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Journal articles on the topic 'Ligand Non Innocence'

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1

Kaspar, Manuel, Philipp J. Altmann, Alexander Pöthig, Stephen Sproules, and Corinna R. Hess. "A macrocyclic ‘Co0’ complex: the relevance of ligand non-innocence to reactivity." Chemical Communications 53, no. 53 (2017): 7282–85. http://dx.doi.org/10.1039/c7cc02239e.

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A formally ‘Co<sup>0</sup>’ compound, containing the redox-active macrocyclic Mabiq ligand, was isolated and characterized. Ligand redox non-innocence in this system has important ramifications for reactivity.
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2

Schneck, Felix, Markus Finger, Moniek Tromp, and Sven Schneider. "Chemical Non-Innocence of an Aliphatic PNP Pincer Ligand." Chemistry - A European Journal 23, no. 1 (2016): 33–37. http://dx.doi.org/10.1002/chem.201604407.

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3

Vinum, Morten Gotthold, Laura Voigt, Colby Bell та ін. "Evidence for Non‐Innocence of a β‐Diketonate Ligand". Chemistry – A European Journal 26, № 10 (2020): 2143–47. http://dx.doi.org/10.1002/chem.201904899.

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4

Kooistra, T. Martijn, Dennis G. H. Hetterscheid, Erik Schwartz, Quinten Knijnenburg, Peter H. M. Budzelaar, and Anton W. Gal. "Chemical ligand non-innocence in pyridine diimine Rh complexes." Inorganica Chimica Acta 357, no. 10 (2004): 2945–52. http://dx.doi.org/10.1016/j.ica.2004.02.012.

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5

Heins, Spencer P., Peter T. Wolczanski, Thomas R. Cundari, and Samantha N. MacMillan. "Redox non-innocence permits catalytic nitrene carbonylation by (dadi)TiNAd (Ad = adamantyl)." Chemical Science 8, no. 5 (2017): 3410–18. http://dx.doi.org/10.1039/c6sc05610e.

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6

Saund, Simran S., Samantha L. Goldschmid, Karina Ng, Veronica Stewart, Maxime A. Siegler, and V. Sara Thoi. "Exploring ligand non-innocence of coordinatively-versatile diamidodipyrrinato cobalt complexes." Chemical Communications 55, no. 12 (2019): 1825–28. http://dx.doi.org/10.1039/c8cc08674e.

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7

McIsaac, Alexandra R., and David A. Mazziotti. "Ligand non-innocence and strong correlation in manganese superoxide dismutase mimics." Physical Chemistry Chemical Physics 19, no. 6 (2017): 4656–60. http://dx.doi.org/10.1039/c6cp07563k.

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8

Ha, Yonghwang, Dhiraj P. Murale, Changsuk Yun, et al. "H+-Assisted fluorescent differentiation of Cu+ and Cu2+: effect of Al3+-induced acidity on chemical sensing and generation of two novel and independent logic gating pathways." Chemical Communications 51, no. 29 (2015): 6357–60. http://dx.doi.org/10.1039/c4cc10025e.

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9

Moskalev, M. V., A. N. Lukoyanov, E. V. Baranov, and I. L. Fedushkin. "Unexpected reactivity of an alkylaluminum complex of a non-innocent 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene ligand (dpp-bian)." Dalton Transactions 45, no. 40 (2016): 15872–78. http://dx.doi.org/10.1039/c6dt01750a.

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10

Garai, Antara, Sebastian Sobottka, Rahel Schepper, et al. "Chromium Complexes with Oxido and Corrolato Ligands: Metal-Based Redox Processes versus Ligand Non-Innocence." Chemistry - A European Journal 24, no. 48 (2018): 12613–22. http://dx.doi.org/10.1002/chem.201801452.

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11

Ke, Iou-Sheng, James S. Jones, and François P. Gabbaï. "Anion-Controlled Switching of an X Ligand into a Z Ligand: Coordination Non-innocence of a Stiboranyl Ligand." Angewandte Chemie International Edition 53, no. 10 (2014): 2633–37. http://dx.doi.org/10.1002/anie.201309132.

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12

Ke, Iou-Sheng, James S. Jones, and François P. Gabbaï. "Anion-Controlled Switching of an X Ligand into a Z Ligand: Coordination Non-innocence of a Stiboranyl Ligand." Angewandte Chemie 126, no. 10 (2014): 2671–75. http://dx.doi.org/10.1002/ange.201309132.

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13

Wieder, Noah L., Michelle Gallagher, Patrick J. Carroll, and Donald H. Berry. "Evidence for Ligand Non-innocence in a Formally Ruthenium(I) Hydride Complex." Journal of the American Chemical Society 132, no. 12 (2010): 4107–9. http://dx.doi.org/10.1021/ja100894h.

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14

Schauer, Phil A., та Paul J. Low. "Ligand Redox Non-Innocence in Transition-Metal σ-Alkynyl and Related Complexes". European Journal of Inorganic Chemistry 2012, № 3 (2011): 390–411. http://dx.doi.org/10.1002/ejic.201100995.

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15

Ehret, Fabian, Martina Bubrin, Stanislav Záliš, and Wolfgang Kaim. "Discovering More Non-Innocence: Triazenido versus Triazenyl Radical Ligand Function, and a Comment on [NO2]nas a “Suspect” Ligand." Angewandte Chemie International Edition 52, no. 17 (2013): 4673–75. http://dx.doi.org/10.1002/anie.201209260.

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16

Hananouchi, Steven, Brandon T. Krull, Joseph W. Ziller, Filipp Furche, and Alan F. Heyduk. "Metal effects on ligand non-innocence in Group 5 complexes of the redox-active [ONO] pincer ligand." Dalton Trans. 43, no. 48 (2014): 17991–8000. http://dx.doi.org/10.1039/c4dt02259a.

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17

Lukens, James T., Ida M. DiMucci, Takashi Kurogi, Daniel J. Mindiola, and Kyle M. Lancaster. "Scrutinizing metal–ligand covalency and redox non-innocence via nitrogen K-edge X-ray absorption spectroscopy." Chemical Science 10, no. 19 (2019): 5044–55. http://dx.doi.org/10.1039/c8sc03350a.

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A series of nitrogen K-edge XAS data obtained for coordination complexes of diverse transition metals is used to calibrate computational pre-edge peak energies and to afford estimates of metal–ligand covalencies. The approach is extended to probe an inner-sphere aminyl radical ligand.
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18

Hui, Alice K., Richard L. Lord, and Kenneth G. Caulton. "In search of redox non-innocence between a tetrazine pincer ligand and monovalent copper." Dalton Trans. 43, no. 21 (2014): 7958–63. http://dx.doi.org/10.1039/c3dt52490f.

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19

Stefanelli, Manuela, Sara Nardis, Luca Tortora, et al. "Nitration of iron corrolates: further evidence for non-innocence of the corrole ligand." Chemical Communications 47, no. 14 (2011): 4255. http://dx.doi.org/10.1039/c0cc05491g.

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20

Vijaykumar, Gonela, Anand Pariyar, Jasimuddin Ahmed, Bikash Kumar Shaw, Debashis Adhikari, and Swadhin K. Mandal. "Tuning the redox non-innocence of a phenalenyl ligand toward efficient nickel-assisted catalytic hydrosilylation." Chemical Science 9, no. 10 (2018): 2817–25. http://dx.doi.org/10.1039/c7sc04687a.

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21

Jones, J. Stuart, Casey R. Wade, Mengxi Yang, and François P. Gabbaï. "On the coordination non-innocence of antimony in nickel(ii) complexes of the tetradentate (o-(Ph2P)C6H4)3Sb ligand." Dalton Transactions 46, no. 17 (2017): 5598–604. http://dx.doi.org/10.1039/c6dt04817j.

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22

Cook, Brian J., Richard L. Lord, Chun-Hsing Chen, and Kenneth G. Caulton. "Gauging the Redox Non-Innocence of a Highly Pi-Acidic Bis-Tetrazine Pincer Ligand." European Journal of Inorganic Chemistry 2019, no. 20 (2019): 2535–42. http://dx.doi.org/10.1002/ejic.201900186.

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23

Das, Amit, Thomas Michael Scherer, Prasenjit Mondal, Shaikh M. Mobin, Wolfgang Kaim та Goutam Kumar Lahiri. "Experimental and DFT Evidence for the Fractional Non-Innocence of a β-Diketonate Ligand". Chemistry - A European Journal 18, № 45 (2012): 14434–43. http://dx.doi.org/10.1002/chem.201201785.

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24

Camp, Clément, та John Arnold. "On the non-innocence of “Nacnacs”: ligand-based reactivity in β-diketiminate supported coordination compounds". Dalton Transactions 45, № 37 (2016): 14462–98. http://dx.doi.org/10.1039/c6dt02013e.

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While β-diketiminate (BDI or ‘nacnac’) ligands have been widely adopted to stabilize a wide range of metal ions in multiple oxidation states and coordination numbers, in several occurrences these ligands do not behave as spectators and participate in reactivity.
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25

Horak, Kyle T., Alexandra Velian, Michael W. Day, and Theodor Agapie. "Arene non-innocence in dinuclear complexes of Fe, Co, and Ni supported by a para-terphenyl diphosphine." Chem. Commun. 50, no. 34 (2014): 4427–29. http://dx.doi.org/10.1039/c4cc00838c.

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26

Chan, Siu-Chung, and Chun-Yuen Wong. "Recent developments in ruthenium–nitrosoarene chemistry: Unconventional synthetic strategies, new ligand designs, and exploration of ligands redox non-innocence." Coordination Chemistry Reviews 402 (January 2020): 213082. http://dx.doi.org/10.1016/j.ccr.2019.213082.

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27

Cozzolino, Anthony F., Carl K. Brozek, Ryan D. Palmer, Junko Yano, Minyuan Li, and Mircea Dincă. "Ligand Redox Non-innocence in the Stoichiometric Oxidation of Mn2(2,5-dioxidoterephthalate) (Mn-MOF-74)." Journal of the American Chemical Society 136, no. 9 (2014): 3334–37. http://dx.doi.org/10.1021/ja411808r.

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28

Ansari, Mohd Asif, Abhishek Mandal, Katharina Beyer, et al. "Non-innocence and mixed valency in tri- and tetranuclear ruthenium complexes of a heteroquinone bridging ligand." Dalton Transactions 46, no. 44 (2017): 15589–98. http://dx.doi.org/10.1039/c7dt03509h.

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29

McNeece, Andrew J., Kate A. Jesse, Jiaze Xie, Alexander S. Filatov, and John S. Anderson. "Generation and Oxidative Reactivity of a Ni(II) Superoxo Complex via Ligand-Based Redox Non-Innocence." Journal of the American Chemical Society 142, no. 24 (2020): 10824–32. http://dx.doi.org/10.1021/jacs.0c03244.

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30

Xu, Jialiang, Li Zhu, Hu Gao, et al. "Ligand Non‐innocence and Single Molecular Spintronic Properties of Ag II Dibenzocorrole Radical on Ag(111)." Angewandte Chemie 133, no. 21 (2021): 11808–12. http://dx.doi.org/10.1002/ange.202016674.

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31

Xu, Jialiang, Li Zhu, Hu Gao, et al. "Ligand Non‐innocence and Single Molecular Spintronic Properties of Ag II Dibenzocorrole Radical on Ag(111)." Angewandte Chemie International Edition 60, no. 21 (2021): 11702–6. http://dx.doi.org/10.1002/anie.202016674.

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32

Chan, Siu-Chung, Jason England, Karl Wieghardt, and Chun-Yuen Wong. "Trapping of the putative 1,2-dinitrosoarene intermediate of benzofuroxan tautomerization by coordination at ruthenium and exploration of its redox non-innocence." Chem. Sci. 5, no. 10 (2014): 3883–87. http://dx.doi.org/10.1039/c4sc01185f.

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33

Man, Wing Y., Jian-Long Xia, Neil J. Brown, et al. "Spectroscopic and Computational Studies of the Ligand Redox Non-Innocence in Mono- and Binuclear Ruthenium Vinyl Complexes." Organometallics 30, no. 7 (2011): 1852–58. http://dx.doi.org/10.1021/om1010534.

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34

Benjamin, Helen, Jonathan G. Richardson, Stephen A. Moggach, et al. "Pressure-induced non-innocence in bis(1,2-dionedioximato)Pt(ii) complexes: an experimental and theoretical study of their insulator–metal transitions." Physical Chemistry Chemical Physics 22, no. 12 (2020): 6677–89. http://dx.doi.org/10.1039/c9cp06749c.

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Bis(1,2-dionedioximato) complexes of Pt(ii) form linear chains of metal complexes that metallise under pressure. Through high-pressure structural, computational and conductivity measurements we show the crucial role of the ligand in dictating these properties.
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35

Widger, Leland R., Yunbo Jiang, Maxime A. Siegler, et al. "Synthesis and Ligand Non-Innocence of Thiolate-Ligated (N4S) Iron(II) and Nickel(II) Bis(imino)pyridine Complexes." Inorganic Chemistry 52, no. 18 (2013): 10467–80. http://dx.doi.org/10.1021/ic4013558.

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36

Johnston, Cooper W., Travis R. Schwantje, Michael J. Ferguson, Robert McDonald, and Robin G. Hicks. "Metal coordination, and metal–ligand redox non-innocence, modulates allosteric C–N bond homolysis in an N-benzyl tetrazine." Chem. Commun. 50, no. 83 (2014): 12542–44. http://dx.doi.org/10.1039/c4cc06235c.

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37

Cowley, Ryan E., Gemma J. Christian, William W. Brennessel, Frank Neese та Patrick L. Holland. "A Reduced (β-Diketiminato)iron Complex with End-On and Side-On Nitriles: Strong Backbonding or Ligand Non-Innocence?" European Journal of Inorganic Chemistry 2012, № 3 (2011): 479–83. http://dx.doi.org/10.1002/ejic.201100787.

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38

Delle Chiaie, K. R., A. B. Biernesser, M. A. Ortuño, et al. "The role of ligand redox non-innocence in ring-opening polymerization reactions catalysed by bis(imino)pyridine iron alkoxide complexes." Dalton Transactions 46, no. 38 (2017): 12971–80. http://dx.doi.org/10.1039/c7dt03067c.

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39

Müller, Igor, Christian Schneider, Clemens Pietzonka, Florian Kraus, and C. Gunnar Werncke. "Reduction of 2,2′-Bipyridine by Quasi-Linear 3d-Metal(I) Silylamides—A Structural and Spectroscopic Study." Inorganics 7, no. 10 (2019): 117. http://dx.doi.org/10.3390/inorganics7100117.

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Quasi-linear anionic 3d-metal(I) silylamides are a new and promising class of molecules. Due to their highly negative reduction potential we wanted to test their capability to reduce substrates under coordination of their monoanionic radicaloid form. In a proof of principle study, we present the results of the reaction of metal(I) silylamides of chromium to cobalt with 2,2′-bipyridine (bipy), the redox non-innocence and reducibility of which was already established. In the course of these studies complexes of the type K{18-crown-6}[M(hmds)2(bipy)] (hmds = –N(SiMe3)2) were obtained. These compo
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40

Agarwala, Hemlata, Thomas Michael Scherer, Shaikh M. Mobin, Wolfgang Kaim та Goutam Kumar Lahiri. "Bidirectional non-innocence of the β-diketonato ligand 9-oxidophenalenone (L−) in [Ru([9]aneS3)(L)(dmso)]n, [9]aneS3 = 1,4,7-trithiacyclononane". Dalton Transactions 43, № 10 (2014): 3939. http://dx.doi.org/10.1039/c3dt53069h.

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41

Hazari, Arijit Singha, Alexa Paretzki, Jan Fiedler, Stanislav Zalis, Wolfgang Kaim та Goutam Kumar Lahiri. "Different manifestations of enhanced π-acceptor ligation at every redox level of [Os(9-OP)L2]n, n = 2+, +, 0, − (9-OP− = 9-oxidophenalenone and L = bpy or pap)". Dalton Transactions 45, № 45 (2016): 18241–51. http://dx.doi.org/10.1039/c6dt03764j.

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42

Berben, Louise A., Bas de Bruin, and Alan F. Heyduk. "Non-innocent ligands." Chemical Communications 51, no. 9 (2015): 1553–54. http://dx.doi.org/10.1039/c4cc90480j.

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43

Gondzik, S., D. Bläser, C. Wölper та S. Schulz. "Non-innocence of β-diketiminato ligands". Journal of Organometallic Chemistry 783 (травень 2015): 92–95. http://dx.doi.org/10.1016/j.jorganchem.2015.02.028.

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44

Braun, Jason D., Paul A. Gray, Baldeep K. Sidhu, Dion B. Nemez, and David E. Herbert. "Zn-Templated synthesis of substituted (2,6-diimine)pyridine proligands and evaluation of their iron complexes as anolytes for flow battery applications." Dalton Transactions 49, no. 45 (2020): 16175–83. http://dx.doi.org/10.1039/d0dt00543f.

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Zn<sup>2+</sup> templating enables synthesis of redox ‘non-innocent’ diimine pyridine ligands with strong electron-withdrawing groups, allowing construction of iron complexes with multiple ligand-based reductions for application in redox flow batteries.
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45

Simler, Thomas, Andreas A. Danopoulos, and Pierre Braunstein. "Non-symmetrical, potentially redox non-innocent imino NHC pyridine ‘pincers’ via a zinc ion template-assisted synthesis." Dalton Transactions 46, no. 18 (2017): 5955–64. http://dx.doi.org/10.1039/c7dt01014a.

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A Zn<sup>II</sup>-promoted modular synthesis allows access to new non-symmetrical, redox-active imino NHC pyridine pincer ligands. Radical anionic and dianionic redox states of the ligand are involved in its Fe<sup>II</sup> complexes obtained from FeBr<sub>2</sub>/KC<sub>8</sub>.
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46

Wan, Ho Chuen, Jing-Xuan Zhang, Chung Sum Leung, Fu Kit Sheong, and Zhenyang Lin. "Inter-ligand delocalisations in transition metal complexes containing multiple non-innocent ligands." Dalton Transactions 48, no. 39 (2019): 14801–7. http://dx.doi.org/10.1039/c9dt02806d.

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47

McQuarters, Ashley B., and Nicolai Lehnert. "{RuNO}6vs. co-ligand oxidation: two non-innocent groups in one ruthenium nitrosyl complex." Dalton Trans. 43, no. 37 (2014): 13835–38. http://dx.doi.org/10.1039/c4dt01388c.

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The one-electron oxidation of the {RuNO}<sup>6</sup> complex [Ru(L)(PPh<sub>3</sub>)(NO)(Cl)]<sup>2+</sup> (where L = 1-phenyl-1-(pyridin-2-yl)-2-(pyridin-2-ylmethylene)hydrazine) leads to the generation of a co-ligand radical. This complex therefore represents a rare example of a ruthenium complex with two different non-innocent ligands bound.
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48

Kaim, Wolfgang, Atanu Das, Jan Fiedler, Stanislav Záliš, and Biprajit Sarkar. "NO and NO2 as non-innocent ligands: A comparison." Coordination Chemistry Reviews 404 (February 2020): 213114. http://dx.doi.org/10.1016/j.ccr.2019.213114.

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49

Chuang, Yu-Chun, Chou-Fu Sheu, Gene-Hsiang Lee, Yu-Sheng Chen, and Yu Wang. "Charge density studies of 3dmetal (Ni/Cu) complexes with a non-innocent ligand." Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials 73, no. 4 (2017): 634–42. http://dx.doi.org/10.1107/s2052520617007119.

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High-resolution X-ray diffraction experiments and atom-specific X-ray absorption experiments are applied to investigate a series of square planar complexes with the non-innocent ligand of maleonitriledithiolate (mnt), [S2C2(CN)2]z−, containingM—S bonds. Four complexes of (PyH)z[M(mnt)2]z−, whereM= Ni or Cu,z= 2 or 1 and PyH+= C5NH6+, were studied in order to clarify whether such one-electron oxidation–reduction, [M(mnt)2]2−/[M(mnt)2]1−, is taking place at the metal or the ligand site. Combining the techniques of metalK-,L-edge and SK-edge X-ray absorption spectroscopy with high-resolution X-ra
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50

Khatua, Manas, Bappaditya Goswami, and Subhas Samanta. "Dehydrogenation of amines in aryl-amine functionalized pincer-like nitrogen-donor redox non-innocent ligands via ligand reduction on a Ni(ii) template." Dalton Transactions 49, no. 20 (2020): 6816–31. http://dx.doi.org/10.1039/d0dt00466a.

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