Relevant bibliographies by topics / Ligand Non Innocence

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  2. Dissertations / Theses
  3. Book chapters

Academic literature on the topic 'Ligand Non Innocence'

Author: Grafiati
Published: 4 June 2021
Last updated: 1 February 2022

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Journal articles on the topic "Ligand Non Innocence"

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Kaspar, Manuel, Philipp J. Altmann, Alexander Pöthig, Stephen Sproules, and Corinna R. Hess. "A macrocyclic ‘Co0’ complex: the relevance of ligand non-innocence to reactivity." Chemical Communications 53, no. 53 (2017): 7282–85. http://dx.doi.org/10.1039/c7cc02239e.

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A formally ‘Co<sup>0</sup>’ compound, containing the redox-active macrocyclic Mabiq ligand, was isolated and characterized. Ligand redox non-innocence in this system has important ramifications for reactivity.
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Schneck, Felix, Markus Finger, Moniek Tromp, and Sven Schneider. "Chemical Non-Innocence of an Aliphatic PNP Pincer Ligand." Chemistry - A European Journal 23, no. 1 (2016): 33–37. http://dx.doi.org/10.1002/chem.201604407.

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Vinum, Morten Gotthold, Laura Voigt, Colby Bell та ін. "Evidence for Non‐Innocence of a β‐Diketonate Ligand". Chemistry – A European Journal 26, № 10 (2020): 2143–47. http://dx.doi.org/10.1002/chem.201904899.

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Kooistra, T. Martijn, Dennis G. H. Hetterscheid, Erik Schwartz, Quinten Knijnenburg, Peter H. M. Budzelaar, and Anton W. Gal. "Chemical ligand non-innocence in pyridine diimine Rh complexes." Inorganica Chimica Acta 357, no. 10 (2004): 2945–52. http://dx.doi.org/10.1016/j.ica.2004.02.012.

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Heins, Spencer P., Peter T. Wolczanski, Thomas R. Cundari, and Samantha N. MacMillan. "Redox non-innocence permits catalytic nitrene carbonylation by (dadi)TiNAd (Ad = adamantyl)." Chemical Science 8, no. 5 (2017): 3410–18. http://dx.doi.org/10.1039/c6sc05610e.

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Saund, Simran S., Samantha L. Goldschmid, Karina Ng, Veronica Stewart, Maxime A. Siegler, and V. Sara Thoi. "Exploring ligand non-innocence of coordinatively-versatile diamidodipyrrinato cobalt complexes." Chemical Communications 55, no. 12 (2019): 1825–28. http://dx.doi.org/10.1039/c8cc08674e.

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McIsaac, Alexandra R., and David A. Mazziotti. "Ligand non-innocence and strong correlation in manganese superoxide dismutase mimics." Physical Chemistry Chemical Physics 19, no. 6 (2017): 4656–60. http://dx.doi.org/10.1039/c6cp07563k.

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Ha, Yonghwang, Dhiraj P. Murale, Changsuk Yun, et al. "H+-Assisted fluorescent differentiation of Cu+ and Cu2+: effect of Al3+-induced acidity on chemical sensing and generation of two novel and independent logic gating pathways." Chemical Communications 51, no. 29 (2015): 6357–60. http://dx.doi.org/10.1039/c4cc10025e.

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Moskalev, M. V., A. N. Lukoyanov, E. V. Baranov, and I. L. Fedushkin. "Unexpected reactivity of an alkylaluminum complex of a non-innocent 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene ligand (dpp-bian)." Dalton Transactions 45, no. 40 (2016): 15872–78. http://dx.doi.org/10.1039/c6dt01750a.

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Garai, Antara, Sebastian Sobottka, Rahel Schepper, et al. "Chromium Complexes with Oxido and Corrolato Ligands: Metal-Based Redox Processes versus Ligand Non-Innocence." Chemistry - A European Journal 24, no. 48 (2018): 12613–22. http://dx.doi.org/10.1002/chem.201801452.

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Dissertations / Theses on the topic "Ligand Non Innocence"

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Adhikari, Debashis. "Synthesis, structure and reactivity studies of nickel pincer complexes and evaluating redox non-innocence of the ligand." [Bloomington, Ind.] : Indiana University, 2009. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:3380057.

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Thesis (Ph.D.)--Indiana University, Dept. of Chemistry, 2009.<br>Title from PDF t.p. (viewed on Jul 19, 2010). Source: Dissertation Abstracts International, Volume: 70-12, Section: B, page: 7557. Adviser: Daniel J. Mindiola.
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Brunel, Paul. "Complexes pince et cooperativité métal/ligand : application en catalyse." Thesis, Toulouse 3, 2018. http://www.theses.fr/2018TOU30275/document.

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Ce travail de thèse porte sur la chimie organométallique des complexes pince indényle/indénediide de palladium et de platine et leurs applications en catalyse coopérative métal-ligand. Le premier chapitre de ce manuscrit fait un point bibliographique non-exhaustif du domaine de la coopérativité métal-ligand, des travaux de Noyori sur l'hydrogénation asymétrique, jusqu'aux récents travaux de Milstein avec les ligands désaromatisés. Les ligands pince sont également présentés. Du premier exemple PCP décrit par Shaw jusqu'au CNC développé par Bezuidenhout. La versatilité de ces ligands est illustr
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King, Evan. "Metal-Ligand Multiple Bonds in High-Spin Complexes." Thesis, Harvard University, 2012. http://dissertations.umi.com/gsas.harvard:10356.

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The chemistry of late first row transition metals supported by dipyrromethane and dipyrromethene ligands bearing sterically bulky substituents was explored. Transition metal complexes (Mn, Fe, Co, Ni, Zn) of the dipyrromethane ligand 1,9-dimesityl-5,5-dimethyldipyrromethane (dpma) were prepared. Structural and magnetic characterization (SQUID, EPR) of the bis-pyridine adducts \((dpma)Mn(py)_2\), \((dpma)Fe(py)_2\), and \((dpma)Co(py)_2\) showed each tetrahedral divalent ion to be high-spin, while square planar \((dpma)Ni^{II}(py)_2\) and tetrahedral \((dpma)Zn(py)_2\) were shown to be diamagne
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Irwin, Mark Robert Floyd. "The synthesis and characterisation of metal complexes containing chemically reduced bipyridyl ligand systems." Thesis, University of Oxford, 2013. http://ora.ox.ac.uk/objects/uuid:44dd8d43-01cf-4a2a-ab66-c7cab1d9201f.

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This thesis describes the synthesis and characterisation of metal complexes that contain chemically reduced bipyridyl ligands. The crystal structures of twenty-six novel complexes are reported alongside detailed discussions on the electronic and spectroscopic effects and trends associated with the different oxidation states within these species. Chapter One introduces the isomers of bipyridine and their redox chemistry, the concept of non-innocent ligands and the spectroscopic techniques that are currently used in determining ligand oxidation states. Subsequently, examples of main group, trans
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Walli, Adam. "Biomimetic Copper(I)-Mediated Activation of Dioxygen and Redox Non-Innocence in Copper(II) Complexes of Bis(oxazoline)s." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2014. http://hdl.handle.net/11858/00-1735-0000-0023-9636-9.

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MUSTIELES, MARÍN Irene. "Oxidation of phosphasalen complexes." Thesis, Université Paris-Saclay (ComUE), 2017. http://www.theses.fr/2017SACLX078/document.

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Les ligands phosphasalen développés au sein du laboratoire peuvent être considérés comme les analogues phosphorés des ligands salen dont ils diffèrent par la présence de groupements iminophosphorane à la place des imines. L’introduction de ces fonctions a d’importantes conséquences sur les propriétés de ces ligands, qui sont plus électrodonneurs et plus flexibles que les dérivés salen correspondants, capables de stabiliser des métaux à haut degré d’oxydation. Ces ligands ont également un caractère redox non-innocent, une propriété très étudiée de nos jours tant en chimie de coordination qu’en
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Aguirre, Fondevila Adiran de. "Non-innocent ligands: from proton shuttle to photo-activation." Doctoral thesis, Universitat Rovira i Virgili, 2019. http://hdl.handle.net/10803/668399.

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En la majoria dels exemples clàssics de catàlisis homogènia, el focus cau en el centre metàl·lic, el qual és el que duu a terme la reacció, mentre que els lligands juguen un rol principalment d'espectadors. Així, l'aproximació inicial per modificar la reactivitat dels sistemas era reemplaçar el metall. Aquest ha sigut el punt inicial en la majoria dels treballs en catálisis homogènia amb complexos organometàl·lics. La modificació de les propietats estèriques o electròniques dels lligands afecta el metall, i pot tindre un gran impacte en el resultat de la reacció: rendiment més alt, millor sele
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Salanouve, Elise. "Complexes de métaux non-nobles de fer et de nickel portant des ligands redox non-innocents et leurs applications en catalyse : de l'activation C-H aux réactions de couplages croisés." Thesis, Paris 6, 2014. http://www.theses.fr/2014PA066620/document.

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Ce travail de thèse s’est intéressé au développement de complexes de métaux non-nobles portant des ligands non-innocents et leurs applications en catalyse comme alternatives efficaces aux complexes de métaux nobles dans un contexte de fortes préoccupations économiques et environnementales. Ainsi, nous avons synthétisé et caractérisé des complexes de fer et de nickel portant des ligands non-innocents, à l’aide de différentes techniques spectroscopiques. Ces ligands pourraient moduler la réactivité du métal et étendre ainsi le champ d’applications de ces métaux de transition. Dans le but de déve
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Reinhardt, Maxwell James. "Metal complexes containing non-innocent ligands for functional materials." Thesis, University of Edinburgh, 2013. http://hdl.handle.net/1842/11723.

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The existence of complexes of that display non-innocence has been of interest in the field of coordination chemistry since the investigations of square-planar dithiolene complexes of the late transition metals in the 1960s. The ligands used in these systems are termed “non-innocent” when bound to a number of the late transition metals, because the orbital energy levels are similar to those of the central metal ion. This allows there to be significant electron delocalisation over the complex with the potential for the complexes to exist in a number of electronic states due to the combined elect
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Mele, Andrea. "Preparation and study of diiron complexes, featuring redox ligands, inspired by the active site of [FeFe]-Hydrogenases." Thesis, Brest, 2019. http://www.theses.fr/2019BRES0100.

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L’hydrogénase [FeFe] est une enzyme capable de catalyser efficacement la réduction des protons en hydrogène moléculaire. La structure du site actif, appelé le cluster-H a été élucidée à la fin des années 90. Depuis, plusieurs systèmes modèles ont été synthétisés en essayant de reproduire ses caractéristiques uniques. Le cluster {4Fe4S}, présent dans le site actif joue un rôle crucial en tant que cofacteur redox, lié de manière covalente à un système difer qui est le site de la conversion H+/H2. Il se comporte comme un réservoir d'électrons capable d'accepter et de partager des électrons avec l
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Book chapters on the topic "Ligand Non Innocence"

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de Bruin, Bas, Pauline Gualco, and Nanda D. Paul. "Redox Non-innocent Ligands." In Ligand Design in Metal Chemistry. John Wiley & Sons, Ltd, 2016. http://dx.doi.org/10.1002/9781118839621.ch7.

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Chirila, Andrei, Braja Gopal Das, Petrus F. Kuijpers, Vivek Sinha, and Bas de Bruin. "Application of Stimuli-Responsive and “Non-innocent” Ligands in Base Metal Catalysis." In Non-Noble Metal Catalysis. Wiley-VCH Verlag GmbH & Co. KGaA, 2018. http://dx.doi.org/10.1002/9783527699087.ch1.

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Wada, Tohru, Koji Tanaka, James T. Muckerman, and Etsuko Fujita. "Water Oxidation by Ruthenium Catalysts with Non-Innocent Ligands." In Molecular Water Oxidation Catalysis. John Wiley & Sons, Ltd, 2014. http://dx.doi.org/10.1002/9781118698648.ch5.

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Lever, A. B. P., and S. I. Gorelsky. "Ruthenium Complexes of Non-Innocent Ligands: Aspects of Charge Transfer Spectroscopy." In Structure and Bonding. Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/b96898.

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Itoh, Shinobu, та Yuma Morimoto. "β-Diketiminates as Redox Non-innocent Supporting Ligands in Coordination Chemistry". У Chemical Science of π-Electron Systems. Springer Japan, 2015. http://dx.doi.org/10.1007/978-4-431-55357-1_42.

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Heims, Florian, and Kallol Ray. "Multiple Spin Scenarios in Transition-Metal Complexes Involving Redox Non-Innocent Ligands." In Spin States in Biochemistry and Inorganic Chemistry. John Wiley & Sons, Ltd, 2015. http://dx.doi.org/10.1002/9781118898277.ch11.

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Varela-Alvarez, Adrian, and Djamaladdin G. Musaev. "Fundamental Aspects of the Metal-Catalyzed C-H Bond Functionalization by Diazocarbenes: Guiding Principles for Design of Catalyst with Non-redox-Active Metal (Such as Ca) and Non-Innocent Ligand." In Understanding Organometallic Reaction Mechanisms and Catalysis. Wiley-VCH Verlag GmbH & Co. KGaA, 2014. http://dx.doi.org/10.1002/9783527678211.ch2.

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