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1

Wagh, Shaila, and B. R. Patil. "Synthesis and Spectral Characterization of Some New Novel Schiff bases Derived from Hydroxy Propiophenone." Oriental Journal Of Chemistry 37, no. 3 (2021): 759–62. http://dx.doi.org/10.13005/ojc/370335.

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New Schiff bases derived by the condensation of methyl, chloro, and bromo substituted 2' hydroxy propiophenones with aliphatic and aromatic amines have been synthesized. The Schiff bases are yellow solids with sharp melting points. Schiff bases The spectral characterization of these newly synthesized Schiff base ligands has been done.These Schiff bases were characterized by IR spectroscopy, Nuclear magnetic resonance spectroscopy, UV spectroscopy, and Mass spectroscopy. IR spectra confirmed the presence of the phenolic OH group and azomethine group.
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2

Singh, Har Lal, and A. K. Varshney. "Synthetic, Structural, and Biochemical Studies of Organotin(IV) with Schiff Bases Having Nitrogen and Sulphur Donor Ligands." Bioinorganic Chemistry and Applications 2006 (2006): 1–7. http://dx.doi.org/10.1155/bca/2006/23245.

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Three bidentate Schiff bases having nitrogen and sulphur donor sequences were prepared by condensing S-benzyldithiocarbazate (NH2NHCS2CH2C6H5) with heterocyclic aldehydes. The reaction of diphenyltin dichloride with Schiff bases leads to the formation of a new series of organotin(IV) complexes. An attempt has been made to prove their structures on the basis of elemental analyses, conductance measurements, molecular weights determinations, UV, infrared, and multinuclear magnetic resonance (H1,C13, andS119n) spectral studies. Organotin(IV) complexes were five- and six-coordinate. Schiff bases an
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3

Singh, Kiran, Parvesh Puri, Yogender Kumar, Chetan Sharma, and Kamal Rai Aneja. "Biological and Spectral Studies of Newly Synthesized Triazole Schiff Bases and Their Si(IV), Sn(IV) Complexes." Bioinorganic Chemistry and Applications 2011 (2011): 1–10. http://dx.doi.org/10.1155/2011/654250.

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The Schiff bases HL1-3have been prepared by the reaction of 5-bromothiophene-2-carboxaldehyde with 4-amino-5-mercapto-3-methyl/propyl/isopropyl-s-triazole, respectively. Organosilicon(IV) and organotin(IV) complexes of formulae (CH3)2MCl(L1-3), (CH3)2M(L1-3)2were synthesized from the reaction of (CH3)2MCl2and the Schiff bases in 1 : 1 and 1 : 2 molar ratio, where and Sn. The synthesized Schiff bases and their metal complexes have been characterized with the aid of various physicochemical techniques like elemental analyses, molar conductance, UV, IR,1H,13C,29Si, and119Sn NMR spectroscopy. Based
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4

Howsaui, Hanan B., Amal S. Basaleh, Magda H. Abdellattif, Walid M. I. Hassan, and Mostafa A. Hussien. "Synthesis, Structural Investigations, Molecular Docking, and Anticancer Activity of Some Novel Schiff Bases and Their Uranyl Complexes." Biomolecules 11, no. 8 (2021): 1138. http://dx.doi.org/10.3390/biom11081138.

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Three novel 2-aminopyrazine Schiff bases derived from salicylaldehyde derivatives and their uranyl complexes were synthesized and characterized by elemental analysis, UV-vis, FTIR, molar conductance, and thermal gravimetric analysis (TGA). The proposed structures were optimized using density functional theory (DFT/B3LYP) and 6–311G ∗(d,p) basis sets. All uranyl complexes are soluble in DMSO and have low molar conductance, which indicates that all the complexes are nonelectrolytes. The DNA binding of those Schiff bases and their uranyl complexes was studied using UV-vis spectroscopy, and screen
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5

Mahon, Mary F., John McGinley, A. Denise Rooney, and John M. D. Walsh. "Calix[4]arene Schiff bases—potential ligands for fluorescent studies." Tetrahedron 64, no. 49 (2008): 11058–66. http://dx.doi.org/10.1016/j.tet.2008.09.091.

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6

Singh, Har Lal, Jangbhadur Singh, and A. Mukherjee. "Synthesis, Spectral, andIn VitroAntibacterial Studies of Organosilicon(IV) Complexes with Schiff Bases Derived from Amino Acids." Bioinorganic Chemistry and Applications 2013 (2013): 1–9. http://dx.doi.org/10.1155/2013/425832.

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The present work stems from our interest in the synthesis, characterization, and antibacterial evaluation of organosilicon(IV) complexes of a class of amino-acid-based Schiff base which have been prepared by the interaction of ethoxytrimethylsilane with the Schiff bases (N OH) in 1 : 1 molar ratio. These complexes have been characterized by elemental analysis, molar conductance, and spectroscopic studies including electronic IR and NMR (1H,13C, and29Si) spectroscopy. The analytical and spectral data suggest trigonal bipyramidal geometry around the silicon atom in the resulting complexes. The l
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7

Ahmed, Riyadh M., Enaam I. Yousif, and Mohamad J. Al-Jeboori. "Co(II) and Cd(II) Complexes Derived from Heterocyclic Schiff-Bases: Synthesis, Structural Characterisation, and Biological Activity." Scientific World Journal 2013 (2013): 1–6. http://dx.doi.org/10.1155/2013/754868.

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New monomeric cobalt and cadmium complexes with Schiff-bases, namely,N′-[(E)-(3-hydroxy-4-methoxyphenyl)methylidene]furan-2-carbohydrazide (L1) andN′-[(E)-(3-hydroxy-4-methoxyphenyl)methylidene]thiophene-2-carbohydrazide (L2) are reported. Schiff-base ligands L1and L2were derived from condensation of 3-hydroxy-4-methoxybenzaldehyde (iso-vanillin) with furan-2-carboxylic acid hydrazide and thiophene-2-carboxylic acid hydrazide, respectively. Complexes of the general formula [M(L)2]Cl2(where M = Co(II) or Cd(II), L = L1or L2) have been obtained from the reaction of the corresponding metal chlori
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8

Shunmugaperumal, Selvaraj, Saranya Dhasarathan, Kamatchi Selvaraj P, and Ilango Kaliappan. "Multi Metal Ion Recognizing Unsymmetrical tetra Dentate Schiff bases associated with Antifungal Activity." Oriental Journal Of Chemistry 37, no. 4 (2021): 833–46. http://dx.doi.org/10.13005/ojc/370410.

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New unsymmetrical Schiff bases containing azomethine moiety with simple aromatic section in one side and ferrocene fragment attached imine on the other side have beensynthesized. Advent of metal-to-ligand charge transfer band for the coordination of Cu2+ ions with receptors and appropriate changes in UV-Visible spectra for other metal ion combination with the sensor is reported. Observed extravagant ΔEpvalues suggest quasi-reversible process. The ΔIpa amount calculated from the anodic current Ipa value noticed for receptor solution and different metal ion added sensor solution discloses the co
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9

Sumrra, Sajjad Hussain, Muhammad Ibrahim, Sabahat Ambreen, Muhammad Imran, Muhammad Danish, and Fouzia Sultana Rehmani. "Synthesis, Spectral Characterization, and Biological Evaluation of Transition Metal Complexes of Bidentate N, O Donor Schiff Bases." Bioinorganic Chemistry and Applications 2014 (2014): 1–10. http://dx.doi.org/10.1155/2014/812924.

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New series of three bidentate N, O donor type Schiff bases(L1)–(L3)were prepared by using ethylene-1,2-diamine with 5-methyl furfural, 2-anisaldehyde, and 2-hydroxybenzaldehyde in an equimolar ratio. These ligands were further complexed with Co(II), Cu(II), Ni(II), and Zn(II) metals to produce their new metal complexes having an octahedral geometry. These compounds were characterized on the basis of their physical, spectral, and analytical data. Elemental analysis and spectral data of the uncomplexed ligands and their metal(II) complexes were found to be in good agreement with their structures
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10

Adeleke, Adesola A., Sizwe J. Zamisa, and Bernard Omondi. "Ag(I) Complexes of Imine Derivatives of Unexpected 2-Thiophenemethylamine Homo-Coupling and Bis-(E)-N-(furan-2-ylmethyl)-1-(quinolin-2-yl)methanimine." Molbank 2021, no. 2 (2021): M1235. http://dx.doi.org/10.3390/m1235.

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Imines are fundamental organic compounds used as synthetic intermediates and as ligands in coordination chemistry. They are also found to be important pharmacophores in various bioactive compounds. In this report, two Schiff bases were prepared using the traditional condensation of 4-pyridinecarboxaldehyde with 2-thiophenemethylamine and 2-quinolinecarboxaldehyde with furfurylamine to form (E)-1-(pyridin-4-yl)-N-(thiophen-2-ylmethyl)methanimine (L1) and (E)-N-(furan-2-ylmethyl)-1-(quinolin-2-yl)methanimine (L2) respectively. L1 and L2 were complexed with silver perchlorate in 2:1 [M:L] stoichi
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11

Halevas, Eleftherios, Antonios Hatzidimitriou, Barbara Mavroidi, Marina Sagnou, Maria Pelecanou, and Dimitris Matiadis. "Synthesis and Structural Characterization of (E)-4-[(2-Hydroxy-3-methoxybenzylidene)amino]butanoic Acid and Its Novel Cu(II) Complex." Molbank 2021, no. 1 (2021): M1179. http://dx.doi.org/10.3390/m1179.

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A novel Cu(II) complex based on the Schiff base obtained by the condensation of ortho-vanillin with gamma-aminobutyric acid was synthesized. The compounds are physico-chemically characterized by elemental analysis, HR-ESI-MS, FT-IR, and UV-Vis. The complex and the Schiff base ligand are further structurally identified by single crystal X-ray diffraction and 1H and 13C-NMR, respectively. The results suggest that the Schiff base are synthesized in excellent yield under mild reaction conditions in the presence of glacial acetic acid and the crystal structure of its Cu(II) complex reflects an one-
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12

Subitha, S., V. Gnana Glory Kanmoni, C. Isac Sobana Raj, J. Jona, and V. Vibi. "Synthesis, Characterization Study of Schiff Base Complexes Derived from Ampicillin and 4 Hydroxy3-Methoxy Benzaldehyde." Oriental Journal Of Chemistry 37, no. 4 (2021): 813–18. http://dx.doi.org/10.13005/ojc/370407.

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Ampicillin is a derived form of pencillin which is emi synthetic -lactum antibiotic used to treat bladder infections, pneumonia, respiratory infection. schiff’s bases are the most widely studied chelating ligands in coordination chemistry. Recently metal complexes of schiff bases particularly derived from carbonyl compounds base on hetero-cyclic rings have been the centre of attraction in many areas. Present paper brief the synthesis of AHMBL and its transition metal (II) complexes and also the coordination / characterization studies such as magnetic susceptibility, molar conductance, Electr
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13

Break, Mohammed Khaled bin, M. Ibrahim M. Tahir, Karen A. Crouse та Teng-Jin Khoo. "Synthesis, Characterization, and Bioactivity of Schiff Bases and TheirCd2+,Zn2+,Cu2+, andNi2+Complexes Derived from Chloroacetophenone Isomers with S-Benzyldithiocarbazate and the X-Ray Crystal Structure of S-Benzyl-β-N-(4-chlorophenyl)methylenedithiocarbazate". Bioinorganic Chemistry and Applications 2013 (2013): 1–13. http://dx.doi.org/10.1155/2013/362513.

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Two bidentate Schiff base ligands having nitrogen sulphur donor sequence were derived from the condensation of S-benzyldithiocarbazate (SBDTC) with 2-chloroacetophenone and 4-chloroacetophenone to give S-benzyl-β-N-(2-chlorophenyl)methylenedithiocarbazate (NS2) and S-benzyl-β-N-(4-chlorophenyl)methylenedithiocarbazate (NS4) isomers. Each of the ligands was then chelated with Cd2+, Zn2+, Cu2+, and Ni2+. The compounds were characterized via IR spectroscopy and melting point while the structure of NS4 was revealed via X-ray crystallography. Finally, the compounds were screened for antimicrobial a
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14

Abdulghani, Ahlam Jameel, and Asmaa Mohammed Noori Khaleel. "Preparation and Characterization of Di-, Tri-, and Tetranuclear Schiff Base Complexes Derived from Diamines and 3,4-Dihydroxybenzaldehyde." Bioinorganic Chemistry and Applications 2013 (2013): 1–14. http://dx.doi.org/10.1155/2013/219356.

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A series of new di-, tri-, and tetranuclear Co(II) and Cu(II) complexes of three new diSchiff base ligands were synthesized by two different methods. The first method involved the synthesis of the three ligands from condensation reaction of 3,4-dihydroxybenzaldehyde (L′H2) with ethylenediamine (en), o-phenylenediamine (o-PD), or 4,5-dimethyl-1,2-phenylendiamine (DMPD) in a mole ratio of 2 : 1 followed by the reaction of the resulting Schiff bases ligands with Cu(II) or Co(II) ions in the presence of 2,2′-bipyridyl (L) to form the di- and trinuclear metal complexes. The second method involved t
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15

Vishwkarma, Arti, A. K. Srivastava, Om P. Pandey, and Soumitra K. Sen Gupta. "Macrocycliczinc(II) Complexes with Tetradentate N2O2 Donor Schiff Base Ligands Incorporating 1,3,4-Thiadiazole Ring." Oriental Journal of Chemistry 36, no. 6 (2020): 1148–53. http://dx.doi.org/10.13005/ojc/360619.

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A new series ofdiazadioxamacrocycliczinc(II) derivatives [{Zn(M)(H2O)2}(OAc)2] (M= macrocyclic ligands) prepared via template synthesis method, by the reaction of Schiff bases derived from bis-(2-hydrazino-1,3,4-thiadiazole-5-yl)arene/alkanes and 3,5-dichlorosalicyldehyde/2-hydroxy-1-naphthaldehyde with 1,4-dibromobutane in the presence of Zn(II) ion. The structures of all these complexes were established on the basis of elemental analyses, spectral data (IR and 1H-NMR), PXRD, SEM techniques. Presence of coordinated water molecules in the Zn(II) complexes were confirmed by TGA analyses. The an
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16

Shieh, C. H., B. L. Karger, L. R. Gelber, and B. Feibush. "Ligand exchange chromatography of amino alcohol enantiomers as Schiff bases." Journal of Chromatography A 406 (October 1987): 343–52. http://dx.doi.org/10.1016/s0021-9673(00)94041-x.

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17

Srivastava, A. K., O. P. Pandey, and S. K. Sengupta. "Synthesis, Spectral and Antimicrobial Studies of Bis(cyclopentadienyl)titanium(IV) Derivatives with Schiff Bases Derived from 2-Amino-5-phenyl-1,3,4-thiadiazole." Bioinorganic Chemistry and Applications 3, no. 3-4 (2005): 289–97. http://dx.doi.org/10.1155/bca.2005.289.

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The reactions of bis(cyclopentadienyl)titanium(IV) dichloride with Schiff bases derived by condensing 2- amino-5-phenyl-1,3,4-thiadiazole with benzaldehyde (SPT), 4-nitrobenzaldehyde (SNT), 4-methoxybenzaldehyde (SMT), 2-hydroxybenzaldehyde (SSTH) or 2-hydroxyacetophenone (SATH) have been studied in refluxing tetrahydrofuran and complexes of types [Cp2TiCl(SB)]Cl (SB= SPT, SNT or SMT) and [Cp2Ti(SB')]Cl (SB'H= SSTH or SATH) have been isolated. Tentative structural conclusions are drawn for these reaction products based upon elemental analyses, electrical conductance, magnetic moment and spectr
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18

Ejidike, Ikechukwu P., and Peter A. Ajibade. "Synthesis, Characterization, Anticancer, and Antioxidant Studies of Ru(III) Complexes of Monobasic Tridentate Schiff Bases." Bioinorganic Chemistry and Applications 2016 (2016): 1–11. http://dx.doi.org/10.1155/2016/9672451.

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Mononuclear Ru(III) complexes of the type [Ru(LL)Cl2(H2O)] (LL = monobasic tridentate Schiff base anion: (1Z)-N′-(2-{(E)-[1-(2,4-dihydroxyphenyl)ethylidene]amino}ethyl)-N-phenylethanimidamide [DAE], 4-[(1E)-N-{2-[(Z)-(4-hydroxy-3-methoxybenzylidene)amino]ethyl}ethanimidoyl]benzene-1,3-diol [HME], 4-[(1E)-N-{2-[(Z)-(3,4-dimethoxybenzylidene)amino]ethyl}ethanimidoyl]benzene-1,3-diol [MBE], andN-(2-{(E)-[1-(2,4-dihydroxyphenyl)ethylidene]amino}ethyl)benzenecarboximidoyl chloride [DEE]) were synthesized and characterized using the microanalytical, conductivity measurements, electronic spectra, and
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19

Al-Riyahee, Ali A. A., Hanaa H. Hadadd, and Baydaa H. Jaaz. "Novel Nickel (II), Copper (II) and Cobalt (II) Complexes of Schiff Bases A, D and E: Preparation, Identification, Analytical and Electrochemical Survey." Oriental Journal of Chemistry 34, no. 6 (2018): 2927–41. http://dx.doi.org/10.13005/ojc/340632.

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A novel set of Cobalt(II), Copper(II) and Nickel(II) complexes of ligands, (E)-2-(((2,5-difluorophenyl)imino) methyl)phenol (A), (E)-2,4-dibromo-1-((2-hydroxybenzylidene) amino)anthracene-9,10-dione (D) & (Z)-1-((1-([1,1'-biphenyl]-4-yl)-2-bromoethylidene) amino)-2,4-dibromo anthracene-9,10-dione (E) were synthesized and characterized. Their structures were investigated on the basis of CHN, conductance measurements and spectral studies (H1-NMR & C13-NMR,FT-infrared and Electronic spectroscopies), cyclic voltammetry. It has observed from spectral and analytical studies that metal comple
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20

Kavitha, Palakuri, and K. Laxma Reddy. "Synthesis, Structural Characterization, and Biological Activity Studies of Ni(II) and Zn(II) Complexes." Bioinorganic Chemistry and Applications 2014 (2014): 1–13. http://dx.doi.org/10.1155/2014/568741.

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Ni(II) and Zn(II) complexes were synthesized from tridentate 3-formyl chromone Schiff bases such as 3-((2-hydroxyphenylimino)methyl)-4H-chromen-4-one (HL1), 2-((4-oxo-4H-chromen-3-yl)methylneamino)benzoic acid (HL2), 3-((3-hydroxypyridin-2-ylimino)methyl)-4H-chromen-4-one (HL3), and 3-((2-mercaptophenylimino)methyl)-4H-chromen-4-one (HL4). All the complexes were characterized in the light of elemental analysis, molar conductance, FTIR, UV-VIS, magnetic, thermal, powder XRD, and SEM studies. The conductance and spectroscopic data suggested that, the ligands act as neutral and monobasic tridenta
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21

Singh, Narinder, Maninder Singh Hundal, Geeta Hundal, and Martin Martinez-Ripoll. "Zinc templated synthesis—a route to get metal ion free tripodal ligands and lariat coronands, containing Schiff bases." Tetrahedron 61, no. 32 (2005): 7796–806. http://dx.doi.org/10.1016/j.tet.2005.05.052.

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22

Feng, Zhi-Qiang, Xiao-Li Yang, and Yuan-Feng Ye. "Pd(II) and Zn(II) Based Complexes with Schiff Base Ligands: Synthesis, Characterization, Luminescence, and Antibacterial and Catalytic Activities." Scientific World Journal 2013 (2013): 1–9. http://dx.doi.org/10.1155/2013/956840.

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Two new metal complexes involving Schiff base ligands, namely, [Pd(L1)2] (1) and [Zn(L2)2] (2), [HL1: 2,4-dibromo-6-((E)-(mesitylimino)methyl)phenol andHL2: 2-((E)-(2,6-diisopropylphenylimino)methyl)-4,6-dibromophenol], have been solvothermally synthesized and characterized by elemental analysis, IR-spectroscopy, thermogravimetric analysis, powder X-ray diffraction, and single-crystal X-ray diffraction. Both1and2are mononuclear cyclometalated complexes with square planar and tetrahedral coordination geometry, respectively.1and2display photoluminescence in the solid state at 298 K (fluorescence
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23

Andrez, Julie, Valentin Guidal, Rosario Scopelliti, Jacques Pécaut, Serge Gambarelli, and Marinella Mazzanti. "Ligand and Metal Based Multielectron Redox Chemistry of Cobalt Supported by Tetradentate Schiff Bases." Journal of the American Chemical Society 139, no. 25 (2017): 8628–38. http://dx.doi.org/10.1021/jacs.7b03604.

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24

Agarwal, Ram K., Lakshman Singh, and Deepak Kumar Sharma. "Synthesis, Spectral, and Biological Properties of Copper(II) Complexes of Thiosemicarbazones of Schiff Bases Derived from 4-Aminoantipyrine and Aromatic Aldehydes." Bioinorganic Chemistry and Applications 2006 (2006): 1–10. http://dx.doi.org/10.1155/bca/2006/59509.

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We have synthesized a novel series of Schiff bases by condensation of 4-aminoantipyrine and various aromatic aldehydes followed by reaction with thiosemicarbazide. These thiosemicarbazones are potential ligands toward transition metal ions. The reaction of copper(II) salts with 4[N-(benzalidene)amino]antipyrinethiosemicarbazone (BAAPTS), 4[N-(4′-methoxybenzalidene) amino] antipyrinethiosemicarbozone (MBAAPTS), 4[N-(4′-dimethylamino benzalidene) amino] antipyrinethiosemicarbazone (DABAAPTS), and 4[N-(cinnamalidene) amino] antipyrinethiosemicarbazone (CAAPTS) resulted in the formation of solid c
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25

Mukherjee, Anuradha, and Amitabha Sarkar. "New pyrazole-tethered Schiffs bases as ligands for the Suzuki reaction." Tetrahedron Letters 46, no. 1 (2005): 15–18. http://dx.doi.org/10.1016/j.tetlet.2004.11.051.

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26

Magd-El-Din, Asmaa A., Hanan A. Mousa, Ammar A. Labib, et al. "Benzimidazole – Schiff bases and their complexes: synthesis, anticancer activity and molecular modeling as Aurora kinase inhibitor." Zeitschrift für Naturforschung C 73, no. 11-12 (2018): 465–78. http://dx.doi.org/10.1515/znc-2018-0010.

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Abstract A new series of Schiff bases containing benzіmidazole moiety 11–17 were synthesized by the reaction of 4-(1H-benzо[d]іmіdazоl-2-yl)anіline (1) with different aromatic aldehydes (4–10) via conventional heating and microwave irradiation methods. The structures of the novel Schiff bases were characterized by using different spectral data. Also, metal complexes 18–21 of compound 13 were synthesized, and their structure was confirmed by spectral measurements (IR, NMR, UV), molar conductivity, magnetic susceptibility and thermo-gravimetric analysis. The novel synthesized ligand 13 and its c
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27

Gaur, Shweta, Nighat Fahmi, and R. V. Singh. "Coordination Behavior of Unsymmetrical Ligand Complexes of Diorganotin and Diorganosilicon Derived From Schiff Bases." Phosphorus, Sulfur, and Silicon and the Related Elements 182, no. 4 (2007): 853–62. http://dx.doi.org/10.1080/10426500601087384.

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28

Aragón-Muriel, Alberto, Yamil Liscano, Yulieth Upegui, et al. "In Vitro Evaluation of the Potential Pharmacological Activity and Molecular Targets of New Benzimidazole-Based Schiff Base Metal Complexes." Antibiotics 10, no. 6 (2021): 728. http://dx.doi.org/10.3390/antibiotics10060728.

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Metal-based drugs, including lanthanide complexes, have been extremely effective in clinical treatments against various diseases and have raised major interest in recent decades. Hence, in this work, a series of lanthanum (III) and cerium (III) complexes, including Schiff base ligands derived from (1H-benzimidazol-2-yl)aniline, salicylaldehyde, and 2,4-dihydroxybenzaldehyde were synthesized and characterized using different spectroscopic methods. Besides their cytotoxic activities, they were examined in human U-937 cells, primate kidney non-cancerous COS-7, and six other, different human tumor
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29

Yılmaz Obalı, Aslıhan, and Ahmed Nuri Kurşunlu. "Lanthanide bindings of phenanthroimidazole-based clicked cage-ligands; designed by schiff base condensation." Journal of Luminescence 228 (December 2020): 117614. http://dx.doi.org/10.1016/j.jlumin.2020.117614.

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30

Luck, Rudy L., Travis A. Olds та Matthias Zeller. "Bis{μ-2,2′-[(butane-2,3-diylidene)bis(azanylylidene)]dibenzenethiolato}dizinc(II)–dimethyl sulfoxide–methanol (2/0.18/0.82)". Acta Crystallographica Section C Crystal Structure Communications 69, № 10 (2013): 1116–19. http://dx.doi.org/10.1107/s0108270113023524.

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The asymmetric unit in the crystal structure of the title compound, [Zn2(C16H14N2S2)2]2·0.18C2H6OS·0.82CH3OH, consists of two ordered bis{μ-2,2′-[(butane-2,3-diylidene)bis(azanylylidene)]dibenzenethiolato}dizinc(II) molecules and a disordered solvent combination at the same location which refined to 18.1 (7)% dimethyl sulfoxide and 81.9 (7)% methanol. The compound has a metallic cluster structure formed by the joining together of two zinc(II) complex molecules, forming a rhomboidal Zn2S2arrangement. This complex was previously suggested on the basis of nonstructural evidence to be a monomer [J
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31

Singh, H. L. "Synthesis, Spectral, and 3D Molecular Modeling of Tin(II) and Organotin(IV) Complexes of Biologically Active Schiff Bases Having Nitrogen and Sulfur Donor Ligands." Phosphorus, Sulfur, and Silicon and the Related Elements 184, no. 7 (2009): 1768–78. http://dx.doi.org/10.1080/10426500802340236.

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32

Liu, Xiao-Hua, M. Nurul Abser, and Duncan W. Bruce. "Synthesis and characterisation of rod-like metallomesogens of Mn(I) based on Schiff base ligands." Journal of Organometallic Chemistry 551, no. 1-2 (1998): 271–80. http://dx.doi.org/10.1016/s0022-328x(97)00437-3.

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33

Hu, Kun, Chensi Liu, Jingui Li, and Fupei Liang. "Copper(ii) complexes based on quinoline-derived Schiff-base ligands: synthesis, characterization, HSA/DNA binding ability, and anticancer activity." MedChemComm 9, no. 10 (2018): 1663–72. http://dx.doi.org/10.1039/c8md00223a.

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Three Cu(ii) complexes (C1–C3) were designed and synthesized.C3, in particular, having a ligand derived from benzocaine, exhibited greater selectivity toward HeLa cells, arrested cell cycles, and promoted tumor cell apoptosis.
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Xu, Li-Qing, Li-Ping Lu, and Miao-Li Zhu. "Analogy to a Chinese knot in an ion-pair copper(II)–neodymium(III) complex based on a hexadentate Schiff base condensation product of 5-bromosalicylaldehyde and glycylglycine." Acta Crystallographica Section C Crystal Structure Communications 69, no. 4 (2013): 376–79. http://dx.doi.org/10.1107/s0108270113006367.

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Self-assembly of CuCl2, NdCl3, 5-bromosalicylaldehyde and glycylglycine yields the ion-pair copper(II)–neodymium(III) complex, poly[[decaaquabis[μ3-2-({2-[(5-bromo-2-oxidobenzylidene)amino]acetyl}azanidyl)acetato]bis[μ2-2-({2-[(5-bromo-2-oxidobenzylidene)amino]acetyl}azanidyl)acetato]tetracopper(II)dineodymium(III)] bis{[2-({2-[(5-bromo-2-oxidobenzylidene)amino]acetyl}azanidyl)acetato]cuprate(II)} tetradecahydrate], {[Cu4Nd2(C11H8BrN2O4)4(H2O)10][Cu(C11H8BrN2O4)]2·14H2O}n. The anion is planar and mononuclear, showing an approximately square-planar coordination of the metal atom, while the cati
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Böhm, Andreas, Karlheinz Sünkel, Kurt Polborn та Wolfgang Beck. "Metal complexes of biologically important ligands, XCVII. Synthesis and characterisation of cyclometallated compounds of Schiff bases from α-amino acid esters with manganese (I) and rhenium (I) carbonyls". Journal of Organometallic Chemistry 552, № 1-2 (1998): 237–46. http://dx.doi.org/10.1016/s0022-328x(97)00579-2.

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Nagalakshmi, Veerasamy, Munusamy Sathya, Muniyappan Premkumar, Dhananjayan Kaleeswaran, Galmari Venkatachalam, and Kasturi Balasubramani. "Palladium(II) complexes comprising naphthylamine and biphenylamine based Schiff base ligands: Synthesis, structure and catalytic activity in Suzuki coupling reactions." Journal of Organometallic Chemistry 914 (May 2020): 121220. http://dx.doi.org/10.1016/j.jorganchem.2020.121220.

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Sen, Pinar, Lekhetho S. Mpeta, John Mack, and Tebello Nyokong. "New difluoroboron complexes based on N,O-chelated Schiff base ligands: Synthesis, characterization, DFT calculations and photophysical and electrochemical properties." Journal of Luminescence 224 (August 2020): 117262. http://dx.doi.org/10.1016/j.jlumin.2020.117262.

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Abu-Khadra, Ahmad S., Ahmed S. Afify, Amr Mohamed, Rabie S. Farag, and Hassan Y. Aboul-Enein. "Preparation, Characterization and Antimicrobial Activity of Schiff Base of (E) - N - (4-(Thiophen-2-ylmethyleneamino) Phenylsulfonyl) Acetamide Metal Complexes." Open Bioactive Compounds Journal 6, no. 1 (2018): 1–10. http://dx.doi.org/10.2174/1874847301806010001.

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Aim:Metal complexes of (E)-N-(4-(thiophen-2-ylmethyleneamino) phenylsulfonyl) acetamide (S.TH) Schiff bases derived from sulfacetamide (N-[4-(amino-phenyl) sulfonil] acetamide) and 2-thiophenecarboxaldehyde were synthesized and characterized.Methods and Results:The synthesized compositions have been characterized using different physico-chemical techniques. The investigation included elemental analysis, melting point measurements, proton NMR, UV spectroscopy, FT-IR, magnetic susceptibility, conductance measurements, mass spectral analysis, and inductively coupled plasma mass spectrometry (ICP-
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Nagalakshmi, Veerasamy, Raja Nandhini, Veerappan Brindha, Bellie Sundaram Krishnamoorthy, and Kasthuri Balasubramani. "Half-sandwich ruthenium(II) complexes containing biphenylamine based Schiff base ligands: Synthesis, structure and catalytic activity in amidation of various aldehydes." Journal of Organometallic Chemistry 912 (April 2020): 121175. http://dx.doi.org/10.1016/j.jorganchem.2020.121175.

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Ramírez, Paola, Raúl Contreras, Mauricio Valderrama та Daphne Boys. "Synthesis and reactivity of new trimethylplatinum(IV) complexes containing chiral Schiff bases as ligands: Crystal structure of (OC-6-44-C)-[PtIMe3{κ2-(R)-Ph2P(C6H4)CHNC*H(Ph)Me-P,N}]". Journal of Organometallic Chemistry 691, № 3 (2006): 491–98. http://dx.doi.org/10.1016/j.jorganchem.2005.08.053.

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Rouco, Lara, Ana M. González-Noya, Rosa Pedrido, and Marcelino Maneiro. "Pursuing the Elixir of Life: In Vivo Antioxidative Effects of Manganosalen Complexes." Antioxidants 9, no. 8 (2020): 727. http://dx.doi.org/10.3390/antiox9080727.

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Manganosalen complexes are coordination compounds that possess a chelating salen-type ligand, a class of bis-Schiff bases obtained by condensation of salicylaldehyde and a diamine. They may act as catalytic antioxidants mimicking both the structure and the reactivity of the native antioxidant enzymes active site. Thus, manganosalen complexes have been shown to exhibit superoxide dismutase, catalase, and glutathione peroxidase activities, and they could potentially facilitate the scavenging of excess reactive oxygen species (ROS), thereby restoring the redox balance in damaged cells and organs.
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42

Sreenivas, V., G. Srikanth, Ch Vinutha, M. Shailaja, P. Muralidhar Reddy, and Ravinder Vadde. "Synthesis, Spectral Characterization and Antimicrobial Studies of Co(II) Complexes with Tetradentate Schiff bases Derived from Ortho-Phthalaldehyde." JOURNAL OF ADVANCES IN CHEMISTRY 9, no. 1 (2016): 1873–82. http://dx.doi.org/10.24297/jac.v9i1.2852.

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A series of cobalt (II) complexes have been synthesized with Schiff bases derived from ortho-phthalaldehyde and various amines in aqueous methanol solution. The newly synthesized Schiff bases and their Co (II) complexes have been characterized by elemental analysis, magnetic susceptibility, thermal, conductance measurements, mass, IR, electronic, 1H,13C-NMR spectral techniques. These ligands act as tetradentate species and coordinate to the metal center through the different potential donor atoms such as N, O and S. The probable octahedral structures have been assigned to these complexes. All
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Gangani, Bhavesh J., and Parsotam H. Parsania. "Microwave Irradiated and Conventional Syntheses of Halogenated Symmetric Double Schiff Bases, their Spectral and Microbial Study." International Letters of Chemistry, Physics and Astronomy 57 (August 2015): 36–44. http://dx.doi.org/10.18052/www.scipress.com/ilcpa.57.36.

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The aim of the present work was to discover various synthetic route of biological active halogenated symmetric double Schiff bases of 1,1’-bis (4-aminophenyl) cyclohexane, their spectral and microbial study. Symmetric double Schiff base ligands of halogenated benzaldehyde and 1,1’-bis (4-aminophenyl) cyclohexane were synthesized by conventional and green chemistry approach. The purity of Schiff bases was checked by Thin Layer Chromatography (TLC). The structures of these ligands were elucidated by UV, FTIR, 1HNMR and MS; and assayed for their antibacterial activity against Escherichia coli (E.
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Ejidike, Ikechukwu P., and Peter A. Ajibade. "Transition metal complexes of symmetrical and asymmetrical Schiff bases as antibacterial, antifungal, antioxidant, and anticancer agents: progress and prospects." Reviews in Inorganic Chemistry 35, no. 4 (2015): 191–224. http://dx.doi.org/10.1515/revic-2015-0007.

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AbstractThe huge research on Schiff base coordination complexes in the past few decades has given rise to several new molecules that have been of biological importance. The ease with which the Schiff base ligands are designed and prepared and their pattern is elucidated have made them to be referred to as “fortunate ligands” possessing azomethine derivatives, the C=N linkage that is essential for biological activity, including antibacterial, antifungal, antioxidant, anticancer, and diuretic activities. A variety of Schiff base and its complexes have been studied as model molecules for biologic
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Costamagna, J., N. P. Barroso, B. Matsuhiro, and M. Villagrán. "Copper(II) complexes with aminosugar derived Schiff bases as ligands." Inorganica Chimica Acta 273, no. 1-2 (1998): 191–95. http://dx.doi.org/10.1016/s0020-1693(97)06075-1.

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46

Isyaku, S., H. N. Aliyu, E. C. Ozoro, and T. Abubakar. "Synthesis, characterization and antimicrobial studies of Mn(II) complexes of acetylthiophene and acetyl Furan Schiff base derivatives." Bayero Journal of Pure and Applied Sciences 12, no. 1 (2020): 85–92. http://dx.doi.org/10.4314/bajopas.v12i1.15s.

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Manganese (II) complexes of Schiff bases; 2-acetylthiophene 4‑phenylthiosemi-carbazone (AT-PTSC) and 2-furylmethylketone-4-phenylthiosemi-carbazone (AF‑PTSC) derived from condensation of 2-acetylthiophene and 2-furylmethylketone (2-acetylfuran) each with 4-phenylthiosemicarbazide in (1:1 molar ratio) ethanol, have been synthesized. The Schiff bases and the Mn(II) complexes were characterized on the basis of melting point/decomposition temperature, solubility, magnetic susceptibility, infrared spectra, molar conductance measurements, elemental and gravimetric analyses. The Mn(II) complexes show
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47

Isyaku, S., H. N. Aliyu, E. C. Ozoro, and T. Abubakar. "Synthesis, characterization and antimicrobial studies of Mn(II) complexes of acetylthiophene and acetyl furan Schiff base derivatives." Bayero Journal of Pure and Applied Sciences 12, no. 1 (2020): 251–58. http://dx.doi.org/10.4314/bajopas.v12i1.39s.

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Manganese(II) complexes of Schiff bases; 2-acetylthiophene-4‑phenylthiosemi-carbazone (AT-PTSC) and 2-furylmethylketone-4-phenylthiosemi-carbazone (AF‑PTSC) derived from condensation of 2-acetylthiophene and 2-furylmethylketone (2-acetylfuran) each with 4-phenylthiosemicarbazide in (1:1 molar ratio) ethanol, have been synthesized. The Schiff bases and the Mn(II) complexes were characterized on the basis of melting point/decomposition temperature, solubility, magnetic susceptibility, infrared spectra, molar conductance measurements, elemental and gravimetric analyses. The Mn(II) complexes show
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48

Journal, Baghdad Science. "Synthesis and Characterization of Novel Methyl 2-(1,7,7-Tri methylbicyclo[2.2.1]hept-2-yieldene)hydrazinecarbodithioate Schiff Bases Derived From Methylhydrazine carbodithioate And Their Bi(III) And Ag(II) Complexes." Baghdad Science Journal 10, no. 3 (2013): 607–17. http://dx.doi.org/10.21123/bsj.10.3.607-617.

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Novel bidentate Schiff bases having nitrogen-sulphur donor sequence was synthesized from condensation of racemate camphor, (R)-camphor and (S)-camphor with Methyl hydrazinecarbodithioate (SMDTC). Its metal complexes were also prepared through the reaction of these ligands with silver and bismuth salts. All complexes were characterized by elemental analyses and various physico-chemical techniques. These Schiff bases behaved as uninegatively charged bidentate ligands and coordinated to the metal ions via ?-nitrogen and thiolate sulphur atoms. The NS Schiff bases formed complexes of general formu
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Divya, Kumble, Geetha M. Pinto, and Asha F. Pinto. "APPLICATION OF METAL COMPLEXES OF SCHIFF BASES AS AN ANTIMICROBIAL DRUG: A REVIEW OF RECENT WORKS." International Journal of Current Pharmaceutical Research 9, no. 3 (2017): 27. http://dx.doi.org/10.22159/ijcpr.2017.v9i3.19966.

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Schiff bases are versatile ligands which are synthesized from the condensation of primary amines with carbonyl groups. Synthesis of Schiff base transition metal complexes by using Schiff base as ligands appears to be fascinating in view of the possibility of obtaining coordination compounds of unusual structure and stability. These transition metal complexes have received exceptional consideration because of their active part in metalloenzymes and as biomimetic model compounds due to their closeness to natural proteins and enzymes. These compounds are very important in pharmaceutical fields be
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Coles, Simon J., Michael B. Hursthouse, David G. Kelly, Andrew J. Toner, and Neil M. Walker. "Schiff base insertion in titanium alkyls; reduction of imine functions by benzyl addition." Canadian Journal of Chemistry 77, no. 12 (1999): 2095–98. http://dx.doi.org/10.1139/v99-205.

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TiBz4 reacts with N-2-fluorenyl(salicylideneimine) to afford a crystallographically characterized titanium(IV) complex containing two conventional bidentate Schiff base ligands and two O-bound ligands in which the imine function has been reduced by the addition of benzyl and hydrogen moieties.Key words: insertion, nucleophilic additions, Schiff bases, titanium
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