characteristics with Scanning Electron Microscope-Energy Dispersive Spectroscopy (SEM-EDS), X-Ray Diffractometer (XRD), Brunauer–Emmett–Teller
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Hsu, Mi-Chung, and 徐米君. "Preparation of Li4SiO4 of higher BET surface area for applications in CO2 capture." Thesis, 2009. http://ndltd.ncl.edu.tw/handle/16070736031505310884.

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Book chapters on the topic "Li4SiO4"

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Benzeşik, Kağan, Ahmet Turan, and Onuralp Yücel. "A New Approach for the Production of Li4SiO4 Powder." In 11th International Symposium on High-Temperature Metallurgical Processing. Springer International Publishing, 2020. http://dx.doi.org/10.1007/978-3-030-36540-0_50.

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Schauer, V., M. Dalle Donne, R. Huber, B. Schmitt, G. Schumacher, and H. Werle. "MECHANICAL PROPERTIES AND DEHYDRATION OF Li4SiO4 PEBBLES." In Fusion Technology 1992. Elsevier, 1993. http://dx.doi.org/10.1016/b978-0-444-89995-8.50290-3.

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Nakazawa, T., K. Noda, Y. Ishii, et al. "STRUCTURAL ANALYSIS OF ION IRRADIATED PURE AND AL-DOPED Li4SiO4." In Fusion Technology 1992. Elsevier, 1993. http://dx.doi.org/10.1016/b978-0-444-89995-8.50283-6.

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Donne, M. Dalle, U. Fischer, A. Goraieb, et al. "CONCEPTUAL DESIGN OF A HELIUM COOLED SOLID BREEDER BLANKET BASED ON THE USE OF A MIXED BED OF BERYLLIUM AND Li4SiO4 PEBBLES." In Fusion Technology 1992. Elsevier, 1993. http://dx.doi.org/10.1016/b978-0-444-89995-8.50259-9.

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Conference papers on the topic "Li4SiO4"

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Lo Frano, R., M. Puccini, E. Stefanelli, et al. "Feasibility Study of a New Fabrication Method for the Li4SiO4 Pebbles." In 2018 26th International Conference on Nuclear Engineering. American Society of Mechanical Engineers, 2018. http://dx.doi.org/10.1115/icone26-82598.

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In the past decades many R&amp;D efforts have been spent in the development of a suitable Li4SiO4 fabrication method (e.g., melt spray process, graphite bed method, capillary-based microfluidic wet method etc.), nevertheless we are still far from an “industrial standard solution”. The aim of the paper is to develop a new fabrication method capable to produce stable and well-sized pebbles of lithium orthosilicate (Li4SiO4) based on the drip casting. This method is mainly based on the dripping at room temperature, which is novel in the framework of available fabrication processes requiring high
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Lo Frano, R., M. Puccini, and E. Stefanelli. "Feasibility Study of a New Fabrication Method for the Li4SiO4 Pebbles." In 2020 International Conference on Nuclear Engineering collocated with the ASME 2020 Power Conference. American Society of Mechanical Engineers, 2020. http://dx.doi.org/10.1115/icone2020-16711.

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Abstract The production of reliable, stable, and durable breeder blanket material is one of the most important open challenge of fusion reactor technology. A new low temperature fabrication method for producing lithium orthosilicate (Li4SiO4) pebbles based on the drip casting was developed at DICI - University of Pisa. The pebbles were produced starting from a suspension of Li4SiO4 precursors prepared by sol-gel method, which was dripped through the experimental device and coagulated into solid spheres in a saline solution. Li4SiO4 pebbles were finally obtained after sintering at high temperat
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Yinjie, Wang, and Liu Jiping. "The Influencing Factor for CO2 Absorption of Li4SiO4 at High Temperature." In 2011 International Conference on Measuring Technology and Mechatronics Automation (ICMTMA). IEEE, 2011. http://dx.doi.org/10.1109/icmtma.2011.782.

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Cui, Shijie, Dalin Zhang, Jie Chang, Wenxi Tian, Suizheng Qiu, and G. H. Su. "Thermo-Hydraulic Analysis of the Optimized Helium Cooled Solid Breeder Blanket for CFETR." In 2016 24th International Conference on Nuclear Engineering. American Society of Mechanical Engineers, 2016. http://dx.doi.org/10.1115/icone24-60144.

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China Fusion Engineering Test Reactor (CFETR) is under design recently, in which a conceptual structure of the helium-cooled solid breeder blanket is proposed as one of the candidate tritium breeding blankets. In this concept, three radial arranged U-shaped breeding zones are designed and optimized for higher Tritium Breeding Ratio (TBR) and structure simplification. This blanket uses the Li4SiO4 lithium ceramic pebbles as the breeder, while beryllium pebbles as the neutron multiplier. In this paper, the thermal and fluid dynamic analyses of the optimized typical outboard blanket module are pe
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Li, Jia, Songlin Liu, Xuebing Ma, Yong Pu, and Xiangcun Chen. "Preliminary Neutronics Design and Analysis of the Bit Helium Cooling Ceramics Blanket for CFETR." In 2013 21st International Conference on Nuclear Engineering. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/icone21-15696.

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CFETR is a Tokamak fusion engineering test reactor whose concept design is being developed in China. It is a key issue for breeding blanket design to attain tritium self-sufficiency as one of important missions of CFETR. This paper presents a preliminary neutronics design and analysis employing a BIT (breeder inside tube) type helium cooling ceramics blanket (HCCB) design concept as one of CFETR blanket design candidates. Firstly, 1D reactor model was designed using ceramic breeder Li4SiO4 and beryllium in pebble for multiplier. The primary blanket parameters were optimized to yield the higher
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Wang, Ke, Pengfei Zhao, Guangtong Zhang, and Jingzhou Wang. "Effects of Calcination Temperature on the Structure and CO2 Sorption Properties of Li4SiO4 Sorbents from Rice Husk Ash." In 2014 International Conference on Mechatronics, Electronic, Industrial and Control Engineering. Atlantis Press, 2014. http://dx.doi.org/10.2991/meic-14.2014.170.

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Xu, Hong, Yongwei Yang, and Zhiwei Zhou. "Study on Neutronics and Fuel Cycle of Fusion-Fission Hybrid Reactor." In 18th International Conference on Nuclear Engineering. ASMEDC, 2010. http://dx.doi.org/10.1115/icone18-30048.

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A conceptual design on neutronics of Fusion-Fission Hybrid Reactor (FFHR) blanket is presented in this paper. The code system COUPLE2.0, which couples the codes MCNP and ORIGEN2 is uesd to simulate the depletion of nucleus for FFHR blanket. By comparing different kinds of coolant, fission fuel and tritium breeding material etc, light water was selected as the coolant, the U-Zr alloy as fuel and Li4SiO4 as tritium breeding material. The volumetric ratio of showed that under that the coolant to fuel is approximately 2.0. The tritium breeding ratio (TBR) must be larger than 1.0, the keff and the
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Zhang, Yaoli, and Tianji Peng. "Modeling TBM Components by Using RELAP5 Code." In 2013 21st International Conference on Nuclear Engineering. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/icone21-16304.

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RELAP5 is a best estimate system code suitable for the analysis of all transients and postulated accidents in Light Water Reactor systems. It was usually used to solve plant thermal-hydraulic problems on system scale. RELAP5 was used to study thermal-hydraulic behavior on component level in this paper. The Test Blanket Module (TBM) was a key component in Chinese Helium-Cooled Solid Breeder (CN HCSB) system. One sub-module of TBM was simulated by RELAP5/MOD3.4. The flow paths, Be pebbles neutron multiplier as well as Li4SiO4 pebbles tritium breeder of TBM were modeled by using hydrodynamic comp
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Hu, Gang, Kaiming Feng, Zhou Zhao, et al. "Updated Design and Development Route for CH HCCB TBM and its Mockup." In 2013 21st International Conference on Nuclear Engineering. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/icone21-16046.

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Chinese helium-cooled ceramics breeder test blanket module (CH HCCB TBM) is determined to be tested in ITER machine to get data for fusion reactor design and development in future. Chinese TBM is designed to occupy half of port C with 484mm in torroidal and 1660mm in poloidal. Radial length is 675mm. TBM is composed of box, 12 submodules and independent backplate. Box formed by first wall, grids and caps have 12 caivities to hold submodules. Box and submodules are supported by backplate by welding. Backplate distribute helium with flow rate 1.36kg/s to cool first wall and then part of it go ou
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