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Relevant bibliographies by topics / LiBH4

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Academic literature on the topic 'LiBH4'

Author: Grafiati

Published: 9 March 2023

Last updated: 31 July 2025

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Journal articles on the topic "LiBH4"

1

de Kort, Laura M., Valerio Gulino, Didier Blanchard, and Peter Ngene. "Effects of LiBF4 Addition on the Lithium-Ion Conductivity of LiBH4." Molecules 27, no. 7 (2022): 2187. http://dx.doi.org/10.3390/molecules27072187.

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Complex hydrides, such as LiBH4, are a promising class of ion conductors for all-solid-state batteries, but their application is constrained by low ion mobility at room temperature. Mixing with halides or complex hydride anions, i.e., other complex hydrides, is an effective approach to improving the ionic conductivity. In the present study, we report on the reaction of LiBH4 with LiBF4, resulting in the formation of conductive composites consisting of LiBH4, LiF and lithium closo-borates. It is believed that the in-situ formation of closo-borate related species gives rise to highly conductive

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Chen, X. Y., Y. H. Guo, L. Gao, and X. B. Yu. "Improved dehydrogenation of LiBH4 supported on nanoscale SiO2 via liquid phase method." Journal of Materials Research 25, no. 12 (2010): 2415–21. http://dx.doi.org/10.1557/jmr.2010.0301.

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A wet loading method was developed to produce nano-sized LiBH4 combined with nano-SiO2 templates. The multicomponent LiBH4/SiO2 material synthesized by the wet method has been found to dehydrogenate at much lower temperatures than the pure LiBH4, as well as LiBH4/SiO2 mixtures prepared by ball milling. For example, the onset of dehydrogenation was decreased to about 200 °C for a wet-treated LiBH4/SiO2 mixture with a mass ratio of 1:1, and the majority of the hydrogen could be released below 350 °C. The improved dehydrogenation of the wet-treated LiBH4/SiO2 mixtures can be attributed to the des

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Xu, Lan, Yu Wang, Ling tong Zhou, et al. "Enhanced Hydrogen Generation by LiBH4 Hydrolysis in MOH/water Solutions (MOH: C2H5OH, C4H8O, C4H9OH, CH3COOH) for Micro Proton Exchange Membrane Fuel Cell Application." Journal of New Materials for Electrochemical Systems 17, no. 2 (2014): 077–83. http://dx.doi.org/10.14447/jnmes.v17i2.427.

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LiBH4 has high hydrogen storage capacity, and its high gravimetric hydrogen density reaches 18.36%. However, LiBH4 exhibits poor hydrolysis performance in water because the abrupt ending caused by the agglomeration of its hydrolysis products limits its full utilization [1, 2]. In this paper, four kinds of organics, namely, ethanol, tetrahydrofuran, acetic acid, and butanol (referred to MOH) were added to water, and the effect of MOH species and amount on the hydrolysis performances of LiBH4 was evaluated. Results show that agglomeration can be avoided and that LiBH4 has a controllable hydrogen

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Leiner, Stefanie, Peter Mayer, and Heinrich Nöth. "Synthesis and Structures of LiBH4 Complexes with N-Heterocycles [1]." Zeitschrift für Naturforschung B 64, no. 7 (2009): 793–99. http://dx.doi.org/10.1515/znb-2009-0703.

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LiBH4 solutions in diethyl ether or tetrahydrofuran react with N-methylmorpholine, Nmethylimidazole or piperidine not only with the formation of adducts LiBH4(L)n (n = 1 or 3) but also with formation of amine boranes BH3(L). While LiBH4 and N-methylimidazole form the 1 : 3 adduct 1, N-methylmorpholine produces the 1 : 1 adduct 2. In both cases the adducts contain hexacoordinated Li atoms. In 1 the Li atom is coordinated to three N atoms and three H atoms. However, in compound 2 the molecules are connected in the solid state with one another to form a two-dimensional polymer built from dimeric

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Nils, Bergemann, Pistidda Claudio, Uptmoor Maike, et al. "A new mutually destabilized reactive hydride system: LiBH4–Mg2NiH4." Journal of Energy Chemistry 14 (March 12, 2019): 240–54. https://doi.org/10.1016/j.jechem.2019.03.011.

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In this work, the hydrogen sorption properties of the LiBH4–Mg2NiH4 composite system with the molar ratio 2:2.5 were thoroughly investigated as a function of the applied temperature and hydrogen pressure. To the best of our knowledge, it has been possible to prove experimentally the mutual destabilization between LiBH 4 and Mg 2 NiH 4 . A detailed account of the kinetic and thermodynamic features of the dehy- drogenation process is reported here.

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Puszkiel, Julián, Aurelien Gasnier, Guillermina Amica, and Fabiana Gennari. "Tuning LiBH4 for Hydrogen Storage: Destabilization, Additive, and Nanoconfinement Approaches." Molecules 25, no. 1 (2019): 163. http://dx.doi.org/10.3390/molecules25010163.

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Hydrogen technology has become essential to fulfill our mobile and stationary energy needs in a global low–carbon energy system. The non-renewability of fossil fuels and the increasing environmental problems caused by our fossil fuel–running economy have led to our efforts towards the application of hydrogen as an energy vector. However, the development of volumetric and gravimetric efficient hydrogen storage media is still to be addressed. LiBH4 is one of the most interesting media to store hydrogen as a compound due to its large gravimetric (18.5 wt.%) and volumetric (121 kgH2/m3) hydrogen d

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7

He, Qing, Dongdong Zhu, Xiaocheng Wu, Duo Dong, Xiaoying Jiang, and Meng Xu. "The Dehydrogenation Mechanism and Reversibility of LiBH4 Doped by Active Al Derived from AlH3." Metals 9, no. 5 (2019): 559. http://dx.doi.org/10.3390/met9050559.

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A detailed analysis of the dehydrogenation mechanism and reversibility of LiBH4 doped by as-derived Al (denoted Al*) from AlH3 was performed by thermogravimetry (TG), differential scanning calorimetry (DSC), mass spectral analysis (MS), powder X-ray diffraction (XRD), scanning electronic microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR). The results show that the dehydrogenation of LiBH4/Al* is a five-step reaction: (1) LiBH4 + Al → LiH + AlB2 + “Li-Al-B-H” + B2H6 + H2; (2) the decomposition of “Li-Al-B-H” compounds liberating H2; (3) 2LiBH4 + Al → 2LiH + AlB2 + 3H2; (4) LiB

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Julián, Puszkiel, Gasnier Aurelien, Amica Guillermina, and Gennari Fabiana. "Tuning LiBH4 for Hydrogen Storage: Destabilization, Additive, and Nanoconfinement Approaches." Molecules 25, no. 1 (2019): 163. https://doi.org/10.3390/molecules25010163.

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Hydrogen technology has become essential to fulfill our mobile and stationary energy needs in a global low–carbon energy system. The non-renewability of fossil fuels and the increasing environmental problems caused by our fossil fuel–running economy have led to our efforts towards the application of hydrogen as an energy vector. However, the development of volumetric and gravimetric efficient hydrogen storage media is still to be addressed. LiBH4 is one of the most interesting media to store hydrogen as a compound due to its large gravimetric (18.5 wt.%) and volumetric (121 kgH2/m3

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LIU, YONGFENG, HAI ZHOU, YUFAN DING, MINGXIA GAO, and HONGGE PAN. "LOW-TEMPERATURE HYDROGEN DESORPTION FROM LiBH4–TiF4 COMPOSITE." Functional Materials Letters 04, no. 04 (2011): 395–99. http://dx.doi.org/10.1142/s1793604711002305.

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Approximately 6.3 wt.% of hydrogen is released from a LiBH4–0.25TiF4 combination below 150°C. Hydrogen desorption from the LiBH4–0.25TiF4 combination undergoes a quite different reaction process with respect to the LiBH4–0.33TiF3 mixture due to the higher oxidation state of Ti4+ and the lower mean bond cleavage energy of Ti–F bonds in TiF4 . This finding provides a viable approach for significantly decreasing the dehydrogenation temperature of LiBH4 by optimizing the additives with high oxidation valency.

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Gulino, Valerio, Laura de Kort, Peter Ngene, Petra de Jongh, and Marcello Baricco. "Combined Effect of Halogenation and SiO2 Addition on the Li-Ion Conductivity of LiBH4." Inorganics 11, no. 12 (2023): 459. http://dx.doi.org/10.3390/inorganics11120459.

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In this work, the combined effects of anion substitution (with Br− and I−) and SiO2 addition on the Li-ion conductivity in LiBH4 have been investigated. Hexagonal solid solutions with different compositions, h-Li(BH4)1−α(X)α (X = Br, I), were prepared by ball milling and fully characterized. The most conductive composition for each system was then mixed with different amounts of SiO2 nanoparticles. If the amount of added complex hydride fully fills the original pore volume of the added silica, in both LiBH4-LiBr/SiO2 and LiBH4-LiI/SiO2 systems, the Li-ion conductivity was further increased com

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Dissertations / Theses on the topic "LiBH4"

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Bösenberg, Ulrike Verfasser], and Rüdiger [Akademischer Betreuer] [Bormann. "LiBH4-MgH2 Composites for Hydrogen Storage : LiBH4-MgH2 Komposite für die Wasserstoffspeicherung / Ulrike Bösenberg ; Betreuer: Rüdiger Bormann." Hamburg : Universitätsbibliothek der Technischen Universität Hamburg-Harburg, 2009. http://d-nb.info/1175884405/34.

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Rivera, Luis A. "Destabilization and characterization of LiBH4/MgH2 complex hydride for hydrogen storage." [Tampa, Fla.] : University of South Florida, 2007. http://purl.fcla.edu/usf/dc/et/SFE0001984.

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Morin, François. "Effet de la pression et de l'addition de fer sur la désorption du système LIBH4 + MgH2." Thèse, Université du Québec à Trois-Rivières, 2012. http://depot-e.uqtr.ca/4464/1/030300172.pdf.

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Marizy, Adrien. "Super-hydrures sous pression pour le stockage de l’hydrogène et la supraconductivité : développement d’outils et résultats sur H3S, CrHx, LiBH4 et NaBHx." Thesis, Université Paris-Saclay (ComUE), 2017. http://www.theses.fr/2017SACLX115/document.

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Récemment, sous des pressions de plusieurs gigapascals, de nouveaux hydrures ont été synthétisés avec des propriétés étonnantes potentiellement porteuses de ruptures technologiques pour le stockage de l’hydrogène ou la supraconductivité. Plusieurs superhydrures sont étudiés expérimentalement et simulés par DFT dans cette thèse. Les diagrammes de phases en pression de LiBH4 et NaBH4, deux composés d’intérêt pour le stockage de l’hydrogène, sont explorés par diffraction de rayons X, spectroscopie Raman et infrarouge jusqu’à des pressions de 300 GPa sans observer de décomposition. L’insertion d’h

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GHAANI, MOHAMMAD REZA. "Study of new materials and their functionality for hydrogen storage and other energy applications." Doctoral thesis, Università degli Studi di Milano-Bicocca, 2014. http://hdl.handle.net/10281/49808.

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The first part of this thesis deals with hydrogen storage materials, in view of their applications as promising energy carriers. One of the main open problems with these materials is: how can their decomposition temperature be lowered, when hydrogen is wanted to be released, so as to improve the energy efficiency of the process. A possible answer is given by joint decomposition of two or more hydrides, if very stable mixed compounds are formed (‘hydride destabilization’). Aiming at this result, the new hydride composite 2LiBH4-Mg2FeH6 was considered, it was synthesized, and its thermodynamic a

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Šašek, Martin. "Charakterizace elektrolytů na bázi směsi iontová kapalina a aprotické rozpouštědlo." Master's thesis, Vysoké učení technické v Brně. Fakulta elektrotechniky a komunikačních technologií, 2017. http://www.nusl.cz/ntk/nusl-318870.

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The thesis deals with liquid aprotic electrolytes based on mixtures of ionic liquid and solvent. EmimBF4, namely 1-ethyl-3-ethylimidazolium tetrafluoroborate, was used as the starting ionic liquid. A mixture of propylene carbonate, ethylene carbonate and dimethyl carbonate was used as solvents. Electrolytes were enriched with two electrolyte salts LiBF4 and NaBF4 from the resulting mixtures selected the most suitable electrolytes for Li-ion and Na-ion accumulators. Electrolytes were selected taking into account the required properties: the width of the potential window, the measured electrical

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Третьяков, Дмитро Олегович. "Фізико-хімічні властивості систем сіль літію (LiBF4, LiCIO4, LiNO3, LiSO3CF3, LiN(SO2CF3)2) - апротонний диполярний розчинник ((CH3)2SO2, (C2H5)2SO2,(CH3)2SO, C3H4O3, C8H18O4)". Дис. канд. хім. наук, Міжвідомче відділ. електрохім. енергетики Нац. акад. наук України, 2012.

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Lee, Jeremy J. "Fabrication and Characterizations of LAGP/PEO Composite Electrolytes for All Solid-State Lithium-Ion Batteries." Wright State University / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=wright1527273235003087.

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Cheng, Yi-Ting, and 鄭宜庭. "The Effect of Pd and Co Additives on the Enhancement of the Dehydrogenation Characteristics for LiBH4 and LiBH4+2LiNH2 systems." Thesis, 2011. http://ndltd.ncl.edu.tw/handle/87727432772319427866.

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碩士<br>國立中央大學<br>材料科學與工程研究所<br>99<br>LiBH4 is a potential hydrogen storage material and gains lots of interests recently due to the extremely high hydrogen capacity (18.4 wt%). However, the initial decomposition temperature (Ti) and main dehydrogenation temperature (Tm) of LiBH4 are as high as 567 and 754 K, respectively. In order to overcome the drawbacks, there are several approaches developed to modify the system thermodynamically or kinetically. In this study, LiBH4 is modified by various additives or mixing with LiNH2 to form a new Li-B-N-H quaternary hydride by ball-milling process. Besid

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CHAN, CHEN-WEI, and 詹鎮瑋. "Computational Study on the Structuresof (LiBH4)n，n=1~12 Clusters forHydrogen Storage." Thesis, 2014. http://ndltd.ncl.edu.tw/handle/41085857259458507073.

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碩士<br>中原大學<br>化學研究所<br>102<br>In the present study, we used density functional theory with B3LYP/6-311g++(d, p) method to calculate the structures, frequencies and energies of (LiBH4)n, n=1~12 clusters which has been known as a candidate hydrogen storage materials. We found that each cluster has several isomers. In order to enhance the hydrogen storage capacity of (LiBH4)n clusters, we added excess electrons to(LiBH4)n clusters. Our calculations show that the hydrogen storage capacity as well as the weight percent is improved with the existence of excess electrons. In addition, we also analyze

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Books on the topic "LiBH4"

1

Uaidh, Mícheál Mac. Slán Libh Boys. Lulu.com, 2019.

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Ar Aghaidh Libh!: Scrúdú Cainte Agus Cluaistuisceana Na HArdteistiméireachta. Edco, The Educational Company of Ireland, 2008.

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Vilas-Boas, Gonçalo. Em torno de viagens e outras deslocações. Edited by Fátima Outeirinho. FLUP-ILC, 2020. http://dx.doi.org/10.21747/9789895478439/lib24.

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Book chapters on the topic "LiBH4"

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Zhao, Wanying, Meiling Liu, Mingyang Liu, Jianhua Zhou, and Xiaoxia Yang. "Hydrogen Storage Properties of Porous Carbon Nano-Confined LiBH4 Materials." In Lecture Notes in Electrical Engineering. Springer Nature Singapore, 2024. http://dx.doi.org/10.1007/978-981-97-7139-4_48.

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Price, T. E. C., D. M. Grant, and G. S. Walker. "Synergistic Effect of LiBH4 + MgH2 as a Potential Reversible High Capacity Hydrogen Storage Material." In Ceramic Transactions Series. John Wiley & Sons, Inc., 2008. http://dx.doi.org/10.1002/9780470483428.ch10.

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Laversenne, L. "Synthesis and crystal structure of alkali metal borohydrides LiBH4, NaBH4, KBH4, RbBH4 and CsBH4." In Hydrogen Storage Materials. Springer Berlin Heidelberg, 2018. http://dx.doi.org/10.1007/978-3-662-54261-3_50.

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Holze, Rudolf. "Ionic conductance of LiBF4." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-49251-2_1049.

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Donoso, J. P., M. G. Cavalcante, W. Gorecki, C. Berthier, and M. Armand. "NMR Study of the Polymer Solid Electrolyte PEO (LIBF4)x." In 25th Congress Ampere on Magnetic Resonance and Related Phenomena. Springer Berlin Heidelberg, 1990. http://dx.doi.org/10.1007/978-3-642-76072-3_171.

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Holze, Rudolf. "Ionic conductivities of binary mixture of LiBF4 and acetonitrile+methanol." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-642-02723-9_1424.

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Holze, Rudolf. "Ionic conductivities of gelled and polymerized TMP+EC+DEC+LiBF4." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-642-02723-9_1723.

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Holze, Rudolf. "Ionic conductivities of binary mixture of LiBF4 and 1B3MIm-BF4+ EC." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-642-02723-9_1388.

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Holze, Rudolf. "Ionic conductivities of binary mixture of LiBF4 and 1B3MIm-BF4+ PC." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-642-02723-9_1389.

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Holze, Rudolf. "Ionic conductivities of binary mixture of LiBF4 and 1E3MIm-BF4+EC." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-642-02723-9_1390.

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Conference papers on the topic "LiBH4"

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Lysenkov, Eduard. "Nanocomposite Polymer Electrolyte Materials Based on Polyether, LiBF4 and Nanofibers for Renewable Electrochemical Devices." In 2024 IEEE 42nd International Conference on Electronics and Nanotechnology (ELNANO). IEEE, 2024. https://doi.org/10.1109/elnano63394.2024.10756817.

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Zamponi, Flavio, Johannes Stingl, Benjamin Freyer, Michael Woerner, Thomas Elsaesser, and Andreas Borgschulte. "Femtosecond X-Ray Powder Diffraction on LiBH4." In International Conference on Ultrafast Structural Dynamics. OSA, 2012. http://dx.doi.org/10.1364/icusd.2012.im2d.5.

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Zamponi, Flavio, Johannes Stingl, Benjamin Freyer, Michael Woerner, Thomas Elsaesser, and Andreas Borgschulte. "LiBH4 Studied by Femtosecond X-Ray Powder Diffraction." In Quantum Electronics and Laser Science Conference. OSA, 2012. http://dx.doi.org/10.1364/qels.2012.qth4h.3.

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Niemann, Michael U., Sesha S. Srinivasan, Ashok Kumar, Elias K. Stefanakos, D. Yogi Goswami, and Kimberly McGrath. "Processing Analysis of the Ternary LiNH2-MgH2-LiBH4 System for Hydrogen Storage." In ASME 2009 International Mechanical Engineering Congress and Exposition. ASMEDC, 2009. http://dx.doi.org/10.1115/imece2009-11520.

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The ternary LiNH2-MgH2-LiBH4 hydrogen storage system has been extensively studied by adopting various processing reaction pathways. The stoichiometric ratio of LiNH2:MgH2:LiBH4 is kept constant with a 2:1:1 molar ratio. All samples are prepared using solid-state mechano-chemical synthesis with a constant rotational speed, but with varying milling duration. All samples are intimate mixtures of Li-B-N-H and MgH2, with varying particle sizes. It is found that the samples with MgH2 particle sizes of approximately 10nm exhibit lower initial hydrogen release at a temperature of 150°C. The as-synthes

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Benzidi, H., O. Mounkachi, M. Lakhal, A. Benyoussef, and A. El Kenz. "Compression effect on electronic properties and hydrogen desroption of LiBH4: First principal study." In 2016 International Renewable and Sustainable Energy Conference (IRSEC). IEEE, 2016. http://dx.doi.org/10.1109/irsec.2016.7984054.

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Yoon, Sungjae, Sangyup Lee, Paul Maldonado Nogales, and Soon Ki Jeong. "Impacts of Lithium Salt on Interfacial Reactions between SiO and Ethlyene Carbonate-Based Solutions in Lithium Secondary Batteries." In International Conference on Advanced Materials, Mechanics and Structural Engineering. Trans Tech Publications Ltd, 2024. http://dx.doi.org/10.4028/p-ldtpq6.

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This study investigates the influence of lithium salt on the interfacial reactions that occur between SiO and ethylene carbonate-based solutions in lithium secondary batteries. Electrochemical reactions occurring at a SiO electrode were examined to gain insights into the effects of lithium salts, such as LiPF6, LiBF4, LiClO4, and LiCF3SO3, on the interfacial resistance. The SiO electrode exhibited a relatively high reversible capacity and Coulomb efficiency in an electrolyte solution containing LiCF3SO3. The interfacial resistance was the highest in the solution containing LiPF6 and the lowest

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Kretzschmar, H. J., I. Stoecker, I. Jaehne, S. Herrmann, and M. Kunick. "Property Libraries for Working Fluids for Calculating Heat Cycles, Turbines, Heat Pumps, and Refrigeration Processes." In ASME 2007 International Mechanical Engineering Congress and Exposition. ASMEDC, 2007. http://dx.doi.org/10.1115/imece2007-42033.

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The program libraries developed for calculating the thermophysical properties of working fluids can be used by engineers who routinely calculate heat cycles, steam or gas turbines, boilers, heat pumps, or other thermal or refrigeration processes. Thermodynamic properties, transport properties, derivatives, and inverse functions can be calculated. Today gas turbines are being developed for higher and higher temperatures and pressures. However, the calculation of the combustion gas as an ideal gas mixture will be inaccurate at high pressures. For this reason, a property library has been develope

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Улихин, А. С., А. В. Измоденова, Н. Ф. Уваров, К. А. Коваленко та В. П. Федин. "ПРОВОДИМОСТЬ БИНАРНОЙ СИСТЕМЫ [C10H22N]BF4–LiBF4 В ПОРАХ МЕТАЛЛ-ОРГАНИЧЕСКОЙ МАТРИЦЫ MIL-101(Cr)". У XV Симпозиум с международным участием "Термодинамика и материаловедение". NIIC SB RAS, 2023. http://dx.doi.org/10.26902/therm_2023_230.

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Sangeetha, M., A. Mallikarjun, M. Jaipal Reddy, and J. Siva Kumar. "SEM, XRD and electrical conductivity studies of PVDF-HFP-LiBF4 –EC plasticized gel polymer electrolyte." In INTERNATIONAL CONFERENCE ON FUNCTIONAL MATERIALS, CHARACTERIZATION, SOLID STATE PHYSICS, POWER, THERMAL AND COMBUSTION ENERGY: FCSPTC-2017. Author(s), 2017. http://dx.doi.org/10.1063/1.4990217.

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Mariam, Siti Nor, Bohari M. Yamin, and Azizan Ahmad. "Synthesis of tetraaza bromide macrocyclic and studies of its effect on poly(methyl methacrylate) grafted natural rubber (MG49) - lithium tertrafluoroborate (LiBF4) films." In THE 2013 UKM FST POSTGRADUATE COLLOQUIUM: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2013 Postgraduate Colloquium. AIP Publishing LLC, 2013. http://dx.doi.org/10.1063/1.4858774.

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